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1. 发明授权

US5244948A Process for the stabilization of polyolefins 失效
标题翻译：稳定聚烯烃的方法
公开(公告)号：US5244948A
公开(公告)日：1993-09-14
申请号：US881322
申请日：1992-05-07
申请人： Rolf Mulhaupt , Jean Rody , Mario Slongo
发明人： Rolf Mulhaupt , Jean Rody , Mario Slongo
IPC分类号： C08F10/00 , C08K5/3492
CPC分类号： C08F10/00 , C08K5/34926
摘要： Polyolefins and olefin copolymers which are prepared by polymerization on a catalyst made from a magnesium halide, a titanium compound and an aluminium alkyl can be stabilized by the addition of certain sterically hindered triazinylpiperidines, which are substituted in the 1-position, to the polymerization.
摘要翻译：通过在由卤化镁，钛化合物和烷基铝制成的催化剂上聚合制备的聚烯烃和烯烃共聚物可以通过将在1位上被取代的某些空间位阻三嗪基哌啶加入到聚合中来稳定化。

2. 发明授权

US5135986A Stabilized styrene copolymers containing elastomer particles 失效
标题翻译：含有弹性体颗粒的稳定苯乙烯共聚物
公开(公告)号：US5135986A
公开(公告)日：1992-08-04
申请号：US742175
申请日：1991-08-01
申请人： Rolf Mulhaupt , Bernard Gilg , Gerhard Rytz , Mario Slongo
发明人： Rolf Mulhaupt , Bernard Gilg , Gerhard Rytz , Mario Slongo
IPC分类号： C08F279/02 , C08F285/00
CPC分类号： C08F285/00 , C08F279/02
摘要： Copolymers of styrene or a-methylstyrene and at least one comonomer, containing crosslinked elastomer particles, can be light-stabilized by modifying the elastomer particles by copolymerization with a suitable derivative of a sterically hindered amine. The modification is preferably carried out by graft polymerization, the elastomer used preferably being polybutadiene.
摘要翻译：含有交联弹性体颗粒的苯乙烯或α-甲基苯乙烯和至少一种共聚单体的共聚物可以通过与空间位阻胺的合适的衍生物共聚改性弹性体颗粒来进行光稳定化。改性优选通过接枝聚合进行，优选使用弹性体为聚丁二烯。

3. 发明申请

US20050054748A1 Dental composition 审中-公开
标题翻译：牙科组成
公开(公告)号：US20050054748A1
公开(公告)日：2005-03-10
申请号：US10943355
申请日：2004-09-17
申请人： Joachim Klee , Uwe Walz , Rolf Mulhaupt
发明人： Joachim Klee , Uwe Walz , Rolf Mulhaupt
IPC分类号： A61K6/00 , A61K6/083 , C07C255/23 , A61K6/08
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/083 , A61K6/09 , C07C255/23 , C08L33/00 , C08L75/16
摘要： A dental composition including a mono- and/or a poly-cyanoacrylate, a polymerizable monomer, a stabilizer, an initiator, and optionally, pigments and a filling material.
摘要翻译：包含单 - 和/或聚 - 氰基丙烯酸酯，可聚合单体，稳定剂，引发剂和任选的颜料和填充材料的牙科用组合物。

4. 发明授权

US6031031A Thermoplastic molding compositions based on polyesters and polycarbonate 失效
标题翻译：基于聚酯和聚碳酸酯的热塑性模塑组合物
公开(公告)号：US6031031A
公开(公告)日：2000-02-29
申请号：US146197
申请日：1998-09-03
申请人： Martin Weber , Rolf Mulhaupt
发明人： Martin Weber , Rolf Mulhaupt
IPC分类号： C08L23/02 , C08L67/02 , C08L69/00 , C08F20/00
CPC分类号： C08L67/02 , C08L69/00 , C08L23/025
摘要： A thermoplastic molding composition comprisesA) from 1 to 97% by weight of a thermoplastic polyesterB) from 1 to 97% by weight of a polycarbonateC) from 1 to 40% by weight of an elastomer containing oxazoline groups and having a glass transition temperature (T.sub.g).ltoreq.0.degree. C.D) from 0.05 to 5% by weight of a bisoxazolineE) from 0 to 70% by weight of other additives and processing aids,where the total of the percentages by weight of components A) to E) is 100%.
摘要翻译：热塑性模塑组合物包含A）1至97重量％的热塑性聚酯B）1至97重量％的聚碳酸酯C）1至40重量％的含有恶唑啉基并具有玻璃化转变的弹性体温度（Tg）

5. 发明授权

US5128423A Moisture curable polyurethane resin having a compound or an oxazolidine containing silane group 失效
标题翻译：具有化合物或含恶唑烷的硅烷基的水溶性聚氨酯树脂
公开(公告)号：US5128423A
公开(公告)日：1992-07-07
申请号：US716713
申请日：1991-06-17
申请人： Giovanni Parrinello , Rolf Mulhaupt , Hubert Simon
发明人： Giovanni Parrinello , Rolf Mulhaupt , Hubert Simon
IPC分类号： C07F7/18 , C08G18/10 , C08G18/83 , C08K5/544 , C08L75/00 , C08L75/04 , C09J175/00 , C09J175/04
CPC分类号： C08G18/10 , C07F7/1836 , C08K5/5442 , Y10T442/2803
摘要： Compounds of the general formula I ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or benzyl,R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, orR.sub.1 and R.sub.2, together with the linking carbon atom, form a 5- or 6-membered ring, andR.sub.3, R.sub.4, R.sub.5 and R.sub.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 alkyl, phenyl or phenyl substituted by 1 to 3 members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, halogen or C.sub.1 -C.sub.4 alkoxy or are a group of formula --CH.sub.2 OR.sub.11, where R.sub.11, where R.sub.11 is C.sub.1 -C.sub.12 alkyl, phenyl or phenyl substituted by 1 to 3 members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, halogen or C.sub.1 -C.sub.4 alkoxy, or are --C(O)--R.sub.12, and R.sub.12, and R.sub.12 is C.sub.1 -C.sub.12 alkyl,R.sub.7 is C.sub.1 -C.sub.4 alkylene, R.sub.8 is C.sub.1 -C.sub.8 alkylene, R.sub.9 is C.sub.1 -C.sub.4 alkyl, or two radicals R.sub.9 together are C.sub.1 -C.sub.4 alkylene, and R.sub.10 is C.sub.1 -C.sub.4 alkyl or phenyl,q is a value from 0 to 2,X is --S--or --NH--,Y is O or S, andZ is an organic radical which is derived from a polyisocyanate or a polyisothiocyanate containing at least three three NCO or NCS groups respectively,n is a value.gtoreq.1 and m is a value .gtoreq.1, with the proviso that n+m.gtoreq.3, are suitable for use as couplers, especially for moisture-curable polyurethane resins.
摘要翻译：通式I的化合物其中R 1是氢，C 1 -C 12烷基，C 5 -C 7环烷基，苯基或苄基，R 2是氢或C 1 -C 4烷基，或者R 1和R 2与连接碳原子形成5-或6-元环，并且R 3，R 4，R 5和R 6相同或不同，为氢，C 1 -C 12烷基，苯基或被1至3个选自C 1 -C 4烷基，卤素或C 1 -C 4烷氧基，或者是式-CH 2 OR 11的基团，其中R 11，其中R 11是C 1 -C 12烷基，苯基或被1至3个选自C 1 -C 4烷基，卤素或C 1 -C 4烷氧基的苯基取代的苯基，或者是-C（O）-R 12，R 12和R 12是C 1 -C 12烷基，R 7是C 1 -C 4亚烷基，R 8是C 1 -C 8亚烷基，R 9是C 1 -C 4烷基或两个基团R 9一起是C 1 -C 4亚烷基，R 10 是C 1 -C 4烷基或苯基，q是0至2的值，X是-S-或-NH-，Y是O或S，Z是衍生自至少含有多异氰酸酯或多异硫氰酸酯的有机基团第三个 ree NCO或NCS基团，n是值> / = 1，m是值> / = 1，条件是n + m> / = 3，适合用作成色剂，特别是用于湿固化聚氨酯树脂。

6. 发明授权

US4963636A Adhesion promoters 失效
标题翻译：粘合促进剂
公开(公告)号：US4963636A
公开(公告)日：1990-10-16
申请号：US479223
申请日：1990-02-12
申请人： Rolf Mulhaupt , Hubert Simon
发明人： Rolf Mulhaupt , Hubert Simon
IPC分类号： C07F7/18 , C08G18/10 , C08G18/73 , C08G18/75 , C08G18/77 , C08G18/80 , C09J175/00 , C09J175/04 , C09J183/00 , C09J183/10
CPC分类号： C09J175/04 , C07F7/1836 , C08G18/10 , C08G18/809 , Y10S528/901 , Y10S528/903
摘要： Compounds of formula (I) ##STR1## wherein one of the radicals R.sup.1 or R.sup.2 is --N.dbd.C.dbd.O and the other is --NHC(O)S(CH.sub.2).sub.3 Si(OR.sup.3).sub.3, wherein R.sup.3 is C.sub.1 -C.sub.4 alkyl or phenyl, are most suitable for use as adhesion promoters for polyurethane single-component or two-component adhesives and also as primers.
摘要翻译：式（I）化合物其中基团R 1或R 2中的一个为-N = C = O，另一个为-NHC（O）S（CH 2）3 Si（OR 3）3，其中R 3为C 1 -C4烷基或苯基，最适合用作聚氨酯单组分或双组分粘合剂以及引物的粘合促进剂。

7. 发明授权

US4874805A Novel oxazolidines 失效
标题翻译：新型恶唑烷
公开(公告)号：US4874805A
公开(公告)日：1989-10-17
申请号：US212853
申请日：1988-06-29
申请人： Rolf Mulhaupt , Hubert Simon
发明人： Rolf Mulhaupt , Hubert Simon
IPC分类号： C07F7/18 , C08G18/10 , C08G18/61 , C08G59/40 , C08K5/54
CPC分类号： C08G18/10 , C07F7/1836 , C08K5/54
摘要： Compounds of the general formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is a group of the formula --CH.sub.2 OR.sup.7 (II) in which R.sup.7 is C.sub.1- C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is --C(O)--R.sup.8, and R.sup.8 is C.sub.1 -C.sub.12 -alkyl, and also not more than two of the radicals R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are one or two groups of the formula --CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (III), --CH.sub.2 OC(O)CH.sub.2 Si(OR.sup.9).sub.3 (IV), --Ch.sub.2 O(C.sub.m H.sub.2m)Si(OR.sup.9).sub.3 (V) or ##STR2## in which R.sup.9 is C.sub.1 -C.sub.4 -alkyl or phenyl and m is a number from 1 to 8 and r is a number 1 or 2 and t is 0, 1, or 2 and R.sup.1 is as defined above, and, in addition, compounds of the formula I in which R.sup.4 and R.sup.5 together from a group of the formula ##STR3## in which R.sup.9 is as defined above and R.sup.3 and R.sup.6 in this case are hydrogen and n is 1 or 2 and, if n is 1, Z is an organic radical which is derived from a primary amine ZNH.sub.2 and can contain one or two --Si(OR.sup.9).sub.3 groups and, if n is 2, Z is a divalent organic radical derived from a diprimary diamine H.sub.2 NZNH.sub.2 ; subject to the proviso that the compounds of the formula I contain one to three --Si(OR.sup.9).sub.3 groups, are suitable for use as adhesion promoters, particularly for moisture-curing epoxide and polyurethane resins.
摘要翻译：其中R 1是氢，C 1 -C 12 - 烷基，C 5 -C 7 - 环烷基，苯基或苄基和R 2是通式I（I）的化合物是氢或C 1 -C 4烷基，或者R 1和R 2一起与其连接的C原子形成5元或6元环，并且R 3，R 4，R 5和R 6相同或不同，为氢，C 1 -C 12 - 烷基，未取代或单取代至或被C1-C4烷基，卤素或C1-C4-烷氧基三取代，或者是其中R 7为C 1 -C 12 - 烷基的式-CH 2 OR 7（II）基团，未取代或单取代至被C1-C4三取代的苯基 - 烷基，卤素或C 1 -C 4 - 烷氧基，或者是-C（O）-R 8，并且R 8是C 1 -C 12烷基，并且不多于两个基团R 3，R 4，R 5和R 6是一个或两个（OR9）3（III），-CH2OC（O）CH2Si（OR9）3（IV），-Ch2O（CmH2m）Si（OR9）3（V）或（VI））的基团，其中 R 9为C 1 -C 4烷基或苯基，m为1至8的数，r为数1或2，t为0,1或2，R 1如上定义， d，此外，其中R 4和R 5一起来自其中R 9如上所定义的式Ⅶ（Ⅶ）基团和R 3和R 6在这种情况下的式I化合物是氢，n是1或2 并且如果n是1，Z是衍生自伯胺ZNH 2的有机基团，并且可以含有一个或两个-Si（OR 9）3基团，并且如果n是2，Z是衍生自二原子的二价有机基团二胺H 2 NZNH 2; 条件是式I化合物含有一至三个-Si（OR9）3基团，适用于粘合促进剂，特别是用于湿固化环氧化物和聚氨酯树脂。

8. 发明授权

US4772716A Oxazolidines containing silane groups 失效
标题翻译：含有硅烷基的恶唑烷
公开(公告)号：US4772716A
公开(公告)日：1988-09-20
申请号：US70741
申请日：1987-07-06
申请人： Rolf Mulhaupt , Hubert Simon
发明人： Rolf Mulhaupt , Hubert Simon
IPC分类号： C07F7/18 , C08G18/10 , C08G18/61 , C08G59/40 , C08K5/54
CPC分类号： C08G18/10 , C07F7/1836 , C08K5/54
摘要： Compounds of the general formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is a group of the formula --CH.sub.2 OR.sup.7 (II) in which R.sup.7 is C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is --C(O)--R.sup.8, and R.sup.8 is C.sub.1 -C.sub.12 -alkyl, and also not more than two of the radicals R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are one or two groups of the formula --CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (III), --CH.sub.2 OC(O)CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (IV), --CH.sub.2 O(C.sub.m H.sub.2m)Si(OR.sup.9).sub.3 (V) or ##STR2## in which R.sup.9 is C.sub.1 -C.sub.4 -alkyl or phenyl and m is a number from 1 to 8 and r is a number 1 or 2 and t is 0, 1 or 2 and R.sup.1 is as defined above, and, in addition, compounds of the formula I in which R.sup.4 and R.sup.5 together form a group of the formula ##STR3## in which R.sup.9 is as defined above and R.sup.3 and R.sup.6 in this case are hydrogen and n is 1 or 2 and, if n is 1, Z is an organic radical which is derived from a primary amine ZnH.sub.2 and can contain one or two --Si(OR.sup.9).sub.3 groups and, if n is 2, Z is a divalent organic radical derived from a diprimary diamine H.sub.2 NZNH.sub.2 ; subject to the proviso that the compounds of the formula I contain one to three --Si(OR.sup.9).sub.3 groups, are suitable for use as adhesion promoters, particularly for moisture-curing epoxide and polyurethane resins.
摘要翻译：其中R 1是氢，C 1 -C 12 - 烷基，C 5 -C 7 - 环烷基，苯基或苄基和R 2是通式I（I）的化合物是氢或C 1 -C 4烷基，或者R 1和R 2一起与其连接的C原子形成5元或6元环，并且R 3，R 4，R 5和R 6相同或不同，为氢，C 1 -C 12 - 烷基，未取代或单取代至或被C1-C4烷基，卤素或C1-C4-烷氧基三取代，或者是其中R 7为C 1 -C 12 - 烷基的式-CH 2 OR 7（II）基团，未取代或单取代至被C1-C4三取代的苯基 - 烷基，卤素或C 1 -C 4 - 烷氧基，或者是-C（O）-R 8，并且R 8是C 1 -C 12烷基，并且不多于两个基团R 3，R 4，R 5和R 6是一个或两个（OR9）3（III），-CH2OC（O）CH2CH2Si（OR9）3（IV），-CH2O（CmH2m）Si（OR9）3（V）或（VI））的基团，其中 R 9为C 1 -C 4烷基或苯基，m为1〜8的数，r为数1或2，t为0,1或2，R 1如上所述，另外，其中R 4和R 5一起形成其中R 9如上所定义并且R 3和R 6在这种情况下为氢且n为1或2的式Ⅶ（Ⅶ）的基团的式I化合物并且如果n是1，Z是衍生自伯胺ZnH 2的有机基团，并且可以含有一个或两个-Si（OR 9）3基团，并且如果n是2，Z是衍生自二原子的二价有机基团二胺H 2 NZNH 2; 条件是式I化合物含有一至三个-Si（OR9）3基团，适用于粘合促进剂，特别是用于湿固化环氧化物和聚氨酯树脂。

9. 发明申请

US20090017360A1 OLIGOMERIC AND POLYMERIC AROMATIC PHOSPHONIC ACIDS, THEIR BLENDS, PROCESSES FOR PREPARING THEM AND USES AS POLYELECTROLYTES 失效
公开(公告)号：US20090017360A1
公开(公告)日：2009-01-15
申请号：US12279794
申请日：2007-02-12
申请人： Helmut Mohwald , Thorsten Bock , Rolf Mulhaupt
发明人： Helmut Mohwald , Thorsten Bock , Rolf Mulhaupt
IPC分类号： H01M8/10 , C08G79/04 , C08L85/02
CPC分类号： H01M8/1041 , B01D67/0009 , B01D67/0011 , B01D71/82 , B01D2325/04 , B01D2325/14 , C08G65/48 , C08G75/23 , C08J5/2256 , C08L65/00 , C08L71/126 , C08L81/06 , H01M8/0289 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , C08L2666/02
摘要： The present invention relates to halogen-free, oligomeric or polymeric phosphonic acids made up of units of the general formula (I) —[(O)m—{R1(X)n(Y)o}pR1(X)q]r—[(O)s—R5(X)t]v— (I), where: Xis —P═O(OH)2, Yis carbonyl or sulfonyl, R1, R5are, independently of one another, divalent or polyvalent, substituted or unsubstituted, heteroatom-free or heteroatom- comprising aromatic radicals, m, o, sare each, independently of one another, 0 or 1, n, q, tare each, independently of one another, 0 or an integer from 1 to 8, with n and s not simultaneously being 0, r, vare each, independently of one another, from 0 to 1, with the sum of r and v being from 0.95 to 1.05, and pis 0 or an integer ≧1, where the radicals X are substituents on R1 and R5 and the radicals Y are parts of polymer or oligomer chain, to a process for preparing these compounds and also to halogen-free mixtures comprising one or more compounds of the general formula (I) and a nitrogen-free solvent having a boiling point of >150° C.

10. 发明申请

US20060122367A1 Process for preparing biocompatible polyurea 审中-公开
标题翻译：制备生物相容性聚脲的方法
公开(公告)号：US20060122367A1
公开(公告)日：2006-06-08
申请号：US10525953
申请日：2003-08-07
申请人： Rolf Mulhaupt , Jacobus Loontjens , Steffen Maier , Jorg Zimmermann
发明人： Rolf Mulhaupt , Jacobus Loontjens , Steffen Maier , Jorg Zimmermann
IPC分类号： C08G73/00
CPC分类号： C08G71/02
摘要： A process is provided for preparing urea-containing polymers by contacting a hydroxy-functional organic compound having a functionality of two or more, with a coupling agent in the presence of a strong base, wherein the coupling agent is a carbonylbislactam compound having the general formula (I): wherein n is an integer from 3 to 15, and that the contacting is conducted at a temperature between 0° C. and 80° C. The polymers thus obtained are believed to be new and are useful e.g. in tissue engineering and coatings applications.
摘要翻译：提供了一种制备含尿素聚合物的方法，其通过使具有两个或多个官能度的羟基官能的有机化合物与强碱的存在下与偶联剂接触，其中偶联剂是具有通式的羰基双内酰胺化合物（I）：其中n为3至15的整数，并且接触在0℃至80℃之间的温度下进行。由此获得的聚合物被认为是新的，可用于例如在组织工程和涂料应用中。

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