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1. 发明授权

US5945571A Preparation of 1,4-butanediol 失效
标题翻译： 1,4-丁二醇的制备
公开(公告)号：US5945571A
公开(公告)日：1999-08-31
申请号：US765577
申请日：1996-12-27
申请人： Rolf Pinkos , Rolf Fischer , Boris Breitscheidel , Peter Polanek
发明人： Rolf Pinkos , Rolf Fischer , Boris Breitscheidel , Peter Polanek
IPC分类号： B01J23/36 , B01J23/46 , B01J23/72 , C07B61/00 , C07C29/10 , C07C29/132 , C07C29/14 , C07C31/20 , C07L27/00
CPC分类号： C07C31/20 , C07C29/132
摘要： Described is a method of producing 1,4-butanediol, the method calling for 2,3-dihydrofuran to be decomposed in a single stage over a hydrogenation catalyst in the presence of water and hydrogen at a temperature of 20 to 300.degree. C. and a pressure of 1 to 300 bar and in neutral or acid conditions.
摘要翻译： PCT No.PCT / EP95 / 02335 Sec。 371日期1996年12月27日第 102（e）日期1996年12月27日PCT归档1995年6月16日PCT公布。公开号WO96 / 00203 日本1996年1月4日描述了一种生产1,4-丁二醇的方法，该方法要求在氢和氢气存在下，在氢化催化剂中，在20〜 300℃，压力为1至300巴，处于中性或酸性条件下。

2. 发明授权

US5981769A Process for preparing 1,6- hexanediol and caprolactone 有权
标题翻译：制备1,6-己二醇和己内酯的方法
公开(公告)号：US5981769A
公开(公告)日：1999-11-09
申请号：US125974
申请日：1998-08-28
申请人： Karl Gerhard Baur , Rolf Fischer , Rolf Pinkos , Frank Stein , Boris Breitscheidel , Harald Rust
发明人： Karl Gerhard Baur , Rolf Fischer , Rolf Pinkos , Frank Stein , Boris Breitscheidel , Harald Rust
IPC分类号： C07D313/04 , C07C27/12 , C07C29/149 , C07C29/80 , C07C29/88 , C07C31/20 , C07C31/27 , C07C51/31 , C07D315/00 , C07D313/00
CPC分类号： C07D315/00 , C07C29/149 , C07C29/80 , C07C29/88 , C07C51/313 , C07C2101/14
摘要： 1,6-hexanediol and .epsilon.-caprolactone are prepared from a carboxylic acid mixture comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols which is obtained as a by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol using oxygen or oxygen-containing gases by water extraction of the reaction mixture, by esterifying and hydrogenating a substream to give hexanediol and cyclizing 6-hydroxycaproic esters to give caprolactone.
摘要翻译： PCT No.PCT / EP97 / 00990 371日期1998年8月28日 102（e）1998年8月28日PCT PCT 1997年2月28日PCT公布。公开号WO97 / 31883 日期1991年9月4日，1991年6月 - 己二醇和ε-己内酯由包含己二酸，6-羟基己酸和少量1,4-环己二醇的羧酸混合物制备，其作为副产物在氧化使用氧或含氧气体通过水提取反应混合物，通过酯化和氢化子流，得到己二醇并环化6-羟基己酸酯，得到己内酯，得到环己烷至环己酮/环己醇。

3. 发明授权

US6008418A Process for preparing 1,6 hexanediol with a level of purity over 99% 有权
标题翻译：制备纯度超过99％的1,6己二醇的方法
公开(公告)号：US6008418A
公开(公告)日：1999-12-28
申请号：US125976
申请日：1998-08-28
申请人： Karl Gerhard Baur , Rolf Fischer , Rolf Pinkos , Frank Stein , Harald Rust , Boris Breitscheidel
发明人： Karl Gerhard Baur , Rolf Fischer , Rolf Pinkos , Frank Stein , Harald Rust , Boris Breitscheidel
IPC分类号： B01J23/80 , B01J23/889 , C07B61/00 , C07C29/149 , C07C31/20
CPC分类号： C07C29/149
摘要： 1,6-Hexanediol is prepared from a carboxylic acid mixture comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols which is obtained as a by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol by water extraction of the reaction mixture, by esterification of the acids and hydrogenation whereina) the monocarboxylic and dicarboxylic acids present in the aqueous dicarboxylic acid mixture are reacted with a low molecular weight alcohol to give the corresponding carboxylic esters,b) the resulting esterification mixture is freed of excess alcohol and low boilers in a first distillation stage,c) the bottoms are fractionated in a second distillation stage to give an ester fraction essentially free of 1,4-cyclohexanediols and a fraction comprising at least the major part of the 1,4-cyclohexanediols,d) the ester fraction essentially free of 1,4-cyclohexanediols is catalytically hydrogenated ande) in a pure distillation stage, 1,6-hexanediol is isolated from the hydrogenation product in a manner known per se.
摘要翻译： PCT No.PCT / EP97 / 00980 Sec。 371日期1998年8月28日 102（e）1998年8月28日PCT PCT 1997年2月28日PCT公布。公开号WO97 / 31882 日期1991年9月4日6,6-己二醇由包含己二酸，6-羟基己酸和少量1,4-环己二醇的羧酸混合物制备，其作为副产物在环己烷氧化成环己酮/ 环己醇通过水提取反应混合物，通过酸的酯化和氢化，其中存在于二羧酸水溶液混合物中的单羧酸和二羧酸与低分子量醇反应得到相应的羧酸酯，b）得到的酯化混合物在第一蒸馏阶段中不含过量的醇和低沸点，c）在第二蒸馏阶段对塔底物进行分馏，得到基本上不含1,4-环己烷二醇的酯馏分和至少包含至少大部分 1,4-环己烷二醇，d）基本上不含1,4-环己烷二醇的酯馏分是催化氢化的，e）在纯蒸馏阶段，以本身已知的方式从加氢产物中分离出1,6-己二醇。

4. 发明授权

US5536691A Cobalt catalysts and a process required for their preparation 失效
标题翻译：钴催化剂及其制备所需的工艺
公开(公告)号：US5536691A
公开(公告)日：1996-07-16
申请号：US269060
申请日：1994-06-30
申请人： Boris Breitscheidel , Peter Polanek , Matthias Irgang , Hermann Petersen , Gerd Linden , Guido Voit , Tom Witzel
发明人： Boris Breitscheidel , Peter Polanek , Matthias Irgang , Hermann Petersen , Gerd Linden , Guido Voit , Tom Witzel
IPC分类号： B01J23/889 , B01J27/185 , B01J27/187 , C07B61/00 , C07C209/48 , C07C209/50 , C07C211/36 , B01J23/04 , B01J23/34 , B01J23/78
CPC分类号： C07C209/50 , B01J23/8892 , B01J27/1853 , B01J27/187 , C07C2101/14
摘要： Cobalt catalysts whose catalytically active material comprises from 55 to 98 wt % of cobalt, from 0.2 to 15 wt % of phosphorus, from 0.2 to 15 wt % of manganese, and from 0.2 to 15 wt % of alkali metal, calculated as oxide, in which the catalyst material is calcined in a first step at final temperatures of from 550.degree. to 750.degree. C. and in a second step at final temperatures of from 800.degree. to 1000.degree. C., and a process for the hydrogenation of organic nitriles and/or imines, in which the novel cobalt catalyst is used.
摘要翻译：钴催化剂，其催化活性材料包含55至98重量％的钴，0.2至15重量％的磷，0.2至15重量％的锰和0.2至15重量％的以氧化物计算的碱金属，催化剂材料在最终温度为550℃至750℃的第一步骤中煅烧，第二步在最终温度为800至1000℃下煅烧，以及有机腈的氢化方法和 /或亚胺，其中使用新的钴催化剂。

5. 发明授权

US07084312B1 Catalyst and method for hydrogenating carbonyl compounds 有权
标题翻译：氢化羰基化合物的催化剂和方法
公开(公告)号：US07084312B1
公开(公告)日：2006-08-01
申请号：US10070275
申请日：2000-08-22
申请人： Sylvia Huber , Michael Jolyon Sprague , Boris Breitscheidel , Joachim Wulff-Döring , Michael Hesse , Rolf Pinkos , Shelue Liang , Otto Kumberger , Marc Walter
发明人： Sylvia Huber , Michael Jolyon Sprague , Boris Breitscheidel , Joachim Wulff-Döring , Michael Hesse , Rolf Pinkos , Shelue Liang , Otto Kumberger , Marc Walter
IPC分类号： C07C29/136 , C07C29/14 , C07C29/141 , C07C29/143 , C07C29/147
CPC分类号： B01J23/80 , C07C29/149 , C07C31/20
摘要： A process for the hydrogenation of an organic compound containing at least one carbonyl group comprises bringing the organic compound in the presence of hydrogen into contact with a shaped body which can be produced by a process in which (i) an oxidic material comprising copper oxide, zinc oxide and aluminum oxide is made available, (ii) pulverulent metallic copper or pulverulent cement or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to form a shaped body.
摘要翻译：氢化含有至少一个羰基的有机化合物的方法包括使氢存在下的有机化合物与成形体接触，成形体可以通过以下工艺制备，其中（i）包含氧化铜的氧化物，提供氧化锌和氧化铝，（ii）将粉末状金属铜或粉状水泥或其混合物加入到氧化物中，和（iii）由（ii）得到的混合物成形为成形体。

6. 发明授权

US06284917B1 Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores 有权
公开(公告)号：US06284917B1
公开(公告)日：2001-09-04
申请号：US09581843
申请日：2000-06-19
申请人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
发明人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
IPC分类号： C07C6974
CPC分类号： C08K5/12 , C07C51/36 , C07C67/303 , C07C69/75 , C07C2601/14 , C07C61/09
摘要： A process for hydrogenating a benzenepolycarboxylic acid or a derivative thereof or a mixture of two or more thereof by bringing the benzenepolycarboxylic acid or the derivative thereof or the mixture of two or more thereof into contact with a hydrogen-containing gas is carried out in the presence of a catalyst which comprises as active metal at least one metal of transition group VIII of the Periodic Table alone or together with at least one metal of transition group I or VII of the periodic table applied to a support which contains macropores with the proviso that if dimethyl terephthalate is hydrogenated, the hydrogenation using a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table applied to a support, where the support has a mean pore diameter of at least 50 nm and a BET surface area of at most 30 m2/g and the amount of the active metal is from 0.01 to 30% by weight, based on the total weight of the catalyst, and the ratio of the surface areas of the active metal and the catalyst support is less than 0.05, and/or a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a support, where from 10 to 50% of the pore volume of the support is formed by macropores having a pore diameter in the range from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support is formed by mesopores having a pore diameter in the range from 2 to 50 nm, where the sum of the pore volumes adds up to 100%, is excluded, and novel hydrogenation products, obtainable by hydrogenating benzenepolycarboxylic acid (derivatives) as well as their use as plasticizers in plastics.

7. 发明授权

US06888021B2 Hydrogenation of benzenepolycarboxylic acids or derivatives thereof using a catalyst containing macropores 有权
标题翻译：使用含有大孔的催化剂氢化苯多元羧酸或其衍生物
公开(公告)号：US06888021B2
公开(公告)日：2005-05-03
申请号：US09879456
申请日：2001-06-13
申请人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
发明人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
IPC分类号： B01J23/46 , C07B61/00 , C07C51/36 , C07C61/08 , C07C61/09 , C07C67/303 , C07C69/75 , C08K5/12 , C07C69/74 , C07C69/66 , C08K5/09
CPC分类号： C08K5/12 , C07C51/36 , C07C67/303 , C07C69/75 , C07C2601/14 , C07C61/09
摘要： A process for producing plasticizers in which a phthalic acid having the CAS Nos. 111381-89-6, 111381-90-9, 111381-91-0, 68515-44-6, 68515-45-7 and 3648-20-7, the formed plasticizers and a method of increasing the plasticity of a plastic product.
摘要翻译：一种生产增塑剂的方法，其中具有CAS号111381-89-6,111381-90-9,111381-91-0,68515-44-6,68515-45-7和3648-20-7的邻苯二甲酸，形成的增塑剂和增加塑料制品的可塑性的方法。

8. 发明授权

US06407294B1 Method for producing 1,6-hexanediol 有权
标题翻译： 1,6-己二醇的制备方法
公开(公告)号：US06407294B1
公开(公告)日：2002-06-18
申请号：US09529789
申请日：2000-04-20
申请人： Boris Breitscheidel , Rolf Pinkos , Frank Stein , Shelue Liang , Rolf Hartmuth Fischer
发明人： Boris Breitscheidel , Rolf Pinkos , Frank Stein , Shelue Liang , Rolf Hartmuth Fischer
IPC分类号： C07C2700
CPC分类号： C07C29/149 , C07C2601/08 , C07C35/06 , C07C31/135 , C07C31/20
摘要： A process for producing 1,6-hexanediol by hydrogenation of adipic esters and/or 6-hydroxycaproic esters in the gas phase at elevated temperature and elevated pressure in the presence of chromium-free catalysts comprises hydrogenating a) over a catalyst comprising copper, manganese and aluminum as essential constituents or over Raney copper, b) at a temperature of from 150 to 230° C. and a pressure of from 10 to 70 bar, c) at a molar ratio of hydrogen to ester to be hydrogenated within the range from 150:1 to 300:1, and d) at a catalyst space velocity of from 0.01 to 0.3 kg of C6 ester per liter of catalyst per hour.
摘要翻译：在无铬催化剂存在下，在升高的温度和升高的压力下，气相中己二酸酯和/或6-羟基己酸酯的氢化制备1,6-己二醇的方法包括在包含铜，锰和铝作为必需组分或在阮内铜上，b）在150-230℃的温度和10至70巴的压力下，c）以氢化至酯的摩尔比在150℃的范围内：1至300:1，和d），催化剂空速为每升催化剂每小时0.01至0.3kg的C6酯。

9. 发明授权

US06313358B1 Method for producing hexanediol 失效
标题翻译：己二醇的制备方法
公开(公告)号：US06313358B1
公开(公告)日：2001-11-06
申请号：US09673125
申请日：2000-10-11
申请人： Boris Breitscheidel , Rolf Pinkos , Frank Stein
发明人： Boris Breitscheidel , Rolf Pinkos , Frank Stein
IPC分类号： C07C2700
CPC分类号： B01J23/72 , C07C29/149 , C07C67/60 , C07C2601/14 , C07C69/44 , C07C31/20 , C07C35/14
摘要： Hexanediol is prepared by hydrogenating dialkyl adipates or mixtures which contain a dialkyl adipate as the essential component and organic halogen compounds as impurities, by a process in which, before the hydrogenation, the dialkyl adipates or the mixtures containing dialkyl adipates are passed at from 50 to 250° C. and from 1 to 100 bar over copper catalysts which have a copper content, calculated as CuO, of from 0.5 to 80% by weight, a surface area of from 5 to 1500 m2/g, a porosity of from 0.05 to 1.5 cm3/g and a copper surface area of from 0.1 to 20 m2/g, in order to remove the organic halogen compounds.
摘要翻译：通过以下方法将含己二酸二烷基酯的二烷基己二酸酯或其混合物加氢制备，其中氢化前，己二酸二烷基酯或含有己二酸二烷基酯的混合物在50至 250℃和1至100巴，铜铜催化剂的铜含量（按CuO计）为0.5至80重量％，表面积为5至1500平方米/克，孔隙率为0.05至 1.5cm 3 / g，铜表面积为0.1〜20m 2 / g，以除去有机卤素化合物。

10. 发明授权

US5696048A Cobalt catalysts 失效
标题翻译：钴催化剂
公开(公告)号：US5696048A
公开(公告)日：1997-12-09
申请号：US641278
申请日：1996-04-30
申请人： Boris Breitscheidel , Peter Polanek , Guido Voit , Tom Witzel , Gerd Linden , Michael Hesse
发明人： Boris Breitscheidel , Peter Polanek , Guido Voit , Tom Witzel , Gerd Linden , Michael Hesse
IPC分类号： B01J23/889 , B01J27/185 , B01J27/187 , C07B61/00 , C07C209/48 , C07C209/52 , C07C211/03
CPC分类号： B01J23/8892 , B01J27/1853 , B01J27/187 , C07C209/48
摘要： Cobalt catalysts whose catalytically active composition comprises from 55 to 98% by weight of cobalt, from 0.2 to 15% by weight of phosphorus, from 0.2 to 15% by weight of manganese and from 0.05 to 5% by weight of alkali metal, calculated as oxide, are prepared by calcining the catalyst composition, reducing it at final temperatures of from 200.degree. to 400.degree. C. in a stream of hydrogen and subsequently surface-oxidizing it by treatment in a stream of air at final temperatures of from 20.degree. to 60.degree. C. and can be used in a process for hydrogenating organic nitriles and/or imines.
摘要翻译：钴催化剂，其催化活性组合物包含55至98重量％的钴，0.2至15重量％的磷，0.2至15重量％的锰和0.05至5重量％的碱金属，计算为氧化物通过煅烧催化剂组合物，在氢气流中在200-400℃的最终温度下还原，然后在最终温度为20℃至大约20℃的空气流中进行表面氧化， 60℃，可用于氢化有机腈和/或亚胺的方法。

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