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    • 3. 发明授权
    • Needle-like crystals of polyoxymethylene and method for manufacture
thereof
    • 聚甲醛的针状晶体及其制造方法
    • US4026873A
    • 1977-05-31
    • US641762
    • 1975-12-17
    • Masatoshi Iguchi
    • Masatoshi Iguchi
    • C08G2/10C07D323/06
    • C08G2/10
    • Needle-like single-crystals of polyoxymethylene are obtained directly from a monomer, trioxane, in the course of polymerization in solution. The method for obtaining the crystals comprises preparing an anhydrous, dilute solution of trioxane in non-polar solvents, adding thereto a specified amount of boron trifluoride or its ether complex derivatives as catalyst and subsequently adding a small specified amount of water as co-catalyst, and maintaining the mixture unstirred at a fixed temperature.The needle-like crystals, measuring 5 to 100 microns long and 1 to 3 microns across, are single crystals having a hexagonal cross-section and constituted of molecular chains extended and aligned in the direction of length with full three dimensional regularity. This single-crystal is believed to be the first example of a `polymer whisker`.
    • 在溶液中聚合过程中,直接从单体三恶烷中获得针状聚甲醛单晶。 获得结晶的方法包括在非极性溶剂中制备无水稀释的三恶烷溶液,加入规定量的三氟化硼或其醚络合物衍生物作为催化剂,随后加入少量的作为助催化剂的水, 并将混合物保持在固定的温度下。