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    • 3. 发明授权
    • Salt compositions and explosives using same
    • US5407500A
    • 1995-04-18
    • US163234
    • 1993-12-06
    • John W. ForsbergRichard W. JahnkeRichard M. LangeMarvin B. DeTar
    • John W. ForsbergRichard W. JahnkeRichard M. LangeMarvin B. DeTar
    • B01F17/00B01F17/16C06B47/14B01F17/36C06B45/00C07C69/40
    • B01F17/0042C06B47/145Y10S516/06Y10S516/07
    • The present invention provides for a novel salt composition comprising: (A) at least one salt moiety derived from (A)(I) at least one high-molecular weight hydrocarbyl-substituted polycarboxylic acylating agent, said hydrocarbyl-substituent of said acylating agent (A)(I) having a number average molecular weight of at least about 280, and (A)(II) one or more members selected from the group consisting of ammonia, at least one amine, at least one alkali or alkaline earth metal, and at least one alkali or alkaline earth metal compound; (B) at least one salt moiety derived from (B)(I) at least one low-molecular weight polycarboxylic acylating agent, said acylating agent (B)(I) optionally having at least one hydrocarbyl substituent having up to about 18 carbon atoms, and (B)(II) one or more members selected from the group consisting of ammonia, at least one amine, at least one alkali or alkaline earth metal, and at least one alkali or alkaline earth metal compound; said moieties (A) and (B) being coupled together by (C) at least one compound comprising (C)(I) and optionally component (C)(II), component (C)(I) being at least one oxazoline represented by the formula ##STR1## wherein in Formula (I), R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are independently (i) hydrogens, (ii) hydrocarbyl groups, (iii) hydroxy-substituted hydrocarbyl groups, (iv) hydroxy-substituted poly(hydrocarbyloxy) groups, (v) amino-substituted hydrocarbyl groups or (vi) amino-substituted poly(hydrocarbyloxy) groups, with the proviso that at least two of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are independently (iii), (iv), (v) or (vi); optional component (C)(II) being at least one compound other than component (C)(I) having (i) two or more primary amino groups, (ii) two or more secondary amino groups, (iii) at least one primary amino group and at least one secondary amino group, (iv) at least two hydroxyl groups or (v) at least one primary or secondary amino group and at least one hydroxyl group. The invention also provides for concentrates and explosive emulsions containing the foregoing composition.
    • 4. 发明授权
    • Oil-water emulsions
    • 油水乳液
    • US5360458A
    • 1994-11-01
    • US717683
    • 1991-06-19
    • John W. ForsbergRichard W. Jahnke
    • John W. ForsbergRichard W. Jahnke
    • B01F17/00C10L1/32C10L1/22C10L1/30
    • B01F17/0042C10L1/328Y10S516/07Y10T137/0391
    • This invention provides for water-oil emulsions comprising water, oil and a minor emulsifying amount of the reaction product of: (A) at least one saturated or unsaturated aliphatic monocarboxylic acid of about 12 to about 24 carbon atoms; (B) at least one acid of the general formula C.sub.19 H.sub.n COOH, wherein n is a number in the range of about 27 to about 31, and having a phenathrene nucleus; and (C) at least one amine. In one hydroxy embodiment, the oil employed in these emulsions can be any oil, the water content of these emulsions being up to about 30% by weight. In a preferred embodiment, the oil employed is crude oil. These emulsions can be facilitatingly pumped through a conduit even when the oil employed is a viscous crude oil. These emulsions are useful as a combustible fuel when the water content is below about 30% by weight.
    • 本发明提供包含水,油和少量乳化量的以下的反应产物的水 - 油乳液:(A)至少一种约12至约24个碳原子的饱和或不饱和脂族单羧酸; (B)至少一种通式C 19 H n COOH的酸,其中n为约27至约31的数,并具有苯并萘核; 和(C)至少一种胺。 在一个羟基实施方案中,这些乳液中使用的油可以是任何油,这些乳液的水含量高达约30重量%。 在优选的实施方案中,所用的油是原油。 即使当所用的油是粘性原油时,这些乳液也可以方便地泵送通过导管。 当水含量低于约30重量%时,这些乳液可用作可燃燃料。
    • 6. 发明授权
    • Salt compositions and concentrates for use in explosive emulsions
    • US5336439A
    • 1994-08-09
    • US743537
    • 1991-08-08
    • John W. ForsbergRichard W. JahnkeRichard M. LangeMarvin B. DeTar
    • John W. ForsbergRichard W. JahnkeRichard M. LangeMarvin B. DeTar
    • B01F17/00B01F17/16C06B47/14B01F17/36C07C69/40
    • B01F17/0042C06B47/145Y10S516/06Y10S516/07
    • The present invention provides for a novel salt composition comprising: (A) at least one salt moiety derived from (A)(I) at least one high-molecular weight hydrocarbyl-substituted polycarboxylic acylating agent, said hydrocarbyl-substituent of said acylating agent (A)(I) having a number average molecular weight of at least about 280, and (A)(II) one or more members selected from the group consisting of ammonia, at least one amine, at least one alkali or alkaline earth metal, and at least one alkali or alkaline earth metal compound; (B) at least one salt moiety derived from (B)(I) at least one low-molecular weight polycarboxylic acylating agent, said acylating agent (B)(I) optionally having at least one hydrocarbyl substituent having up to about 18 carbon atoms, and (B)(II) one or more members selected from the group consisting of ammonia, at least one amine, at least one alkali or alkaline earth metal, and at least one alkali or alkaline earth metal compound; said moieties (A) and (B) being coupled together by (C) at least one compound comprising (C)(I) and optionally component (C)(II), component (C)(I) being at least one oxazoline represented by the formula ##STR1## wherein in Formula (I), R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are independently (i) hydrogens, (ii) hydrocarbyl groups, (iii) hydroxy-substituted hydrocarbyl groups, (iv) hydroxy-substituted poly(hydrocarbyloxy) groups, (v) amino-substituted hydrocarbyl groups or (vi) amino-substituted poly(hydrocarbyloxy) groups, with the proviso that at least two of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are independently (iii), (iv), (v) or (vi); optional component (C)(II) being at least one compound other than component (C)(I) having (i) two or more primary amino groups, (ii) two or more secondary amino groups, (iii) at least one primary amino group and at least one secondary amino group, (iv) at least two hydroxyl groups or (v) at least one primary or secondary amino group and at least one hydroxyl group. The invention also provides for concentrates and explosive emulsions containing the foregoing composition.
    • 9. 发明授权
    • Methods of using acidizing fluids in wells, and compositions used therein
    • 在井中使用酸化液的方法及其中使用的组合物
    • US5599777A
    • 1997-02-04
    • US132511
    • 1993-10-06
    • Richard W. JahnkeJohn W. Forsberg
    • Richard W. JahnkeJohn W. Forsberg
    • C09K8/74E21B43/27
    • C09K8/74Y10S507/933
    • The present invention relates to a method, comprising the steps of:introducing into a well borehole a composition, comprising water, an acid, and (A) at least one reaction product of (A-1) at least one hydrocarbyl-substituted carboxylic acylating agent selected from the group consisting of a dicarboxylic acylating agent, a succinic acylating agent, a Dieis-Alder diacid, a dimer acid acylating agent, a tricarboxylic acylating agent, a polycarboxylic acylating agent, or mixtures thereof, and (A-2) at least one amine-terminated polyoxyalkylene or (A-3) at least one hydroxy-terminated polyoxyalkylene having a number average molecular weight from about 600 to about 30,000, or a mixture of said (A-2) amine-terminated polyoxyalkylenes and (A-3) hydroxy-terminated polyoxyalkylenes. The reaction product (A) may be used alone, or in combination with one or more surfactants.
    • 本发明涉及一种方法,该方法包括以下步骤:向井眼中导入包含水,酸的组合物和(A)至少一种(A-1)至少一种烃基取代的羧基酰化反应的反应产物 选自二羧酸酰化剂,琥珀酰化剂,二聚酸酰化剂,三羧酸酰化剂,多元羧酸酰化剂或其混合物的组分的化合物和(A-2)在 至少一个胺封端的聚氧化烯或(A-3)至少一个数均分子量为约600至约30,000的羟基封端的聚氧化烯,或所述(A-2)胺封端的聚氧化烯和(A- 3)羟基封端的聚氧化烯。 反应产物(A)可以单独使用或与一种或多种表面活性剂组合使用。