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    • 7. 发明授权
    • Reverse thermal gels as support for rapid prototyping
    • 反向热凝胶作为快速原型的支持
    • US07368484B2
    • 2008-05-06
    • US11544624
    • 2006-10-10
    • Avraham Levy
    • Avraham Levy
    • G03C9/08C08F2/46
    • B29C35/02B29C64/106B29C64/40B29C67/24B29K2995/0012B33Y10/00B33Y70/00C08L1/14C08L71/02C08L75/16C08L2666/02
    • The present invention relates to novel polymeric compositions that exhibit Reverse Thermal Gelation (RTG) properties for use as Support Materials (SM) in the manufacture of three-dimensional objects. These polymers are Temperature Sensitive Polymers that respond with a significant change of properties to a small change in temperature. Temperature Sensitive Polymers exhibit cloud point (CP) or lower critical solution temperature (LCST) in aqueous solutions. Water-soluble Temperature Sensitive Polymers are chosen to give low viscosity liquid at low temperature when dissolved in water and by that to permit easy dispensing at low temperature. Raising the temperature above their gelation temperature (Tgel) will result in solidification of the composition. At its gel position the material has favorable characteristics as a support and building material. The gel layers have the appropriate toughness and dimensional stability to support the model layers during the building process. After the building process is completed the gel can be cooled down to a temperature below its Tgel so the gel can liquefy and be removed easily by rinsing with water.
    • 本发明涉及在三维物体的制造中表现出用作支撑材料(SM)的反向热凝胶(RTG)性质的新型聚合物组合物。 这些聚合物是温度敏感聚合物,其响应特性的显着变化达到微小的温度变化。 温度敏感聚合物在水溶液中显示浊点(CP)或较低临界溶解温度(LCST)。 选择水溶性温度敏感聚合物,以便在溶解在水中时在低温下得到低粘度液体,并允许在低温下容易分配。 提高温度超过其凝胶化温度(T凝胶)会导致组合物的凝固。 在其凝胶位置,该材料具有作为支撑和建筑材料的有利特征。 凝胶层在建造过程中具有适当的韧性和尺寸稳定性以支持模型层。 在完成构建过程之后,凝胶可以冷却至低于其凝胶的温度,因此凝胶可以液化并通过用水冲洗容易地除去。
    • 8. 发明申请
    • Reverse thermal gels as support for rapid prototyping
    • 反向热凝胶作为快速原型的支持
    • US20070032563A1
    • 2007-02-08
    • US11544624
    • 2006-10-10
    • Avraham Levy
    • Avraham Levy
    • C08F2/50
    • B29C35/02B29C64/106B29C64/40B29C67/24B29K2995/0012B33Y10/00B33Y70/00C08L1/14C08L71/02C08L75/16C08L2666/02
    • The present invention relates to novel polymeric compositions that exhibit Reverse Thermal Gelation (RTG) properties for use as Support Materials (SM) in the manufacture of three-dimensional objects. These polymers are Temperature Sensitive Polymers that respond with a significant change of properties to a small change in temperature. Temperature Sensitive Polymers exhibit cloud point (CP) or lower critical solution temperature (LCST) in aqueous solutions. Water-soluble Temperature Sensitive Polymers are chosen to give low viscosity liquid at low temperature when dissolved in water and by that to permit easy dispensing at low temperature. Raising the temperature above their gelation temperature (Tgel) will result in solidification of the composition. At its gel position the material has favorable characteristics as a support and building material. The gel layers have the appropriate toughness and dimensional stability to support the model layers during the building process. After the building process is completed the gel can be cooled down to a temperature below its Tgel so the gel can liquefy and be removed easily by rinsing with water.
    • 本发明涉及在三维物体的制造中表现出用作支撑材料(SM)的反向热凝胶(RTG)性质的新型聚合物组合物。 这些聚合物是温度敏感聚合物,其响应特性的显着变化达到微小的温度变化。 温度敏感聚合物在水溶液中显示浊点(CP)或较低临界溶解温度(LCST)。 选择水溶性温度敏感聚合物,以便在溶解在水中时在低温下得到低粘度液体,并允许在低温下容易分配。 提高温度超过其凝胶化温度(T凝胶)会导致组合物的凝固。 在其凝胶位置,该材料具有作为支撑和建筑材料的有利特征。 凝胶层在建造过程中具有适当的韧性和尺寸稳定性以支持模型层。 在完成构建过程之后,凝胶可以冷却至低于其凝胶的温度,因此凝胶可以液化并通过用水冲洗容易地除去。
    • 10. 发明授权
    • Reverse thermal gels and the use thereof for rapid prototyping
    • 反向热凝胶及其用于快速成型
    • US06863859B2
    • 2005-03-08
    • US10218514
    • 2002-08-15
    • Avraham Levy
    • Avraham Levy
    • B29C67/00B29C67/24B29C35/02C08J5/00G03C5/00
    • B29C35/02B29C64/106B29C64/40B29C67/24B29K2995/0012B33Y10/00B33Y70/00C08L1/14C08L71/02C08L75/16C08L2666/02
    • The present invention relates to novel polymeric compositions that exhibit Reverse Thermal Gelation (RTG) properties for use as Support Materials (SM) in the manufacture of three-dimensional objects. These polymers are Temperature Sensitive Polymers that respond with a significant change of properties to a small change in temperature. Temperature Sensitive Polymers exhibit cloud point (CP) or lower critical solution temperature (LCST) in aqueous solutions. Water-soluble Temperature Sensitive Polymers are chosen to give low viscosity liquid at low temperature when dissolved in water and by that to permit easy dispensing at low temperature. Raising the temperature above their gelation temperature (Tgel) will result in solidification of the composition. At its gel position the material has favorable characteristics as a support and building material. The gel layers have the appropriate toughness and dimensional stability to support the model layers during the building process. After the building process is completed the gel can be cooled down to a temperature below its Tgel so the gel can liquefy and be removed easily by rinsing with water.
    • 本发明涉及在三维物体的制造中表现出用作支撑材料(SM)的反向热凝胶(RTG)性质的新型聚合物组合物。 这些聚合物是温度敏感聚合物,其响应特性的显着变化达到微小的温度变化。 温度敏感聚合物在水溶液中显示浊点(CP)或较低临界溶解温度(LCST)。 选择水溶性温度敏感聚合物,以便在溶解在水中时在低温下得到低粘度液体,并允许在低温下容易分配。 提高温度超过其凝胶化温度(Tgel)将导致组合物的凝固。 在其凝胶位置,该材料具有作为支撑和建筑材料的有利特征。 凝胶层在建造过程中具有适当的韧性和尺寸稳定性以支持模型层。 建筑过程完成后,凝胶可以冷却到低于其Tgel的温度,因此凝胶可以液化并通过用水冲洗容易地去除。