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1. 发明授权

US06524372B1 Silica gel incorporating polyazacycloalkane structural units 有权
标题翻译：掺有多氮杂环烷结构单元的硅胶
公开(公告)号：US06524372B1
公开(公告)日：2003-02-25
申请号：US09600954
申请日：2000-07-25
申请人： Robert Corriu , Catherine Reye , Ahmad Mehdi , Gérard Dubois , Claude Chuit , Franck Denat , Bruno Roux-Fouillet , Roger Guilard , Gilles Lagrange , Stéphane Brandes
发明人： Robert Corriu , Catherine Reye , Ahmad Mehdi , Gérard Dubois , Claude Chuit , Franck Denat , Bruno Roux-Fouillet , Roger Guilard , Gilles Lagrange , Stéphane Brandes
IPC分类号： B01D5302
CPC分类号： C07F7/0896 , B01D53/02 , B01D2253/20 , B01D2253/202 , B01D2256/12 , B01D2257/104 , C01B13/0262 , C01B15/013 , C01B21/0455 , C01B2210/0045 , C01B2210/0046 , C07F7/1804
摘要： A novel compound which can be used in the field of separation and purification of gases is disclosed. The compound can be incorporated into a silica gel incorporating polyazacycloalkane structural units for separating a predetermined gas from a mixture of gases. The mixture of gases is brought into contact with a metallated hybrid gel under conditions which make possible the absorption of the gas to be separated, followed by a phase of desorption of the attached gas, and the recovery of the gas.
摘要翻译：公开了一种可用于气体分离和纯化领域的新型化合物。该化合物可以并入含有用于从气体混合物中分离预定气体的多氮杂环烷结构单元的硅胶中。使气体混合物与金属化混合凝胶接触，使得可能吸收待分离的气体，随后附着气体的解吸相和气体的回收。

2. 发明授权

US06372903B1 Method for preparing polyazacycloalkanes grafted on silica gel and use of grafted compounds 失效
标题翻译：制备接枝在硅胶上的多氮杂环烷烃和使用接枝化合物的方法
公开(公告)号：US06372903B1
公开(公告)日：2002-04-16
申请号：US09600996
申请日：2000-07-26
申请人： Ahmad Mehdi , Franck Denat , Frédéric Barbette , Roger Guilard , Gilles Lagrange
发明人： Ahmad Mehdi , Franck Denat , Frédéric Barbette , Roger Guilard , Gilles Lagrange
IPC分类号： C07D25502
CPC分类号： B01J20/3263 , B01J20/3204 , B01J20/3219 , B01J20/3259 , B01J45/00 , C07F7/1804
摘要： The invention concerns a method for preparing polyazacycloalkanes immobilised on a silica gel from a polyazacycloalkane of formula (A) in which: R1 and R2 represent a hydrogen atom, an alkyl radical, or a [hetero(aryl)]alkyl radical; W1, W2 and W3 represent a radical of formula (B): —[(CT1T2)n—[N(R3)]p—(CT3T4)m]l— such as defined in the description; R3 represents a hydrogen atom, an alkyl radical or a [hetero(aryl)]alkyl radical, provided that the polyazacycloalkane ring of the compound of formula (A) comprises not more than 30 cyclic carbon atoms, and not more than 6 cyclic nitrogen atoms. The invention is characterised in that: (a) the compound of formula (A) is reacted with a compound of formula (C): Z—R4—Si(X1)(X2)(X3), such as defined in the description to form a compound of formula (D); (b) said compound of formula (D) is condensed on the silanol sites of a silica gel to form the immobilised polyazacycloalkane of formula (E); and (c) some ethanol sites having not reacted are, if required, protected by Z′, a group protecting the hydroxyl function. The invention is useful for separating oxygen from air.
摘要翻译：本发明涉及一种由式（A）的多氮杂环烷固定在硅胶上的多氮杂环烷烃的方法，其中：R1和R2表示氢原子，烷基或[杂（芳基）]烷基; W1，W2和W3表示式（B）的基团： - [（CT1T2）n- [N（R3）] p-（CT3T4）m] -1-如描述中所定义; R 3表示氢原子，烷基或[杂（芳基）]烷基，条件是式（A）化合物的多氮杂环烷烃环包含不多于30个环状碳原子，并且不超过6个环状氮原子。本发明的特征在于：（a）式（A）化合物与式（C）化合物：Z-R 4 -Si（X 1）（X 2）（X 3）形成式（D）的化合物; （b）所述式（D）化合物在硅胶的硅烷醇位上缩合形成式（E）的固定化的多氮杂环烷烃; 和（c）如果需要，一些没有反应的乙醇部位被保护羟基官能团的Z'保护。本发明可用于从空气中分离氧气。

3. 发明授权

US06534649B1 Silica gel incorporating polyazacycloalkane units comprising more than six nitrogen atoms, preparation process and use 有权
标题翻译：包含多于六个氮原子的多氮杂环烷烃单元的硅胶，制备方法和用途
公开(公告)号：US06534649B1
公开(公告)日：2003-03-18
申请号：US09624341
申请日：2000-07-24
申请人： Franck Denat , Géraud Dubois , Raphaël Tripier , Roger Guilard , Bruno Roux-Fouillet
发明人： Franck Denat , Géraud Dubois , Raphaël Tripier , Roger Guilard , Bruno Roux-Fouillet
IPC分类号： C07F718
CPC分类号： C07F7/18
摘要： Compound of formula (I): in which W1, W2 and W3, which are identical or different, each represent, independently of one another, a divalent radical chosen from those represented by the general formula (A): —[(CT5T6)a—(CT1T2)n—[N(R4)]p—(CT3T4)m—(CT7T8)b]1— (A) as defined in the description and in which R4 represents a hydrogen atom, an alkyl radical, a [(hetero)aryl]alkyl radical or a radical represented by the general formula (B), R5—Si(X1) (X2) (X3), as defined in the description, and R1, R2 and R3, which are identical or different, each represent, independently of one another and of R4, a hydrogen atom, an alkyl radical, a [(hetero)aryl]alkyl radical comprising from 7 to 12 carbon atoms or a radical represented by the general formula (B), it being understood that the compound of formula (I) comprises more than six cyclic nitrogen atoms.
摘要翻译：式（I）化合物：其中相同或不同的W 1，W 2和W 3彼此独立地表示选自由通式（A）表示的二价基团：如说明书和其中R 4表示氢原子，烷基，[（杂）芳基]烷基或由通式（B）表示的基团，R5-Si（X1）（X2）（X3）描述和相同或不同的R 1，R 2和R 3各自彼此独立地表示和R 4表示氢原子，烷基，含有7至12个碳原子的[（杂）芳基]烷基或由通式（B）表示的基团，应理解式（I）化合物包含六个以上的环状氮原子。

4. 发明授权

US07901948B2 Use of molecular tweezers as sensitive materials in chemical sensors for detecting or assaying organic compounds in the vapour state 有权
标题翻译：在化学传感器中使用分子镊子作为敏感材料，用于检测或测定蒸气状态的有机化合物
公开(公告)号：US07901948B2
公开(公告)日：2011-03-08
申请号：US11883393
申请日：2006-02-01
申请人： Lionel Hairault , Pierre Montmeat , Eric Pasquinet , Jean-Michel Barbe , Stéphane Brandes , Franck Denat , Claude Gros , Roger Guilard
发明人： Lionel Hairault , Pierre Montmeat , Eric Pasquinet , Jean-Michel Barbe , Stéphane Brandes , Franck Denat , Claude Gros , Roger Guilard
IPC分类号： G01N1/22
CPC分类号： G01N33/0026 , G01N33/0047 , G01N33/0049 , Y10T436/17 , Y10T436/18 , Y10T436/193333 , Y10T436/20 , Y10T436/212 , Y10T436/25875
摘要： The invention relates to the use of molecular tweezers as sensitive materials in chemical sensors intended to detect or assay organic compounds in the vapour state, and in particular nitro compounds.These molecular tweezers correspond to the general formula (I): in which: MC1 and MC2 represent macrocycles; p and q are equal to 0 or 1; X and Y are optionally substituted C1 to C10 alkylene groups; while E represents an optionally substituted cyclic or heterocyclic spacer group; and in which MC1 and MC2 are positioned facing each other. Fields of application: detection of explosives, control and monitoring of atmospheric pollution and of the quality of ambient air in relatively confined spaces, and monitoring of industrial sites.
摘要翻译：本发明涉及在化学传感器中使用分子镊子作为敏感材料，其用于检测或测定蒸气状态的有机化合物，特别是硝基化合物。这些分子镊子对应于通式（I）：其中：MC1和MC2代表大环; p和q等于0或1; X和Y是任选取代的C 1至C 10亚烷基; 而E表示任选取代的环状或杂环型间隔基; 并且其中MC1和MC2定位成彼此面对。应用领域：检测爆炸物，控制和监测大气污染和相对狭窄空间环境空气质量，监测工业场所。

5. 发明授权

US07659393B2 Method of preparing cis-8b-methyldecahydro-2a,4a,6a,8a-tetraazacyclopenta[fg]acenaphthylene, cis-decahydro-2a,4a,6a,8a-tetraazacyclopenta[fg]acenaphthylene, cyclene and functionalised cyclenes 失效
标题翻译：顺式-8-甲基十氢化合物2a，4a，6a，8a-四氮杂环戊二烯并[fg]苊烯，顺 - 十氢-2a，4a，6a，8a-四氮杂环戊烯[fg]苊烯，环烯和官能化环烯
公开(公告)号：US07659393B2
公开(公告)日：2010-02-09
申请号：US10560162
申请日：2004-06-04
申请人： Frederic Boschetti , Fanny Chaux , Franck Denat , Roger Guilard , Henry Ledon
发明人： Frederic Boschetti , Fanny Chaux , Franck Denat , Roger Guilard , Henry Ledon
IPC分类号： C07D245/00
CPC分类号： C07D487/08 , C07D257/02
摘要： A method of preparing cyclene having formula (I) from triethylenetetraamine having formula (VIII) or ethylenediamine having formula (VIII′) includes a series of steps. The first series of steps (I) includes a step A (one-pot preparation of the compound having formula (IIa) from the compound having formula (VIII)), followed by a step B (transforming the compound having formula (IIa) into cyclene having formula (I)). The second series of steps (II) includes a step C (preparing the compound having formula (IIb) from the compound having formula (VIII)), followed by a step D (transforming the compound having formula (IIb) into cylcene having formula (I)). The third series of steps (III) includes a step E involving the onepot preparation of the compound having formula (IIa) from the compound having formula (VIII), followed by a step B involving the transformation of the compound having formula (IIa) into cyclene having formula (I).
摘要翻译：由具有式（VIII）的三亚乙基四胺或具有式（VIII'）的乙二胺制备具有式（I）的环烯的方法包括一系列步骤。第一系列步骤（I）包括步骤A（具有式（VIII）化合物的具有式（IIa）的化合物的一锅法制备），然后是步骤B（将具有式（IIa）的化合物转化为具有式（I）的环烯）。第二系列步骤（II）包括步骤C（由具有式（VIII）的化合物制备具有式（IIb）的化合物），然后是步骤D（将具有式（IIb）的化合物转化成具有式一世））。第三系列步骤（III）包括步骤E，其包括从具有式（VIII）的化合物开始制备具有式（IIa）的化合物的步骤E，随后是涉及将具有式（IIa）的化合物转化为具有式（I）的环烯烃。

6. 发明授权

US08975395B2 Materials for the solid/liquid extraction of heavy metal ions, containing supported N-functionalized polyazacycloalkanes 有权
标题翻译：用于固体/液体提取重金属离子的材料，含有负载的N-官能化的多氮杂环烷烃
公开(公告)号：US08975395B2
公开(公告)日：2015-03-10
申请号：US12735980
申请日：2009-02-20
申请人： Michel Meyer , Arnaud Bucaille , Francois Cuenot , Franck Denat , Frédéric Boschetti , Roger Guilard
发明人： Michel Meyer , Arnaud Bucaille , Francois Cuenot , Franck Denat , Frédéric Boschetti , Roger Guilard
IPC分类号： C07D257/02 , B01J20/22 , B01J20/26 , C07F7/08
CPC分类号： C07F7/0836 , C07B2200/11
摘要： The present invention relates to a material notably adapted for the extraction of metal cations in an aqueous medium, comprising a solid support on which are attached polyazacycloalkane compounds having a ring including at least 4 nitrogen atoms, and wherein the nitrogen atoms of the ring are substituted with coordinating groups, which each are independently: a coordinating group of formula: —(CH2)n—C(═O)—NR1R2 or else a both coordinating and binding group, fitting the formula: —(CH2)p—C(═O)—NR3-(A)-[support]. The invention also relates to methods for preparing the aforementioned materials and to different uses thereof, notably for the extraction of Pb2+ cations in an aqueous medium.
摘要翻译：本发明涉及一种特别适用于在含水介质中萃取金属阳离子的材料，其中包括一种固体载体，其中连接有多环氮杂环烷烃化合物，该化合物具有包含至少4个氮原子的环，并且其中该环的氮原子被取代配位基团，各自独立地是： - （CH 2）n -C（= O）-NR 1 R 2的配位基团，或者是配位和结合基团，配合下式： - （CH 2）p -C（= O）-NR 3 - （A） - [支持]。本发明还涉及制备上述材料及其不同用途的方法，特别是用于在水性介质中萃取Pb 2+阳离子。

7. 发明申请

US20110079557A1 MATERIALS FOR THE SOLID/LIQUID EXTRACTION OF HEAVY METAL IONS, CONTAINING SUPPORTED N-FUNCTIONALIZED POLYAZACYLOALKANES 有权
标题翻译：用于固体/液体提取重金属离子的材料，含有支持的N-官能化聚山梨醇
公开(公告)号：US20110079557A1
公开(公告)日：2011-04-07
申请号：US12735980
申请日：2009-02-20
申请人： Michel Meyer , Arnaud Bucaille , Francois Cuenot , Franck Denat , Frédéric Boschetti , Roger Guilard
发明人： Michel Meyer , Arnaud Bucaille , Francois Cuenot , Franck Denat , Frédéric Boschetti , Roger Guilard
IPC分类号： C07F7/18 , C02F1/26 , C02F1/62 , B01D11/02
CPC分类号： C07F7/0836 , C07B2200/11
摘要： The present invention relates to a material notably adapted for the extraction of metal cations in an aqueous medium, comprising a solid support on which are attached polyazacycloalkane compounds having a ring including at least 4 nitrogen atoms, and wherein the nitrogen atoms of the ring are substituted with coordinating groups, which each are independently: a coordinating group of formula: —(CH2)n—C(═O)—NR1R2 or else a both coordinating and binding group, fitting the formula: —(CH2)p—C(═O)—NR3-(A)-[support]. The invention also relates to methods for preparing the aforementioned materials and to different uses thereof, notably for the extraction of Pb2+ cations in an aqueous medium.
摘要翻译：本发明涉及一种特别适用于在含水介质中萃取金属阳离子的材料，其中包括一种固体载体，其中连接有多环氮杂环烷烃化合物，该化合物具有包含至少4个氮原子的环，并且其中该环的氮原子被取代配位基团，各自独立地是： - （CH 2）n -C（= O）-NR 1 R 2的配位基团，或者是配位和结合基团，配合下式： - （CH 2）p -C（= O）-NR 3 - （A） - [支持]。本发明还涉及制备上述材料及其不同用途的方法，特别是用于在水性介质中萃取Pb 2+阳离子。

8. 发明授权

US08841384B2 Material comprising polyazacycloalkanes, grafted on polypropylene fibres, its process of preparation, and process for removing metal cations from a liquid 有权
标题翻译：包含聚氮杂环烷烃，接枝在聚丙烯纤维上的材料，其制备方法和从液体中除去金属阳离子的方法
公开(公告)号：US08841384B2
公开(公告)日：2014-09-23
申请号：US12523330
申请日：2008-01-14
申请人： Frédéric Rascalou , Franck Denat , Roger Guilard , Jean-Louis Babouhot , Hervé Chollet , Michel Meyer
发明人： Frédéric Rascalou , Franck Denat , Roger Guilard , Jean-Louis Babouhot , Hervé Chollet , Michel Meyer
IPC分类号： C08F255/02 , C08J7/16 , C08F8/30 , D06M14/10 , D06M14/28
CPC分类号： D06M14/10 , C08F8/30 , D06M14/28 , C08F10/06
摘要： Material composed of a polyazacycloalkane grafted on polypropylene fibres.Process for the preparation of this material.Process for removing metal cations present in a liquid by bringing this liquid into contact with the said material.
摘要翻译：由在聚丙烯纤维上接枝的多氮杂环烷烃组成的材料。制备该材料的方法。通过使该液体与所述材料接触来除去存在于液体中的金属阳离子的方法。

9. 发明申请

US20100059446A1 MATERIAL COMPRISING POLYAZACYCLOALKANES, GRAFTED ON POLYPROPYLENE FIBRES, ITS PROCESS OF PREPARATION, AND PROCESS FOR REMOVING METAL CATIONS FROM A LIQUID 有权
标题翻译：包含在聚丙烯纤维上制备聚丙烯酰胺的材料，其制备方法以及从液体中除去金属的方法
公开(公告)号：US20100059446A1
公开(公告)日：2010-03-11
申请号：US12523330
申请日：2008-01-14
申请人： Frederic Rascalou , Franck Denat , Roger Guilard , Jean-Louis Babouhot , Herve Chollet , Michel Meyer
发明人： Frederic Rascalou , Franck Denat , Roger Guilard , Jean-Louis Babouhot , Herve Chollet , Michel Meyer
IPC分类号： C08F271/02 , C08J3/28 , C02F1/42
CPC分类号： D06M14/10 , C08F8/30 , D06M14/28 , C08F10/06
摘要： Material composed of a polyazacycloalkane grafted on polypropylene fibres.Process for the preparation of this material.Process for removing metal cations present in a liquid by bringing this liquid into contact with the said material.
摘要翻译：由在聚丙烯纤维上接枝的多氮杂环烷烃组成的材料。制备该材料的方法。通过使该液体与所述材料接触来除去存在于液体中的金属阳离子的方法。

10. 发明申请

US20060217548A1 Method of preparing cis-8b-methyldecahydro-2a,4a,6a,8a-tetraazacyclopenta[fg] acenaphthylene, cis-decahydro-2a,4a,6a,8a-tetraazacyclopenta[fg] acenaphthylene, cyclene and functionalised cyclenes 失效
标题翻译：顺式-8-甲基十氢二氢-2a，4a，6a，8a-四氮杂环戊二烯并[f]苊，顺 - 十氢-2a，4a，6a，8a-四氮杂环戊二烯并[fg]苊烯的方法，
公开(公告)号：US20060217548A1
公开(公告)日：2006-09-28
申请号：US10560162
申请日：2004-06-04
申请人： Frèderic Boschetti , Fanny Chaux , Franck Denat , Roger Guilard , Henry Ledon
发明人： Frèderic Boschetti , Fanny Chaux , Franck Denat , Roger Guilard , Henry Ledon
IPC分类号： C07D257/02
CPC分类号： C07D487/08 , C07D257/02
摘要： A method of preparing cyclene having formula (I) from triethylenetetraamine having formula (VIII) or ethylenediamine having formula (VIII′) includes a series of steps. The first series of steps (I) includes a step A (one-pot preparation of the compound having formula (IIa) from the compound having formula (VIII)), followed by a step B (transforming the compound having formula (IIa) into cyclene having formula (I)). The second series of steps (II) includes a step C (preparing the compound having formula (IIb) from the compound having formula (VIII)), followed by a step D (transforming the compound having formula (IIb) into cylcene having formula (I)). The third series of steps (III) includes a step E involving the one-pot preparation of the compound having formula (IIa) from the compound having formula (VIII), followed by a step B involving the transformation of the compound having formula (IIa) into cyclene having formula (I).
摘要翻译：由具有式（VIII）的三亚乙基四胺或具有式（VIII'）的乙二胺制备具有式（I）的环烯的方法包括一系列步骤。第一系列步骤（I）包括步骤A（具有式（VIII）化合物的具有式（IIa）的化合物的一锅法制备），然后是步骤B（将具有式（IIa）的化合物转化为具有式（I）的环烯）。第二系列步骤（II）包括步骤C（由具有式（VIII）的化合物制备具有式（IIb）的化合物），然后是步骤D（将具有式（IIb）的化合物转化成具有式一世））。步骤（III）的第三系列包括步骤E，该步骤E涉及具有式（Ⅷ）化合物的具有式（IIa）的化合物的一锅法制备的步骤E，随后是涉及使式（IIa）化合物转化的步骤B ）转化为具有式（I）的环烯烃。

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