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1. 发明申请

US20050085614A1 Multiple component coating composition utilizing dilution stable polyisocyanates 有权
标题翻译：使用稀释稳定的多异氰酸酯的多组分涂料组合物
公开(公告)号：US20050085614A1
公开(公告)日：2005-04-21
申请号：US10917765
申请日：2004-08-13
申请人： Robert Barsotti , Christopher Scopazzi , Douglas Lamb
发明人： Robert Barsotti , Christopher Scopazzi , Douglas Lamb
IPC分类号： C08G18/00 , C08G18/40 , C08G18/76 , C08G18/81 , C09D20060101 , C09D175/04
CPC分类号： C08G18/765 , C08G18/4063 , C08G18/8108 , C09D175/04
摘要： The present invention is directed to a multiple component coating composition comprising (a) a film forming binder component having isocyanate reactive groups; (b) a stable polyisocyanate solution comprising organic liquid and up to 30% by weight, based on the weight of the polyisocyanate solution, of a polyisocyanate having reactive isocyanate groups selected from an aromatic polyisocyanate having tertiary isocyanate groups or a (meth)acrylic polymer containing reactive isocyanate groups; and (c) optionally, a tinting composition comprising pigment, a dispersing agent and an organic liquid carrier; whereby components (a), (b) and (c) are blended together before application to a substrate and after application to a substrate the composition is cured to form a finish. The present invention is also directed to a method of producing a finish on a substrate and to the resulting coated substrate.
摘要翻译：本发明涉及一种多组分涂料组合物，其包含（a）具有异氰酸酯反应性基团的成膜粘合剂组分; （b）稳定的多异氰酸酯溶液，其包含有机液体和至多30重量％（基于多异氰酸酯溶液的重量）的具有选自具有叔异氰酸酯基的芳族多异氰酸酯或（甲基）丙烯酸聚合物的反应性异氰酸酯基团的多异氰酸酯含有活性异氰酸酯基团; 和（c）任选的包含颜料，分散剂和有机液体载体的着色组合物; 其中组分（a），（b）和（c）在施加到基底之前混合在一起，并且在施用到基底之后，将组合物固化以形成整理剂。本发明还涉及一种在基材和所得的涂布基材上生产精加工的方法。

2. 发明申请

US20060100353A1 Coating compositions for basecoats containing acrylic branched polymers 审中-公开
标题翻译：含有丙烯酸支链聚合物的底漆的涂料组合物
公开(公告)号：US20060100353A1
公开(公告)日：2006-05-11
申请号：US10984647
申请日：2004-11-08
申请人： Robert Barsotti , Christopher Scopazzi , Frank Sobonya
发明人： Robert Barsotti , Christopher Scopazzi , Frank Sobonya
IPC分类号： A61K9/16
CPC分类号： C08F290/046 , C09D151/003 , C09D155/005 , C08L2666/14
摘要： This invention relates to rapid drying coating compositions that are particularly useful for automotive and truck refinish applications; the coating composition is pigmented and contains a branched acrylic polymer and is particularly useful as a basecoat for a basecoat clear coat finish; the coating composition may preferably be used as a lacquer coating, which dries via solvent evaporation absent any substantial crosslinking occurring or it optionally may contain a polyisocyanate crosslinking agent and be used a clear topcoat.
摘要翻译：本发明涉及特别适用于汽车和卡车修补漆应用的快速干燥涂料组合物; 涂料组合物着色并含有支链丙烯酸聚合物，并且特别可用作底漆透明涂层的底漆; 涂料组合物可优选用作漆涂层，其通过溶剂蒸发而干燥而不发生任何实质性交联，或者其任选地可含有多异氰酸酯交联剂并用于透明的面漆。

3. 发明授权

US06646055B2 Microgels and process for their preparation 有权
标题翻译：微凝胶及其制备方法
公开(公告)号：US06646055B2
公开(公告)日：2003-11-11
申请号：US09969706
申请日：2001-10-03
申请人： Charles T. Berge , Michael Fryd , Jeffrey W. Johnson , Graeme Moad , Ezio Rizzardo , Christopher Scopazzi , San Hoa Thang
发明人： Charles T. Berge , Michael Fryd , Jeffrey W. Johnson , Graeme Moad , Ezio Rizzardo , Christopher Scopazzi , San Hoa Thang
IPC分类号： C08F238
CPC分类号： C08F265/04 , C08F290/04 , C08F290/061 , C08F293/00 , C08F293/005 , Y10S514/944
摘要： A process for preparing microgel(s) that uses a wide range of activatable prepolymers. In the process, a polymer composition of crosslinked component A and soluble components B and C is formed from mono-olefinic and multi-olefinic monomers in the presence of catalyst and initiator. The process comprises: I) introducing mono-olefinic monomer, catalyst, and initiator into a reactor in the absence of multi-olefinic monomer and producing an activatable prepolymer, component B; II) contacting the product of I) with multi-olefinic monomer to produce components A and C, optionally in the presence of additional initiator; also optionally in the presence of additional mono-olefinic monomer and initiator. The ratio of components A/(B+C) can be controlled by varying the mole ratio of The Component B/multi-olefinic monomer from 0.05/1 up to 5/1, by decreasing the mole ratio to increase the ratio of A/(B+C), and increasing the mole ratio to decrease the ratio of A/(B+C).
摘要翻译：一种制备使用多种可活化预聚物的微凝胶的方法。在该方法中，交联组分A和可溶组分B和C的聚合物组合物在催化剂和引发剂存在下由单烯烃和多烯属单体形成。该方法包括：I）在不存在多烯属单体的情况下将单烯烃单体，催化剂和引发剂引入反应器，并产生可活化的预聚物组分B; II）使I）的产物与多烯属单体接触，产生组分A和C，任选地在另外的引发剂的存在下; 也可任选在另外的单烯属单体和引发剂的存在下进行。组分A /（B + C）的比例可以通过将组分B /多烯烃单体的摩尔比从0.05 / 1增加到5/1来控制，通过降低摩尔比以增加A / （B + C），并且增加摩尔比以降低A /（B + C）的比例。

4. 发明授权

US5412039A Acrylic copolymer core with catalyst grafted with macromonomers 失效
标题翻译：丙烯酸共聚物芯与催化剂接枝与大分子单体
公开(公告)号：US5412039A
公开(公告)日：1995-05-02
申请号：US272342
申请日：1994-07-08
申请人： Robert J. Barsotti , Charles T. Berge , Christopher Scopazzi
发明人： Robert J. Barsotti , Charles T. Berge , Christopher Scopazzi
IPC分类号： C08F290/04 , C08F8/00 , C08G59/42 , C08G59/68 , C09D163/00 , C08F265/02 , C08L33/14
CPC分类号： C09D163/00 , C08F8/44 , C08G59/42 , C08G59/688
摘要： A branched acrylic copolymer with a core which is insoluble in a non-polar organic solvent and formed from the polymerization of an ethylenically unsaturated monomer with at least about 5% by weight of acid functionality wherein a catalyst such as a phosphonium compound is reacted with the acid functionality of the core, and organic solvent-soluble macromonomer stabilizers grafted to the core, is useful as a catalytic component in a coating composition comprising a non-cyclic anhydride resin and a resin derived from an ethylenically unsaturated epoxy monomer.
摘要翻译：具有核心的支链丙烯酸共聚物，其不溶于非极性有机溶剂，并且由烯键式不饱和单体与至少约5重量％的酸官能团的聚合形成，其中诸如鏻化合物的催化剂与核心的酸官能团和接枝到芯上的有机溶剂可溶性大分子单体稳定剂可用作包含非环状酸酐树脂和衍生自烯属不饱和环氧单体的树脂的涂料组合物中的催化组分。

5. 发明授权

US5290633A Coating compositions based on graft polymers 失效
标题翻译：基于接枝聚合物的涂料组合物
公开(公告)号：US5290633A
公开(公告)日：1994-03-01
申请号：US72366
申请日：1993-06-07
申请人： Brian P. Devlin , Joseph A. Antonelli , Christopher Scopazzi
发明人： Brian P. Devlin , Joseph A. Antonelli , Christopher Scopazzi
IPC分类号： C08G18/08 , C08G18/63 , C08G18/78 , C08L51/00 , C08L75/00
CPC分类号： C08G18/638 , C08G18/0852 , C08G18/633 , C08G18/635 , C08G18/7831 , Y10T428/31551
摘要： A coating composition comprising a hydroxy functional graft copolymer characterized by macromoners attached at a terminal point to a polymeric backbone. The composition further comprises a polyisocyanate curing agent. Such compositions provide an improved balance of pot life and cure properties.
摘要翻译：一种包含羟基官能接枝共聚物的涂料组合物，其特征在于在端点连接到聚合物主链上的大分子单体。组合物还包含多异氰酸酯固化剂。这样的组合物提供了适用期和固化性能的改善的平衡。

6. 发明授权

US4746714A Stabilized acrylic resin 失效
标题翻译：稳定的丙烯酸树脂
公开(公告)号：US4746714A
公开(公告)日：1988-05-24
申请号：US875059
申请日：1986-06-17
申请人： Harry J. Spinelli , Christopher Scopazzi , Joseph A. Antonelli
发明人： Harry J. Spinelli , Christopher Scopazzi , Joseph A. Antonelli
IPC分类号： C08F4/58 , C08F4/00 , C08F265/00 , C08F265/06 , C08F290/00 , C08F290/04 , C08F299/00 , C09D133/00 , C09D151/00 , C09D151/06 , C08L51/00 , C08L33/08 , C08L33/10
CPC分类号： C08F290/046 , Y10S524/923
摘要： Stabilized acrylic resin having a core of acrylic polymer and a substantially linear stabilizer having one polymerizable functional group at one end of the stabilizer molecule, the resins being useful as rheology control agents for coating compositions.
摘要翻译：具有丙烯酸聚合物核心的稳定化丙烯酸树脂和在稳定剂分子的一端具有一个可聚合官能团的基本上线性的稳定剂，该树脂可用作涂料组合物的流变控制剂。

7. 发明授权

US07479525B2 Coating compositions containing isocyanate-functional non-aqueous dispersed polymers 失效
标题翻译：含有异氰酸酯官能的非水分散聚合物的涂料组合物
公开(公告)号：US07479525B2
公开(公告)日：2009-01-20
申请号：US10673831
申请日：2003-09-29
申请人： Robert J. Barsotti , Laura Ann Lewin , Christopher Scopazzi
发明人： Robert J. Barsotti , Laura Ann Lewin , Christopher Scopazzi
IPC分类号： C08L51/00
CPC分类号： C08G18/0871 , C08G18/6254 , C08G18/633 , C08G18/728 , C09D175/04
摘要： A coating composition containing about 40-90% by weight of film forming binder and 10-60% by weight of an organic liquid carrier; wherein the binder contains about (a) 10-70% by weight, based on the weight of the binder, of a dispersed gelled acrylic polymer having (i) a core of gelled polymerized ethylenically unsaturated monomers which is not soluble in the organic liquid carrier and having chemically grafted thereto (ii) substantially linear stabilizer polymeric components that are soluble in the organic liquid carrier and comprise polymerized ethylenically unsaturated monomers and have a weight average molecular weight of about 500-20,000 determined by GPC (gel permeation chromatography) using polystyrene as the standard; wherein the core, the stabilizer polymeric component, or both contain at least 3% by weight of polymerized ethylenically unsaturated monomers having isocyanate groups attached thereto that are capable of reacting with component (b); (b) 30-90% by weight, based on the weight of the binder, of an oligomer or polymer or both having functional groups capable of reacting with the isocyanate groups of component (a); and (c) 0-60% by weight, based on the weight of the binder, of an organic polyisocyanate crosslinking agent.
摘要翻译：一种涂料组合物，其含有约40-90重量％的成膜粘合剂和10-60重量％的有机液体载体; 其中所述粘合剂包含基于粘合剂重量的约（a）10-70重量％的分散的凝胶状丙烯酸聚合物，其具有（i）不溶于有机液体载体的凝胶化聚合的烯键式不饱和单体核心并且化学接枝到其上（ii）可溶于有机液体载体并且包含聚合的烯键式不饱和单体的基本上线性的稳定剂聚合物组分，并且通过使用聚苯乙烯作为聚苯乙烯的GPC（凝胶渗透色谱）测定的重均分子量为约500-20,000 标准; 其中所述核心，所述稳定剂聚合物组分或两者含有至少3重量％的能够与组分（b）反应的具有连接到其上的异氰酸酯基团的聚合烯属不饱和单体; （b）基于粘合剂重量的30-90重量％的低聚物或聚合物或具有能够与组分（a）的异氰酸酯基反应的官能团的二者; 和（c）基于粘合剂重量的0-60重量％的有机多异氰酸酯交联剂。

8. 发明授权

US06653407B2 Process for preparing star shaped microgels from macromonomers with terminal ethylenic unsaturation 有权
标题翻译：从具有末端烯属不饱和键的大分子单体制备星形微凝胶的方法
公开(公告)号：US06653407B2
公开(公告)日：2003-11-25
申请号：US09969672
申请日：2001-10-03
申请人： Charles T. Berge , Michael Fryd , Jeffrey W. Johnson , Graeme Moad , Ezio Rizzardo , Christopher Scopazzi , San Hoa Thang
发明人： Charles T. Berge , Michael Fryd , Jeffrey W. Johnson , Graeme Moad , Ezio Rizzardo , Christopher Scopazzi , San Hoa Thang
IPC分类号： C08F238
CPC分类号： C08F265/04 , C08F290/04 , C08F290/061 , C08F293/00 , C08F293/005 , Y10S514/944
摘要： The present invention is directed to a process for forming star shaped microgels which include a core of crosslinked polymer and multiplicity of substantially linear polymeric arms of macromonomers attached to the core. The process includes polymerizing monoethylenically unsaturated monomers in the presence of a chain transfer agent to form macromonomers each having a terminal polymerizable ethylenically unsaturated group and then polymerizing, in presence of the macromonomers, the monoethylenically unsaturated monomers and multi-olefinic crosslinking monomers. The microgels of the present invention can be used as rheology control agents in waterborne and solvent-borne coatings and in adhesives and cosmetics.
摘要翻译：本发明涉及一种形成星形微凝胶的方法，其包括交联聚合物的核心和连接到核心的大分子单体的基本上线性的多个聚合物臂的多个。该方法包括在链转移剂的存在下聚合单烯属不饱和单体以形成各自具有末端可聚合烯属不饱和基团的大分子单体，然后在大分子单体存在下，单烯属不饱和单体和多烯属交联单体聚合。本发明的微凝胶可用作水性和溶剂型涂料以及粘合剂和化妆品中的流变控制剂。

9. 发明授权

US5770646A Aqueous branched polymer dispersant for hydrophobic materials 失效
标题翻译：水性支链聚合物分散剂用于疏水材料
公开(公告)号：US5770646A
公开(公告)日：1998-06-23
申请号：US740464
申请日：1996-10-29
申请人： Joseph Albert Antonelli , Christopher Scopazzi , Kerstin Stranimaier
发明人： Joseph Albert Antonelli , Christopher Scopazzi , Kerstin Stranimaier
IPC分类号： C08F290/04 , C08L55/00 , C08L51/00 , C08L61/28 , C08L61/32
CPC分类号： C08F290/046 , C08L55/005
摘要： A waterbased dispersion useful for forming aqueous coating compositions containing dispersed hydrophobic material, an aqueous carrier and a branched polymer dispersant (binder); the branched polymer has a weight average molecular weight of about 5,000-100,000 and contains 20-80% by weight of a hydrophilic backbone and correspondingly 80-20% by weight of macromonomer side chains; wherein the backbone is of polymerized ethylenically unsaturated monomers and 2-30% by weight, based on the weight of the backbone of polymerized ethylenically unsaturated monomers having an acid-functional group; and wherein at least 10% of the acid-functional groups are neutralized with an amine or an inorganic base and is hydrophilic in comparison to the side chains; and the side chains are of macromonomers of polymerized ethylenically unsaturated monomers that are polymerized into the backbone via an ethylenically unsaturated group and the macromonomers have a weight average molecular weight of about 1,000-30,000 and wherein the weight ratio of hydrophobic material to binder is about 1/100-200/100.
摘要翻译：用于形成含有分散的疏水性材料的水性涂料组合物，水性载体和支化聚合物分散剂（粘合剂）的水基分散体; 支链聚合物的重均分子量为约5,000-100,000，并且包含20-80重量％的亲水性主链和相应的80-20重量％的大分子单体侧链; 其中所述骨架是聚合的烯键式不饱和单体和2-30重量％，基于具有酸官能团的聚合的烯属不饱和单体的主链的重量; 并且其中至少10％的酸官能团用胺或无机碱中和，并且与侧链相比是亲水的; 并且侧链是聚合的烯属不饱和单体的大分子单体，其通过烯键式不饱和基团聚合成主链，并且大分子单体的重均分子量为约1,000-3,000，并且其中疏水材料与粘合剂的重量比为约1 / 100-200 / 100。

10. 发明授权

US5750619A Coating composition of non-cyclic anhydride resin, polyepoxy oligomer and stabilized acrylic resin 失效
标题翻译：非环状酸酐树脂，聚环氧低聚物和稳定化丙烯酸树脂的涂料组合物
公开(公告)号：US5750619A
公开(公告)日：1998-05-12
申请号：US765706
申请日：1997-01-06
申请人： Robert John Barsotti , Christopher Scopazzi
发明人： Robert John Barsotti , Christopher Scopazzi
IPC分类号： C08F290/04 , C09D151/00 , C09D155/00 , C09D163/00 , C09D173/02 , C08L51/00 , C08L63/00 , C08L67/02
CPC分类号： C09D163/00 , C08F290/046
摘要： A curable coating composition comprises an organic solvent, a binder obtained from (a) an anhydride resin with a molecular weight of less than about 3000 containing a central organic moiety having bonded thereto non-cyclic anhydride moieties and (b) an oligomer possessing an epoxy functionality of at least 2 and a molecular weight of less than about 1500, from about 3-40% by weight of the binder of (c) a stabilized acrylic resin prepared from an acrylic polymer core having grafted thereto linear stabilizer components of an acrylic backbone with at least about 3% of epoxy-functional ethylenically unsaturated monomers, and (d) an active catalyst.
摘要翻译： PCT No.PCT / US95 / 07124 Sec。 371日期1997年1月6日 102（e）日期1997年1月6日PCT提交1995年6月16日PCT公布。公开号WO96 / 01880 日期1996年1月25日可固化涂料组合物包含有机溶剂，从（a）分子量小于约3000的酸酐树脂获得的粘合剂，其含有与非环状酸酐部分键合的中心有机部分，和（b）具有至少2的分子量和小于约1500的分子量的低聚物，约3至40重量％的粘合剂（c）由丙烯酸聚合物芯制备的稳定的丙烯酸树脂，其具有接枝到其上的线性稳定剂具有至少约3％环氧官能烯属不饱和单体的丙烯酸骨架的组分，和（d）活性催化剂。

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