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    • 2. 发明授权
    • Thermal treatment wall
    • 热处理墙
    • US6142706A
    • 2000-11-07
    • US78376
    • 1998-05-13
    • Roger D. AinesRobin L. NewmarkKevin G. Knauss
    • Roger D. AinesRobin L. NewmarkKevin G. Knauss
    • B09C1/00B09C1/06B09C1/08E02D19/14B09B1/00
    • B09C1/08B09C1/002B09C1/062B09C2101/00
    • A thermal treatment wall emplaced to perform in-situ destruction of contaminants in groundwater. Thermal destruction of specific contaminants occurs by hydrous pyrolysis/oxidation at temperatures achievable by existing thermal remediation techniques (electrical heating or steam injection) in the presence of oxygen or soil mineral oxidants, such as MnO.sub.2. The thermal treatment wall can be installed in a variety of configurations depending on the specific objectives, and can be used for groundwater cleanup, wherein in-situ destruction of contaminants is carried out rather than extracting contaminated fluids to the surface, where they are to be cleaned. In addition, the thermal treatment wall can be used for both plume interdiction and near-wellhead in-situ groundwater treatment. Thus, this technique can be utilized for a variety of groundwater contamination problems.
    • 一个热处理墙放置在地下水中进行原位破坏污染物。 在氧气或土壤矿物氧化剂如MnO2存在下,通过现有热修复技术(电加热或蒸汽注入)可实现的温度,通过含水热解/氧化发生特定污染物的热破坏。 热处理壁可以根据具体目标安装在各种配置中,并且可用于地下水净化,其中进行污染物的原位破坏,而不是将污染的流体提取到表面,在那里它们将被 清理 此外,热处理墙可用于羽流拦截和近井口原位地下水处理。 因此,这种技术可以用于各种地下水污染问题。
    • 4. 发明授权
    • Active cooling-based surface confinement system for thermal soil
treatment
    • 用于热土处理的主动冷却表面约束系统
    • US5681130A
    • 1997-10-28
    • US603112
    • 1996-02-20
    • Roger D. AinesRobin L. Newmark
    • Roger D. AinesRobin L. Newmark
    • B09C1/06E21B43/24B09B3/00A62D3/00
    • B09C1/06E21B43/24B09C2101/00
    • A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders.
    • 公开了一种用于表面限制的热障,主动冷却以在浅(5-20​​英尺)的地下污染物的热修复期间控制地下压力。 如果蒸汽注入用于地下加热,则主动冷却的热屏障允许蒸汽以比土壤的约束强度高得多(20-60 psi)的压力注入土壤,同时防止蒸汽渗透。 上升的蒸汽在热障 - 地表面界面处被冷凝成液态水。 由热障强迫的快速温度下降将地下压力降至大气压以下。 蒸汽和污染物蒸气由热毯包含,热毯可以由各种材料制成,例如钢板,混凝土板,膜,织物袋或橡胶囊。
    • 9. 发明申请
    • SYNTHESIS OF TRIAZOLE-BASED AND IMIDAZOLE-BASED ZINC CATALYSTS
    • 基于三唑和基于咪唑的锌金属催化剂的合成
    • US20110293496A1
    • 2011-12-01
    • US12787356
    • 2010-05-25
    • Carlos A. ValdezJoe H. Satcher, JR.Roger D. AinesSarah E. Baker
    • Carlos A. ValdezJoe H. Satcher, JR.Roger D. AinesSarah E. Baker
    • B01D53/62C07D403/14C07F3/06
    • C07D403/14B01D53/1493B01D53/62B01D2252/00B01D2257/504B01J31/1815B01J2231/34B01J2531/0258B01J2531/26Y02C10/04Y02P20/152
    • Various methods and structures of complexes and molecules are described herein related to a zinc-centered catalyst for removing carbon dioxide from atmospheric or aqueous environments. According to one embodiment, a method for creating a tris(triazolyl)pentaerythritol molecule includes contacting a pentaerythritol molecule with a propargyl halide molecule to create a trialkyne molecule, and contacting the trialkyne molecule with an azide molecule to create the tris(triazolyl)pentaerythritol molecule. In another embodiment, a method for creating a tris(imidazolyl)pentaerythritol molecule includes alkylating an imidazole 2-carbaldehyde molecule to create a monoalkylated aldehyde molecule, reducing the monoalkylated aldehyde molecule to create an alcohol molecule, converting the alcohol molecule to create an alkyl halide molecule using thionyl halide, and reacting the alkyl halide molecule with a pentaerythritol molecule to create a tris(imidazolyl)pentaerythritol molecule. In another embodiment, zinc is bound to the tris(triazolyl)pentaerythritol molecule to create a zinc-centered tris(triazolyl)pentaerythritol catalyst for removing carbon dioxide from atmospheric or aqueous environments.
    • 本文描述了复合物和分子的各种方法和结构,涉及用于从大气或水性环境中除去二氧化碳的锌中心催化剂。 根据一个实施方案,用于产生三(三唑基)季戊四醇分子的方法包括使季戊四醇分子与炔丙基卤化物分子接触以产生三炔分子,并使三炔分子与叠氮化物分子接触以产生三(三唑基)季戊四醇分子 。 在另一个实施方案中,产生三(咪唑基)季戊四醇分子的方法包括将咪唑2-甲醛分子烷基化以产生单烷基化醛分子,还原单烷基化醛分子以产生醇分子,转化醇分子以产生烷基卤 分子,并使烷基卤化物分子与季戊四醇分子反应以产生三(咪唑基)季戊四醇分子。 在另一个实施方案中,锌与三(三唑基)季戊四醇分子结合以产生用于从大气或水环境中除去二氧化碳的锌中心三(三唑基)季戊四醇催化剂。