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    • 1. 发明授权
    • Polymeric thickeners for aqueous compositions
    • 含水组合物的聚合增稠剂
    • US5728895A
    • 1998-03-17
    • US727983
    • 1996-10-09
    • Michael S. WigginsReuben GrinsteinStephen A. Fischer
    • Michael S. WigginsReuben GrinsteinStephen A. Fischer
    • C08G65/32C09D7/00C07C43/30C07C43/11
    • C09D7/002Y10S526/933
    • Latexes are thickened by compounds of the formula ##STR1## wherein R.sup.1 is an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having a valence of from 2 to 8; each of B.sub.1 -B.sub.8 is independently an ester, amide, amine, ether, sulfide, disulfide, thiocarbamate, urea, thiourea, urethane, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage; each of X.sup.1 -X.sup.8 is independently -A.sub.1 -R.sup.2 -A.sub.2 - or -A.sub.1 - wherein each of A.sub.1 and A.sub.2 is independently an ester, amide, amine, ether, sulfide, disulfide, urethane, thiocarbamate, urea, thiourea, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage and R.sup.2 is a divalent aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical with the proviso that only one of B.sub.1 -B.sub.8 is urethane and that when one of B.sub.1 -B.sub.8 is urethane, one of A.sub.1 and A.sub.2 is not urethane; each of d, g, j, m, p, s, v, y is independently 0 or 1, each of c, f, i, l, o, r, u, x is independently any integer or non-integer from 0 to about 200; each of J, K, L, M, N, P, Q, S is 0 or 1; each of e, h, k, n, q, t, w, z is independently any integer or non-integer from 0 to about 200; each of R.sup.3 -R.sup.10 is independently an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having from 1 to about 50 carbon atoms; each of AG and AO is independently an ethyleneoxy, 1,2-propyleneoxy, 1,2-butyleneoxy unit or combinations thereof.
    • 乳胶由式(I)的化合物增稠,其中R 1是2至8价的脂族,取代的脂族,芳族或取代的芳族基团; 每个B1-B8独立地是酯,酰胺,胺,醚,硫化物,二硫化物,硫代氨基甲酸酯,脲,硫脲,氨基甲酸酯,硫酸酯,磷酸酯,羰基,亚甲基,硫代酰胺,碳酸酯或酰亚胺键; X1-X8各自独立地为-A1-R2-A2-或-A1-,其中A1和A2各自独立地为酯,酰胺,胺,醚,硫醚,二硫化物,氨基甲酸酯,硫代氨基甲酸酯,脲,硫脲,硫酸酯,磷酸酯 ,羰基,亚甲基,硫代酰胺,碳酸酯或酰亚胺键,R 2是二价脂族,取代的脂族,芳族或取代的芳族基团,条件是B1-B8中只有一个是氨基甲酸酯,当B1-B8中的一个是氨基甲酸酯时 A1和A2之一不是氨基甲酸酯; d,g,j,m,p,s,v,y中的每一个独立地为0或1,c,f,i,l,o,r,u,x中的每一个独立地为0以上的整数或非整数 至约200; J,K,L,M,N,P,Q,S中的每一个为0或1; e,h,k,n,q,t,w,z中的每一个独立地为0至约200的任何整数或非整数; 每个R 3 -R 10独立地是具有1至约50个碳原子的脂族,取代的脂族,芳族或取代的芳族基团; AG和AO各自独立地为亚乙氧基,1,2-亚丙氧基,1,2-亚丁基氧基单元或其组合。