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1. 发明授权

US4055520A Polyphosphazene blends 失效
标题翻译：聚磷腈混合物
公开(公告)号：US4055520A
公开(公告)日：1977-10-25
申请号：US705116
申请日：1976-07-14
申请人： Ronald L. Dieck , Edwin J. Quinn
发明人： Ronald L. Dieck , Edwin J. Quinn
IPC分类号： C08L85/00 , C08G79/02 , C08J9/00 , C08J9/04 , C08J9/10 , C08L85/02 , C08J9/06
CPC分类号： C08J9/0061 , C08G79/025 , C08J9/10 , C08L85/02 , C08J2385/02 , C08J2485/00 , Y10S521/903 , Y10S521/907
摘要： Polyphosphazene blends and foams thereof are described. The blends comprise of at least one polyphosphazene copolymer having a Young's Modulus of up to about 5.times.10.sup.8 dynes/cm.sup.2 and at least one polyphosphazene homopolymer or copolymer having a Young's Modulus of at least about 5.times.10.sup.8 dynes/cm.sup.2. The copolymers used to prepare the blends comprise randomly repeating units represented by the formulas ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and are hydrogen, a C.sub.1 - C.sub.10 linear or branched alkyl radical, or a C.sub.1 - C.sub.4 linear or branched alkoxy radical substituted on any sterically permissible position on the phenoxy group, with the proviso that when R.sub.2 is alkoxy, R.sub.1 and R.sub.2 are different. The blends of this invention can be formed into sheets or films, or into flexible or semi-rigid foams. The blends are extremely fire retardant and produce low smoke loads, or essentially no smoke, when heated in an open flame.
摘要翻译：描述了聚磷腈共混物及其泡沫。共混物包含至少一种具有高达约5×10 8达因/平方厘米的杨氏模量的聚磷腈共聚物和至少约5×10 8达因/厘米2的杨氏模量的至少一种聚磷腈均聚物或共聚物。用于制备共混物的共聚物包括由下式表示的无规重复单元：其中R 1和R 2相同或不同，为氢，C 1 -C 10直链或支链烷基或C1〜在苯氧基上任何空间上允许的位置上取代的C4直链或支链烷氧基，条件是当R 2为烷氧基时，R 1和R 2不同。本发明的共混物可以形成片或膜，或形成柔性或半刚性泡沫。当在明火中加热时，混合物具有极强的阻燃性，并产生低烟雾负荷，或基本上不含烟雾。

2. 发明授权

US4026839A Polyphosphazene polymer/silicone rubber blends and foams therefrom 失效
标题翻译：聚磷腈聚合物/硅橡胶混合物和泡沫
公开(公告)号：US4026839A
公开(公告)日：1977-05-31
申请号：US718412
申请日：1976-08-30
申请人： Ronald L. Dieck , Edwin J. Quinn
发明人： Ronald L. Dieck , Edwin J. Quinn
IPC分类号： C08L83/00 , C08J9/00 , C08J9/04 , C08L83/04 , C08L85/00 , C08L85/02 , C08J9/10
CPC分类号： C08J9/0061 , C08L83/04 , C08L85/02 , C08G77/20 , C08G77/70 , C08J2383/04 , C08J2385/02 , C08J2483/00 , C08J2485/00 , Y10S521/903 , Y10S521/907
摘要： This invention relates to blends of polyphosphazenes and silicone polymers. The blends of this invention can be formed into coatings, sheets or films or into flexible or semi-rigid foams. The blends are extremely fire retardant and produce low smoke loads, or essentially no smoke, when heated in an open flame.
摘要翻译：本发明涉及聚磷腈和硅氧烷聚合物的共混物。本发明的共混物可以形成为涂料，片材或膜或柔性或半刚性泡沫。当在明火中加热时，混合物具有极强的阻燃性，并产生低烟雾负荷，或基本上不含烟雾。

3. 发明授权

US4026838A Smoke-suppressant additives for polyphosphazenes 失效
标题翻译：聚磷腈的防烟添加剂
公开(公告)号：US4026838A
公开(公告)日：1977-05-31
申请号：US712149
申请日：1976-08-06
申请人： Ronald L. Dieck , Edwin J. Quinn
发明人： Ronald L. Dieck , Edwin J. Quinn
IPC分类号： C08J9/04 , C01B21/097 , C01B21/098 , C08J9/00 , C08L85/00 , C08L85/02 , C09K21/06 , C09K21/12 , C08J9/10
CPC分类号： C08J9/0023 , C01B21/097 , C01B21/0986 , C08J9/0014 , C08K5/09 , C08K5/13 , C08K5/16 , C08K5/18 , C08K5/32 , C08K5/45 , C08J2385/02 , Y10S521/903
摘要： Smoke suppressant additives for poly(aryloxyphosphazene) homopolymers, copolymers and foams thereof are described. Smoke suppression occurs by the incorporation of an effective amount of a normally solid carboxylic acid.
摘要翻译：描述了聚（芳氧基磷腈）均聚物，共聚物和泡沫的防烟添加剂。通过掺入有效量的常规固体羧酸来发生烟抑制。

4. 发明授权

US4107146A Curable aryloxyphosphazene polymers 失效
公开(公告)号：US4107146A
公开(公告)日：1978-08-15
申请号：US768603
申请日：1977-02-14
申请人： Ronald L. Dieck , Alan B. Magnusson , Edwin J. Quinn
发明人： Ronald L. Dieck , Alan B. Magnusson , Edwin J. Quinn
IPC分类号： C08G79/00 , C08G79/02 , C08J9/04 , C08J9/06 , C08K5/14 , C08K5/36 , C08L85/02 , C08G79/04 , C08J9/10
CPC分类号： C08J9/06 , C08G79/025 , C08L85/02 , C08J2385/02 , Y10S260/24
摘要： Polymers comprising randomly repeating units of the general formula ##STR1## wherein R.sub.1 is linear or branched C.sub.1 -C.sub.10 alkoxy, R.sub.2 is linear or branched C.sub.1 -C.sub.10 alkyl, hydrogen or halogen, and W is C.sub.2 to C.sub.10 alkenyl-substituted aryloxy. These novel polymers are elastomers and may be used to form flexible and semirigid foams and coatings. They display good fire retardance and low smoke levels.

5. 发明授权

US4107108A Polyphosphazene plasticized resins 失效
公开(公告)号：US4107108A
公开(公告)日：1978-08-15
申请号：US766780
申请日：1977-02-08
申请人： Ronald L. Dieck , Edwin J. Quinn
发明人： Ronald L. Dieck , Edwin J. Quinn
IPC分类号： C08L85/00 , C08G79/00 , C08G79/02 , C08J9/04 , C08J9/06 , C08K3/30 , C08K5/14 , C08K5/36 , C08K5/5399 , C08L85/02 , C08J9/10
CPC分类号： C08J9/06 , C08G79/025 , C08K5/49 , C08K5/5399 , C08J2385/02 , Y10S260/24
摘要： Flame-retardant and low-smoke plasticized polyphosphazenes are disclosed. The plasticizers are substituted cyclotriphosphazenes and cyclotetraphosphazenes.

6. 发明授权

US4113670A Curable aryloxyphosphazene polymers 失效
标题翻译：可固化芳氧基膦腈聚合物
公开(公告)号：US4113670A
公开(公告)日：1978-09-12
申请号：US878679
申请日：1978-02-17
申请人： Ronald L. Dieck , Alan B. Magnusson , Edwin J. Quinn
发明人： Ronald L. Dieck , Alan B. Magnusson , Edwin J. Quinn
IPC分类号： C08G79/00 , C08G79/02 , C08J9/04 , C08J9/06 , C08K5/14 , C08K5/36 , C08L85/02 , C08G79/04 , C08J9/10
CPC分类号： C08J9/06 , C08G79/025 , C08L85/02 , C08J2385/02 , Y10S260/24
摘要： Polymers comprising randomly repeating units of the general formula ##STR1## wherein R.sub.1 is linear or branched C.sub.1 -C.sub.10 alkoxy, R.sub.2 is linear or branched C.sub.1 -C.sub.10 alkyl, hydrogen or halogen, and W is C.sub.2 to C.sub.10 alkenyl-substituted aryloxy. These novel polymers are elastomers and may be used to form flexible and semirigid foams and coatings. They display good fire retardance and low smoke levels.
摘要翻译：包含无规重复单元的聚合物，其中R 1为直链或支链C 1 -C 10烷氧基，R 2为直链或支链C 1 -C 10烷基，氢或卤素，W为C 2至C 10烯基取代的芳氧基。这些新型聚合物是弹性体，可用于形成柔性和半刚性泡沫和涂层。它们显示良好的阻燃性和低烟度。

7. 发明授权

US4083820A Low smoke polyphosphazene compositions 失效
标题翻译：低烟聚磷腈组合物
公开(公告)号：US4083820A
公开(公告)日：1978-04-11
申请号：US798818
申请日：1977-05-20
申请人： Ronald L. Dieck , Edwin J. Quinn
发明人： Ronald L. Dieck , Edwin J. Quinn
IPC分类号： C08L85/00 , C08G79/02 , C08J9/00 , C08K9/04 , C08L85/02
CPC分类号： C08J9/009 , C08G79/025 , C08K9/04 , C08J2385/02 , Y10S521/903
摘要： Smoke-suppressant additives for polyphosphazene homopolymers, copolymers and foams thereof are described. Smoke suppression occurs by the incorporation of an effective amount of organo titanate-treated mineral filler.
摘要翻译：描述了用于聚磷腈均聚物，共聚物和泡沫的防烟添加剂。通过掺入有效量的有机钛酸盐处理的矿物填料来发生烟抑制。

8. 发明授权

US4055523A Poly(dialkylaminoaryloxyphosphazene) polymers and foams 失效
标题翻译：聚（二烷基氨基氧基磷腈）聚合物和泡沫
公开(公告)号：US4055523A
公开(公告)日：1977-10-25
申请号：US714526
申请日：1976-08-16
申请人： Ronald L. Dieck , Alan B. Magnusson , Edwin J. Quinn
发明人： Ronald L. Dieck , Alan B. Magnusson , Edwin J. Quinn
IPC分类号： C08L85/00 , C08G79/00 , C08G79/02 , C08J9/04 , C08L85/02
CPC分类号： C08L85/02 , C08G79/025 , Y10S260/24
摘要： Poly(aryloxyphosphazene) polymers and foams thereof having di(C.sub.1 -C.sub.10)alkylaminophenoxy groups are described. The polymers consist of the units which occur in a nonregular fashion and are represented by the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and are C.sub.1 -C.sub.10 linear or branched alkyl radical. Copolymeric dialkylaminoaryloxy-aryloxyphosphazenes are disclosed represented by units of the general formula: ##STR2## wherein R.sub.1 and R.sub.2 are defined above and R represents hydrogen, halogen, C.sub.1 -C.sub.10 linear or branched alkyl radical, or C.sub.1 -C.sub.4 linear or branched alkoxy radical substituted on any sterically permissible position on the other phenoxy group. The radical NR.sub.1 R.sub.2 is substituted in the meta or para position on the phenoxy radical. The polymers are elastomers, have desirable tensile strengths and may be used to form flexible or semi-rigid films, sheets, and foams. The polymers are extremely fire retardant and produce low smoke loads when heated in an open flame. They readily form salts with mineral acids that are water soluble.
摘要翻译：描述了具有二（C1-C10）烷基氨基苯氧基的聚（芳氧基磷腈）聚合物及其泡沫。聚合物由以非规则形式出现并由下列通式表示的单元组成：其中R 1和R 2相同或不同，为C 1 -C 10直链或支链烷基。公开的共聚二烷基氨基芳氧基 - 芳氧基磷腈由以下通式的单元表示：其中R 1和R 2如上定义，R代表氢，卤素，C 1 -C 10直链或支链烷基或C 1 -C 4直链或在另一个苯氧基的任何空间允许位置上取代的支链烷氧基。在苯氧基上的间位或对位取代基NR1R2。聚合物是弹性体，具有所需的拉伸强度，并且可用于形成柔性或半刚性膜，片和泡沫。当在明火中加热时，聚合物具有极强的阻燃性和低烟度。它们容易与水溶性的无机酸形成盐。

9. 发明授权

US4053456A Poly(aryloxyphosphazene) copolymers 失效
标题翻译：聚（芳基二苯甲酮）共聚物
公开(公告)号：US4053456A
公开(公告)日：1977-10-11
申请号：US661862
申请日：1976-02-27
申请人： Ronald L. Dieck , Edwin J. Quinn
发明人： Ronald L. Dieck , Edwin J. Quinn
IPC分类号： C08G79/00 , C08G79/02 , C08J9/04 , C08J9/06 , C08L85/00 , C08L85/02
CPC分类号： C08J9/06 , C08G79/025 , C08L85/02 , C08J2385/02 , Y10S521/903 , Y10S521/907 , Y10S521/921
摘要： Poly(aryloxyphosphazene) copolymers and foams thereof having a significant portion of C.sub.1 - C.sub.4 alkoxyphenoxy groups are described. The copolymers consist of the units which occur in a nonregular fashion and are represented by the following general formulas: ##STR1## wherein R.sub.1 represents a C.sub.1 - C.sub.4 linear or branched alkyl radical in the ortho-, meta-, or para-position, and R.sub.2 represents hydrogen, a C.sub.1 - C.sub.10 linear or branched alkyl radical, or a C.sub.1 - C.sub.4 linear or branched alkoxy radical substituted on any sterically permissible position on the phenoxy group, with the proviso that when R.sub.2 is alkoxy, OR.sub.1 and R.sub.2 are different. The copolymers of this invention may contain small amounts of randomly distributed units in addition to the repeating units described above, these additional units containing reactive sites enabling the properties of the copolymers to be modified by crosslinking and/or curing. The copolymers are elastomers, have desirable tensile strengths and may be used to form flexible or semirigid foams. The copolymers are extremely fire retardant and produce low smoke loads, or essentially no smoke, when heated in an open flame.
摘要翻译：描述了具有大部分C 1 -C 4烷氧基苯氧基的聚（芳氧基磷腈）共聚物和泡沫。共聚物由以非规则形式出现并由下列通式表示的单元组成：其中R 1表示邻 - ，间 - 或邻 - 间的C1-C4直链或支链烷基对位，R2表示氢，C1-C10直链或支链烷基或在苯氧基上任何空间允许位置取代的C1-C4直链或支链烷氧基，条件是当R 2为烷氧基时，OR 1 和R2是不同的。除了上述重复单元之外，本发明的共聚物可以含有少量的无规分布的单元，这些含有能够通过交联和/或固化改性共聚物性质的反应性位点的这些附加单元。共聚物是弹性体，具有理想的拉伸强度，可用于形成柔性或半刚性泡沫。当在明火中加热时，共聚物具有极强的阻燃性，并产生低烟雾负荷，或基本上不含烟雾。

10. 发明授权

US4124557A Polyphosphazene plasticized resins 失效
标题翻译：聚磷腈增塑树脂
公开(公告)号：US4124557A
公开(公告)日：1978-11-07
申请号：US889534
申请日：1978-03-23
申请人： Ronald L. Dieck , Edwin J. Quinn
发明人： Ronald L. Dieck , Edwin J. Quinn
IPC分类号： C08L85/00 , C08G79/00 , C08G79/02 , C08J9/04 , C08J9/06 , C08K3/30 , C08K5/14 , C08K5/36 , C08K5/5399 , C08L85/02 , C08J9/10
CPC分类号： C08J9/06 , C08G79/025 , C08K5/49 , C08K5/5399 , C08J2385/02 , Y10S260/24
摘要： Flame-retardant and low-smoke plasticized polyphosphazenes are disclosed. The plasticizers are substituted cyclotriphosphazenes and cyclotetraphosphazenes.
摘要翻译：公开了阻燃和低烟增塑的聚磷腈。增塑剂是取代的环三磷腈和环四磷腈。

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