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    • 1. 发明授权
    • Clear surface-active mixtures containing anionic surfactant, APG, and
temporarily cationic copolymer
    • 含有阴离子表面活性剂,APG和临时阳离子共聚物的透明表面活性混合物
    • US5811386A
    • 1998-09-22
    • US903683
    • 1997-07-31
    • Reinhard MuellerKurt SeidelDetlef HollenbergManuela Ehlert
    • Reinhard MuellerKurt SeidelDetlef HollenbergManuela Ehlert
    • A61K8/00A61K8/36A61K8/46A61K8/60A61K8/73A61K8/81A61Q5/00A61Q5/02A61Q7/00A61Q19/10B01F17/00C08L39/06C11D1/04C11D1/06C11D1/08C11D1/12C11D1/14C11D1/28C11D1/29C11D1/66C11D1/68C11D1/83C11D3/37A61K7/075C11D3/22
    • A61K8/604A61K8/463A61K8/817A61K8/8182A61Q5/00A61Q5/02B01F17/0085C11D1/83C11D3/3776A61K2800/5426A61K2800/596C11D1/04C11D1/06C11D1/08C11D1/123C11D1/126C11D1/14C11D1/28C11D1/29C11D1/662
    • A surface active mixture comprising: (A) from about 1 to about 50% by weight of an anionic surfactant having one or two lipophilic groups and having from 1 to 22 carbon atoms and a polar group selected from the group consisting of carboxylate, sulfate and sulfonate groups; (B) from about 0.5 to about 15% by weight of an alkyl glycoside of the formula R(G).sub.x, wherein R is a linear saturated alkyl radical having from 8 to 22 carbon atoms and (G).sub.x is a glycoside or oligoglycoside unit with a degree of oligomerization x of 1 to 10; (C) from about 0.1 to about 7% by weight of a nitrogen-containing copolymer having a molecular weight of from about 15,000 to about 1,500,000 wherein said copolymer is comprised of: (i) from about 99.5 to about 45 mole-% of units derived from vinyl pyrrolidone, (ii) from at 0.5 to about 50 mole-% of units derived from a monomer corresponding to formula (I): CH.sub.2 .dbd.CHR.sup.1 --COOR.sup.2 --NR.sup.3 R.sup.4 (I) R.sup.1 is hydrogen or methyl, R.sup.2 is a C.sub.1-20 alkylene group and each of R.sup.3 and R.sup.4 is independently a C.sub.1-4 alkyl group and, (iii) from 0 to about 50 mole-% of units derived from at least one ethylenically unsaturated copolymerizable monomer different from (i) and (ii), and; (D) from about 28 to about 98.4% by weight of water with the proviso that: (a) the pH value of the mixture Is in the range from 3 to 7 so that the copolymer (C) is present in temporarily cationic form, (b) the sum of components (B) and (C) is no greater than the content of component (A) and, (c) the mixture is free from nitrogen-containing copolymers wherein the nitrogen atoms are present at least partly in permanent cationic form.
    • 一种表面活性混合物,其包含:(A)约1至约50重量%的具有一个或两个亲脂基团并且具有1至22个碳原子的阴离子表面活性剂和极性基团,所述极性基团选自羧酸根,硫酸根和 磺酸酯基; (B)约0.5至约15重量%的式R(G)x的烷基糖苷,其中R是具有8至22个碳原子的直链饱和烷基,(G)是糖苷或寡聚糖苷单元 低聚度x为1〜10; (C)约0.1至约7重量%的分子量为约15,000至约1,500,000的含氮共聚物,其中所述共聚物包含:(i)约99.5至约45摩尔%的单元 衍生自乙烯基吡咯烷酮的(ii)0.5至约50摩尔%衍生自对应于式(I)的单体的单元:CH 2 = CHR 1 -COOR 2 -NR 3 R 4(I)R 1是氢或甲基,R 2是C 1 -20亚烷基,R3和R4各自独立地为C1-4烷基,和(iii)0至约50摩尔%的衍生自不同于(i)和(ii)的至少一种烯属不饱和可共聚单体的单元 ),和; (D)约28至约98.4重量%的水,条件是:(a)混合物的pH值在3至7的范围内,使得共聚物(C)以暂时阳离子形式存在, (b)组分(B)和(C)的总和不大于组分(A)的含量,和(c)混合物不含含氮共聚物,其中氮原子至少部分存在于永久 阳离子形式。
    • 4. 发明授权
    • Mild cleaning preparations
    • 温和的清洁剂
    • US06172018B2
    • 2001-01-09
    • US08204150
    • 1994-05-02
    • Reinhard MuellerKurt SeidelDetlef HollenbergAnja Patten
    • Reinhard MuellerKurt SeidelDetlef HollenbergAnja Patten
    • A61K750
    • A61K8/463A61K8/604A61K8/86A61K2800/5424A61K2800/596A61Q5/02
    • Aqueous cleaning compositions having high foaming power and minimal effect on the skin which comprise (A) from about 1 to about 50% by weight of one or more anionic surfactants having 1 or 2 lipophilic groups each of which has from 1 to 22 carbon atoms and a polar group selected from the group consisting of a carboxylate, a sulfate, and a sulfonate group; (B) from about 0.5 to about 10% by weight of one or more alkyl glycosides of the formula R(G)x wherein R is a linear, saturate C8-22 alkyl group, (G) is a glycoside or oligoglycoside moiety, and x is a number from 1 to 4; (C) from about 0.1 to about 5% by weight of an anionic polymer; (D) from about 35 to about 98.4% by weight of water; wherein the sum total of components (B) and (C) is no greater man the amount of component (A).
    • 具有高发泡能力和对皮肤影响最小的水性清洁组合物,其包含(A)约1至约50重量%的一种或多种具有1或2个具有1至22个碳原子的亲脂基团的阴离子表面活性剂和 选自羧酸酯,硫酸酯和磺酸酯基的极性基团; (B)约0.5至约10重量%的一种或多种糠醛的烷基糖苷R是直链饱和的C 8-22烷基,(G)是糖苷或低聚糖苷部分,x是1 到4; (C)约0.1至约5重量%的阴离子聚合物; (D)约35至约98.4重量%的水; 其中组分(B)和(C)的总和不大于组分(A)的量。
    • 6. 发明授权
    • Emulsions
    • 乳液
    • US5830483A
    • 1998-11-03
    • US702483
    • 1996-09-12
    • Kurt SeidelChristian PriebeDetlef Hollenberg
    • Kurt SeidelChristian PriebeDetlef Hollenberg
    • A61K8/06A61K8/39A61K8/60A61Q5/00A61Q19/00B01F17/00A61K7/075A61K7/08A61K7/48B01J13/00
    • A61K8/064A61K8/06A61K8/39A61K8/60A61Q19/00A61Q5/00B01F17/0085B01F17/0092Y10S514/941Y10S514/975
    • An oil-in-water emulsion comprising (A) from about 50 to about 99% by weight of water; (B) from about 1 to about 30% by weight of an oil phase; and (C) an emulsifying effective quantity of an emulsifier system consisting essentially of (i) at least one nonionic emulsifier of formula (I): Z.sub.x R.sup.1 (R.sup.2 --CO).sub.y G.sub.z (I) in which Z is a sugar unit selected from the group consisting of pentoses and hexoses, x is a number of 1 to 5, R.sup.1 is a saturated alkyl radical containing 1 to 3 carbon atoms, R.sup.2 is a linear or branched alkyl radical or mono- or polyunsaturated alkenyl radical containing 8 to 22 carbon atoms, y is the number 1 or 2, G is a polyglycerol residue consisting of 2 to 10 glycerol units and z is the number 1 or 2, and (ii) at least one ionic emulsifier selected from the group consisting of cationic and anionic emulsifiers.
    • PCT No.PCT / EP95 / 00533 Sec。 371日期:1996年9月12日 102(e)日期1996年9月12日PCT提交1995年2月14日PCT公布。 公开号WO95 / 22313 日期1995年8月24日一种水包油乳液,其包含(A)约50至约99重量%的水; (B)约1至约30重量%的油相; 和(C)乳化剂有效量的乳化剂体系,其基本上由(i)至少一种式(I)的非离子乳化剂:ZxR1(R2-CO)yGz(I)组成,其中Z是选自下组的糖单元 由戊糖和己糖组成,x为1至5的数,R1为含有1至3个碳原子的饱和烷基,R2为直链或支链烷基或含有8至22个碳原子的单或多不饱和链烯基, y是数字1或2,G是由2至10个甘油单元组成的聚甘油残基,z是数字1或2,和(ii)至少一种选自阳离子和阴离子乳化剂的离子乳化剂。
    • 10. 发明授权
    • Cationic polymers as antistatic additives for hair preparations
    • 阳离子聚合物作为头发制剂的抗静电添加剂
    • US4900543A
    • 1990-02-13
    • US885387
    • 1986-07-17
    • Wolfgang RitterRolf TenhaefHorst HoffkesKurt Seidel
    • Wolfgang RitterRolf TenhaefHorst HoffkesKurt Seidel
    • C08C19/40C08G59/34C08G73/02C11D3/37
    • A61K8/84A61Q5/02C08C19/40C08G59/027C08G73/0273A61Q5/10Y10S514/88Y10S514/881
    • An aqueous hair-treatment preparation containing an antistatic additive imparting an antistatic effect to the hair, characterized in that said antistatic additive is at least one cationic polymer produced by the process of (1) epoxidizing 1,3-diene homopolymers or copolymers, (2) amine reacting the epoxide compound so produced with low molecular weight amines selected from the group consisting of primary amines, secondary amines and tertiary amines, and (3) converting the reaction products into the salt form or into polymeric quaternary ammonium salts. The use of these polymeric amine salts or quaternary ammonium salts in cosmetic hair-treatment preparations provides these preparations with antistatic effects. Preferred cationic polymers are obtained by the expoxidation of polybutadiene, of which more than 50% of the monomer units show the 1,4-cis- configuration, reaction with dimethylamine or morpholine and conversion into the hydrochlorides or alkylation with glycidyl trimethylammonium chloride, 3-chloro-2-hydroxypropyl trimethylammonium chloride or ethylene oxide. The cationic polymers are preferably used in shampoos in quantities of from 0.5 to 5.0% by weight in addition to 5 to 30% by weight of alkylether sulfate tensides and 1 to 5% by weight of a zwitterionic or amphoteric washing-active substance.
    • 一种含有对头发赋予抗静电效果的抗静电添加剂的水性护发剂,其特征在于,所述抗静电添加剂是通过(1)环氧化1,3-二烯均聚物或共聚物的方法制备的至少一种阳离子聚合物,(2 )胺使如此制备的环氧化合物与选自伯胺,仲胺和叔胺的低分子量胺反应,和(3)将反应产物转化为盐形式或转化为聚合季铵盐。 在化妆品头发处理制剂中使用这些聚合胺盐或季铵盐使这些制剂具有抗静电效果。 优选的阳离子聚合物通过聚合丁二烯的过氧化获得,其中多于50%的单体单元显示1,4-顺式构型,与二甲胺或吗啉反应并转化为盐酸盐或用缩水甘油基三甲基氯化铵进行烷基化, 氯-2-羟丙基三甲基氯化铵或环氧乙烷。 除了5〜30重量%的烷基醚硫酸盐表面活性剂和1〜5重量%的两性离子或两性洗涤活性物质之外,阳离子性聚合物优选以洗发剂的量计为0.5〜5.0重量%。