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    • 4. 发明授权
    • Benzylidenecyanoacetates and a method for making benzylidenecyanoacetates
    • 亚苄基乙酰乙酸盐和制备亚苄基乙酰乙酸盐的方法
    • US06180813B2
    • 2001-01-30
    • US09330723
    • 1999-06-11
    • Robin F. Righettini
    • Robin F. Righettini
    • C07C25503
    • C07C255/23C08G63/91
    • Benzylidenecyanoacetates having a structure represented by wherein each R4 and R5 is the same or different and is selected from alkoxy, alkyl or alkyl ether. These benzylidenecyanoacetates are liquid at room temperature, have low volatility and are odor free and, thus, are useful in formulating adhesives and coatings. There is also provided a method for making a benzylidenecyanoacetate having a structure represented by formula B the method including: (e) reacting an alkyl cyanoacetate with a benzaldehyde to produce an alkyl benzylidenecyanoacetate and then (f) reacting the resulting alkyl benzylidenecyanoacetate with a hydroxy-functional reactant to produce the benzylidenecyanoacetate of formula B, wherein R6 is an alkyl, alkoxy, alkyl ether or a polymer backbone residue moiety.
    • 具有由R4和R5各自表示的结构的亚苄基乙酰乙酸酯相同或不同,选自烷氧基,烷基或烷基醚。 这些亚苄基乙酰乙酸酯在室温下为液体,挥发性低,无臭,因此可用于配制粘合剂和涂料。还提供了制备具有式B所示结构的亚苄基亚乙酸乙酯的方法,该方法包括:(e) 使氰基乙酸烷基酯与苯甲醛反应以产生亚苄基亚乙酰基烷基烷基酯,然后(f)使所得的烷基亚苄基乙酰基乙酸烷基酯与羟基官能的反应物反应,生成式B的亚苄基亚乙酰乙酸酯,其中R 6是烷基,烷氧基,烷基醚或聚合物骨架 残基部分。
    • 10. 发明授权
    • Reactive adhesives and coatings with trifunctional olefinic monomers
    • 具有三官能烯烃单体的反应性粘合剂和涂料
    • US06562181B2
    • 2003-05-13
    • US09330489
    • 1999-06-11
    • Robin F. Righettini
    • Robin F. Righettini
    • B32B3100
    • C09J4/00C08F222/32C08J5/124Y10T156/1158C08F222/14
    • A method for bonding together two substrates that includes applying to a first substrate an adhesive composition that includes (a) a trifunctional olefinic first monomer, (b) an olefinic second monomer that is copolymerizable with the first monomer and (c) a free radical initiator and then contacting a second substrate to the composition-applied first substrate so that the first and second substrate adhesively bond together. There is also provided a method for providing a coating on a substrate that includes applying to the substrate a composition that includes (a) a trifunctional olefinic first monomer, (b) an olefinic second monomer that is copolymerizable with the first monomer and (c) a free radical initiator and then allowing the composition to cure. Preferably, the adhesive or coating composition includes (a) a free radical polymerizable monomer component that includes a trifunctional olefinic first monomer and an olefinic second monomer that is copolymerizable with the first monomer and (b) a redox initiator system, wherein the adhesive composition is a liquid at room temperature and is curable at room temperature.
    • 一种粘合在一起的两个基材的方法,包括向第一基材施加粘合剂组合物,所述粘合剂组合物包括(a)三官能烯烃第一单体,(b)可与第一单体共聚的烯属第二单体和(c)自由基引发剂 然后使第二基板与组合物施加的第一基板接触,使得第一和第二基板粘合在一起。 还提供了一种在基材上提供涂层的方法,包括向基材施加包含(a)三官能烯烃第一单体的组合物,(b)可与第一单体共聚的烯属第二单体和(c) 自由基引发剂,然后使组合物固化。 优选地,粘合剂或涂料组合物包括(a)可自由基聚合的单体组分,其包含三官能烯烃第一单体和可与第一单体共聚的烯属第二单体和(b)氧化还原引发剂体系,其中粘合剂组合物为 室温下为液体,在室温下可固化。