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    • 9. 发明授权
    • Color photographic materials containing stabilizers
    • 含有稳定剂的彩色照相材料
    • US4430425A
    • 1984-02-07
    • US389995
    • 1982-06-18
    • David G. Leppard
    • David G. Leppard
    • G03C7/26C07C27/00C07C39/11C07C41/00C07C43/178C07C51/00C07C59/52C07C67/00C07C69/732C07C231/00C07C233/00C07C233/25C07C233/43C07C235/32C07C235/34C07C237/20C07C253/00C07C255/00C07C255/36C07C301/00C07C303/00C07C311/29C07D307/12C07D307/42C07D309/12C07F9/38C07F9/40G03C7/392G03C7/38
    • C07D307/42C07C43/1785C07D307/12C07D309/12C07F9/4006C07F9/4056G03C7/39216
    • Color photographic silver halide material which contains in at least one coupler containing silver halide emulsion layer or in a layer adjacent thereto(a) a hydroquinone of the formula ##STR1## wherein p is 1 or 2 and q is 0 or 1, provided that p+q is 1 or 2, R is a radical of the formula ##STR2## wherein Q is selected from the residues (1) --COZR.sub.4, wherein Z is O or NR.sub.5, and R.sub.4 is hydrogen, alkyl optionally interrupted by oxygen, cycloalkyl, alkenyl, aryl, aralkyl or a heterocyclic ring, and R.sub.5 is hydrogen or alkyl or together with R.sub.4 and the nitrogen atom to which they are bonded form a heterocyclic ring,(2) --OX, wherein X is R.sub.5 or --COR.sub.7, wherein R.sub.7 is hydrogen, alkyl cycloalkyl, alkenyl, aryl or aralkyl,(3) --NR.sub.8 R.sub.9, wherein R.sub.8 is hydrogen or alkyl, and R.sub.9 is hydrogen, alkyl or --COR.sub.7, or R.sub.8 and R.sub.9 together with the nitrogen atom to which they are bonded form a ring,(4) --P(O)(OR.sub.10 ')([O].sub.x R.sub.11 '), wherein x is 0 or 1, and if x is 1, R.sub.10 ' and R.sub.11 ' are hydrogen or alkyl or form together an alkylene chain, and if x is 0 R.sub.10 ' is alkyl,(5) --SO.sub.2 NR.sub.5 R.sub.6, wherein R.sub.5 and R.sub.6 are hydrogen or alkyl, or(6) cyano, n is 1 to 20, k is 1 or 2, R.sub.2 and R.sub.3 are alkyl and if Q is CO.sub.2 R.sub.4, either R.sub.2 or R.sub.3 is optionally substituted by --CO.sub.2 R.sub.4, or R.sub.2 and R.sub.3 form together an alkylene chain, and R.sub.1 is alkyl or a group of the formula ##STR3## or (b) a salt thereof, has an improved stability to light.
    • 在含有卤化银乳剂层的至少一个成色剂或与其相邻的层中含有(a)下式的氢醌的彩色照相卤化银材料:其中p为1或2,q为0或1,条件是p 其中Q选自残基(1)-COZR4,其中Z为O或NR5,R4为氢,任选被氧环烷基取代的烷基,环烷基,环烷基, 烯基,芳基,芳烷基或杂环,R 5为氢或烷基,或与R 4一起形成杂环的氮原子,(2)-OX,其中X为R5或-COR7为氢, 烷基环烷基,烯基,芳基或芳烷基,(3)-NR8R9,其中R8是氢或烷基,R9是氢,烷基或-COR7或R8和R9与它们所键合的氮原子一起形成环, (4)-P(O)(OR 10')([O] x R 11'),其中x为0或1,如果x为1,则R 10'和R 11'为氢或烷基或一起形成亚烷基 (5)-SO 2 NR 5 R 6,其中R 5和R 6为氢或烷基,或(6)氰基,n为1至20,k为1或2,R 2和R 3为烷基 并且如果Q是CO 2 R 4,则R 2或R 3任选被-CO 2 R 4取代,或者R 2和R 3一起形成亚烷基链,并且R 1是烷基或下式的基团或其(b)其盐, 提高光稳定性。