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1. 发明授权

US5408181A NMR system for measuring polymer properties 失效
标题翻译：用于测量聚合物性质的NMR系统
公开(公告)号：US5408181A
公开(公告)日：1995-04-18
申请号：US113833
申请日：1993-08-30
申请人： Ronald L. Dechene , Thomas B. Smith , David R. Day , Christian I. Tanzer , Scott A. Marino , Ronald J. Tache , Ajoy K. Roy
发明人： Ronald L. Dechene , Thomas B. Smith , David R. Day , Christian I. Tanzer , Scott A. Marino , Ronald J. Tache , Ajoy K. Roy
IPC分类号： G01N24/08 , G01R33/31 , G01R33/32 , G01R33/36 , G01R33/44 , G01R33/563 , G01R33/20
CPC分类号： G01N24/085 , G01R33/31 , G01R33/563
摘要： A pulsed nmr analysis system for polymers materials extracted from industrial processes at a mobility enhancing temperature (at or above glass transition temperature for amorphous polymers, at the crystalline transition temperature for crystalline and semi-crystalline polymers). The sample is measured via nmr techniques and results correlated to viscosity and melt index or melt flow (which are related to average molecular weights). The nmr system (in or out of resonance) includes: sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which components functions are determined using linear or non-linear regression techniques to correlate the curve components to the target nuclei and to flow rates in plastics. Substantial improvement of correlation of nmr derived constants and equations of a free induction decay curve with the foregoing polymer properties is obtained via (1) conducting the nmr process at a mobility enhancing temperature (normally elevated compared to the industrial process temperature of the industrial process) and (2) holding temperature substantially constant at such elevated temperature.
摘要翻译：用于在工业过程中以迁移率增强温度（对于无定形聚合物的玻璃化转变温度以上，在结晶和半结晶聚合物的结晶转变温度下）提取的聚合物材料的脉冲nmr分析系统。样品通过nmr技术测量，结果与粘度和熔体指数或熔体流动相关（与平均分子量相关）。 nmr系统（进出谐振）包括：采样吞吐系统（P，LI，V1，V2）和用户系统控制（104）建立数字化的自由感应衰减曲线（C），从中可以使用线性或非线性回归技术来将曲线分量与目标核相关联，并使塑料中的流速相关。通过（1）以迁移率提高温度（与工业过程的工业过程温度相比通常升高）进行nmr工艺，获得具有上述聚合物性质的自由诱导衰变曲线的nmr导出常数和方程的相关性的显着改善，和（2）在这种升高的温度下保持温度基本恒定。

2. 发明授权

US5367260A Apparatus to obtain flow rates (melt index) in plastics via fixed frequency, pulsed NMR 失效
标题翻译：通过固定频率，脉冲NMR获得塑料中的流速（熔体指数）的装置
公开(公告)号：US5367260A
公开(公告)日：1994-11-22
申请号：US961264
申请日：1992-10-15
申请人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ronald J. Tache , Ajoy K. Roy
发明人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ronald J. Tache , Ajoy K. Roy
IPC分类号： G01F1/716 , G01R33/31 , G01R33/32 , G01R33/44 , G01R33/20
CPC分类号： G01R33/31 , G01N24/085
摘要： A pulsed NMR analysis system and process comprising an air curtain (137), sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C) , from which components functions are determined using linear or nonlinear regression techniques to correlate the curve components to the target nuclei and to flow rates in plastic including MI and FRR for polyethylene and MF for polypropylene.
摘要翻译：脉冲NMR分析系统和方法，其包括空气幕（137），样品通量系统（P，LI，V1，V2）和用户系统控制（104）以建立数字化的自由感应衰减曲线（C），组分函数使用线性或非线性回归技术确定曲线分量与目标核的关系，以及包括聚乙烯和MF的聚丙烯的MI和FRR在内的塑料流速。

3. 发明授权

US5596275A NMR analysis of polypropylene in real time 失效
标题翻译：实时聚丙烯的NMR分析
公开(公告)号：US5596275A
公开(公告)日：1997-01-21
申请号：US625973
申请日：1996-04-01
申请人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ronald J. Tache , Ajoy K. Roy
发明人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ronald J. Tache , Ajoy K. Roy
IPC分类号： G01R33/389 , G01R33/44 , G01R33/46 , G01R33/20
CPC分类号： G01N24/085 , G01R33/389 , G01N24/082 , G01R33/4625
摘要： Pulsed NMR system for industrial measurements comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay (FID) curves (C), from which fast Gaussian, slower modified Gaussian or preferably slower Gaussian, and exponential components are determined using a Marquardt-Levenberg iteration technique, and using regression techniques to correlate the FID curve components to the physical quantities of the target nuclei.
摘要翻译：用于工业测量的脉冲NMR系统包括采样吞吐系统（P，LI，V1，V2）和用户系统控制（104）以建立数字化的自由感应衰减（FID）曲线（C），从其中快速高斯，较慢修正的高斯或优选使用Marquardt-Levenberg迭代技术确定较慢的高斯和指数分量，并使用回归技术将FID曲线分量与目标核的物理量相关联。

4. 发明授权

US5519319A Obtaining measurements of improved accuracy of one or more polymer properties with an on-line NMR system 失效
标题翻译：使用在线NMR系统获得改进的一种或多种聚合物性质的精度的测量
公开(公告)号：US5519319A
公开(公告)日：1996-05-21
申请号：US491632
申请日：1995-06-19
申请人： Thomas B. Smith , Scott A. Marino , Ronald J. Tache , David R. Day , Christian I. Tanzer , Tadd B. Hughes , Ajoy K. Roy
发明人： Thomas B. Smith , Scott A. Marino , Ronald J. Tache , David R. Day , Christian I. Tanzer , Tadd B. Hughes , Ajoy K. Roy
IPC分类号： G01R33/389 , G01R33/44 , G01R33/46 , G01V3/00
CPC分类号： G01R33/389 , G01N24/085 , G01N24/082 , G01R33/4625
摘要： A nuclear magnetic resonance (NMR) system, and related method, develops two or more regression equations or models for a particular polymer property of interest (e.g., melt index or MI) during a calibration procedure using known samples of a material. The polymer material can be, for example, a plastic (e.g., polyethylene, polypropylene, or polystyrene) or a rubber (e.g., ethylene propylene rubber). Regression models for one or more discrete (i.e., two-valued) variables also are developed during calibration, and these models allow a prediction to be made about which of the two or more property (e.g., MI) models should be used for any particular sample of unknown material. The prediction obtained from the discrete variable model indicates which of the two or more models will produce the most accurate estimation of the property of interest for the unknown sample. The best model is thus selected, and then it is used to estimate the property of interest.
摘要翻译：核磁共振（NMR）系统和相关方法在使用已知材料样品的校准过程期间针对特定的感兴趣的聚合物性质（例如熔体指数或MI）开发两个或多个回归方程或模型。聚合物材料可以是例如塑料（例如聚乙烯，聚丙烯或聚苯乙烯）或橡胶（例如乙丙橡胶）。在校准期间，还开发了一个或多个离散（即二值）变量的回归模型，这些模型允许对两个或多个属性（例如，MI）模型中的哪一个应用于任何特定的模型进行预测未知材料样品。从离散变量模型获得的预测表明两个或更多个模型中的哪一个将产生未知样本的关注属性的最准确估计。因此选择最佳模型，然后用于估计感兴趣的属性。

5. 发明授权

US5319308A Real time magnetic resonance analysis with non-linear regression means 失效
标题翻译：实时磁共振分析采用非线性回归方法
公开(公告)号：US5319308A
公开(公告)日：1994-06-07
申请号：US959739
申请日：1992-10-13
申请人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ronald J. Tache , Ajoy Roy
发明人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ronald J. Tache , Ajoy Roy
IPC分类号： G01R33/31 , G01R33/44 , G01R33/46 , G01R33/20
CPC分类号： G01R33/31 , G01N24/085 , G01N24/082 , G01R33/4625
摘要： A pulsed NMR analysis system and process comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which components functions are determined using non-linear regression techniques to correlate the curve components to the target nuclei.
摘要翻译：包括采样吞吐量系统（P，LI，V1，V2）和用户系统控制（104）的脉冲NMR分析系统和过程以建立数字化的自由感应衰减曲线（C），使用非线性回归技术来确定组分函数将曲线分量与目标细胞核相关联。

6. 发明授权

US5530350A Magnetic resonance analysis in real time, industrial usage mode 失效
标题翻译：实时磁共振分析，工业使用模式
公开(公告)号：US5530350A
公开(公告)日：1996-06-25
申请号：US370862
申请日：1995-01-10
申请人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ajoy K. Roy
发明人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ajoy K. Roy
IPC分类号： G01R33/32 , G01R33/389 , G01R33/44 , G01R33/46 , G01V3/00
CPC分类号： G01N24/085 , G01R33/389 , G01N24/082 , G01R33/4625
摘要： Pulsed NMR system for industrial measurements comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which Abragam, Gaussian, and exponential components are determined using a Marquardt-Levenberg iteration technique, and using regression techniques to correlate the curve components to the target nuclei.
摘要翻译：用于工业测量的脉冲NMR系统包括采样吞吐系统（P，LI，V1，V2）和用户系统控制（104）以建立数字化的自由感应衰减曲线（C），从其中确定Abragam，高斯和指数分量 Marquardt-Levenberg迭代技术，并使用回归技术将曲线分量与目标核相关联。

7. 发明授权

US5302896A Magnetic resonance analysis in real time industrial usage mode 失效
标题翻译：磁共振分析实时工业使用模式
公开(公告)号：US5302896A
公开(公告)日：1994-04-12
申请号：US794931
申请日：1991-11-20
申请人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ajoy K. Roy
发明人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino , Ajoy K. Roy
IPC分类号： G01R33/389 , G01R33/44 , G01R33/46 , G01R33/20
CPC分类号： G01N24/085 , G01R33/389 , G01N24/082 , G01R33/4625
摘要： Pulsed NMR system for industrial measurements comprising sample throughout system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which Abragam, Gaussianand exponential components are determined using a Marquardt-Levenberg iteration technique, and using regression techniques to correlate the curve components to the target nuclei.
摘要翻译：用于工业测量的脉冲NMR系统包括整个系统（P，LI，V1，V2）和用户系统控制（104）中的样本，以建立数字化的自由感应衰减曲线（C），使用Marquardt- Levenberg迭代技术，并使用回归技术将曲线分量与目标细胞核相关联。

8. 发明授权

US5302897A NMR analysis of polypropylene in real time 失效
标题翻译：实时聚丙烯的NMR分析
公开(公告)号：US5302897A
公开(公告)日：1994-04-12
申请号：US885633
申请日：1992-05-19
申请人： Ronald J. Tache , Ajoy Roy , Ronald L. Dechene , Thomas B. Smith , Scott A. Marino
发明人： Ronald J. Tache , Ajoy Roy , Ronald L. Dechene , Thomas B. Smith , Scott A. Marino
IPC分类号： G01R33/389 , G01R33/44 , G01R33/46 , G01R33/20
CPC分类号： G01N24/085 , G01R33/389 , G01N24/082 , G01R33/4625
摘要： Pulsed NMR system for industrial measurements comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay (FID) curves (C), from which fast Gaussian, slower modified Gaussian and exponential components are determined using a Marquardt-Levenberg iteration technique, and using regression techniques to correlate the FID curve components to the physical quantities of the target nuclei.
摘要翻译：用于工业测量的脉冲NMR系统包括采样吞吐量系统（P，LI，V1，V2）和用户系统控制（104）以建立数字化自由感应衰减（FID）曲线（C），从其中快速高斯，较慢修正的高斯和指数使用Marquardt-Levenberg迭代技术确定组分，并使用回归技术将FID曲线组分与目标核的物理量相关联。

9. 发明授权

US5015954A Magnetic resonance analysis in real time, industrial usage mode 失效
标题翻译：实时磁共振分析，工业使用模式
公开(公告)号：US5015954A
公开(公告)日：1991-05-14
申请号：US374493
申请日：1989-06-30
申请人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino
发明人： Ronald L. Dechene , Thomas B. Smith , Scott A. Marino
IPC分类号： G01R33/31 , G01R33/44
CPC分类号： G01R33/31 , G01N24/085
摘要： Magnestic resonance system for industrial purposes comprising sample throughput system (P, LI, V1, V2) magnetic field adjustment (120, 124) and thermal adjustment (134-138 and 142-146). The resonance is established by a coil (100), excited by a transceiver (104) and interacting with the sample and the magnetic field at resonance to establish received and digitized free induction decay curve forms (C) which are synthesized into bound (Gaussian) and unbound (exponential) components--pairing simplified high speed computation means with repetitive test sequence and thermal controls that systematically minimize errors to assure reliable determination of target nuclei quantities in successive samples from an industrial process.
摘要翻译：用于工业目的的大气共振系统包括样品通量系统（P，LI，V1，V2）磁场调节（120,124）和热调节（134-138和142-146）。共振由线圈（100）建立，由收发器（104）激发并与样品和磁场在共振处相互作用以建立接收和数字化的自由感应衰减曲线形式（C），其被合成为约束（高斯）和非绑定（指数）组件 - 配对简化的高速计算装置，具有重复的测试序列和热控制，系统地最小化误差，以确保来自工业过程的连续样品中目标核数量的可靠确定。

10. 发明授权

US5396806A On-line mass flow measurement in flowing two component systems 失效
标题翻译：流动双组分系统中的在线质量流量测量
公开(公告)号：US5396806A
公开(公告)日：1995-03-14
申请号：US150961
申请日：1993-11-12
申请人： Ronald L. Dechene , David R. Day , Thomas B. Smith
发明人： Ronald L. Dechene , David R. Day , Thomas B. Smith
IPC分类号： B01J8/00 , G01F1/64 , G01F1/708 , G01F1/712 , G01F1/74 , G01N27/22
CPC分类号： G01N27/221 , B01J8/001 , B01J8/0015 , G01F1/64 , G01F1/7088 , G01F1/712 , G01F1/74
摘要： Apparatus and process for measuring mass flow of a slurry mixture of two components of materials, such as a flow of catalyst solid particles (the first component) or droplets in a fluid carrier (the second component). The slurry mixture is added to a process stream (10) or batch reactor. The flow velocity and the volume fraction of one component are measured and combined with the known specific gravity, of the component being measured, and the physical dimensions of the pipe, in which the slurry mixture is flowing, to determine the mass flow of the component. The flow velocity is measured by correlating signals at two separated locations along the flow path, and the volume fraction is measured by combining the known dielectric constants of each of the materials in the mixture and the measured capacitance of the mixture. The capacitance is measured from electrodes which may be isolated from the flowing materials in some applications, but not isolated from the flowing materials in other applications. The temperature (9) and pressure (11) are compensated in the final calculation, and the mass flow result is used to control, via feedback, the amount of such materials delivered. Also, a subtraction technique to remove interfering power line noise is implemented to improve sensitivity.
摘要翻译：用于测量材料的两种组分的浆料混合物的质量流量的装置和方法，例如流体载体（第二组分）中的催化剂固体颗粒（第一组分）或液滴的流动。将浆料混合物加入到工艺流（10）或间歇式反应器中。测量一个组分的流速和体积分数，并与所测量的组分的已知比重和浆料混合物流动的管的物理尺寸相结合以确定组分的质量流量。通过在沿着流动路径的两个分开的位置处相关联信号来测量流速，并且通过组合混合物中每种材料的已知介电常数和混合物的测量电容来测量体积分数。从一些应用中可以从流动材料中分离的电极测量电容，但在其它应用中不与流动材料隔离。在最终计算中补偿温度（9）和压力（11），质量流量结果用于通过反馈控制所输送的材料的数量。此外，实施用于消除干扰电力线噪声的减法技术来提高灵敏度。

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