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    • 1. 发明申请
    • Ionic liquids as solvents
    • 离子液体作为溶剂
    • US20090012297A1
    • 2009-01-08
    • US12108347
    • 2008-04-23
    • Philip F. PagoriaAmitesh MaitiAlexander GashThomas Yong HanChristine OrmeLaurence Fried
    • Philip F. PagoriaAmitesh MaitiAlexander GashThomas Yong HanChristine OrmeLaurence Fried
    • C07C209/84C07D241/20
    • C07C209/84C07D241/20Y02P20/542C07C211/52
    • A method in one embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having a fluoride anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of about 90° C. or less during the contacting. A method in another embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having an acetate or formate anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of less than about 90° C. during the contacting. A method for purifying a strongly hydrogen bonded organic material according to one another embodiment includes dissolving a strongly hydrogen bonded organic material, selected from a group consisting of 1,3,5-triamino-2,4,6-trinitrobenzene and 2,6-diamino-3,5-dinitropyrazine-1-oxide, in a solution comprising an ionic liquid, the ionic liquid having an anion selected from a group consisting of a fluoride anion, an acetate anion, and a formate anion; maintaining the solution at a temperature of about 70° C. or less during the contacting; and recrystallizing the strongly hydrogen bonded organic material.
    • 在一个实施方案中的方法包括使强氢键合有机材料与具有氟阴离子的离子液体接触,以溶解强氢键合的有机材料; 并且在接触期间将离子液体维持在约90℃或更低的温度。 在另一个实施方案中的方法包括使强氢键合有机材料与具有乙酸盐或甲酸根阴离子的离子液体接触,以溶解强氢键合有机材料; 并且在接触期间将离子液体保持在小于约90℃的温度。 根据另一个实施方案的用于纯化强氢键合的有机材料的方法包括将选自1,3,5-三氨基-2,4,6-三硝基苯和2,6-二硝基苯的强氢键合有机材料溶解, 二氨基-3,5-二硝基吡嗪-1-氧化物,在包含离子液体的溶液中,所述离子液体具有选自氟化物阴离子,乙酸根阴离子和甲酸根阴离子的阴离子; 在接触期间将溶液保持在约70℃或更低的温度; 并重结晶强氢键合的有机材料。