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1. 发明申请

US20090264688A1 CATALYTIC OXY-FUNCTIONALIZATION OF METAL-CARBON BONDS 审中-公开
标题翻译：金属碳的催化氧化功能
公开(公告)号：US20090264688A1
公开(公告)日：2009-10-22
申请号：US12354318
申请日：2009-01-15
申请人： Roy A. Periana , William A. Goddard, III , William Tenn
发明人： Roy A. Periana , William A. Goddard, III , William Tenn
IPC分类号： C07C27/22
CPC分类号： C07C29/48 , C07C31/02 , C07C31/04
摘要： The development of compatible functionalization reactions with methyl rhenium(I) species, for integration with the CH activation reaction of hydrocarbons by transition metal alkoxo complexes is described. The invention is applicable to the design of rapid, stable CH activation systems integrated with an oxy-functionalization reaction for selective, low temperature hydrocarbon oxidation catalysts.
摘要翻译：描述了与甲基铼（I）物质的相容官能化反应的发展，用于通过过渡金属烷氧基配合物与烃的CH活化反应的一体化。本发明适用于与用于选择性低温烃氧化催化剂的氧官能化反应相结合的快速，稳定的CH活化体系的设计。

2. 发明申请

US20090234121A1 TRIDENTATE (NNC) CATALYSTS FOR THE SELECTIVE OXIDATION OF HYDROCARBONS 审中-公开
标题翻译：三氯甲烷（NNC）催化剂选择性氧化烃
公开(公告)号：US20090234121A1
公开(公告)日：2009-09-17
申请号：US12354409
申请日：2009-01-15
申请人： Roy A. Periana , William A. Goddard, III , Jonas Oxgaard , Kenneth Young
发明人： Roy A. Periana , William A. Goddard, III , Jonas Oxgaard , Kenneth Young
IPC分类号： C07C51/255 , C07F17/02 , C07C15/04 , C07C9/04 , C07C37/58 , C07C29/50 , C07C53/00
CPC分类号： B01J31/1815 , B01J2231/52 , B01J2231/70 , B01J2531/0244 , B01J2531/825 , B01J2531/827 , C07B33/00 , C07B2200/05 , C07C29/48 , C07C37/60 , C07C67/035 , Y02P20/52 , C07C31/04 , C07C69/63 , C07C39/04
摘要： The synthesis of discrete, air, protic, and thermally stable transition metal NNC complexes that catalyze the CH activation and functionalization of alkanes and arenes is disclosed. Methods for the selective conversion of methane to methanol or methyl esters in acidic and neutral media are disclosed.
摘要翻译：公开了催化烷烃和芳烃的CH活化和官能化的离散的，空气的，质子的和热稳定的过渡金属NNC络合物的合成。公开了在酸性和中性介质中甲烷选择性转化成甲醇或甲酯的方法。

3. 发明授权

US07915459B2 Catalytic systems for the conversion of hydrocarbons to functionalized products 有权
标题翻译：用于将碳氢化合物转化为官能化产物的催化体系
公开(公告)号：US07915459B2
公开(公告)日：2011-03-29
申请号：US11361315
申请日：2006-02-24
申请人： Roy A. Periana , William A. Goddard, III
发明人： Roy A. Periana , William A. Goddard, III
IPC分类号： C07C29/48
CPC分类号： C07C29/48 , B01J27/0573 , B01J31/1805 , C07B33/00 , C07C37/58 , C07C37/60 , Y02P20/52 , C07C31/04 , C07C39/04
摘要： This invention discloses methods and processes for selectively converting hydrocarbons such as methane to materials such as alcohols or other materials containing more reactive functionalities.
摘要翻译：本发明公开了用于选择性地将诸如甲烷的烃转化为诸如醇或其它含有更多反应性官能团的材料的材料的方法和方法。

4. 发明授权

US5177049A Oxidation of tertiary-alkyl substituted aromatics 失效
标题翻译：叔烷基取代芳烃的氧化
公开(公告)号：US5177049A
公开(公告)日：1993-01-05
申请号：US746903
申请日：1991-08-19
申请人： Roy A. Periana , George F. Schaefer
发明人： Roy A. Periana , George F. Schaefer
IPC分类号： B01J31/04 , C07C2/86 , C07C51/265
CPC分类号： B01J31/0231 , B01J31/04 , B01J31/26 , C07C2/861 , C07C51/265 , B01J2231/70 , B01J2531/72 , B01J2531/845
摘要： A process for the production of para-oriented dicarboxylic aromatic acids is disclosed in which an aromatic compound, having a tertiary alkyl group, is oxidized with molecular oxygen in the presence of a catalytic composition comprising a cobalt salt, a minor amount of a manganese salt, and a source of chloride in the presence of a solvent.
摘要翻译：公开了一种制备对位二羧酸芳香酸的方法，其中具有叔烷基的芳族化合物在包含钴盐，少量锰盐的催化组合物存在下被分子氧氧化，和在溶剂存在下的氯化物源。

5. 发明授权

US5068407A Oxidation of tertiary-alkyl substituted aromatics 失效
标题翻译：烷基取代的芳族化合物的氧化
公开(公告)号：US5068407A
公开(公告)日：1991-11-26
申请号：US473031
申请日：1990-01-31
申请人： Roy A. Periana , George F. Schaefer
发明人： Roy A. Periana , George F. Schaefer
IPC分类号： B01J27/10 , B01J27/128 , B01J31/04 , B01J31/30 , C07B61/00 , C07C2/86 , C07C51/265 , C07C63/333
CPC分类号： B01J31/0231 , B01J31/04 , C07C2/861 , C07C51/265 , B01J2231/70 , B01J2531/72 , B01J2531/845
摘要： A process for the production of para-oriented dicarboxylic aromatic acids is disclosed in which an aromatic compound, having a tertiary alkyl group, is oxidized with molecular oxygen in the presence of a catalytic composition comprising a cobalt salt, a minor amount of a manganese salt, and a source of chloride in the presence of a solvent.

6. 发明授权

US5233113A Process for converting lower alkanes to esters 失效
标题翻译：将低级烷烃转化为酯的方法
公开(公告)号：US5233113A
公开(公告)日：1993-08-03
申请号：US656910
申请日：1991-02-15
申请人： Roy A. Periana , Eric R. Evitt , Henry Taube
发明人： Roy A. Periana , Eric R. Evitt , Henry Taube
IPC分类号： C07C29/48 , C07C29/50 , C07C67/035 , C07C303/24 , C07C303/28 , C07C305/06 , C07C309/65 , C07C391/00
CPC分类号： C07C391/00 , C07C29/48 , C07C29/50 , C07C303/24 , C07C303/28 , C07C67/035 , Y02P20/52 , Y10S585/943
摘要： This invention is a process for converting lower alkanes into their corresponding esters and optionally into various intermediates (such as methanol) and other liquid hydrocarbons. The alkanes are oxidatively converted to oxy-esters at high selectivity using catalytic amounts of a Group VIII noble metal. If so desired, the alkyl oxy-esters may be converted to alcohols or other intermediates such as alkyl halides. The oxy-esters, alcohols, and other intermediates may optionally be converted to liquid hydrocarbons such as gasoline.
摘要翻译：本发明是将低级烷烃转化成其相应的酯，任选地转化为各种中间体（如甲醇）和其它液体烃的方法。使用催化量的VIII族贵金属，烷烃以高选择性氧化转化为氧酯。如果需要，烷基氧酯可以转化成醇或其它中间体，如烷基卤化物。氧酯，醇和其它中间体可以任选地转化成液体烃如汽油。

7. 发明授权

US07368598B2 Process for converting methane to acetic acid 有权
标题翻译：将甲烷转化为乙酸的方法
公开(公告)号：US07368598B2
公开(公告)日：2008-05-06
申请号：US11186077
申请日：2005-07-19
申请人： Roy A. Periana
发明人： Roy A. Periana
IPC分类号： C07C51/16 , C07C51/215 , C07C51/285 , C07C51/295 , C07C51/305
CPC分类号： C07C51/145 , C07C51/305 , C07C53/08
摘要： Provided herein are processes for conversion of methane to acetic acid. In one embodiment, the processes are for direct, selective conversion of methane to acetic acid in a single step.
摘要翻译：本文提供了将甲烷转化为乙酸的方法。在一个实施方案中，该方法用于在一个步骤中将甲烷直接，选择性转化成乙酸。

8. 发明授权

US4879398A Process for producing 2,6-disubstituted tyrosine 失效
标题翻译： 2,6-二取代酪氨酸的制备方法
公开(公告)号：US4879398A
公开(公告)日：1989-11-07
申请号：US139999
申请日：1987-12-31
申请人： Daniel P. Getman , Roy A. Periana , Dennis P. Riley
发明人： Daniel P. Getman , Roy A. Periana , Dennis P. Riley
IPC分类号： C07C227/32
CPC分类号： C07C227/32
摘要： A process for making 2,6-disubstituted tyrosine by the noble metal coupling of a disubstituted aromatic halide or diazonium salt with an amino-protected 2-aminoacrylic acid to form a (Z)-.beta.-(disubstituted phenyl)-.alpha.-acylaminoacrylate, and asymmetrically hydrogenating the acrylate to produce the 2,6-disubstituted tyrosine.
摘要翻译：通过二取代的芳族卤化物或重氮盐与氨基保护的2-氨基丙烯酸的贵金属偶联制备2,6-二取代的酪氨酸以形成（Z）-β-（二取代的苯基）-α-酰基氨基丙烯酸酯的方法，并不对称地氢化丙烯酸酯以产生2,6-二取代的酪氨酸。

9. 发明授权

US5306855A Catalytic process for converting lower alkanes to esters, alcohols, and to hydrocarbons 失效
标题翻译：将低级烷烃转化为酯，醇和烃的催化方法
公开(公告)号：US5306855A
公开(公告)日：1994-04-26
申请号：US799446
申请日：1991-11-27
申请人： Roy A. Periana , Douglas J. Taube , Henry Taube , Eric R. Evitt
发明人： Roy A. Periana , Douglas J. Taube , Henry Taube , Eric R. Evitt
IPC分类号： C07B61/00 , C07C2/84 , C07C9/02 , C07C29/48 , C07C29/50 , C07C31/04 , C07C67/035 , C07C303/06 , C07C303/24 , C07C303/28 , C07C305/04 , C07C305/06 , C07C305/08 , C07C309/65 , C07C391/00 , C10G3/00 , C10G50/00 , C07C2/00
CPC分类号： C07C29/48 , C07C29/50 , C07C303/24 , C07C303/28 , C07C391/00 , C07C67/035 , Y02P20/52 , Y02P30/20 , Y10S585/943
摘要： This invention is a process for converting lower alkanes into their corresponding esters and optionally into various intermediates (such as alcohols) and other liquid hydrocarbons. The alkanes are oxidatively converted to oxy-esters at high selectivity and conversion and at practical reaction rates using at least catalytic amounts of certain class "B" metals and/or metal ions defined by the Pearson definition as "soft" or "borderline". Desirable catalysts comprise such metals as Pd, Tl, Pt, Hg, and Au. If so desired, the alkyl oxy-esters may be converted to alcohols or other intermediates such as alkyl halides. The oxy-esters, alcohols, and other intermediates may optionally be converted to liquid hydrocarbons such as gasoline.
摘要翻译：本发明是将低级烷烃转化成其相应的酯，任选地转化成各种中间体（如醇）和其它液体烃的方法。烷烃以高选择性和转化率以及实际的反应速率使用至少催化量的由“皮尔逊”定义的“B”族金属和/或金属离子作为“软”或“边界”而氧化转化为氧酯。理想的催化剂包括诸如Pd，Tl，Pt，Hg和Au的金属。如果需要，烷基氧酯可以转化成醇或其它中间体，如烷基卤化物。氧酯，醇和其它中间体可以任选地转化成液体烃如汽油。

10. 发明授权

US4746760A Process for functionalizing alkanes 失效
标题翻译：官能化烷烃的方法
公开(公告)号：US4746760A
公开(公告)日：1988-05-24
申请号：US703640
申请日：1985-02-21
申请人： Robert G. Bergman , Andrew H. Janowicz , Roy A. Periana
发明人： Robert G. Bergman , Andrew H. Janowicz , Roy A. Periana
IPC分类号： C07C17/00 , C07F15/00 , B01J19/12
CPC分类号： C07F15/0073 , C07C17/00
摘要： Process for functionalizing saturated hydrocarbons comprising:(a) reacting said saturated hydrocarbons of the formula:R.sub.1 H wherein H represents a hydrogen atom; and R.sub.1 represents a saturated hydrocarbon radical, with a metal complex of the formula:CpRh[P(R.sub.2).sub.3 ]H.sub.2 whereinCp represents a cyclopentadienyl or alkylcyclopentadienyl radical;Rh represents a rhodium atom;P represents a phosphorus atom;R.sub.2 represents a hydrocarbon radical;H represents a hydrogen atom, in the presence of ultraviolet radiation to form a hydridoalkyl complex of the formula:CpRh[P(R.sub.2).sub.3 ](R.sub.1)H(b) reacting said hydridoalkyl complex with an organic halogenating agent such as a tetrahalomethane or a haloform of the formulas:CX'X''X'''X'''' or CHX'X''X''' wherein X', X'', X'", X"" represent halogens selected from bromine, iodine or chlorine atom, at a temperature in the range of about -60.degree. to -17.degree. C. to form the corresponding haloalkyl complex of step (a) having the formula:CpRhPMe.sub.3 RX; and,(c) reacting said haloalkyl complex formed in (b) with halogen (X.sub.2) at a temperature in the range of about -60.degree. to 25.degree. C. (i.e., ambient) to form a functional haloalkyl compound.
摘要翻译：使饱和烃官能化的方法包括：（a）使所述式R 1 H的饱和烃反应其中H代表氢原子; 并且R1表示饱和烃基，其具有下式的金属络合物：CpRh [P（R2）3] H2，其中Cp表示环戊二烯基或烷基环戊二烯基; Rh表示铑原子; P表示磷原子; R2表示烃基; H表示氢原子，在紫外线辐射下形成下式的氢化烷基络合物：CpRh [P（R2）3]（R1）H（b）使所述氢化烷基络合物与有机卤化剂如四卤代甲烷或其中X'，X“，X”'，X“”代表卤素的卤代基，如下式所示：CX'X'X“'X”'或CHX'X''X“ 在约-60℃至-17℃的温度范围内选自溴，碘或氯原子，形成具有下式的步骤（a）的相应的卤代烷基络合物：CpRhPMe3RX; 和（c）使（b）中形成的卤代烷基络合物与卤素（X2）在约-60°至25℃（即环境温度）的温度下反应，形成官能的卤代烷基化合物。

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