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    • 1. 发明申请
    • Crosslinkable Vinyl Fluoride Copolymer Coated Film and Process for Making Same
    • 可交联乙烯基氟共聚物涂膜及其制造方法
    • US20080156367A1
    • 2008-07-03
    • US11962135
    • 2007-12-21
    • Ronald Earl UscholdJian WangMasahiro Yamamoto
    • Ronald Earl UscholdJian WangMasahiro Yamamoto
    • H01L31/0216B05D5/12B32B27/08
    • C08F214/20C08F214/18C08F214/202Y10T428/2495Y10T428/24967Y10T428/26Y10T428/263Y10T428/264Y10T428/265Y10T428/266Y10T428/269Y10T428/3154Y10T428/31544Y10T428/31721Y10T428/31725Y10T428/3175Y10T428/31794Y10T428/31797Y10T428/31935
    • The invention provides a fluoropolymer coated film comprising: a polymeric substrate film; and a fluoropolymer coating on the polymeric substrate film, the fluoropolymer coating comprising a vinyl fluoride copolymer comprised of about 40 to about 90 mole % of repeat units derived from vinyl fluoride and about 10 to about 60 mole % of repeat units derived from monomer selected from the group consisting of (a) and (b) below and mixtures thereof, with the proviso that about 0.1 mole % to 50 mole % of repeat units in the copolymer are derived from monomer selected from (b): (a) monomer selected from the group consisting of, tetrafluoroethylene, trifluoroethylene, chlorotrifluoroethylene and mixtures thereof; and (b) vinyl monomer containing at least one functional group selected from the group consisting of hydroxyls, thiols, carbonyls, carboxylic acids, carboxylic esters, acid anhydrides, sulfonyls, sulfonic acids, sulfonic esters, phosphoric acids, phosphoric esters, boric acids, boric esters, epoxies, isocyanates, thiocyanates, amines, amides, nitriles and halogen selected from bromide and iodide, wherein the polymeric substrate film comprises functional groups that interact with the functional groups of the vinyl fluoride copolymer to promote bonding of the fluoropolymer coating to the polymeric substrate film.
    • 本发明提供一种含氟聚合物涂覆膜,包括:聚合物基底膜; 和含氟聚合物涂层,所述含氟聚合物涂层包含由约40至约90摩尔%的衍生自氟乙烯的重复单元和约10至约60摩尔%的衍生自选自以下的单体的重复单元组成的氟乙烯共聚物: 由(a)和(b)组成的组和其混合物,共聚物中约0.1摩尔%至50摩尔%的重复单元衍生自选自(b)的单体:(a)选自 由四氟乙烯,三氟乙烯,一氯三氟乙烯及其混合物组成的组; 和(b)含有至少一种选自羟基,硫醇,羰基,羧酸,羧酸酯,酸酐,磺酰基,磺酸,磺酸酯,磷酸,磷酸酯,硼酸等的官能团的乙烯基单体, 硼酸酯,环氧化物,异氰酸酯,硫氰酸酯,胺,酰胺,腈和选自溴化物和碘化物的卤素,其中聚合物基底膜包含与氟乙烯共聚物的官能团相互作用以促进含氟聚合物涂层与 聚合物基底膜。
    • 3. 发明授权
    • Crosslinkable vinyl fluoride copolymer coated film and process for making same
    • 可交联的氟乙烯共聚物涂膜及其制备方法
    • US08124221B2
    • 2012-02-28
    • US11962135
    • 2007-12-21
    • Ronald Earl UscholdJian WangMasahiro Yamamoto
    • Ronald Earl UscholdJian WangMasahiro Yamamoto
    • C08F14/20B32B7/04B32B27/28B32B27/34B32B27/36
    • C08F214/20C08F214/18C08F214/202Y10T428/2495Y10T428/24967Y10T428/26Y10T428/263Y10T428/264Y10T428/265Y10T428/266Y10T428/269Y10T428/3154Y10T428/31544Y10T428/31721Y10T428/31725Y10T428/3175Y10T428/31794Y10T428/31797Y10T428/31935
    • The invention provides a fluoropolymer coated film comprising: a polymeric substrate film; and a fluoropolymer coating on the polymeric substrate film, the fluoropolymer coating comprising a vinyl fluoride copolymer comprised of about 40 to about 90 mole % of repeat units derived from vinyl fluoride and about 10 to about 60 mole % of repeat units derived from monomer selected from the group consisting of (a) and (b) below and mixtures thereof, with the proviso that about 0.1 mole % to 50 mole % of repeat units in the copolymer are derived from monomer selected from (b): (a) monomer selected from the group consisting of, tetrafluoroethylene, trifluoroethylene, chlorotrifluoroethylene and mixtures thereof; and (b) vinyl monomer containing at least one functional group selected from the group consisting of hydroxyls, thiols, carbonyls, carboxylic acids, carboxylic esters, acid anhydrides, sulfonyls, sulfonic acids, sulfonic esters, phosphoric acids, phosphoric esters, boric acids, boric esters, epoxies, isocyanates, thiocyanates, amines, amides, nitriles and halogen selected from bromide and iodide, wherein the polymeric substrate film comprises functional groups that interact with the functional groups of the vinyl fluoride copolymer to promote bonding of the fluoropolymer coating to the polymeric substrate film.
    • 本发明提供一种含氟聚合物涂覆膜,包括:聚合物基底膜; 和含氟聚合物涂层,所述含氟聚合物涂层包含由约40至约90摩尔%的衍生自氟乙烯的重复单元和约10至约60摩尔%的衍生自选自以下的单体的重复单元组成的氟乙烯共聚物: 由(a)和(b)组成的组和其混合物,共聚物中约0.1摩尔%至50摩尔%的重复单元衍生自选自(b)的单体:(a)选自 由四氟乙烯,三氟乙烯,一氯三氟乙烯及其混合物组成的组; 和(b)含有至少一种选自羟基,硫醇,羰基,羧酸,羧酸酯,酸酐,磺酰基,磺酸,磺酸酯,磷酸,磷酸酯,硼酸等的官能团的乙烯基单体, 硼酸酯,环氧化物,异氰酸酯,硫氰酸酯,胺,酰胺,腈和选自溴化物和碘化物的卤素,其中聚合物基底膜包含与氟乙烯共聚物的官能团相互作用以促进含氟聚合物涂层与 聚合物基底膜。
    • 7. 发明授权
    • Process for making vinyl fluoride interpolymers and dispersions thereof
    • 制备氟乙烯互聚物及其分散体的方法
    • US07378475B2
    • 2008-05-27
    • US10095922
    • 2002-03-11
    • Ronald Earl Uschold
    • Ronald Earl Uschold
    • C08F4/04
    • C08F214/18C08F214/20C08F214/26Y10S250/909Y10T428/3154
    • Interpolymers of 1-99 mol % vinyl fluoride and 99-1 mol % of at least one highly fluorinated monomer such as tetrafluoroethylene are disclosed. The interpolymers are characterized by the presence of ionic end groups and are prepared by polymerizing VF and fluorinated monomer in water with water-soluble free-radical initiators such as azoamidine initiators or persulfate initiators at temperatures within the range of 60 to 100° C. and reactor pressures within the range of 1 to 12 MPa (145 to 1760 psi). The invention further provides for protective self-supporting films and coatings formed from nonaqueous dispersions of the interpolymers, both for use on the surfaces of substrates including metal, plastic, ceramic, glass, concrete, fabric and wood.
    • 公开了1-99mol%乙烯基氟化物和99-1mol%的至少一种高度氟化的单体如四氟乙烯的共聚物。 互聚物的特征在于存在离子端基,并且通过在水中与水溶性自由基引发剂如偶氮脒引发剂或过硫酸盐引发剂在60至100℃的温度范围内聚合VF和氟化单体来制备, 反应器压力在1至12MPa(145至1760psi)的范围内。 本发明还提供了保护性自支撑膜和由互聚物的非水分散体形成的涂层,两者用于包括金属,塑料,陶瓷,玻璃,混凝土,织物和木材在内的表面。