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1. 发明申请

US20100240913A1 PROCESS FOR PREPARING EPSILON-CAPROLACTONE 有权
标题翻译：制备EPSILON-CAPROLACTONE的方法
公开(公告)号：US20100240913A1
公开(公告)日：2010-09-23
申请号：US12741383
申请日：2008-10-28
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C. Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C. Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
IPC分类号： C07D313/02
CPC分类号： C07D313/04
摘要： The present invention provides a process for preparing ε-caprolactone in a purity of more than 99% by cyclizing 6-hydroxycaproic esters in the liquid phase at from 150 to 400° C. and from 1 to 1020 hPa abs., and removing and condensing the compounds which are volatile under cyclization conditions, which comprises thermally treating the remaining bottom product of the cyclization in at least one further reactor, removing and condensing volatile compounds and obtaining ε-caprolactone by distillation from the condensates.
摘要翻译：本发明提供一种制备纯度大于99％的己内酯的方法，其通过在150至400℃和1至1020hPa绝对压力下使液相中的6-羟基己酸酯环化，冷凝在环化条件下挥发的化合物，其包括在至少一个另外的反应器中热处理剩余的环化的底部产物，除去和冷凝挥发性化合物，并通过从冷凝物蒸馏获得ε-己内酯。

2. 发明授权

US08247580B2 Process for preparing ε-caprolactone 有权
标题翻译：己内酯的制备方法
公开(公告)号：US08247580B2
公开(公告)日：2012-08-21
申请号：US12741383
申请日：2008-10-28
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
IPC分类号： C07D313/00
CPC分类号： C07D313/04
摘要： The present invention provides a process for preparing ε-caprolactone in a purity of more than 99% by cyclizing 6-hydroxycaproic esters in the liquid phase at from 150 to 400° C. and from 1 to 1020 hPa abs., and removing and condensing the compounds which are volatile under cyclization conditions, which comprises thermally treating the remaining bottom product of the cyclization in at least one further reactor, removing and condensing volatile compounds and obtaining ε-caprolactone by distillation from the condensates.
摘要翻译：本发明提供了通过在150至400℃和1至1020hPa绝对压力下使液相中的6-羟基己酸酯环化来制备纯度大于99％的己内酯的方法，冷凝在环化条件下挥发的化合物，其包括在至少一个另外的反应器中热处理剩余的环化的底部产物，除去和冷凝挥发性化合物，并通过从冷凝物蒸馏获得ε-己内酯。

3. 发明申请

US20100256398A1 PROCESS FOR PREPARING EPSILON-CAPROLACTONE 失效
标题翻译：制备EPSILON-CAPROLACTONE的方法
公开(公告)号：US20100256398A1
公开(公告)日：2010-10-07
申请号：US12746680
申请日：2008-12-10
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
IPC分类号： C07D313/04
CPC分类号： C07D313/04
摘要： The invention relates to a process for preparing ε-caprolactone from 6-hydroxycaproic ester in the gas phase in the presence of activated carbon as a catalyst and subsequent distillation.
摘要翻译：本发明涉及一种在活性炭作为催化剂存在下随后蒸馏的在气相中由6-羟基己酸酯制备ε-己内酯的方法。

4. 发明申请

US20080207958A1 Method For Production Of 1,6-Hexanediol With A Purity In Excess of 99.5% 失效
标题翻译： 1,6-己二醇生产方法纯度超过99.5％
公开(公告)号：US20080207958A1
公开(公告)日：2008-08-28
申请号：US10569980
申请日：2005-07-07
申请人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
发明人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
IPC分类号： C07C29/143
CPC分类号： C07C29/145 , C07C29/149 , C07C2601/14 , C07C31/20 , C07C35/08
摘要： The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
摘要翻译：本发明提供了一种通过以下方式制备1,6-己二醇的方法：通过以下方法将氢化己二酸二烷基酯，6-羟基己酸烷基酯，1,4-环己二酮和4-羟基环己烷-1-酮作为包含杂质的酯混合物，在第一蒸馏阶段（醇去除）中的过量醇和低锅炉的b），b）在第二蒸馏阶段中将底部产物分离成基本上不含1,4-环己二醇的酯馏分和至少包含大部分1,4-环己烷二醇，c）催化氢化基本上不含1,4-环己二醇的酯馏分（酯氢化）和d）在纯化蒸馏阶段，以一种方式从氢化流出物中获得1,6-己二醇本身已知，其包括在阶段a）和/或阶段b）之前选择性地氢化酯混合物（纯化氢化）。

5. 发明授权

US08217186B2 Process for preparing epsilon-caprolactone 失效
标题翻译：制备ε-己内酯的方法
公开(公告)号：US08217186B2
公开(公告)日：2012-07-10
申请号：US12746680
申请日：2008-12-10
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
IPC分类号： C07D313/00
CPC分类号： C07D313/04
摘要： The invention relates to a process for preparing ε-caprolactone from 6-hydroxycaproic ester in the gas phase in the presence of activated carbon as a catalyst and subsequent distillation.
摘要翻译：本发明涉及一种在活性炭作为催化剂存在下随后蒸馏的在气相中由6-羟基己酸酯制备ε-己内酯的方法。

6. 发明授权

US07449609B2 Method for production of 1,6-hexanediol with a purity in excess of 99.5% 失效
标题翻译：制备纯度超过99.5％的1,6-己二醇的方法
公开(公告)号：US07449609B2
公开(公告)日：2008-11-11
申请号：US10569980
申请日：2005-07-07
申请人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
发明人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
IPC分类号： C07C29/149
CPC分类号： C07C29/145 , C07C29/149 , C07C2601/14 , C07C31/20 , C07C35/08
摘要： The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
摘要翻译：本发明提供了一种通过以下方式制备1,6-己二醇的方法：通过以下方法将氢化己二酸二烷基酯，6-羟基己酸烷基酯，1,4-环己二酮和4-羟基环己烷-1-酮作为包含杂质的酯混合物，在第一蒸馏阶段（醇去除）中的过量醇和低锅炉的b），b）在第二蒸馏阶段中将底部产物分离成基本上不含1,4-环己烷二醇的酯馏分和至少包含大部分1,4-环己烷二醇，c）催化氢化基本上不含1,4-环己二醇的酯馏分（酯氢化）和d）在纯化蒸馏阶段，以一种方式从氢化流出物中获得1,6-己二醇本身已知，其包括在阶段a）和/或阶段b）之前选择性地氢化酯混合物（纯化氢化）。

7. 发明授权

US08759594B2 Method for producing 1,6-hexanediol by hydrogenation of oligo- and polyesters 有权
标题翻译：低聚和聚酯氢化生产1,6-己二醇的方法
公开(公告)号：US08759594B2
公开(公告)日：2014-06-24
申请号：US13258207
申请日：2010-03-29
申请人： Olivier Abillard , Rolf Pinkos , Gerd-Dieter Tebben , Tilman Sirch , Daniel Urbanczyk , Heiko Urtel , Rolf Tompers
发明人： Olivier Abillard , Rolf Pinkos , Gerd-Dieter Tebben , Tilman Sirch , Daniel Urbanczyk , Heiko Urtel , Rolf Tompers
IPC分类号： C07C27/00
CPC分类号： C07C45/33 , C07C29/149 , C07C29/50 , C07C51/313 , C07C67/08 , C07C2601/14 , C07C31/20 , C07C35/08 , C07C49/403 , C07C55/14 , C07C69/44
摘要： The present invention relates to a process for hydrogenating oligo- and/or polyesters obtainable by esterifying a DCS with a diol or diol mixture, said hydrogenation being performed in the presence of a catalyst whose catalyst precursor comprises copper oxide, aluminum oxide and at least one oxide of lanthanum, of iron, of tungsten, of molybdenum, of titanium or of zirconium, and to a process for preparing 1,6-hexanediol by catalytically hydrogenating ester mixtures which comprise, as main components, oligo- and polyesters of adipic acid and 6-hydroxycaproic acid, and are obtained by esterifying DCS with diols, especially 1,6-hexanediol or diol mixtures.
摘要翻译：本发明涉及一种氢化通过用二醇或二醇混合物酯化DCS得到的低聚物和/或聚酯的方法，所述氢化在其催化剂前体包含氧化铜，氧化铝和至少一种镧，铁，钨，钼，钛或锆的氧化物，以及通过催化氢化酯混合物制备1,6-己二醇的方法，所述酯混合物作为主要组分包含己二酸的低聚和聚酯和 6-羟基己酸，并且通过用二醇，特别是1,6-己二醇或二醇混合物酯化DCS获得。

8. 发明申请

US20080004475A1 PROCESS FOR THE PRODUCTION OF NEOPENTYLGLYCOL USING FORMALDEHYDE WITH A LOW METHANOL CONTENT 审中-公开
公开(公告)号：US20080004475A1
公开(公告)日：2008-01-03
申请号：US11476161
申请日：2006-06-28
申请人： Tilman Sirch , Michael Steiniger , Steffen Mass , Stefan Rittinger , Stephan Schlitter , Ludwig E. Heck , Todd C. Spengeman , Jeffrey T. Andress
发明人： Tilman Sirch , Michael Steiniger , Steffen Mass , Stefan Rittinger , Stephan Schlitter , Ludwig E. Heck , Todd C. Spengeman , Jeffrey T. Andress
IPC分类号： C07C29/74
CPC分类号： C07C29/141 , C07C45/75 , C07C45/82 , C07C47/19 , C07C47/04 , C07C31/20 , C07C31/22 , C07C31/245
摘要： A process is provided for the preparation of polymethylol compounds of formula (I): (HOCH2)2—C—(R)2 , (I) in which the radicals R independently of one another are each a further methylol group, an alkyl group having from 1 to 22 C atoms or an aryl or aralkyl group having from 6 to 22 C atoms, by (a) condensing aldehydes having from 2 to 24 C atoms with formaldehyde in an aldol reaction using tertiary amines as a catalyst to give alkanals of formula (II): in which the radicals R independently of one another are each as defined above, (b) then separating, by distillation, the reaction mixture obtained into a bottom product comprising predominantly the compounds of formula II and a low-boiling stream consisting of unconverted or partially converted starting materials, and (c) hydrogenating the distillation bottom, wherein the aldol reaction is carried out with an aqueous formaldehyde solution having a methanol content of 0.35 to 0.5% by weight of methanol, the low-boiling stream is separated off at a pressure of 1 to 3 bar and temperatures of 100 to 135° C. and completely or partially recycled into the aldol reaction. This procedure advantageously makes it possible specifically to prevent the formation of by-products and hence to increase the yield of the desired polymethylol compound.We have found that this object is achieved by a process for the preparation of polymethylol compounds of formula (I): (HOCH2)2—C—(R)2 , (I) in which the radicals R independently of one another are each a further methylol group, an alkyl group having from 1 to 22 C atoms or an aryl or aralkyl group having from 6 to 22 C atoms, by (a) condensing aldehydes having from 2 to 24 C atoms with formaldehyde in an aldol reaction using tertiary amines as a catalyst to give alkanals of formula (II): in which the radicals R independently of one another are each as defined above, (b) then separating, by distillation, the reaction mixture obtained (aldolization product) into a bottom product comprising predominantly the compounds of formula II and a low-boiling stream consisting of unconverted or partially converted starting materials, and (c) hydrogenating the distillation bottom, wherein the aldol reaction is carried out with an aqueous formaldehyde solution having a methanol content of 0.35 to 0.5% by weight, the separation of the low-boiling stream is effected at a pressure of 1.1 to 3 bar, preferably 1.5 bar, and a temperature of 100 to 135° C., preferably of 102 to 125° C., and the low-boiling stream is completely or partially recycled into the aldol reaction, preferably the entire low-boiling stream being recycled. In the aldol reaction, a partially converted starting compound of formula (III): can also be formed in which the radicals R independently of one another are each hydrogen or are as defined above. According to the invention, this partially converted starting compound of formula (III), together with the desired alkanal of formula (II), is separated from the other by-products and the unreacted starting compounds and reacted again in an aldol reaction with formaldehyde having a methanol content of 0.35% by weight to 0.5% by weight, using tertiary amines as a catalyst.

9. 发明授权

US08183411B2 Process for preparing 6-hydroxycaproic esters 有权
标题翻译： 6-羟基己酸酯的制备方法
公开(公告)号：US08183411B2
公开(公告)日：2012-05-22
申请号：US12867509
申请日：2009-01-29
申请人： Rolf Pinkos , Tilman Sirch , Gerd-Dieter Tebben , Rolf-Hartmuth Fischer
发明人： Rolf Pinkos , Tilman Sirch , Gerd-Dieter Tebben , Rolf-Hartmuth Fischer
IPC分类号： C07C51/42
CPC分类号： C07C29/50 , C07C45/33 , C07C51/367 , C07C67/08 , C07C2601/14 , C07C49/403 , C07C59/01 , C07C69/675 , C07C35/08
摘要： The present application relates to an improved process for preparing 6-hydroxycaproic esters from the by-product mixtures which are obtained in the oxidation of cyclohexane to cyclohexanol and cyclohexanone with oxygen or oxygen-comprising gas mixtures.
摘要翻译：本申请涉及一种从副产物混合物中制备6-羟基己酸酯的改进方法，该方法是在用含氧或含氧气体混合物将环己烷氧化成环己醇和环己酮时获得的。

10. 发明申请

US20120035399A1 METHOD FOR PRODUCING 1,6-HEXANEDIOL BY HYDROGENATION OF OLIGO- AND POLYESTERS 有权
标题翻译：通过氢化和聚酯的氢化生产1,6-庚二醇的方法
公开(公告)号：US20120035399A1
公开(公告)日：2012-02-09
申请号：US13258207
申请日：2010-03-29
申请人： Olivier Abillard , Rolf Pinkos , Gerd-Dieter Tebben , Tilman Sirch , Daniel Urbanczyk , Heiko Urtel , Rolf Tompers
发明人： Olivier Abillard , Rolf Pinkos , Gerd-Dieter Tebben , Tilman Sirch , Daniel Urbanczyk , Heiko Urtel , Rolf Tompers
IPC分类号： C07C29/147
CPC分类号： C07C45/33 , C07C29/149 , C07C29/50 , C07C51/313 , C07C67/08 , C07C2601/14 , C07C31/20 , C07C35/08 , C07C49/403 , C07C55/14 , C07C69/44
摘要： The present invention relates to a process for hydrogenating oligo- and/or polyesters obtainable by esterifying a DCS with a diol or diol mixture, said hydrogenation being performed in the presence of a catalyst whose catalyst precursor comprises copper oxide, aluminum oxide and at least one oxide of lanthanum, of iron, of tungsten, of molybdenum, of titanium or of zirconium, and to a process for preparing 1,6-hexanediol by catalytically hydrogenating ester mixtures which comprise, as main components, oligo- and polyesters of adipic acid and 6-hydroxycaproic acid, and are obtained by esterifying DCS with diols, especially 1,6-hexanediol or diol mixtures.
摘要翻译：本发明涉及一种氢化通过用二醇或二醇混合物酯化DCS得到的低聚物和/或聚酯的方法，所述氢化在其催化剂前体包含氧化铜，氧化铝和至少一种镧，铁，钨，钼，钛或锆的氧化物，以及通过催化氢化酯混合物制备1,6-己二醇的方法，所述酯混合物作为主要组分包含己二酸的低聚和聚酯和 6-羟基己酸，并且通过用二醇，特别是1,6-己二醇或二醇混合物酯化DCS获得。

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