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1. 发明授权

US5505837A Sensor arrangement for determining gas components and/or gas concentrations of gas mixtures 失效
标题翻译：用于确定气体组分和/或气体混合物气体浓度的传感器装置
公开(公告)号：US5505837A
公开(公告)日：1996-04-09
申请号：US290704
申请日：1994-12-12
申请人： Karl-Hermann Friese , Hermann Dietz , Werner Gruenwald , Gerhard Hoetzel , Harald Neumann , Johann Riegel , Bernd Schumann
发明人： Karl-Hermann Friese , Hermann Dietz , Werner Gruenwald , Gerhard Hoetzel , Harald Neumann , Johann Riegel , Bernd Schumann
IPC分类号： G01N27/12 , G01N27/416 , G01N27/419 , G01N27/26
CPC分类号： G01N27/419
摘要： A sensor arrangement for determining at least one of gas components and gas concentrations of gas mixtures including CO, NO.sub.x and HC in exhaust gases of internal combustion engines, includes a measuring element which has a sensitive region; and a pump cell that includes a solid electrolyte and inner and outer pump electrodes which are opposingly disposed at least on the solid electrolyte and which effect an oxygen transfer to the measuring element, wherein the pump cell and the measuring element are spatially separated from one another, are located in different temperature zones during operation of the sensor arrangement, and are connected to one another by a diffusion segment through which oxygen can diffuse from the pump cell to the measuring element.
摘要翻译： PCT No.PCT / DE94 / 00289 Sec。 371日期1994年12月12日第 102（e）日期1994年12月12日PCT 1994年3月17日PCT公布。公开号WO94 / 24550 PCT 日期：1994年10月27日。一种用于确定内燃机废气中的CO，NO x和HC气体混合气体组分和气体浓度中的至少一种的传感器装置，包括具有敏感区域的测量元件; 以及泵电池，其包括固体电解质和内部和外部泵电极，所述内部和外部泵电极相对设置在至少在所述固体电解质上并且对所述测量元件进行氧传递，其中所述泵浦单元和所述测量元件在空间上彼此分离位于传感器装置的操作期间的不同温度区域中，并且通过扩散段彼此连接，通过该扩散段，氧气可以从泵电池扩散到测量元件。

2. 发明授权

US5476001A Sensor for determining gas components and/or gas concentrations of gas mixtures 失效
标题翻译：用于确定气体组分和/或气体混合物气体浓度的传感器
公开(公告)号：US5476001A
公开(公告)日：1995-12-19
申请号：US244660
申请日：1994-06-06
申请人： Gerhard Hoetzel , Harald Neumann , Johann Riegel , Karl-Hermann Friese , Werner Gruenwald
发明人： Gerhard Hoetzel , Harald Neumann , Johann Riegel , Karl-Hermann Friese , Werner Gruenwald
IPC分类号： G01N27/12 , G01N27/14 , G01N27/416 , G01N27/419 , G01N27/62 , G01N27/417 , F02D41/14
CPC分类号： G01N27/419
摘要： A sensor for determining gas components and/or gas concentrations in gas mixtures, in particular in exhaust gases of internal combustion engines. The sensor has an oxygen pump cell and a measuring element having a sensitive region. Provided between the pump cell and the gas mixture is a diffusion path in which there are formed an oxygen gradient XO.sub.2 and a gradient X.sub.CO of the gas component to be determined, which extend respectively in opposite directions. The measuring element is positioned relative to the pump cell and the diffusion path in such a way that an excess of oxygen is present on the sensitive region of the measuring element.
摘要翻译： PCT No.PCT / DE93 / 01164 Sec。 371日期：1994年6月6日 102（e）日期1994年6月6日PCT提交1993年12月7日PCT公布。公开号WO94 / 15206 日期1997年7月7日。一种用于确定气体混合物，特别是内燃机废气中的气体成分和/或气体浓度的传感器。传感器具有氧气泵电池和具有敏感区域的测量元件。提供在泵电池和气体混合物之间的是扩散路径，其中形成分别沿相反方向延伸的要确定的气体成分的氧梯度XO2和梯度XCO。测量元件相对于泵电池和扩散路径被定位成使得过量的氧存在于测量元件的敏感区域上。

3. 发明授权

US5334350A Resistance probe for determining gas compositions and method of producing it 失效
标题翻译：用于确定气体成分的电阻探针及其制备方法
公开(公告)号：US5334350A
公开(公告)日：1994-08-02
申请号：US861810
申请日：1992-06-19
申请人： Karl-Hermann Friese , Werner Gruenwald , Hans-Martin Wiedenmann , Gerhard Hoetzel
发明人： Karl-Hermann Friese , Werner Gruenwald , Hans-Martin Wiedenmann , Gerhard Hoetzel
IPC分类号： G01N27/12 , G01N33/00 , G01N27/04 , H01C1/02 , H01C7/00
CPC分类号： G01N27/12
摘要： A resistance probe is proposed for detecting gas compositions, particularly in the exhaust gases of internal combustion engines. This resistance probe has the advantage over prior art resistance probes that, with a short response time, it is considerably more aging resistant. This is accomplished in that the resistance layer configured as a semiconductor layer is introduced or sintered into recesses or slits provided for this purpose in the prefabricated sensor carrier body and above it is applied a porous, electrically non-conductive engobe or a protective layer structure in the form of a grid or raster. These measures enable the measuring gas to gain access to the semiconductor layer, but the semiconductor layer is simultaneously protected against corrosive, erosive and/or cavitative attacks from the exhaust gas.
摘要翻译： PCT No.PCT / DE90 / 00909 Sec。 371日期：1992年6月19日 102（e）日期1992年6月19日PCT提交1990年11月24日PCT公布。出版物WO91 / 09301 日期：1991年6月27日。提出了用于检测气体组成的电阻探针，特别是在内燃机的废气中。该电阻探针具有优于现有技术的电阻探针的优点，其具有较短的响应时间，其耐老化性更强。这是通过将构造为半导体层的电阻层引入或烧结到预制传感器载体本体中为此而设置的凹部或狭缝中，并且在其上施加多孔，非导电性或者保护层结构网格或栅格的形式。这些措施使得测量气体能够进入半导体层，但同时保护半导体层免受来自废气的腐蚀性，侵蚀性和/或空穴化攻击。

4. 发明授权

US5595647A Method for determining gas components and/or gas concentrations of gas mixture 失效
标题翻译：气体混合物气体组分和/或气体浓度的测定方法
公开(公告)号：US5595647A
公开(公告)日：1997-01-21
申请号：US290703
申请日：1995-01-19
申请人： Gerhard Hoetzel , Harald Neumann , Johann Riegel
发明人： Gerhard Hoetzel , Harald Neumann , Johann Riegel
IPC分类号： G01N27/419 , G01N27/12 , G01N27/407 , G01N27/41
CPC分类号： G01N27/407 , G01N27/4074
摘要： A method of determining at least one of gas constituents and gas concentrations of a gas mixture such as exhaust gas from an internal combustion engine includes producing a change in gas concentration of the gas mixture at a semiconductor gas sensor by pumping a variable supply of oxygen to the semiconductor gas sensor by means of a solid electrolyte pumping cell; detecting at least one reaction speed selected from the group consisting of adsorption speed and desorption speed caused by the change in gas concentration as a signal from the semiconductor gas sensor which is a reply function; evaluating the signal from the semiconductor gas sensor over time to provide a time response of the reply function; and comparing the time response of the reply function with a stored, standardized time response of different gas constituents whereby at least one of the gas constituents and the gas concentrations of the gas mixture are determined.
摘要翻译： PCT No.PCT / DE94 / 00188 Sec。 371日期1995年1月19日 102（e）日期1995年1月19日PCT 1994年2月19日PCT PCT。公开号WO94 / 22007 日期1994年9月29日一种确定气体混合物（例如来自内燃机的废气）的气体组分和气体浓度中的至少一种的方法包括通过泵送一个半导体气体传感器来产生气体混合物的气体浓度的变化通过固体电解质泵送单元向半导体气体传感器供应氧气; 检测从由作为回复功能的半导体气体传感器的信号的气体浓度的变化引起的吸附速度和解吸速度中选择的至少一个反应速度; 评估来自半导体气体传感器的信号随时间提供回复功能的时间响应; 以及将回复函数的时间响应与不同气体成分的存储的，标准化的时间响应进行比较，由此确定气体混合物的气体成分和气体浓度中的至少一种。

5. 发明授权

US5473304A Method of protecting catalytic converters for exhaust gas purification and heat tone sensor for implementing the method 失效
标题翻译：保护废气净化用催化转化器和实现该方法的热色调传感器的方法
公开(公告)号：US5473304A
公开(公告)日：1995-12-05
申请号：US971904
申请日：1992-12-28
申请人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Gerhard Hoetzel
发明人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Gerhard Hoetzel
IPC分类号： F01N3/20 , F01N9/00 , F01N11/00 , F02D35/00 , F02D41/14 , G01K7/22 , G01K17/00 , G01N25/30 , H01C7/10
CPC分类号： F01N11/002 , F02D41/1446 , F01N2550/02 , Y02T10/47
摘要： A method is disclosed for the protection of catalytic converters for exhaust gas purification by measuring the temperature with a heat tone sensor suitable particularly for the implementation of the method, wherein a heat tone sensor composed of at least two NTC or PTC resistors and provided with a coating of a catalytically active material on the sensor in the region of at least one of these resistors is arranged ahead of the catalytic converter in the exhaust gas stream or a part thereof, with the catalytically active material initiating the same exothermal reactions as they take place in the catalytic converter employed for the exhaust gas purification. If the resistor is overheated due to an overly intensive exothermal reaction, resulting in a change in resistance, the heat tone sensor detects the drop in the throughput rate of the catalytic converter.
摘要翻译： PCT No.PCT / DE91 / 00447 Sec。 371日期1992年12月28日 102（e）日期1992年12月28日PCT提交1993年5月8日PCT公布。出版物WO92 / 1992年1月9日公开了一种用于通过用于实施该方法的热色调传感器测量温度来保护用于废气净化的催化转化器的方法，其中由至少两个NTC组成的热音传感器或PTC电阻器并且在这些电阻器中的至少一个的区域中在传感器上提供催化活性材料的涂层布置在排气流或其一部分中的催化转化器之前，催化活性材料起始于在用于废气净化的催化转化器中发生相同的放热反应。如果由于过度强烈的放热反应导致电阻器过热，导致电阻变化，则热调传感器检测催化转化器的生产率下降。

6. 发明授权

US5137615A Sensor element for limiting current sensors for determination of the .lambda. value of gas mixtures 失效
标题翻译：用于限制用于确定气体混合物（（LAMBDA））值的电流传感器的传感器元件
公开(公告)号：US5137615A
公开(公告)日：1992-08-11
申请号：US566376
申请日：1990-08-30
申请人： Karl-Hermann Friese , Gerhard Hoetzel
发明人： Karl-Hermann Friese , Gerhard Hoetzel
IPC分类号： G01N27/41 , B41M1/12 , B81B1/00 , C04B35/00 , F02D41/00 , F02D41/14 , G01N27/00 , G01N27/12 , G01N27/407 , G01N27/416 , G01N27/417 , H01L49/00
CPC分类号： G01N27/4071 , G01N27/4072
摘要： A sensor element for limiting current sensors for determination of the .lambda.-value of gas mixtures is proposed, which has at least one outer pumping electrode and one inner pumping electrode, on a solid electrolyte in platelet or foil form, conducting O.sup.2- ions, of which the inner pumping electrode is arranged in a diffusion channel for the measuring gas. It consists of a porous three-dimensional precious metal electrode having a supporting structure, the thickness of which electrode corresponds to the height of the diffusion channel. Characteristic of the inner pumping electrode is a greatly improved load-bearing capacity in comparison with electrodes of sheet-like design, whereby the service life of the sensor element is increased. A further advantage of the three-dimensional design of the inner pumping electrode is that it takes on a supporting function during lamination in the production of the sensor element by ceramic foil and screen printing techniques.
摘要翻译： PCT No.PCT / DE89 / 00102 Sec。 371日期1990年8月30日第 102（e）1990年8月30日PCT PCT 1989年2月23日提交PCT。出版物WO89 / 08840 日本1989年9月21日提出了一种用于限制用于确定气体混合物的λ值的电流传感器的传感器元件，其具有至少一个外部泵浦电极和一个内部泵浦电极，在片状或箔形式的固体电解质上，其中内部泵浦电极布置在用于测量气体的扩散通道中的O2-离子。它由具有支撑结构的多孔三维贵金属电极组成，其电极的厚度对应于扩散通道的高度。与片状设计的电极相比，内部泵送电极的特性是大大改善的承载能力，从而传感器元件的使用寿命增加。内部泵送电极的三维设计的另一优点在于，通过陶瓷箔和丝网印刷技术在传感器元件的制造中层压期间它具有支撑功能。

7. 发明授权

US06192738B1 Method and arrangement for analyzing exhaust gas from an internal combustion engine 失效
标题翻译：用于分析来自内燃机的废气的方法和装置
公开(公告)号：US06192738B1
公开(公告)日：2001-02-27
申请号：US09244933
申请日：1999-02-04
申请人： Roland Stahl , Dietrich Adolph , Gerhard Hoetzel , Johann Riegel
发明人： Roland Stahl , Dietrich Adolph , Gerhard Hoetzel , Johann Riegel
IPC分类号： G01N700
CPC分类号： G01N33/0013
摘要： In order to provide a method and arrangement for analytical determination of the relative amounts of exhaust gas components, except for water, but including hydrogen in the rich range or oxygen in the lean range, and for determining a &lgr; value, in which the exhaust gas sample can be taken at any arbitrary location, an arrangement is provided in which at least one portion of the exhaust gas is passed through a catalytic reactor (2, 22), a condenser (3,23) connected to the catalytic reactor to receive the gas passed through it, and, after passing through the condenser, the gas passes through an IR spectrometer and by a &lgr;-sensor. The oxidizable and reducible components of the exhaust gas are reacted with each other in the catalytic reactor which is heated to temperatures greater than 450° C. The relative amounts of CO2, hydrocarbons and, if present, CO are measured with the IR spectrometer and either the relative amount of hydrogen in the rich range or of O2+½ NO in the lean range is determined with the help of the signal (Ip) from the &lgr;-sensor. A &lgr; value is calculated from the measured exhaust gas component concentrations or relative amounts.
摘要翻译：为了提供除了水以外的排气组分的相对量的分析确定方法和装置，但是包括富含范围内的氢或贫浓范围的氧，并且用于确定l值，其中废气可以在任何任意位置取样，其中提供排气的至少一部分通过催化反应器（2,22）的排列，连接到催化反应器的冷凝器（3,23），以接收气体通过它，并且在通过冷凝器之后，气体通过IR光谱仪和羔羊传感器。废气中的可氧化和可还原的组分在催化反应器中彼此反应，催化反应器被加热至高于450℃。如果使用红外光谱仪测量CO 2，烃和CO（如果存在的话）的相对量，借助于来自羔羊传感器的信号（Ip）来确定浓范围中的氢的相对量或在稀疏范围内的O2 +½NO的相对量。从测量的废气组分浓度或相对量计算羔羊值。

8. 发明授权

US06942772B1 Measuring sensor for the determination of a concentration of gas constituents in gaseous mixtures 失效
标题翻译：用于测定气体混合物中气体成分浓度的测量传感器
公开(公告)号：US06942772B1
公开(公告)日：2005-09-13
申请号：US09786903
申请日：2000-06-29
申请人： Jens Stefan Schneider , Gerhard Hoetzel , Bernd Schumann , Thomas Moser
发明人： Jens Stefan Schneider , Gerhard Hoetzel , Bernd Schumann , Thomas Moser
IPC分类号： G01N27/406 , G01N27/30 , G01N27/407 , G01N27/416 , G01N27/409
CPC分类号： G01N27/4075
摘要： A sensor for determining a concentration of gas components in gas mixtures having a first measuring electrode (mixed potential electrode) which has little or no catalytic effect on the establishment of an equilibrium in the gas mixture and a second measuring electrode (equilibrium electrode) which catalyzes the establishment of an equilibrium in the gas mixture as well as a solid electrolyte that is conductive for oxygen ions arranged between the two measuring electrodes, with the two measuring electrodes being exposed to the gas mixture. At least the first measuring electrode (16) is a cermet electrode, where at least one metal oxide component of the cermet electrode is capable of reversible incorporation of oxygen.
摘要翻译：一种用于确定气体混合物中气体组分浓度的传感器，其具有对气体混合物中的平衡建立几乎没有催化作用的第一测量电极（混合电位电极）和催化剂的第二测量电极（平衡电极）在气体混合物中建立平衡以及在两个测量电极之间的氧离子导电的固体电解质，两个测量电极暴露于气体混合物。至少第一测量电极（16）是金属陶瓷电极，其中金属陶瓷电极的至少一种金属氧化物组分能够可逆地引入氧。

9. 发明授权

US5880353A Gas sensor 失效
标题翻译：气体传感器
公开(公告)号：US5880353A
公开(公告)日：1999-03-09
申请号：US945297
申请日：1997-12-14
申请人： Theodor Graser , Gerhard Hoetzel , Johann Wehrmann , Heinz Eisenschmid
发明人： Theodor Graser , Gerhard Hoetzel , Johann Wehrmann , Heinz Eisenschmid
IPC分类号： G01N27/409 , G01N27/407 , G01N27/413 , B60H1/32 , H01L7/00
CPC分类号： G01N27/4078 , G01N27/4077
摘要： A gas sensor having a sensor element which is immobilized in gas-tight fashion in a metal housing. The gas sensor has a double-walled protective tube with an outer protective sleeve and an inner protective sleeve, each of which possesses openings for the entry and/or exit of gas. The inner protective sleeve forms a gas space into which the sensor element projects with a section at the measurement-gas end. The outer protective sleeve is a sleeve having a closed enveloping surface, the openings for the entry and/or exit of gas being arranged in the cavity at the end face of the sleeve. The gas space formed by the inner protective sleeve has, perpendicular to the extension direction of the sensor element, a rectangular cross section.
摘要翻译： PCT No.PCT / DE96 / 02210 Sec。 371日期1997年10月14日第 102（e）1997年10月14日PCT PCT 1996年11月20日PCT公布。出版物WO97 / 33165 日期1997年9月12日一种具有传感器元件的气体传感器，其以气密方式固定在金属壳体中。气体传感器具有双壁保护管，其具有外部保护套和内部保护套，每个保护套具有用于进入和/或排出气体的开口。内部保护套形成气体空间，传感器元件在测量气体端部与部分一起突出。外保护套是具有封闭的包络表面的套筒，用于气体的进入和/或排出的开口布置在套筒的端面处的空腔中。由内保护套筒形成的气体空间垂直于传感器元件的延伸方向具有矩形截面。

10. 发明授权

US5632883A Method and a device for detecting the oxygen content in gases 失效
标题翻译：用于检测气体中氧含量的方法和装置
公开(公告)号：US5632883A
公开(公告)日：1997-05-27
申请号：US545848
申请日：1995-11-13
申请人： Gerhard Hoetzel
发明人： Gerhard Hoetzel
IPC分类号： G01N27/409 , G01N27/419 , G01N27/407
CPC分类号： G01N27/419
摘要： The invention relates to a device for detecting the oxygen content in a gas to be measured, wherein the device comprises at least one concentration cell which includes a measuring electrode, a solid electrolyte and a reference electrode. The measuring electrode communicates with the gas to be measured and is connected via the solid electrolyte to the reference electrode, which communicates with a reference gas volume. The reference gas volume is separated from the gas to be measured in such a way that a particle exchange between the reference gas volume and the gas to be measured is at least impeded. The output voltage of the concentration cell, which voltage can be tapped off between the measuring electrode and the reference electrode, represents a measure of the difference in the oxygen concentrations in the gas to be measured and in the reference gas volume. The device further comprises a current source which can be coupled in between the reference electrode and the measuring electrode in such a way that in the coupled-in state a current flow results which is directed such that oxygen is transported in the solid electrolyte from the measuring electrode to the reference electrode. The device further comprises switching means which, in a first switching state, couples the current source to the concentration cell and which, in a second switching state, decouples the current source from the concentration cell, so that the voltage between the measuring electrode and the reference electrode in the decoupled state is not affected by the current source.
摘要翻译： PCT No.PCT / DE95 / 00258 Sec。 371日期：1995年11月13日 102（e）1995年11月13日，PCT提交1995年2月28日PCT公布。 WO95 / 24643 PCT出版物日期1995年9月14日本发明涉及一种用于检测待测气体中的氧含量的装置，其中该装置包括至少一个浓度池，其包括测量电极，固体电解质和参比电极。测量电极与待测气体连通，并通过固体电解质与参比电极连接，参比电极与参考气体体积连通。将参考气体体积与待测量的气体以至少阻碍参考气体体积和被测量气体之间的颗粒交换的方式分离。可以在测量电极和参比电极之间抽出电压的浓度单元的输出电压表示待测气体和参考气体体积中的氧气浓度差的度量。该装置还包括电流源，其可以以这样的方式耦合在参考电极和测量电极之间，使得在耦合状态下导致电流流动导致氧气在固体电解质中从测量电极到参比电极。该装置还包括开关装置，其在第一开关状态下将电流源耦合到浓度电池，并且在第二开关状态下，将电流源与浓度电池分离，使得测量电极和解耦状态的参比电极不受电流源的影响。

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