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    • 4. 发明授权
    • Alkoxy endblocked polydiorganosiloxane and room temperature vulcanizable
silicone elastomers made therefrom
    • 烷氧基封端的聚二有机硅氧烷和室温可硫化的硅氧烷弹性体
    • US5276123A
    • 1994-01-04
    • US940158
    • 1992-09-03
    • Russell K. KingChi-long Lee
    • Russell K. KingChi-long Lee
    • C08G77/388C07F7/10C07F7/18C08G77/26C08G77/38C08G77/54C08K5/549C08L83/04C08L83/08C08L83/14C09K3/10C08G77/04
    • C08K5/549C07F7/10C07F7/1836C08G77/26C08G77/54C08L83/08C08L83/14
    • An alkoxy endblocked polydiorgansiloxane of the formulaZ--(SiR.sub.2 O).sub.n SiR.sub.2 --Zwhere Z is ##STR1## where Y isR.sub.a (R'O).sub.(3-a) Si--,X is ##STR2## in which a is 0 or 1, d has a value of 1 to 3 inclusive, v is 0 or 1, n.ltoreq.8, p has a value of 3 to 6 inclusive, q has a value of 2 to 6 inclusive, r has a value of 4 to 6 inclusive, w is 0 or 1, Me is methyl, R.sup.1 is an alkyl radical having from 1 to 6 inclusive carbon atoms, each R is a monovalent radical independently selected from the group consisting of hydrocarbon radicals and halogenated hydrocarbon radicals, R' is an alkyl radical of 1 to 3 inclusive carbon atoms, R" is a divalent hydrocarbon radical selected from the group consisting of --(CH.sub.2).sub.b -- and --CH(Me)(CH.sub.2).sub.c --, b is from 2 to 6 inclusive, c is from 0 to 4 inclusive, the bond at ** is attached to the silicon atom Si*, can be used as the base polymer for making one package room temperature vulcanizable silicone elastomer compositions by combining it with alkoxysilane, titanium catalyst and filler. These RTV's cure rapidly and exhibit adhesion to substrates upon which they are cure.
    • 其中Z为(*化学结构*)(组I)或(*化学结构*)(组II)的式Z-(SiR 2 O)n SiR 2-Z的烷氧基封端的聚二恶烷硅氧烷,其中Y为Ra(R'O) -a)Si-,X是(*化学结构*)(*化学结构*)(*化学结构*)(*化学结构*)(*化学结构*)其中a是0或1,d具有值 1〜3,v为0或1,n <8,p为3〜6,p为2〜6,r为4〜6,w为0 或1,Me是甲基,R 1是具有1-6个碳原子的烷基,每个R是独立地选自烃基和卤代烃基的一价基团,R'是1至 3的碳原子,R“是选自 - (CH 2)b - 和-CH(Me)(CH 2)c - 的二价烃基,b为2-6以下,c为0〜4 包括,**处的键连接到硅原子Si *上, 可以用作通过与烷氧基硅烷,钛催化剂和填料组合来制备一包装室温可硫化硅橡胶组合物的基础聚合物。 这些RTV快速固化,并显示出与它们固化的基材的粘合性。