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    • 2. 发明授权
    • Manufacture of water chemistries
    • 水化学品的制造
    • US08268269B2
    • 2012-09-18
    • US11880797
    • 2007-07-23
    • Richard Alan HaaseJohn Smaardyk
    • Richard Alan HaaseJohn Smaardyk
    • C01B17/00
    • C25B1/00C01B11/062C01B11/14C01D1/20C01D3/04C01D5/02C01F7/48C01F7/56C01F7/74
    • As population density increases, the transportation of hazardous chemicals, including acids and disinfectants, lead to an increased incidence of spills while the consequences of spills become more serious. While solutions of halide acids, hypohalites and halites are safer disinfectants for transportation, handling, storage and use than traditional gaseous chlorine, the manufacturing cost of these disinfectants has here-to-fore limited their use. Economical processes are presented for the manufacture of O2, halogen oxides, halide acids, hypohalites, and halates; as well as polynucleate metal compounds, metal hydroxides and calcium sulfate hydrate (gypsum). The instant invention presents methods and processes that incorporate the use of sulfur. This is while environmental regulators, such as the US EPA, require an increased removal of sulfur from hydrocarbon fuels, thereby creating an abundance of sulfur, such that the refining industry is in need of a way to dispose of said abundance of sulfur.
    • 随着人口密度的增加,危险化学品(包括酸和消毒剂)的运输导致泄漏事件的发生率增加,而泄漏事件的后果更为严重。 虽然卤化物酸,次卤酸盐和卤盐酸盐的溶液是比传统气态氯更安全的运输,处理,储存和使用的消毒剂,但是这些消毒剂的制造成本在此受到限制。 提供了用于制造O 2,卤素氧化物,卤化物酸,次卤酸盐和卤化物的经济方法; 以及多核金属化合物,金属氢氧化物和硫酸钙水合物(石膏)。 本发明提出了结合使用硫的方法和方法。 这就是美国环保署(EPA)等环境监管机构要求从碳氢化合物燃料中增加硫的去除,从而产生大量的硫,从而炼油行业需要一种处理所述丰度的硫的方式。
    • 4. 发明授权
    • Application of magnesium oxide and magnesium hydroxide as preservatives
    • 应用氧化镁和氢氧化镁作为防腐剂
    • US6066349A
    • 2000-05-23
    • US946707
    • 1997-10-08
    • Richard Alan Haase
    • Richard Alan Haase
    • A23B4/24A23B4/26A23B4/02
    • A23B4/26A23B4/24Y10S426/807
    • The present invention provides a chemical product having magnesium oxide, magnesium hydroxide or both and being applied as a preservative for animal or animal parts containing fats, proteins or both. The animal or animal part are meat, meat by-product, blood, blood products and animal feed. The preservative may also be combined with an anti-oxidant (such as Vitamin E, i.e. Tocopheryl Acetate), sodium hydroxide, potassium hydroxide, calcium hydroxide, calcium oxide or sodium bicarbonate. The preservative is used as a neutralizer of acids in degradation reactions of proteins and as a neutralizer of acids in degradation reactions of fats. The method of application of the preservative for neutralizing acids during degradation reactions of proteins and for neutralizing acids during degradation reactions of fats is also presented. By stabilizing pH of acidic media, degradation reactions of fats and proteins are slowed.
    • 本发明提供了一种具有氧化镁,氢氧化镁或两者的化学产品,并被用作含有脂肪,蛋白质或二者的动物或动物部分的防腐剂。 动物或动物部分是肉类,肉类副产品,血液,血液制品和动物饲料。 防腐剂也可以与抗氧化剂(如维生素E,即生育酚乙酸酯),氢氧化钠,氢氧化钾,氢氧化钙,氧化钙或碳酸氢钠组合。 防腐剂用作蛋白质降解反应中的酸中和剂,并用作脂肪降解反应中的酸中和剂。 还提出了在蛋白质降解反应期间用于中和酸和在脂肪降解反应中中和酸的防腐剂的应用方法。 通过稳定酸性介质的pH值,脂肪和蛋白质的降解反应减缓。
    • 5. 发明授权
    • Biotreatment of wastewater from hydrocarbon processing units
    • 来自碳氢化合物处理单元的废水生物处理
    • US5705072A
    • 1998-01-06
    • US794532
    • 1997-02-03
    • Richard Alan Haase
    • Richard Alan Haase
    • C02F3/34
    • C02F3/345Y10S210/903
    • This invention provides a process for the biotreatment of effluent from waste gas scrubbing systems of hydrocarbon processing facilities and for the biotreatment of sulfide- and ammonia-containing wastewater streams from other sources. Sulfides are minimized by bacteria cultures, particularly Thiobacillus. COD, TKN and BOD are concurrently minimized by co-cultures of the bacteria with various heterotrophs. In a version of the process, the co-cultures of the bacteria with various heterotrophs are also capable of performing nitrification, without application of nitrifiers. Acclimation of the heterotrophs to the species to be removed is accomplished by biological acclimation and enrichment reactors which reduce mycell toxicity to the heterotrophs. To control pH of the heterotrophic reaction with sulfides, magnesium oxide (MgO) and caustic are used separately or in combination. With adequate removal of the COD, TKN and BOD, nitrification and removal of ammonia can be accomplished by nitrifying bacteria cultures, particularly nitrosomonas and nitrobacters. Enrichment of the nitrosomonas and nitrobacters is accomplished by using a biological enrichment reactor. To control pH and provide a carbon source for the nitrosomonas and nitrobacters, a combination of magnesium oxide and sodium bicarbonate is utilized.
    • 本发明提供了一种用于生物处理来自烃处理设备的废气洗涤系统的流出物以及用于从其他来源生物处理含硫化物和氨的废水流的方法。 硫化物通过细菌培养物,特别是硫杆菌最小化。 COD,TKN和BOD通过细菌与各种异养体的共培养同时最小化。 在该方法的一个版本中,细菌与各种异养菌的共同培养物也能够进行硝化,而不需要硝化剂。 通过生物驯化和富集反应器来实现对要去除的物种的异养菌的适应,这可以降低对异养菌的细胞毒性。 为了用硫化物控制异养反应的pH,可以单独或组合使用氧化镁(MgO)和苛性碱。 通过充分去除COD,TKN和BOD,硝化和除去氨可以通过硝化细菌培养物,特别是亚硝化单胞菌和硝化物来完成。 通过使用生物富集反应器来实现亚硝化单核细胞和亚硝基的富集。 为了控制pH并提供亚硝基和亚硝基的碳源,使用氧化镁和碳酸氢钠的组合。
    • 8. 发明授权
    • Clarification of water and wastewater
    • 澄清水和废水
    • US6120690A
    • 2000-09-19
    • US140203
    • 1998-08-12
    • Richard Alan Haase
    • Richard Alan Haase
    • C02F1/52C02F1/56
    • C02F1/56C02F1/5245
    • This invention provides a process for clarifying waters and wastewaters by using aluminum salts and/or aluminum polymers and newly formulated high molecular weight quaternized polymers. The aluminum polymers and the high molecular weight quaternized polymers are blended in the water or wastewater to form a flocculated suspension, causing liquid-solid separation. The quaternized polymers have a molecular weight of greater than approximately 1,000,000 and have a viscosity greater than about 1,000 cps at a concentration of approximately 20% in water. Preferably, poly-aluminum hydroxychloride, poly-aluminum chloride and poly-aluminum siloxane sulfate are used as aluminum polymers along with high molecular weight quaternized polymers such as di-allyl di-methyl ammonium chloride (DADMAC), to significantly improve liquid-solid separation in waters and wastewaters. Aluminum salts, such as alums and aluminum chloride, can also be used along with the quaternized polymers to clarify water. In addition, algae can be removed from water by blending at least one aluminum salt and/or at least one aluminum polymer with a quaternized polymer.
    • 本发明提供一种通过使用铝盐和/或铝聚合物和新配制的高分子量季铵化聚合物来澄清水和废水的方法。 将铝聚合物和高分子量季铵化聚合物混合在水或废水中以形成絮凝悬浮液,引起液固分离。 季铵化聚合物的分子量大于约1,000,000,并且在水中约20%的浓度下具有大于约1,000cps的粘度。 优选地,聚铝羟基氯化物,聚氯化铝和聚硅氧烷硫酸铝用作铝聚合物以及高分子量季铵化聚合物如二烯丙基二甲基氯化铵(DADMAC),以显着改善液固分离 在水和废水中。 铝盐如明矾和氯化铝也可与季铵化聚合物一起使用以澄清水。 此外,可以通过将至少一种铝盐和/或至少一种铝聚合物与季铵化聚合物共混来从水中除去藻类。
    • 9. 发明授权
    • Biological injector and method of application thereof
    • 生物注射器及其应用方法
    • US5770079A
    • 1998-06-23
    • US882568
    • 1997-06-25
    • Richard Alan Haase
    • Richard Alan Haase
    • C02F1/68C02F3/06C02F3/10C02F3/34C02F1/58
    • C02F1/685C02F3/06C02F3/10Y02W10/15
    • This invention provides a biological injector suitable for biologically treating a fluid flowing through or contained in a collection or treatment system. The biological injector comprises at least one porous section for containing bacterial cultures, at least one non-porous solid section and at least one removable piece which, combinedly, form an enclosed container. Each porous section is attached to at least one non-porous solid section. At least one non-porous solid section is used as a base to which some components of the biological injector can be attached. Each removable piece is attached to one non-porous solid section. The biological injector may include means for fastening the biological injector to a selected location within the collection or treatment system. The biological injector may include means for feeding liquid bacterial cultures and additives to the fluid. When the removable piece is removed, bacterial cultures and, optionally, additives such as nitrogenous salts, phosphorous salts, buffers, surfactants, enzymes and organic substrates, are placed in the biological injector. The biological injector is immersed into the collection or treatment system. Any fluid that passes through the biological injector undergoes biological decomposition.
    • 本发明提供一种适于生物处理流过或包含在收集或处理系统中的流体的生物喷射器。 生物注射器包括用于容纳细菌培养物的至少一个多孔部分,至少一个无孔固体部分和组合形成封闭容器的至少一个可移除部件。 每个多孔部分连接至至少一个无孔固体部分。 使用至少一个无孔固体部分作为生物注射器的一些部件可以附接到的基部。 每个可拆卸件连接到一个无孔固体部分。 生物注射器可以包括用于将生物注射器固定到收集或处理系统内的选定位置的装置。 生物注射器可以包括用于将液体细菌培养物和添加剂供入流体的装置。 当去除可去除的部件时,细菌培养物和任选的添加剂如含氮盐,磷盐,缓冲液,表面活性剂,酶和有机底物置于生物注射器中。 将生物注射器浸入收集或处理系统中。 通过生物注射器的任何流体经历生物分解。
    • 10. 发明申请
    • Means for sequestration and conversion of COx and NOx, CONOx
    • COX和NOx,CONOx的螯合和转化手段
    • US20100173355A1
    • 2010-07-08
    • US12660945
    • 2010-03-08
    • Richard Alan HaaseFadhil SalihCandice Marie Haase
    • Richard Alan HaaseFadhil SalihCandice Marie Haase
    • C12P1/00
    • C12P39/00C12N1/12C12P3/00
    • The instant invention presents means for sequestering COX and NOX; further comprising algae means to convert COX into oxygen (O2), as well as biological means to convert sulfides into elemental sulfur. The instant invention comprises algae, heterotrophs, facultative bacteria and Thiobacillus. The instant invention comprises means of light (photon) transfer. Fiber optics is a means of photon transfer to provide photons to a biological reactor. The instant invention comprises the photon depth adsorption capability of algae in biological reactor means. The instant invention comprises means of energy management so that the instant invention may be used in most any environment, wherein a photon (light) source is available and can comprise a means of photon source generation when a light source is not available. The instant invention is an economical means of hydrocarbon production.
    • 本发明提供了螯合COX和NOX的方法; 还包括将COX转化为氧(O 2)的藻类,以及将硫化物转化为元素硫的生物学手段。 本发明包括藻类,异养菌,兼性细菌和硫杆菌。 本发明包括光(光子)传递的装置。 光纤是光子转移的手段,以向生物反应器提供光子。 本发明包括藻类在生物反应器装置中的光子深度吸附能力。 本发明包括能量管理的手段,使得本发明可以在大多数任何环境中使用,其中光源(光源)是可用的,并且当光源不可用时可以包括光子源产生的手段。 本发明是烃生产的经济手段。