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    • 1. 发明授权
    • Method and arrangement for analyzing exhaust gas from an internal combustion engine
    • 用于分析来自内燃机的废气的方法和装置
    • US06192738B1
    • 2001-02-27
    • US09244933
    • 1999-02-04
    • Roland StahlDietrich AdolphGerhard HoetzelJohann Riegel
    • Roland StahlDietrich AdolphGerhard HoetzelJohann Riegel
    • G01N700
    • G01N33/0013
    • In order to provide a method and arrangement for analytical determination of the relative amounts of exhaust gas components, except for water, but including hydrogen in the rich range or oxygen in the lean range, and for determining a &lgr; value, in which the exhaust gas sample can be taken at any arbitrary location, an arrangement is provided in which at least one portion of the exhaust gas is passed through a catalytic reactor (2, 22), a condenser (3,23) connected to the catalytic reactor to receive the gas passed through it, and, after passing through the condenser, the gas passes through an IR spectrometer and by a &lgr;-sensor. The oxidizable and reducible components of the exhaust gas are reacted with each other in the catalytic reactor which is heated to temperatures greater than 450° C. The relative amounts of CO2, hydrocarbons and, if present, CO are measured with the IR spectrometer and either the relative amount of hydrogen in the rich range or of O2+½ NO in the lean range is determined with the help of the signal (Ip) from the &lgr;-sensor. A &lgr; value is calculated from the measured exhaust gas component concentrations or relative amounts.
    • 为了提供除了水以外的排气组分的相对量的分析确定方法和装置,但是包括富含范围内的氢或贫浓范围的氧,并且用于确定l值,其中废气 可以在任何任意位置取样,其中提供排气的至少一部分通过催化反应器(2,22)的排列,连接到催化反应器的冷凝器(3,23),以接收 气体通过它,并且在通过冷凝器之后,气体通过IR光谱仪和羔羊传感器。 废气中的可氧化和可还原的组分在催化反应器中彼此反应,催化反应器被加热至高于450℃。如果使用红外光谱仪测量CO 2,烃和CO(如果存在的话)的相对量, 借助于来自羔羊传感器的信号(Ip)来确定浓范围中的氢的相对量或在稀疏范围内的O2 +½NO的相对量。 从测量的废气组分浓度或相对量计算羔羊值。
    • 3. 发明授权
    • Method for determining gas components and/or gas concentrations of gas
mixture
    • 气体混合物气体组分和/或气体浓度的测定方法
    • US5595647A
    • 1997-01-21
    • US290703
    • 1995-01-19
    • Gerhard HoetzelHarald NeumannJohann Riegel
    • Gerhard HoetzelHarald NeumannJohann Riegel
    • G01N27/419G01N27/12G01N27/407G01N27/41
    • G01N27/407G01N27/4074
    • A method of determining at least one of gas constituents and gas concentrations of a gas mixture such as exhaust gas from an internal combustion engine includes producing a change in gas concentration of the gas mixture at a semiconductor gas sensor by pumping a variable supply of oxygen to the semiconductor gas sensor by means of a solid electrolyte pumping cell; detecting at least one reaction speed selected from the group consisting of adsorption speed and desorption speed caused by the change in gas concentration as a signal from the semiconductor gas sensor which is a reply function; evaluating the signal from the semiconductor gas sensor over time to provide a time response of the reply function; and comparing the time response of the reply function with a stored, standardized time response of different gas constituents whereby at least one of the gas constituents and the gas concentrations of the gas mixture are determined.
    • PCT No.PCT / DE94 / 00188 Sec。 371日期1995年1月19日 102(e)日期1995年1月19日PCT 1994年2月19日PCT PCT。 公开号WO94 / 22007 日期1994年9月29日一种确定气体混合物(例如来自内燃机的废气)的气体组分和气体浓度中的至少一种的方法包括通过泵送一个半导体气体传感器来产生气体混合物的气体浓度的变化 通过固体电解质泵送单元向半导体气体传感器供应氧气; 检测从由作为回复功能的半导体气体传感器的信号的气体浓度的变化引起的吸附速度和解吸速度中选择的至少一个反应速度; 评估来自半导体气体传感器的信号随时间提供回复功能的时间响应; 以及将回复函数的时间响应与不同气体成分的存储的,标准化的时间响应进行比较,由此确定气体混合物的气体成分和气体浓度中的至少一种。
    • 5. 发明授权
    • Gas sensor
    • 气体传感器
    • US5880353A
    • 1999-03-09
    • US945297
    • 1997-12-14
    • Theodor GraserGerhard HoetzelJohann WehrmannHeinz Eisenschmid
    • Theodor GraserGerhard HoetzelJohann WehrmannHeinz Eisenschmid
    • G01N27/409G01N27/407G01N27/413B60H1/32H01L7/00
    • G01N27/4078G01N27/4077
    • A gas sensor having a sensor element which is immobilized in gas-tight fashion in a metal housing. The gas sensor has a double-walled protective tube with an outer protective sleeve and an inner protective sleeve, each of which possesses openings for the entry and/or exit of gas. The inner protective sleeve forms a gas space into which the sensor element projects with a section at the measurement-gas end. The outer protective sleeve is a sleeve having a closed enveloping surface, the openings for the entry and/or exit of gas being arranged in the cavity at the end face of the sleeve. The gas space formed by the inner protective sleeve has, perpendicular to the extension direction of the sensor element, a rectangular cross section.
    • PCT No.PCT / DE96 / 02210 Sec。 371日期1997年10月14日第 102(e)1997年10月14日PCT PCT 1996年11月20日PCT公布。 出版物WO97 / 33165 日期1997年9月12日一种具有传感器元件的气体传感器,其以气密方式固定在金属壳体中。 气体传感器具有双壁保护管,其具有外部保护套和内部保护套,每个保护套具有用于进入和/或排出气体的开口。 内部保护套形成气体空间,传感器元件在测量气体端部与部分一起突出。 外保护套是具有封闭的包络表面的套筒,用于气体的进入和/或排出的开口布置在套筒的端面处的空腔中。 由内保护套筒形成的气体空间垂直于传感器元件的延伸方向具有矩形截面。
    • 6. 发明授权
    • Method and a device for detecting the oxygen content in gases
    • 用于检测气体中氧含量的方法和装置
    • US5632883A
    • 1997-05-27
    • US545848
    • 1995-11-13
    • Gerhard Hoetzel
    • Gerhard Hoetzel
    • G01N27/409G01N27/419G01N27/407
    • G01N27/419
    • The invention relates to a device for detecting the oxygen content in a gas to be measured, wherein the device comprises at least one concentration cell which includes a measuring electrode, a solid electrolyte and a reference electrode. The measuring electrode communicates with the gas to be measured and is connected via the solid electrolyte to the reference electrode, which communicates with a reference gas volume. The reference gas volume is separated from the gas to be measured in such a way that a particle exchange between the reference gas volume and the gas to be measured is at least impeded. The output voltage of the concentration cell, which voltage can be tapped off between the measuring electrode and the reference electrode, represents a measure of the difference in the oxygen concentrations in the gas to be measured and in the reference gas volume. The device further comprises a current source which can be coupled in between the reference electrode and the measuring electrode in such a way that in the coupled-in state a current flow results which is directed such that oxygen is transported in the solid electrolyte from the measuring electrode to the reference electrode. The device further comprises switching means which, in a first switching state, couples the current source to the concentration cell and which, in a second switching state, decouples the current source from the concentration cell, so that the voltage between the measuring electrode and the reference electrode in the decoupled state is not affected by the current source.
    • PCT No.PCT / DE95 / 00258 Sec。 371日期:1995年11月13日 102(e)1995年11月13日,PCT提交1995年2月28日PCT公布。 WO95 / 24643 PCT出版物 日期1995年9月14日本发明涉及一种用于检测待测气体中的氧含量的装置,其中该装置包括至少一个浓度池,其包括测量电极,固体电解质和参比电极。 测量电极与待测气体连通,并通过固体电解质与参比电极连接,参比电极与参考气体体积连通。 将参考气体体积与待测量的气体以至少阻碍参考气体体积和被测量气体之间的颗粒交换的方式分离。 可以在测量电极和参比电极之间抽出电压的浓度单元的输出电压表示待测气体和参考气体体积中的氧气浓度差的度量。 该装置还包括电流源,其可以以这样的方式耦合在参考电极和测量电极之间,使得在耦合状态下导致电流流动导致氧气在固体电解质中从测量 电极到参比电极。 该装置还包括开关装置,其在第一开关状态下将电流源耦合到浓度电池,并且在第二开关状态下,将电流源与浓度电池分离,使得测量电极和 解耦状态的参比电极不受电流源的影响。
    • 9. 发明授权
    • Electrochemical measuring sensor
    • 电化学测量传感器
    • US5389223A
    • 1995-02-14
    • US62497
    • 1993-05-17
    • Gerhard Hoetzel
    • Gerhard Hoetzel
    • G01N27/417G01N27/419
    • G01N27/417
    • An electrochemical measuring sensor for the determination of the air/fuel ratio in exhaust gases of internal combustion engines both in the low-fuel and also in the fuel-rich range with a sensor element with an electrochemical oxygen concentration cell and an oxygen pumping cell with solid electrolyte base is proposed, in which the sensor element is arranged in a housing, capable of insertion in the exhaust gas pipe, in a manner such that the electrodes of the electrochemical oxygen concentration cell and of the oxygen pumping cell of the sensor element in the measuring sensor are situated outside the exhaust gas pipe, the communication with the atmosphere taking place via openings in the housing and the communication with the exhaust gas taking place via a diffusion slit. The sensor element is characterized by a particularly simple construction, free oxygen being available to the oxygen pumping cell both in the lean and also in the rich lambda range. The electrodes of the oxygen pumping cell can be of large dimension, for which reason only comparatively small current densities are necessary. A severe cooling of the sensor element in the electrode range due to cold exhaust gas (test gas) is prevented.
    • 一种电化学测量传感器,用于利用具有电化学氧浓度池的传感器元件和具有氧气浓缩池的氧气泵浦单元来确定低燃料和富燃料范围内燃机的废气中的空气/燃料比 提出了固体电解质基底,其中传感器元件布置在能够插入排气管中的壳体中,使得电化学氧浓度池的电极和传感器元件的氧气泵浦单元的电极 测量传感器位于废气管外部,通过壳体中的开口与大气连通,并且通过扩散狭缝进行与废气的连通。 传感器元件的特征在于特别简单的结构,氧气泵浦电池在贫和还在富λ范围内均可获得游离氧。 氧抽取电池的电极可以是大尺寸的,因此仅需要相对较小的电流密度。 防止由于冷排气(试验气体)引起的电极范围内的传感器元件的严重冷却。