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1. 发明授权

US4682982A Antistatic N-higher mono alkyl and mono alkenyl neoalkanamides, processes for manufacturing thereof, antistatic compositions containing such amides, and processes for decreasing accumulations of static charges on laundry 失效
标题翻译：抗静电N型高级单烷基和单链烯基新烷酰胺，其制造方法，含有这些酰胺的抗静电组合物，以及降低衣物上静电荷累积的方法
公开(公告)号：US4682982A
公开(公告)日：1987-07-28
申请号：US716871
申请日：1985-03-27
申请人： Robert J. Steltenkamp , Michael A. Camara
发明人： Robert J. Steltenkamp , Michael A. Camara
IPC分类号： C11D3/32 , C07C67/00 , C07C231/00 , C07C231/02 , C07C233/05 , C09K3/16 , C11D1/52 , D06M13/38 , C07C103/34
CPC分类号： C11D3/0084 , C11D1/521 , Y10S524/913
摘要： N-higher alk(en)yl neoalkanamides are new compounds which unlike many other amides, are oily at washing temperatures, in the 10.degree. to 90.degree. C. range, and are capable of being adsorbed from wash and rinse waters by fibrous materials, such as laundry of synthetic, e.g., polyester, fabrics, which laundry is susceptible to being electrostatically charged, and decrease any electrostatic charge or inhibit accumulation thereof on such materials. Such neoalkanamides, e.g., N-coco-alkyl neodecanamide, can be incorporated in detergent compositions and in compositions for addition to laundry rinse waters, and in some instances it may be desirable for bentonite powder or agglomerate to also be included in such compositions to contribute fabric softening and other useful physical properties. Washing and rinsing operations are described in which N-higher alk(en)yl neoalkanamide is present in the waters, with and without supplementing small proportions of quaternary ammonium salt. Also described is a process for manufacturing higher alk(en)yl neoalkanamides in the form of oils which are desirably light in color and of improved purity.
摘要翻译： N-高级烷基（烯）基新烷酰胺是与许多其他酰胺不同的新化合物，在10至90℃的范围内在洗涤温度下是油性的，并且能够被纤维材料从洗涤和漂洗水中吸附，例如合成的衣服，例如聚酯，织物，衣物易于静电充电，并且减少任何静电荷或抑制其在这些材料上的积累。这种新烷酰胺，例如N-椰油烷基新癸酰胺，可以掺入洗涤剂组合物和用于添加到洗衣漂洗水中的组合物中，并且在一些情况下，膨胀土粉末或附聚物也可以包含在这种组合物中以促成织物柔软等有用的物理性质。描述了洗涤和漂洗操作，其中N-高级烷基（烯）基新烷酰胺存在于水中，有和没有补充少量的季铵盐。还描述了一种制备油的形式的高级烷基（烯）基新烷酰胺的方法，其期望是浅色和纯度提高。

2. 发明授权

US4619775A Antistatic agents which are multiamides of trialkylacetic acids and multiamines 失效
标题翻译：作为三烷基乙酸和多胺的多酰胺类的抗静电剂
公开(公告)号：US4619775A
公开(公告)日：1986-10-28
申请号：US734508
申请日：1985-05-16
申请人： Robert J. Steltenkamp , Michael A. Camara
发明人： Robert J. Steltenkamp , Michael A. Camara
IPC分类号： C11D3/32 , C08G69/02 , C08G69/26 , C09K3/16 , C11D3/37 , D06M3/30
CPC分类号： C08G69/02 , C08G69/26 , C11D3/3719
摘要： Polyamides of trialkylacetic acids and polyamines are new compounds which are of an oily nature at washing temperatures in the 10.degree. to 90.degree. C. range, are capable of being adsorbed from wash and rinse waters by fibrous material, such as laundry, of synthetic, fabrics, e.g., polyester, which laundry is susceptible to being electrostatically charged, and decrease any electrostatic charge or inhibit accumulation thereof on such materials. Such polyamides, e.g., that of neodecanoic acid and an alkylene polyoxyalkylene triamine, such as that which is sold by Exxon Chemical Americas under the name Jeffamine.RTM. T-403, can be incorporated in detergent compositions, in compositions for addition to rinse waters and in composition for application to laundry in a laundry dryer, and in some instances it may be desirable for bentonite powder or agglomerate also to be included in such compositions to contribute fabric softening and other useful physical properties. Washing and rinsing operations are described in which the polyamide is present in the wash or rinse water, with and without supplementing small proportions of quaternary ammonium salt, which improves antistatic effects on laundry containing polyamide (nylon) and acetate synthetics. Because the proportion of quaternary salt may be decreased, due to the presence of the invented polyamide, which is very effective in reducing static electricity on polyester fabric, its presence does not cause objectionable deposits on the treated fabrics and reduction of detergency due to reaction with anionic detergent is no longer a severe liability. There is also no reduction in brightening activity of optical brightener(s) present in the detergent composition and in the wash water.
摘要翻译：三烷基乙酸和多胺的聚酰胺是在10至90℃范围内的洗涤温度下具有油性的新化合物，能够通过纤维材料（例如衣物）吸收合成，织物，例如聚酯，其易于被静电带电，并且减少任何静电荷或抑制这些材料上的积聚。这样的聚酰胺，例如新癸酸和亚烷基聚氧化烯三胺，例如由Exxon Chemical Americas以名称Jeffamine TM T-403出售的那些，可以掺入洗涤剂组合物中，用于添加到漂洗水中的组合物和用于在衣物干燥器中应用于衣物的组合物，并且在一些情况下，膨胀土粉末或附聚物也可以包含在这种组合物中以有助于织物软化和其它有用的物理性质。描述了洗涤和漂洗操作，其中聚酰胺存在于洗涤或冲洗水中，具有和不具有补充少量的季铵盐，这改善了对含有聚酰胺（尼龙）和乙酸酯合成物的衣物的抗静电效果。由于季盐的比例可能降低，由于存在本发明的聚酰胺，这对聚酯织物的静电非常有效，其存在不会对经处理的织物造成令人反感的沉积物，并因与阴离子洗涤剂不再是严重责任。洗涤剂组合物和洗涤水中存在的荧光增白剂的增亮活性也没有降低。

3. 发明授权

US4714559A Antistatic agents which are diamines of trialkylacetic acids and diamines 失效
标题翻译：作为三烷基乙酸和二胺的二胺的抗静电剂
公开(公告)号：US4714559A
公开(公告)日：1987-12-22
申请号：US883193
申请日：1986-07-08
申请人： Robert J. Steltenkamp , Michael A. Camara
发明人： Robert J. Steltenkamp , Michael A. Camara
IPC分类号： C08G69/02 , C08G69/26 , C11D3/37 , D06M3/30
CPC分类号： C08G69/02 , C08G69/26 , C11D3/3719
摘要： Polyamides of trialkylacetic acids and polyamines are new compounds which are of an oily nature at washing temperatures in the 10.degree. to 90.degree. C. range, are capable of being adsorbed from wash and rinse waters by fibrous material, such as laundry, of synthetic fabrics, e.g., polyesters, which laundry is susceptible to being electrostatically charged, and decrease any electrostatic charge or inhibit accumulation thereof on such materials. Such polyamides, e.g., those of neodecanoic acid and ethylene diamine or hexamethylene diamine, N,N'-ethylene-bis-neodecanoamide and N,N'-hexamethylene-bis-neodecanoamide, respectively, can be incorporated in detergent compositions, in compositions for addition to rinse waters and in compositions for application to laundry in a laundry dryer.
摘要翻译：三烷基乙酸和多胺的聚酰胺是在10至90℃范围内的洗涤温度下具有油性的新化合物，能够被纤维材料如衣物从合成织物中吸收到洗涤和冲洗水中，例如聚酯，其易于被静电带电，并且减少任何静电电荷或抑制其在这些材料上的积聚。这些聚酰胺，例如新癸酸和乙二胺或六亚甲基二胺，N，N'-亚乙基 - 双 - 新癸酰胺和N，N'-六亚甲基 - 二新癸酰胺的那些分别可以掺入洗涤剂组合物中，除了在洗衣干衣机中冲洗水和用于洗衣的组合物中。

4. 发明授权

US4715862A Wash cycle fabric conditioning composition, process for manufacture of such composition, and method of use thereof 失效
标题翻译：洗涤循环织物调理组合物，这种组合物的制造方法及其使用方法
公开(公告)号：US4715862A
公开(公告)日：1987-12-29
申请号：US939653
申请日：1986-12-08
申请人： Robert J. Steltenkamp , Michael A. Camara
发明人： Robert J. Steltenkamp , Michael A. Camara
IPC分类号： C11D3/32 , C09K3/16 , C11D1/52 , D06M13/40
CPC分类号： C11D3/0084 , C11D1/521
摘要： A wash cycle fabric conditioning composition, which makes laundry washed in an automatic washing machine and dried in an automatic laundry dryer resistant to the accumulation of static charges thereon, and which may be in particulate, liquid, or other suitable form, comprises an antistatic N-higher alkyl neoalkanamide or an antistatic N-higher alkenyl neoalkanamide, or a mixture thereof, and a detergent builder, such as a water soluble builder salt or a zeolite, or a mixture thereof, as a carrier, or an aqueous medium containing a nonionic surface active agent. Specifically preferred neoalkanamides of the type described are N-higher alkyl neodecanamides, such as tallowalkyl neodecanamide. In some instances, bentonite may be included in the particulate compositions to soften the fabrics that are washed, and tertiary amines may be formulated into the liquid compositions to increase fabric softening action. Despite the fact that the conditioning composition is added to the was water in the wash cycle of the automatic washing machine, the neoalkanamide thereof does not react adversely with anionic detergents in the wash water, (unlike quaternary ammonium halide antistatic agents) so the cleaning power of the detergent in the wash water is not comprised, even when the detergent employed is an anionic detergent.Also within the invention are a process for manufacturing the particulate fabric conditioning composition and a method of using the compositions described.
摘要翻译：一种洗涤循环织物调理组合物，其使衣物在自动洗衣机中洗涤并在自动衣物干燥器中干燥，耐受其上的静电荷的积累，并且其可以是颗粒状，液体或其它合适的形式，包括抗静电N 或较高的烷基新烷酰胺或抗静电的N-高级链烯基新链烷酰胺或其混合物，以及洗涤剂助洗剂如水溶性助洗剂盐或沸石或其混合物作为载体，或含有非离子表面活性剂的水性介质表面活性剂。特别优选的所述类型的新烷酰胺类是N-高级烷基新癸酰胺，例如牛油烷基新癸酰胺。在某些情况下，膨润土可以包括在颗粒组合物中以使洗涤的织物软化，并且可以将叔胺配制成液体组合物以增加织物软化作用。尽管在自动洗衣机的洗涤循环中将调理组合物添加到水中，但是其新的烷酰胺不会与洗涤水中的阴离子洗涤剂（（不同于季铵卤化物抗静电剂））发生反应，因此清洁力即使使用的洗涤剂是阴离子洗涤剂也不包含洗涤水中的洗涤剂。本发明还涉及制造颗粒织物调理组合物的方法和使用所述组合物的方法。

5. 发明授权

US4676915A Antistatic composition and detergent compositions containing antistatic components 失效
标题翻译：含有抗静电成分的抗静电组合物和洗涤剂组合物
公开(公告)号：US4676915A
公开(公告)日：1987-06-30
申请号：US745731
申请日：1985-06-17
申请人： Robert J. Steltenkamp , Michael A. Camara
发明人： Robert J. Steltenkamp , Michael A. Camara
IPC分类号： A61K8/00 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/45 , A61Q5/00 , A61Q5/02 , A61Q5/12 , C08G69/02 , C08G69/26 , C09K3/16 , C11D1/52 , C11D1/62 , C11D3/20 , C11D3/26 , C11D3/32 , C11D3/37 , D06M13/02 , D06M13/224 , D06M13/244 , D06M13/248 , D06M13/256 , D06M13/262 , D06M13/322 , D06M13/345 , D06M13/402 , D06M13/405 , D06M13/438 , D06M13/46 , D06M13/463 , D06M3/30
CPC分类号： C11D3/32 , A61K8/416 , A61K8/42 , A61K8/45 , A61Q5/12 , C08G69/02 , C08G69/26 , C11D1/521 , C11D1/528 , C11D1/62 , C11D3/0084 , C11D3/3719
摘要： An antistatic composition, useful for addition to laundry detergents, shampoos and other preparations for treating fibrous and other materials to diminish tendencies thereof to accumulate electrostatic charges, comprises an amide of trialkylacetic acid and/or an amide of isostearic acid, and a quaternary ammonium salt in a certain range of proportions, with the proportion of amide(s) being greater than that of quaternary ammonium salt. The antistatic composition and the components thereof, in described proportion, are compatible with anionic detergents and other anionic compounds and good antistatic effects are obtainable on washed laundry, dryer-treated laundry and on shampooed hair when the antistatic composition or the components thereof is/are included in the laundry detergent composition, in the dryer product or in the shampoo, and such effects are obtained without the disadvantages attendant the presence of quaternary ammonium halide in anionic synthetic organic detergent based laundry detergent compositions and shampoos in sufficient proportion for the quaternary ammonium halide to make washed laundry or shampooed hair antistatic.
摘要翻译：可用于加入洗衣洗涤剂，洗发剂和其它用于处理纤维和其它材料以减少其趋势以积累静电荷的制剂的抗静电组合物包含三烷基乙酸和/或异硬脂酸酰胺和季铵盐在一定比例范围内，酰胺的比例大于季铵盐的比例。所述比例的抗静电组合物及其组分与阴离子洗涤剂和其它阴离子化合物相容，并且当抗静电组合物或组分为/或其组分时，可以在洗涤的衣物，干燥剂处理的衣物和洗发剂上获得良好的抗静电效果包括在洗衣洗涤剂组合物中，干燥器产品中或洗发剂中，并且获得了这样的效果，而没有伴随着季铵卤化物在阴离子合成有机洗涤剂的洗衣洗涤剂组合物和洗发剂中的季铵卤化物的比例足够的缺点使洗衣或洗发水的头发抗静电。

6. 发明授权

US4764291A Process for treating laundry with multiamide antistatic agents 失效
标题翻译：用多酰胺抗静电剂处理衣物的方法
公开(公告)号：US4764291A
公开(公告)日：1988-08-16
申请号：US122975
申请日：1987-11-19
申请人： Robert J. Steltenkamp , Michael A. Camara
发明人： Robert J. Steltenkamp , Michael A. Camara
IPC分类号： C08G69/02 , C08G69/26 , C11D3/37 , D06M3/30
CPC分类号： C11D3/3719 , C08G69/02 , C08G69/26
摘要： Polyamides of trialkylacetic acids and polyamines are new compounds which are of an oily nature at washing temperatures in the 10.degree. to 90.degree. C. range, are capable of being adsorbed from wash and rinse waters by fibrous material, such as laundry, of synthetic fabrics, e.g., polyesters, which laundry is susceptible to being electrostatically charged, and decrease any electrostatic charge or inhibit accumulation thereof on such materials. Such polyamides, e.g., those of neodecanoic acid and an alkylene polyoxyalkylene triamine, such as that which is sold by Exxon Chemical Americas under the name Jeffamine.RTM. T-403, can be incorporated in detergent compositions, in compositions for addition to rinse waters and in compositions for application to laundry in a laundry dryer.
摘要翻译：三烷基乙酸和多胺的聚酰胺是在10至90℃范围内的洗涤温度下具有油性的新化合物，能够被纤维材料如衣物从合成织物中吸收到洗涤和冲洗水中，例如聚酯，其易于被静电带电，并且减少任何静电电荷或抑制其在这些材料上的积聚。这样的聚酰胺，例如新癸酸和亚烷基聚氧化烯三胺的那些，例如由Exxon Chemical Americas以名称Jeffamine TM T-403出售的那些，可以加入到洗涤剂组合物中，用于添加到漂洗水中的组合物中用于在洗衣机中应用于衣物的组合物。

7. 发明授权

US4715970A Wash cycle additive antistatic composition for treatment of laundry, process for manufacture of such composition and method of use thereof 失效
标题翻译：用于洗涤洗涤循环添加剂抗静电组合物，用于制造这种组合物的方法及其使用方法
公开(公告)号：US4715970A
公开(公告)日：1987-12-29
申请号：US939313
申请日：1986-12-08
申请人： Robert J. Steltenkamp , Michael A. Camara
发明人： Robert J. Steltenkamp , Michael A. Camara
IPC分类号： C08G69/02 , C08G69/26 , C09K3/16 , C11D1/52 , C11D3/32 , C11D3/37
CPC分类号： C08G69/02 , C08G69/26 , C11D1/528 , C11D3/32 , C11D3/3719
摘要： A wash cycle additive antistatic composition, which, when added to a wash water in a washing machine, makes laundry washed in such automatic washing machine and dried in an automatic laundry dryer resistant to the accumulation of static charges thereon, and which may be in particulate, liquid or other suitable form, comprises an antistatic polyamide of trialkylacetic acid and polyamine, wherein the alkyls of the trialkylacetic acid moiety are of 1 to 10 carbon atoms each and the polyamine moiety contains from 2 to 5 amino groups, and a particulate carrier or liquid medium for the polyamide, which is a detergent builder or filler, or is an aqueous medium containing a nonionic surface active agent.
摘要翻译：一种洗涤循环添加剂抗静电组合物，其在洗衣机中加入洗涤水中时，使洗衣机在这种自动洗衣机中洗涤并在自动衣物干燥器中干燥，以抵抗其上的静电荷的累积，并且其可以是颗粒液体或其它合适的形式，包括三烷基乙酸和多胺的抗静电聚酰胺，其中三烷基乙酸部分的烷基各自为1至10个碳原子，多胺部分含有2至5个氨基，颗粒状载体或作为洗涤剂助剂或填料的聚酰胺的液体介质，或是含有非离子表面活性剂的水性介质。

8. 发明授权

US4931203A Method for making an automatic dishwashing detergent powder by spraying drying and post-adding nonionic detergent 失效
标题翻译：通过喷雾干燥和后添加非离子洗涤剂制造自动餐具洗涤剂粉末的方法
公开(公告)号：US4931203A
公开(公告)日：1990-06-05
申请号：US330928
申请日：1989-03-27
申请人： Fahim U. Ahmed , Charles E. Buck , Michael A. Camara , James F. Cush, Jr. , James A. Kaeser
发明人： Fahim U. Ahmed , Charles E. Buck , Michael A. Camara , James F. Cush, Jr. , James A. Kaeser
IPC分类号： C11D1/72 , C11D3/06 , C11D3/075 , C11D3/08
CPC分类号： C11D3/08 , C11D1/72 , C11D11/0088 , C11D3/06 , C11D3/3761
摘要： A free flowing, stable, water-soluble, powdered automatic dishwashing detergent with superior solubility, handling and storage characteristics is provided. The compositions comprises an inorganic polyphosphate carrier onto which is absorbed a nonionic detergent. The "loaded" carrier is mixed with powdered silicate and the other usual adjuvants such as bleach, pigment, etc. High levels of detergent are possible without adversely affecting the aforementioned advantages and superior characteristics.
摘要翻译：提供自由流动，稳定，水溶性，粉末状的自动洗碗洗涤剂，具有优异的溶解性，处理和储存特性。组合物包含无机多磷酸盐载体，其上吸收有非离子洗涤剂。 “负载”载体与粉状硅酸盐和其它通常的助剂如漂白剂，颜料等混合。高水平的洗涤剂是可能的，而不会不利地影响上述优点和优异的特性。

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