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1. 发明授权

US4786698A Polymerization of chloroprene 失效
标题翻译：氯丁二烯的聚合
公开(公告)号：US4786698A
公开(公告)日：1988-11-22
申请号：US132975
申请日：1987-12-15
申请人： Rudiger Musch , Eberhard Muller , Peter Wendling , Wolfgang Konter , Gerhard Hohmann
发明人： Rudiger Musch , Eberhard Muller , Peter Wendling , Wolfgang Konter , Gerhard Hohmann
IPC分类号： C08F2/22 , C08F2/24 , C08F2/26 , C08F2/38 , C08F4/30 , C08F4/40 , C08F36/18
CPC分类号： C08F36/18
摘要： Gel-free polychloroprene is obtained, at high monomer conversions, using a polymerization initiator comprising sodium dithionite or a mixture of sodium dithionite with formamidinesulphinic acid or with potassium peroxydisulphate or with formamidinesulphinic acid and potassium peroxodisulphate or with potassium peroxodisulphate and sodium anthraquinon-.beta.-sulphonate or with formamidinesulphinic acid and potassium peroxodisulphate and sodium anthraquinone-.beta.-sulphonate, and in the presence of oxygen and a chain transfer agent when 30 to 90% of the initiator is present at the commencement of polymerization and the remainder is added in portions during the polymerization, only further sodium dithionite being added at a conversion >60% in the case of an initiator combination, and when 20 to 80% by weight of the total amount of chain transfer agents is present before or at the commencement of polymerization and the remaining amount is added in one or more parts at monomer conversions of greater than 20%.
摘要翻译：使用包含连二亚硫酸钠或连二亚硫酸钠与甲酰胺亚磺酸钠或与过氧二硫酸钾或与甲脒亚磺酸和过氧二硫酸钾或与过氧二硫酸钾和蒽醌-β-磺酸钠的混合物的聚合引发剂，以高单体转化率获得无凝胶的聚氯丁二烯或与甲酰胺亚磺酸和过二硫酸钾和蒽醌-β-磺酸钠反应，并且在氧和链转移剂存在下，当聚合开始时存在30至90％的引发剂，其余部分在在引发剂组合的情况下，只有进一步的连二亚硫酸钠以60％的转化率加入，并且当在聚合开始之前或在聚合开始时存在20至80重量％的链转移剂的总量在单体转化时，一个或多个部分加入量大于20％。

2. 发明授权

US4975501A Process for polymerization of chloroprene 失效
标题翻译：氯丁二烯聚合方法
公开(公告)号：US4975501A
公开(公告)日：1990-12-04
申请号：US399333
申请日：1989-08-28
申请人： Rudiger Musch , Eberhard Muller , Wolfgang Konter , Gerhard Hohmann , Ludwig Mott
发明人： Rudiger Musch , Eberhard Muller , Wolfgang Konter , Gerhard Hohmann , Ludwig Mott
IPC分类号： C08F2/28 , C08F2/24 , C08F2/26 , C08F36/18
CPC分类号： C08F36/18
摘要： The polymerization of chloroprene leads to non-colored products when a mixture of 2.0 to 5.0% by weight of a salt of disproportionated abietic acid and 0.1 to 1.0% by weight, in each case relative to the total amount of monomer, of a compound of the formula ##STR1## in which R.sub.1 and R.sub.2, independently of one another, denote hydrogen or CH.sub.3,m denotes a number from 0 to 14,n denotes a number from 0 to 13,p denotes a number from 0 to 2, andy denotes hydrogen, Na or K, andthe total number of aliphatic carbon atoms is 11 to 15,is used as emulsifier, the emulsifiers having the advantage of being biologically degradable.
摘要翻译：氯丁二烯的聚合导致当2.0％至5.0％重量比例的歧化松香酸和0.1至1.0％重量（在每种情况下相对于单体的总量）的混合物的混合物中的无色产物为式中，R 1和R 2彼此独立地表示氢或CH 3，m表示0〜14的数，n表示0〜13的数，p表示0〜2的数，y表示表示氢，Na或K，脂族碳原子的总数为11〜15，用作乳化剂，乳化剂具有生物可降解的优点。

3. 发明授权

US4485216A Polychloroprene mixtures and the use thereof 失效
标题翻译：聚氯丁二烯混合物及其用途
公开(公告)号：US4485216A
公开(公告)日：1984-11-27
申请号：US529389
申请日：1983-09-06
申请人： Rudiger Musch , Wilhelm Gobel , Wolfgang Konter , Eberhard Muller
发明人： Rudiger Musch , Wilhelm Gobel , Wolfgang Konter , Eberhard Muller
IPC分类号： C08L33/00 , C08L7/00 , C08L11/00 , C08L21/00 , C08L33/04 , C08L27/22
CPC分类号： C08L11/00 , C08L2205/02
摘要： Solid polychloroprene mixtures consisting of sol and gel polymer, wherein the sol component consists of a copolymer of chloroprene and from 0.75 to 0.32% by weight of sulphur, based on the total quantity of unsaturated compounds of the sol polychloroprene, and the gel component consists of a copolymer of chloroprene, from 0.4 to 1.0% by weight of sulphur, based on the total quantity of unsaturated compounds of the gel polychloroprene and from 7.5.times.10.sup.-3 to 3.0.times.10.sup.-2 mols, based on 100 g of the total quantity of monomer of the gel polychloroprene, of a compound corresponding to the general formula ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom or C.sub.1 -C.sub.4 alkyl group, and X represents a C.sub.2 -C.sub.10 alkylene group,are suitable for the production by extrusion and by calandering of rubber articles which may be subjected to high strains.
摘要翻译：由溶胶和凝胶聚合物组成的固体聚氯丁二烯混合物，其中溶胶组分由氯丁二烯和0.75至0.32重量％硫的共聚物组成，基于溶胶聚氯丁二烯的不饱和化合物的总量，凝胶组分由基于凝胶聚氯丁二烯的不饱和化合物的总量和基于100g单体总量的7.5×10 -3至3.0×10 -2摩尔的氯丁二烯共聚物，为0.4至1.0重量％的硫的凝胶聚氯丁二烯，其通式为：其中R1和R2各自表示氢原子或C1-C4烷基，X代表C2-C10亚烷基，适用于通过挤出和通过压缩可能经受高应变的橡胶制品。

4. 发明授权

US4482676A Production of sulfur-modified solid chloroprene rubbers 失效
标题翻译：生产硫改性固体氯丁橡胶
公开(公告)号：US4482676A
公开(公告)日：1984-11-13
申请号：US473697
申请日：1983-03-09
申请人： Rudiger Musch , Wilhelm Gobel , Eberhard Muller , Wolfgang Konter
发明人： Rudiger Musch , Wilhelm Gobel , Eberhard Muller , Wolfgang Konter
IPC分类号： C08F2/00 , C08F2/22 , C08F2/44 , C08F36/00 , C08F36/18 , C08L11/00 , C08L21/00 , C08L11/02
CPC分类号： C08F36/18 , C08L11/02 , C08L2205/02
摘要： Vulcanizable, elastomeric chloroprene/sulfur copolymers having viscosities of from 60 to 35 ME, strengths of greater than 20 MPa and sulfur contents of from about 0.3 to 0.45% by weight are obtained by polymerizing chloroprene in the presence of from 0.05 to 0.40% by weight of sulfur to form a latex I, polymerizing chloroprene in the presence of from 0.5 to 1.5% by weight of sulfur to form a latex II, mixing latices I and II, optionally together with other sulfur-modified polychloroprene latices, in a ratio of from 4:1 to 1:4 (based in each case on solids) and peptizing the mixture, followed by working up to form the solid rubber, the percentages quoted being based on the quantity of monomer.
摘要翻译：通过在0.05至0.40重量％的存在下聚合氯丁二烯，可获得粘度为60至35MW，强度大于20MPa，硫含量为约0.3至0.45重量％的可硫化的弹性体氯丁二烯/硫共聚物的硫以形成胶乳I，在0.5至1.5重量％的硫存在下聚合氯丁二烯以形成胶乳II，任选地将胶乳I和II与其它硫改性的聚氯丁二烯胶乳混合，其比例为 4：1至1：4（基于每种情况下为固体）和胶体化混合物，然后加工形成固体橡胶，所引用的百分比基于单体的量。

5. 发明授权

US4452947A Process for the production of sulphur-modified solid chloroprene rubbers 失效
标题翻译：生产硫改性固体氯丁橡胶的方法
公开(公告)号：US4452947A
公开(公告)日：1984-06-05
申请号：US496413
申请日：1983-05-20
申请人： Rudiger Musch , Wilhelm Gobel , Eberhard Muller , Wolfgang Konter
发明人： Rudiger Musch , Wilhelm Gobel , Eberhard Muller , Wolfgang Konter
IPC分类号： C08L7/00 , C08C1/00 , C08C19/08 , C08F2/00 , C08F2/44 , C08F8/50 , C08F36/00 , C08F36/18 , C08K3/00 , C08L11/00 , C08L21/00 , C08F8/00
CPC分类号： C08F36/18 , C08L11/02 , C08L2205/02
摘要： Vulcanisable, elastomeric chloroprene-sulphur copolymers having viscosities of from 60 to 35 MU, strengths of >20 MPa and sulphur contents of from about 0.5 to 0.7%, by weight, in the batch are obtained by polymerising chloroprene in the presence of from 0.10 to 0.35%, by weight, of sulphur to form a latex I, polymerising chloroprene in the presence of from 0.50 to 1.00% by weight, of sulphur to form a latex II, mixing latices I and II in a ratio of from 4:1 to 1:4 (based in each case on solids), optionally together with other sulphur-modified polychloroprene latices, the mixture is peptised and worked-up to form the solid rubber, the percentages quoted being based on the quantity of monomer.
摘要翻译：通过将氯丁二烯在0.10〜0.1重量％的存在下聚合，得到批次中粘度为60〜35MW，强度> 20MPa，硫含量为约0.5〜0.7％的可硫化弹性体氯丁二烯 - 硫共聚物 0.35重量％的硫以形成胶乳I，在0.50至1.00重量％的硫存在下聚合氯丁二烯以形成胶乳II，将胶乳I和II以4:1至4:1的比例混合 1：4（基于固体的每种情况），任选地与其它硫改性的聚氯丁二烯胶乳一起，对混合物进行胶溶和后处理以形成固体橡胶，所引用的百分比是基于单体的量。

6. 发明授权

US4857616A Process for the preparation of polychloroprene 失效
标题翻译：制备聚氯丁二烯的方法
公开(公告)号：US4857616A
公开(公告)日：1989-08-15
申请号：US154936
申请日：1988-02-11
申请人： Rudiger Musch , Eberhard Muller , Gerhard Hohmann , Karl-Heinz Schabel
发明人： Rudiger Musch , Eberhard Muller , Gerhard Hohmann , Karl-Heinz Schabel
IPC分类号： C08F6/14 , C08C19/08 , C08F2/26 , C08F2/38 , C08F4/30 , C08F4/40 , C08F6/06 , C08F36/18
CPC分类号： C08C19/08 , C08F36/18
摘要： Storage-stable polychloroprene is obtained, by aqueous emulsion polymerization, using xanthogen disulphides as molecular weight regulators, when a peptizing agent is added after the end of the polymerization.
摘要翻译：当聚合结束后加入胶溶剂时，通过水乳液聚合获得储存稳定的聚氯丁二烯，使用黄原酸二硫化物作为分子量调节剂。

7. 发明授权

US4895906A Polychloroprene mixtures 失效
标题翻译：聚氯丁二烯混合物
公开(公告)号：US4895906A
公开(公告)日：1990-01-23
申请号：US221430
申请日：1988-07-19
申请人： Peter Wendling , Werner Obrecht , Wilhelm Gobel , Rudiger Musch , Rudolf Casper , Eberhard Muller
发明人： Peter Wendling , Werner Obrecht , Wilhelm Gobel , Rudiger Musch , Rudolf Casper , Eberhard Muller
IPC分类号： C08C1/00 , C08C19/08 , C08C19/20 , C08F8/34 , C08F36/18 , C08J3/16 , C08L11/00 , C08L21/00
CPC分类号： C08C19/08 , C08F36/18
摘要： The invention relates to a polychloroprene rubber which shows advantages over the prior art in the sum total of its performance properties, namely vulcanization rate, tensile strength, elongation at break, modulus, tear propagation resistance and thermal stability of the vulcanizate.
摘要翻译：本发明涉及一种聚氯丁二烯橡胶，其在其性能性能，即硫化速率，拉伸强度，断裂伸长率，模量，抗撕裂蔓延性和硫化橡胶的热稳定性的总和中显示出优于现有技术的优点。

8. 发明授权

US5298580A Process for the production of vulcanizable mercaptan-and/or xanthogen disulfide-regulated polychloroprene rubbers with minimal mold fouling 失效
标题翻译：生产可硫化硫醇和/或黄原二硫键调节聚氯丁二烯橡胶的方法，具有最小的模具污染
公开(公告)号：US5298580A
公开(公告)日：1994-03-29
申请号：US946655
申请日：1992-09-18
申请人： Peter Wendling , Werner Obrecht , Michael Happ , Rudiger Musch , Eberhard Muller
发明人： Peter Wendling , Werner Obrecht , Michael Happ , Rudiger Musch , Eberhard Muller
IPC分类号： C08F2/22 , C08F2/24 , C08F2/26 , C08F2/38 , C08F2/44 , C08F36/18
CPC分类号： C08F36/18
摘要： Vulcanizable, mercaptan- and/or xanthogen-disulfide-regulated polychloroprene rubber are produced by emulsion polymerization of chloroprene and, based on polymerizable monomer used, 0 to 30 parts by weight ethylenically unsaturated, other monomers copolymerizable with chloroprene in an alkaline medium by a process in which(1) 0.1 to 10 parts by weight of a tricyclic diterpene carboxylic acid containing at least two conjugated C.dbd.C double bonds per molecule, based on the polymerizable monomer used, and optionally(2) 0.1 to 5 parts by weight, based on polymerizable monomer used, fatty acid estersare used for their production.The polychloroprene produced in accordance with the invention may be used for the production of vulcanized rubber articles. The polychloroprene rubbers produced by the process according to the invention have a minimal tendency to foul metal molds. The pollution of wastewaters by the process according to the invention is minimal. The well-known favorable properties of polychloroprene remain unaffected.
摘要翻译：通过氯丁二烯的乳液聚合制备可硫化，硫醇和/或黄原二硫化物调节的聚氯丁二烯橡胶，并且基于所使用的可聚合单体，0至30重量份烯键式不饱和，可通过工艺在碱性介质中与氯丁二烯共聚的其它单体其中（1）基于所使用的可聚合单体，每分子含有至少两个共轭C = C双键的三环二萜羧酸0.1至10重量份，和任选地（2）0.1至5重量份的基于在使用的可聚合单体上，使用脂肪酸酯来制造。根据本发明生产的聚氯丁二烯可用于硫化橡胶制品的生产。通过根据本发明的方法生产的聚氯丁二烯橡胶具有污染金属模具的最小趋势。通过根据本发明的方法对废水的污染是最小的。聚氯丁二烯的众所周知的有利特性保持不变。

9. 发明授权

US4954585A Process for the production of sulfur-modified polychloroprene 失效
标题翻译：硫改性聚氯丁二烯生产工艺
公开(公告)号：US4954585A
公开(公告)日：1990-09-04
申请号：US289816
申请日：1988-12-27
申请人： Werner Obrecht , Peter Wendling , Rudiger Musch , Eberhard Muller
发明人： Werner Obrecht , Peter Wendling , Rudiger Musch , Eberhard Muller
IPC分类号： C08F2/24 , C08F2/26 , C08F2/44 , C08F36/18 , C08L11/00
CPC分类号： C08F36/18
摘要： The combination of unmodified resinic acids and direct peptization in the production of sulfur-modified polychloroprene leads to a favorable ratio of elasticity to viscosity.
摘要翻译：在改性聚氯丁二烯的生产中，未改性树脂酸和直接胶溶的组合导致弹性与粘度的有利比例。

10. 发明授权

US4443582A Mixtures of chloroprene polymers and the production thereof 失效
标题翻译：氯丁二烯聚合物的混合物及其制备
公开(公告)号：US4443582A
公开(公告)日：1984-04-17
申请号：US379919
申请日：1982-05-19
申请人： Rudiger Musch , Gottfried Pampus , Peter Muller , Ulrich Eisele , Wolfgang Konter , Wilhelm Gobel
发明人： Rudiger Musch , Gottfried Pampus , Peter Muller , Ulrich Eisele , Wolfgang Konter , Wilhelm Gobel
IPC分类号： C08F36/00 , C08F36/18 , C08F236/18 , C08L7/00 , C08L11/00 , C08L21/00 , C08L27/04
CPC分类号： C08F36/18 , C08L11/00 , C08L11/02 , C08L2205/02
摘要： This invention relates to a polychloroprene elastomer distinguished by good processing properties and high tensile strength in the form of a polychloroprene mixture containing a sol polymer and a gel polymer in a ratio, by weight, of from 1:4 to 9:1, characterized in that both polymers have been produced in the presence of from 2.5 to 4.0 parts, by weight, of the potassium salt of disproportionated abietic acid (expressed as acid), from 0.3 to 1.0 part, by weight, of a condensation product of naphthalene sulphonic acid and formaldehyde and from 0.1 to 1.5 parts, by weight, of potassium hydroxide, based in each case on 100 parts, by weight, of monomer, and in that the gel polymer is a copolymer of chloroprene and from 1.5 to 2.5 mole percent, based on total monomer, of a diester corresponding to the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 represent hydrogen, chlorine or C.sub.1 -C.sub.4 alkyl; andX represents C.sub.2 -C.sub.10 alkylene.
摘要翻译：本发明涉及一种聚氯丁二烯弹性体，其特征在于以包含溶胶聚合物和凝胶聚合物的重量比为1:4至9:1的聚氯丁二烯混合物形式的良好加工性能和高拉伸强度，其特征在于两种聚合物已经在2.5至4.0重量份歧化松香酸钾盐（以酸表示）的存在下制备，0.3至1.0重量份的萘磺酸的缩合产物和甲醛，和0.1至1.5重量份的氢氧化钾，基于每种情况下为100重量份的单体，并且凝胶聚合物是氯丁二烯和基于1.5至2.5摩尔％的基于对于相应于以下通式的二酯的总单体：其中R 1和R 2表示氢，氯或C 1 -C 4烷基; X表示C2-C10亚烷基。

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