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1. 发明授权

US07723450B2 Transition metal compound, ligand system, catalyst system and process for preparing polyolefins 失效
标题翻译：过渡金属化合物，配体体系，催化剂体系及制备聚烯烃的方法
公开(公告)号：US07723450B2
公开(公告)日：2010-05-25
申请号：US11597346
申请日：2005-06-02
申请人： Robert L. Jones , Michael J. Elder , Jennifer Kipke , Alexander Koeppl , Markus Schopf , John Ewen
发明人： Robert L. Jones , Michael J. Elder , Jennifer Kipke , Alexander Koeppl , Markus Schopf , John Ewen
IPC分类号： C08F4/50
CPC分类号： C07D333/78 , C07D495/04 , C07F7/0814 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/17 , C08F2500/20 , C08F2500/04 , C08F210/14
摘要： The present invention relates to organometallic transition metal compounds of the formula (I) Z1AnZ2MXm (I) where Z1 is a coordinating group which comprises a six-π-electron central group which coordinates directly to M, A is a divalent bridge between the groups Z1 and Z2, Z2 is a coordinating group having the same meaning as Z1 or is a group comprising an open pentadienyl, a cyclopentadienyl-containing group or a heterocyclic, 5- or 6-membered group containing six π electrons, n=zero or 1, M is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements, the radicals X are identical or different and are each an organic or inorganic radical, m is 0, 1 or 2, and at least one of the three molecule fragments Z1, Z2 and A bears a monovalent organic radical.
摘要翻译：本发明涉及式（I）Z1AnZ2MXm（I）的有机金属过渡金属化合物，其中Z1是包括与M直接配位的六元电子中心基团的配位基团，A是组之间的二价桥接 Z 1和Z 2中，Z 2是具有与Z1相同含义的配位基团，或者是包含开式戊二烯基，含环戊二烯基的基团或杂环基，含有6个碳原子的5或6元基团; 电子，n = 0或1，M是元素周期表第3,4,5或6族的元素，基团X相同或不同，各自为有机或无机基团，m为0,1 或2，并且三个分子片段Z1，Z2和A中的至少一个具有一价有机基团。

2. 发明申请

US20070260023A1 Transition Metal Compound, Ligand System, Catalyst System and Process for Preparing Polyolefins 失效
标题翻译：过渡金属化合物，配体体系，催化剂体系和制备聚烯烃的方法
公开(公告)号：US20070260023A1
公开(公告)日：2007-11-08
申请号：US11597346
申请日：2005-06-02
申请人： Robert Jones , Michael Elder , Jennifer Kipke , Alexander Koeppl , Markus Schopf , John Ewen
发明人： Robert Jones , Michael Elder , Jennifer Kipke , Alexander Koeppl , Markus Schopf , John Ewen
IPC分类号： C08F10/00 , C07F17/00
CPC分类号： C07D333/78 , C07D495/04 , C07F7/0814 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/17 , C08F2500/20 , C08F2500/04 , C08F210/14
摘要： The present invention relates to organometallic transition metal compounds of the formula (I) Z1AnZ2MXm (I) where Z1 is a coordinating group which comprises a six-π-electron central group which coordinates directly to M, A is a divalent bridge between the groups Z1 and Z2, Z2 is a coordinating group having the same meaning as Z1 or is a group comprising an open pentadienyl, a cyclopentadienyl-containing group or a heterocyclic, 5- or 6-membered group containing six π electrons, n=zero or 1, M is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements, the radicals X are identical or different and are each an organic or inorganic radical, m is 0, 1 or 2, and at least one of the three molecule fragments Z1, Z2 and A bears a monovalent organic radical.
摘要翻译：本发明涉及式（I）的有机金属过渡金属化合物<？in-line-formula description =“In-line Formulas”end =“lead”→> Z （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Z 1是一个配位基团，其包括直接与M配位的6-π电子中心基团，A是Z 1和Z 2之间的二价桥， 2，Z 2是具有与Z 1 1相同含义的配位基团，或是包含开戊二烯基，含环戊二烯基的基团或杂环基含有六个π电子的5-或6-元基团，n = 0或1，M为元素周期表第3,4,5或6族元素，基团X相同或不同，各自独立地为有机或无机基团，m为0,1或2，并且三个分子片段Z 1，Z 2和A中的至少一个具有monov 有机基团。

3. 发明申请

US20050165184A1 Alpha olefin catalyst systems 失效
标题翻译： α-烯烃催化剂体系
公开(公告)号：US20050165184A1
公开(公告)日：2005-07-28
申请号：US11085969
申请日：2005-03-21
申请人： John Ewen
发明人： John Ewen
IPC分类号： C08F4/44
CPC分类号： C08F110/06 , C08F4/65912 , Y10S526/943 , C08F10/00 , C08F4/65927 , C08F4/6492 , C08F2500/02 , C08F2500/03 , C08F2500/15 , C08F2500/17
摘要： The present invention provides a method for varying the melting points and molecular weights of polyolefins by changing the structure of the catalyst used in the polymerization. The catalysts that are useful in the present invention are chiral, stereorigid metallocene catalyst of the formula R″(C5R′m)2MeQ. The catalysts include a bridge structure between the (C5R′m) groups and may contain substituents on the groups. It has been discovered that the melting points and molecular weights of the polymers produced by such catalysts are influenced by the bridge and substituents added to the (C5R′m) groups. Thus, the present invention provides a method for varying the melting points of the polymer product and a method of varying the molecular weights of the product by changing the components and structure of the metallocene catalysts. The present invention also provides a process for polymerizing olefins in which the melting points and/or molecular weights of the product may be controlled. Also included in the invention is the discovery that the melting points of the products are controlled by the number of inversions in the xylene insoluble fraction of the polymer.
摘要翻译：本发明提供了通过改变聚合中使用的催化剂的结构来改变聚烯烃的熔点和分子量的方法。可用于本发明的催化剂是式R“（C 5 R'm）2的手性，立体刚性茂金属催化剂 MeQ。催化剂包括在（C 5 -C 15）m N基团之间的桥结构，并且可以在基团上含有取代基。已经发现，由这种催化剂制备的聚合物的熔点和分子量受到加入到（C 5 -C 15）基团中的桥和取代基的影响。因此，本发明提供了改变聚合物产物的熔点的方法和通过改变茂金属催化剂的组分和结构来改变产物分子量的方法。本发明还提供了可以控制产物的熔点和/或分子量的烯烃聚合方法。本发明还包括以下发现：产物的熔点由聚合物的二甲苯不溶部分的反转次数控制。

4. 发明申请

US20080090978A1 Heterocyclic metallocenes and polymerization catalysts 有权
标题翻译：杂环金属茂和聚合催化剂
公开(公告)号：US20080090978A1
公开(公告)日：2008-04-17
申请号：US11823802
申请日：2007-06-28
申请人： John Ewen , Michael Elder , Robert Jones
发明人： John Ewen , Michael Elder , Robert Jones
IPC分类号： C08F4/42 , C07F17/00 , C07F7/02 , C08F10/00 , C08F10/06 , C08F4/64 , C08F4/6592 , C08L23/12 , C08F4/68 , C08F4/659 , C08F4/622 , C08F110/02 , C08F110/06 , C08F4/00
CPC分类号： C08F10/00 , C07D333/70 , C07D495/04 , C07F17/00 , C08F4/61912 , C08F4/65912 , C08F110/02 , C08F110/06 , C08F2420/05 , C08F4/65925 , C08F4/65927 , C08F4/619
摘要： A new class of heterocyclic metallocenes, a catalytic system containing them and a process for polymerizing addition polymerizable monomers using the catalytic system are disclosed; the heterocyclic metallocenes correspond to the formula (I): YjR″iZjjMeQkPl wherein Y is a coordinating group containing a six π electron central radical directly coordinating Me, to which are associated one or more radicals containing at least one non-carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R″ is a divalent bridge between the Y and Z groups; Z is a coordinating group, optionally being equal to Y; Me is a transition metal; Q is halogen or hydrocarbon substituents; P is a counterion; i is 0 or 1; j is 1-3; jj is 0-2; k is 1-3; and l is 0-2.
摘要翻译：公开了一类新的杂环金属茂，含有它们的催化体系和使用催化体系聚合加成聚合单体的方法; 所述杂环金属茂对应于式（I）：Y Z i R Z Z 其中Y是包含直接配位Me的六个π电子中心基团的配位基团，其中与一个或多个选自B，N，O，Al的至少一个非碳原子相连; ，Si，P，S，Ga，Ge，As，Se，In，Sn，Sb和Te; R“是Y和Z基团之间的二价桥; Z是一个协调组，任选地等于Y; 我是过渡金属; Q是卤素或烃取代基; P是一个抗衡离子; 我是0或1; j为1-3; jj是0-2; k为1-3; 和l是0-2。

5. 发明申请

US20090286945A9 Heterocyclic metallocenes and polymerization catalysts 有权
标题翻译：杂环金属茂和聚合催化剂
公开(公告)号：US20090286945A9
公开(公告)日：2009-11-19
申请号：US11823802
申请日：2007-06-28
申请人： John Ewen , Michael Elder , Robert Jones
发明人： John Ewen , Michael Elder , Robert Jones
IPC分类号： C08F4/42 , C07F17/00 , C07F7/02 , C08F10/00 , C08F10/06 , C08F4/64 , C08F4/6592 , C08L23/12 , C08F4/68 , C08F4/659 , C08F4/622 , C08F110/02 , C08F110/06 , C08F4/00
CPC分类号： C08F10/00 , C07D333/70 , C07D495/04 , C07F17/00 , C08F4/61912 , C08F4/65912 , C08F110/02 , C08F110/06 , C08F2420/05 , C08F4/65925 , C08F4/65927 , C08F4/619
摘要： A new class of heterocyclic metallocenes, a catalytic system containing them and a process for polymerizing addition polymerizable monomers using the catalytic system are disclosed; the heterocyclic metallocenes correspond to the formula (I): YjR″iZjjMeQkPl wherein Y is a coordinating group containing a six π electron central radical directly coordinating Me, to which are associated one or more radicals containing at least one non-carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R″ is a divalent bridge between the Y and Z groups; Z is a coordinating group, optionally being equal to Y; Me is a transition metal; Q is halogen or hydrocarbon substituents; P is a counterion; i is 0 or 1; j is 1-3; jj is 0-2; k is 1-3; and l is 0-2.
摘要翻译：公开了一类新的杂环金属茂，含有它们的催化体系和使用催化体系聚合加成聚合单体的方法; 杂环金属茂对应于式（I）：其中Y是含有直接配位Me的6个π电子中心基团的配位基团，其中与一个或多个含有至少一个选自以下的非碳原子的基团相关联： B，N，O，Al，Si，P，S，Ga，Ge，As，Se，In，Sn，Sb和Te; R“是Y和Z基团之间的二价桥; Z是一个协调组，任选地等于Y; 我是过渡金属; Q是卤素或烃取代基; P是一个抗衡离子; 我是0或1; j为1-3; jj是0-2; k为1-3; 和l是0-2。

6. 发明申请

US20070260025A1 Organometallic Transition Metal Compound, Biscyclopentadienyl Ligand System, Catalyst System and Process for Preparing Polyolefins 失效
公开(公告)号：US20070260025A1
公开(公告)日：2007-11-08
申请号：US10578059
申请日：2004-11-02
申请人： Michael Elder , Robert Jones , John Ewen
发明人： Michael Elder , Robert Jones , John Ewen
IPC分类号： B01J31/16 , C07D209/56 , C07D307/93 , C07D311/00 , C07D333/00 , C07D333/52 , C07D345/00 , C07F11/00 , C07F17/00 , C07F7/00 , C07F7/02 , C07F9/02 , C07F9/28 , C07F9/74 , C07F9/90 , C08F4/42
CPC分类号： C07D333/54 , C07F7/0814 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F210/16
摘要： The present invention relates to organometallic transition metal compounds of the formula (I) M1 is a metal of group 3, 4, 5 or 6 of the Periodic Table of the Elements or the lanthanicles, X are identical or different and are each an organic or inorganic radical, where two radicals X can also be joined to one another, n is a natural number from 1 to 4, T1, T2 are identical or different and are each a divalent group selected from the group consisting of —O—, —S—, —Se—, —Te—, —N(R13)_′—P(R13)—, —As(R13)—, Sb(R13)—, —Si(R13)2-, —C(R13 R14)—C(R13 R15)— and —C(R14)═C(R15)—, where R13, R14 and R15 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R1, R7 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R2 R8 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R3 R9 are identical or different and are each halogen or an organic radical having from 1 to 40 carbon atoms, where R3 is not methyl when T1 is —C(H)═C(H)—, R4, R5 R6, R10, R11 and R12 are identical or different and are each hydrogen, halogen or an organic radical having from 1 to 40 carbon atoms, or two adjacent radicals R4 , R5, R6, R10, R11 and R12 together with the atoms connecting them form a monocyclic or polycyclic, substituted or unsubstituted ring system which has from 1 to 40 carbon atoms and may also contain heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P, As, Sb and Si, or, if T1 or T2 is —O—, —S—, —Se— or —Te—, the radical R3 together with R4 and/or the radical R9 together with R10 forms a monocyclic or polycyclic, substituted or unsubstituted ring system which has from 1 to 40 carbon atoms and may also contain heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P, As, Sb and Si, and A is a bridge consisting of a divalent atom or a divalent group, biscyclopentadienyl ligand systems having such a substitution pattern, catalyst systems comprising at least one of the organometallic transition metal compounds of the present invention, a process for preparing polyolefins by polymerization or copolymerization of at least one olefin in the presence of one of the catalyst systems of the present invention and the polyolefins obtainable in this way, the use of the biscyclopentaclienyl ligand systems of the present invention for preparing organometallic transition metal compounds and a process for preparing organometallic transition metal compounds using the biscyclopentaclienyl ligand systems.

7. 发明授权

US06600441B2 Subsurface exploratory radar detector for a hand tool device 有权
标题翻译：用于手动工具的地下探测雷达探测器
公开(公告)号：US06600441B2
公开(公告)日：2003-07-29
申请号：US09973408
申请日：2001-10-09
申请人： Stefan Liedtke , Harald Schmitzer , John Ewen , Klaus Dass
发明人： Stefan Liedtke , Harald Schmitzer , John Ewen , Klaus Dass
IPC分类号： G01S1388
CPC分类号： H01Q21/24 , B25F5/00 , G01S7/025 , G01S7/411 , G01S13/885 , G01S13/90 , G01V3/12 , H01Q9/285
摘要： A radar detector for exploration of subsurface embedded objects comprising an antenna array (1) for high-frequency electromagnetic waves, which is connected and individually switchable with at least one transmit/receive unit, a time-controlled signal processor, an evaluation device for SAR and a display device. The antenna array (1) exhibiting at least three antennas (sx, rx, sy, ry) scanning an area by their positioning.
摘要翻译：一种用于探测地下嵌入物体的雷达检测器，包括用于高频电磁波的天线阵列（1），其与至少一个发射/接收单元连接并可单独切换，时间控制信号处理器，用于SAR的评估装置和显示装置。显示至少三个天线（sx，rx，sy，ry）的天线阵列（1）通过它们的定位扫描区域。

8. 发明申请

US20060100092A1 Polymerization catalysts, organic transition metal compounds, process for preparing polyolefins and polyolefins 失效
标题翻译：聚合催化剂，有机过渡金属化合物，制备聚烯烃和聚烯烃的方法
公开(公告)号：US20060100092A1
公开(公告)日：2006-05-11
申请号：US10543961
申请日：2004-02-05
申请人： Robert Jones , Naka Seidel , Michael Elder , John Ewen
发明人： Robert Jones , Naka Seidel , Michael Elder , John Ewen
IPC分类号： B01J31/00
CPC分类号： C08F10/06 , C07F7/003 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2410/03 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F2500/26 , C08F4/025 , C08F4/64189 , C08F4/69474
摘要： The present invention relates to catalyst systems for preparing isotactic polyolefins obtainable by reacting at least one chiral transition metal compound and at least one cocatalyst which is able to convert the chiral transition metal compound into a cation, where the chiral transition metal compound contains two bidentate chelating ligands connected to one another via a bridge and, if desired, one or two further monodentate ligands, with the four coordinating atoms of the two chelating ligands being in an approximately planar arrangement around the transition metal ion and up to two further ligands being located above and below this approximately planar coordination sphere formed by the four coordinating atoms of the two chelating ligands and, in the case of two such further ligands, these being in the trans position relative to one another, to the use of the catalyst systems of the present invention for preparing polyolefins, to a process for preparing polyolefins by polymerization or copolymerization of at least one olefin in the presence of one of the catalyst systems of the present invention, to the use of chiral transition metal compounds for preparing a catalyst system for the polymerization of olefins, to chiral transition metal compounds, to a process for preparing a catalyst system for olefin polymerization, to a process for preparing isotactic polyolefins, to polyolefins obtainable by a process according to the present invention, to polyolefin compositions comprising the polyolefins of the present invention and to products produced from such polyolefin compositions.
摘要翻译：本发明涉及用于制备全同立构聚烯烃的催化剂体系，其通过使至少一种手性过渡金属化合物和能够将手性过渡金属化合物转化为阳离子的至少一种助催化剂反应而获得，其中手性过渡金属化合物含有两个二齿螯合配体通过桥连接并且如果需要，一个或两个另外的单齿配体，两个螯合配体的四个配位原子在过渡金属离子周围处于大致平面的布置，并且多达两个另外的配体位于上面并且在由两个螯合配体的四个配位原子形成的该近似平面的配位球之下，在两个这样的另外的配体的情况下，它们相对于彼此处于反式位置，使用本发明的催化剂体系用于制备聚烯烃的方法，通过聚合制备聚烯烃的方法或在本发明的一种催化剂体系存在下至少一种烯烃的共聚合使用手性过渡金属化合物用于制备用于烯烃聚合的催化剂体系，至手性过渡金属化合物的方法，制备用于烯烃聚合的催化剂体系，制备全同立构聚烯烃的方法，可通过本发明的方法获得的聚烯烃包含本发明聚烯烃的聚烯烃组合物和由这种聚烯烃组合物制备的产品。

9. 发明申请

US20050192418A1 Heterocyclic metallocenes and polymerization catalysts 有权
标题翻译：杂环金属茂和聚合催化剂
公开(公告)号：US20050192418A1
公开(公告)日：2005-09-01
申请号：US10395686
申请日：2003-03-24
申请人： John Ewen , Michael Elder , Robert Jones , Yuri Bubitsky
发明人： John Ewen , Michael Elder , Robert Jones , Yuri Bubitsky
IPC分类号： C07D333/12 , C07D209/52 , C07D333/70 , C07D333/78 , C07D487/04 , C07D495/04 , C07F7/00 , C07F7/08 , C07F7/10 , C07F17/00 , C07F19/00 , C08F4/60 , C08F4/619 , C08F4/64 , C08F4/642 , C08F10/00 , C08F110/02 , C08F110/06 , C08F4/44
CPC分类号： C08F10/00 , C07D333/70 , C07D495/04 , C07F17/00 , C08F4/61912 , C08F4/65912 , C08F110/02 , C08F110/06 , C08F2420/05 , C08F4/65925 , C08F4/65927 , C08F4/619
摘要： A new class of heterocyclic metallocenes, a catalytic system containing them and a process for polymerizing addition polymerizable monomers using said catalytic system are disclosed; the heterocyclic metallocenes correspond to the formula (I): YjR″iZjjMeQkPl wherein Y is a coordinating group containing a six π electron central radical directly coordinatng Me, to which are associated one or more radicals containing at least one non-carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R″ is a divalent bridge between the Y and Z groups; Z is a coordinating group, optionally being equal to Y; Me is a transition metal; Q is halogen or hydrocarbon substituents; P is a counterion; i os 0 or 1; j is 1-3; jj is 0-2; k is 1-3; and l is 0-2.
摘要翻译：公开了一类新的杂环金属茂，含有它们的催化体系和使用所述催化体系聚合加成聚合单体的方法; 所述杂环金属茂对应于式（I）：Y Z i R Z Z 其中Y是含有直接配位于Me的六个π电子中心基团的配位基团，其中与一个或多个选自B，N，O，Al的至少一个非碳原子相连; ，Si，P，S，Ga，Ge，As，Se，In，Sn，Sb和Te; R“是Y和Z基团之间的二价桥; Z是一个协调组，任选地等于Y; 我是过渡金属; Q是卤素或烃取代基; P是一个抗衡离子; 我os 0或1; j为1-3; jj是0-2; k为1-3; 和l是0-2。

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