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    • 5. 发明授权
    • Polyol-based method for forming thin film aerogels on semiconductor
substrates
    • 用于在半导体衬底上形成薄膜气凝胶的基于多元醇的方法
    • US5807607A
    • 1998-09-15
    • US748926
    • 1996-11-14
    • Douglas M. SmithWilliam C. AckermanRichard A. Stoltz
    • Douglas M. SmithWilliam C. AckermanRichard A. Stoltz
    • B05D3/02H01L21/31H01L21/316H01L21/469B05D5/12H01L21/00
    • H01L21/02126H01L21/02203H01L21/02216H01L21/02282H01L21/02337H01L21/02343H01L21/02359H01L21/31695
    • This invention has enabled a new, simple nanoporous dielectric fabrication method. In general, this invention uses a polyol, such as glycerol, as a solvent. This new method allows both bulk and thin film aerogels to be made without supercritical drying, freeze drying, or a surface modification step before drying. Prior art aerogels have required at least one of these steps to prevent substantial pore collapse during drying. Thus, this invention allows production of nanoporous dielectrics at room temperature and atmospheric pressure, without a separate surface modification step. Although not required to prevent substantial densification, this new method does not exclude the use of supercritical drying or surface modification steps prior to drying. In general, this new method is compatible with most prior art aerogel techniques. Although this new method allows fabrication of aerogels without substantial pore collapse during drying, there may be some permanent shrinkage during aging and/or drying.
    • 本发明已经实现了一种新的简单的纳米多孔电介质制造方法。 通常,本发明使用多元醇如甘油作为溶剂。 这种新方法允许在超临界干燥,冷冻干燥或干燥前的表面改性步骤中制造体积和薄膜气凝胶。 现有技术的气凝胶需要这些步骤中的至少一个来防止在干燥期间大量的孔隙破裂。 因此,本发明允许在室温和大气压下制备纳米多孔电介质,而无需单独的表面改性步骤。 尽管不需要防止实质致密化,但是这种新方法并不排除在干燥之前使用超临界干燥或表面改性步骤。 通常,这种新方法与大多数现有技术的气凝胶技术相兼容。 虽然这种新方法允许在干燥期间制造气凝胶而没有实质的孔隙塌陷,但在老化和/或干燥期间可能存在一些永久收缩。
    • 8. 发明授权
    • Molten salt extractive distillation process for zirconium-hafnium
separation
    • 用于锆 - 铪分离的熔盐萃取蒸馏方法
    • US4874475A
    • 1989-10-17
    • US242570
    • 1988-09-12
    • David F. McLaughlinRichard A. Stoltz
    • David F. McLaughlinRichard A. Stoltz
    • B01D3/32B01D3/40C01G25/04C01G27/04C22B34/14
    • B01D3/322B01D3/40C01G25/04C01G27/04C22B34/14Y10S203/17Y10S203/90
    • Improvements are described to a process in which the extractive distillation separation of zirconium or hafnium may be accomplished using mixtures of fused alkali metal or alkali metal and alkaline earth chlorides as the solvent. The solvent composition is adjusted to provide a low-melting eutectic, permitting recirculation of the stripped solvent in the liquid phase, as well as reducing the temperature required for thermal stripping (reducing the corrosivity of the fluid). Stripping of the bottoms is accomplished at least partially by direct electrolysis of the bottoms stream, producing the zirconium-free salt recycle stream to be transferred to the top of the column, and at least partially eliminating the need for chemical reduction of the tetrachlorides to metal (a costly process generating undersirable waste streams). Regeneration of the reflux is accomplished in a presurized condenser system, of one or more stages, with all material transport to be done in either the liquid or vapor states.
    • 将改进描述为可以使用熔融碱金属或碱金属和碱土金属氯化物作为溶剂的混合物来完成锆或铪的萃取蒸馏分离的方法。 调节溶剂组成以提供低熔点共晶体,允许汽提溶剂在液相中再循环,以及降低热剥离所需的温度(降低流体的腐蚀性)。 至少部分地通过底部物流的直接电解来完成底部物质的汽提,产生无锆盐再循环物流转移到塔顶部,并且至少部分地消除了将四氯化碳化学还原成金属的需要 (造成不良废物流的成本高昂的过程)。 回流的再生在一个或多个阶段的预先冷凝器系统中实现,所有的物质输送都以液态或蒸汽状态进行。
    • 10. 发明授权
    • Polyol-based method for forming thin film aerogels on semiconductor substrates
    • 用于在半导体衬底上形成薄膜气凝胶的基于多元醇的方法
    • US06821554B2
    • 2004-11-23
    • US09757073
    • 2001-01-08
    • Douglas M. SmithWilliam C. AckermanRichard A. Stoltz
    • Douglas M. SmithWilliam C. AckermanRichard A. Stoltz
    • B05D302
    • H01L21/02126H01L21/02203H01L21/02216H01L21/02282H01L21/02337H01L21/02343H01L21/02359H01L21/31695
    • This invention has enabled a new, simple nanoporous dielectric fabrication method. In general, this invention uses a polyol, such as glycerol, as a solvent. This new method allows both bulk and thin film aerogels to be made without supercritical drying, freeze drying, or a surface modification step before drying. Prior art aerogels have required at least one of these steps to prevent substantial pore collapse during drying. Thus, this invention allows production of nanoporous dielectrics at room temperature and atmospheric pressure, without a separate surface modification step. Although not required to prevent substantial densification, this new method does not exclude the use of supercritical drying or surface modification steps prior to drying. In general, this new method is compatible with most prior art aerogel techniques. Although this new method allows fabrication of aerogels without substantial pore collapse during drying, there may be some permanent shrinkage during aging and/or drying.
    • 本发明已经实现了一种新的简单的纳米多孔电介质制造方法。 通常,本发明使用多元醇如甘油作为溶剂。 这种新方法允许在超临界干燥,冷冻干燥或干燥前的表面改性步骤中制造体积和薄膜气凝胶。 现有技术的气凝胶需要这些步骤中的至少一个来防止在干燥期间大量的孔隙破裂。 因此,本发明允许在室温和大气压下制备纳米多孔电介质,而无需单独的表面改性步骤。 尽管不需要防止实质致密化,但是这种新方法并不排除在干燥之前使用超临界干燥或表面改性步骤。 通常,这种新方法与大多数现有技术的气凝胶技术相兼容。 虽然这种新方法允许在干燥期间制造气凝胶而没有实质的孔隙塌陷,但在老化和/或干燥期间可能存在一些永久收缩。