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1. 发明授权

US4530990A Process for the preparation of viscosity stable polyurethane solutions 失效
标题翻译：制备粘度稳定的聚氨酯溶液的方法
公开(公告)号：US4530990A
公开(公告)日：1985-07-23
申请号：US433596
申请日：1982-10-08
申请人： Reinhard Halpaap , Josef Pedain , Wilhelm Thoma , Jurgen Grammel
发明人： Reinhard Halpaap , Josef Pedain , Wilhelm Thoma , Jurgen Grammel
IPC分类号： C08G18/00 , C08G18/10 , C08G18/65 , C08G2/28 , C08G18/08
CPC分类号： C08G18/10
摘要： A process is described for the preparation of predominantly linear polyurethane solutions which comprises(a) reacting(A) an organic diisocyanate or diisocyanate mixture optionally containing small portions of a triisocyanate with(B) one or more polyhydroxyl compounds which are predominantly bifunctional and generally have molecular weights of from about 400 to 5000 and(C) optionally one or more chain lengthening agents having at least two isocyanate reactive hydrogen atoms and molecular weights of from about 32 to 399, wherein the proportion of isocyanate groups to the number of isocyanate-reactive hydrogen atoms is in the range of from about 0.9:1 to 1:0.9, and(b) when the polyurethane formed has reached the required viscosity, adding a monofunctional, low molecular weight oxime having a molecular weight of from about 73 to 325, preferably butanone oxime, to the reaction mixture as chain breaking agent in a quantity equivalent to or in excess of the equivalents of unreacted isocyanate groups.The new chain breaking agents are simple compounds which effect rapid chain breaking and have no undesirable side effects as regards subsequent breakdown of the chains and even enable further synthesizing reactions to be carried out if desired, for example with diamines.
摘要翻译：描述了用于制备主要为线性聚氨酯溶液的方法，其包括（a）使（A）任选地含有少量三异氰酸酯的有机二异氰酸酯或二异氰酸酯混合物与（B）一种或多种主要是双官能的多羟基化合物反应，并且通常具有约400至5000的分子量和（C）任选的一种或多种具有至少两个异氰酸酯反应性氢原子和分子量为约32至399的链延长剂，其中异氰酸酯基团与异氰酸酯反应性数目的比例氢原子在约0.9:1至1:0.9的范围内，和（b）当所形成的聚氨酯达到所需粘度时，加入分子量为约73至325的单官能低分子量肟，优选丁酮肟作为断链剂的反应混合物，其量等于或超过未反应的异氰酸酯的当量 anate组。新的断链剂是简单的化合物，其能够快速断链，并且对链的随后分解没有不期望的副作用，并且甚至能够进一步合成反应，如果需要，例如用二胺进行。

2. 发明授权

US5237058A Polyisocyanates containing uretdione and/or isocyanurate groups, a process for their production 失效
标题翻译：含有URETDIONE和/或异氰酸酯基团的聚异氰酸酯，其生产过程
公开(公告)号：US5237058A
公开(公告)日：1993-08-17
申请号：US774687
申请日：1991-10-11
申请人： Hans J. Laas , Reinhard Halpaap , Josef Pedain
发明人： Hans J. Laas , Reinhard Halpaap , Josef Pedain
IPC分类号： C07D229/00 , C07D251/34 , C08G18/79 , C09D175/00 , C09D175/04
CPC分类号： C07D229/00 , C08G18/792 , C08G18/798
摘要： The present invention relates to a process for the production of polyisocyanates containing uretdione and/or isocyanurate groups bya) partially oligomerizing the isocyanate groups of organic diisocyanates to form uretdione and/or isocyanurate groups in the presence of catalysts containing trivalent phosphorus,b) terminating the oligomerization reaction at the desired degree of oligomerization by converting the catalyst into a catalytically inactive oxidized form by the addition of an oxidizing agent andc) subsequently removing unreacted diisocyanate by thin-layer distillation.The present invention also relates to the polyisocyanates containing uretdione and/or isocyanurate groups obtained by this process.Finally, the present invention also relates to the use of these polyisocyanates, optionally blocked with blocking agents for isocyanate groups, as the isocyanate component in polyurethane coating compositions.
摘要翻译：本发明涉及通过以下方法制备含有脲二酮和/或异氰脲酸酯基团的多异氰酸酯的方法：a）在含有三价磷的催化剂存在下，部分低聚有机二异氰酸酯的异氰酸酯基团以形成脲二酮和/或异氰脲酸酯基团，b）终止通过加入氧化剂将催化剂转化成催化惰性氧化形式，并且c）通过薄层蒸馏随后除去未反应的二异氰酸酯，从而在所需的低聚程度下进行低聚反应。本发明还涉及通过该方法获得的含有脲二酮和/或异氰脲酸酯基团的多异氰酸酯。最后，本发明还涉及这些聚异氰酸酯，任选地用封端剂封端的异氰酸酯基团作为聚氨酯涂料组合物中的异氰酸酯组分的用途。

3. 发明授权

US5143994A Polyisocyanate mixture, a process for its preparation and its use in polyurethane coating compositions 失效
标题翻译：聚异氰酸酯混合物，其制备方法及其在聚氨酯涂料组合物中的用途
公开(公告)号：US5143994A
公开(公告)日：1992-09-01
申请号：US759315
申请日：1991-09-13
申请人： Hans J. Laas , Reinhard Halpaap , Josef Pedain , Jurgen Mosbach
发明人： Hans J. Laas , Reinhard Halpaap , Josef Pedain , Jurgen Mosbach
IPC分类号： C07D229/00 , C07D251/30 , C07D251/34 , C08G18/72 , C08G18/79 , C09D175/00 , C09D175/04
CPC分类号： C07D229/00 , C07D251/34 , C08G18/792 , C08G18/798 , C08G2150/20
摘要： The present invention relates to polyisocyanate mixtures prepared from 1,6-diisocyanatohexane (HDI) and 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethyl cyclohexane (IPDI), which have a uretdione content (calculated as C.sub.2 N.sub.2 O.sub.2) of 8 to 25% by weight and an isocyanurate content (calculated as C.sub.3 N.sub.3.sub.O.sub.3) of not more than 24% by weight and containa) 20 to 60% by weight of uretdione diisocyanatesb) 0 to 40% by weight of isocyanurate triisocyanatesc) 15 to 60% by weight of higher homologues of the polyisocyanates of components a) and b) containing more than one uretdione ring and/or isocyanurate ring andd) a total of not more than 1% by weight of (HDI) and (IPDI).The present invention also relates to a process for the preparation of these polyisocyanate mixtures and to their use, optionally blocked with blocking agents for isocyanate groups, as the isocyanate component in polyurethane coating compositions.
摘要翻译：本发明涉及由1,6-二异氰酸根合己烷（HDI）和1-异氰酸根合-3,3,5-三甲基-5-异氰酸甲酯环己烷（IPDI）制备的多异氰酸酯混合物，其具有脲二酮含量（以C 2 N 2 O 2计算）为8 至25重量％，并且异氰脲酸酯含量（以C3N3O3计算）不超过24重量％，并含有a）20至60重量％的脲二酮二异氰酸酯b）0至40重量％的异氰脲酸酯三异氰酸酯c）15至 60重量％的含有多于一个脲二环和/或异氰脲酸酯环的组分a）和b）的多异氰酸酯的高级同系物和d）总共不超过1重量％的（HDI）和（IPDI）。本发明还涉及一种制备这些多异氰酸酯混合物的方法及其用途，任选地用聚异氰酸酯基团的封端剂封端，作为聚氨酯涂料组合物中的异氰酸酯组分。

4. 发明授权

US5126479A Process for the production of blocked polyisocyanates containing carbodiimide groups, the polyisocyanates obtainable by this process and their use for the production of plastics 失效
标题翻译：用于制备含有碳二亚胺基团的封端多异氰酸酯的方法，可通过该方法获得的多异氰酸酯及其用于生产塑料的方法
公开(公告)号：US5126479A
公开(公告)日：1992-06-30
申请号：US351683
申请日：1989-05-15
申请人： Willi Dunwald , Reinhard Halpaap , Josef Pedain
发明人： Willi Dunwald , Reinhard Halpaap , Josef Pedain
IPC分类号： C07C267/00 , C03C25/32 , C07C67/00 , C07C241/00 , C07C263/18 , C07C265/14 , C08G18/79 , C08G18/80 , C09D5/25 , C09D175/00 , C09D175/04 , C09D175/14 , H01B3/30
CPC分类号： C03C25/326 , C08G18/797 , C08G18/8061 , H01B3/302
摘要： The present invention relates to a process for the production of organic compounds containing (i) carbodiimide and/or uretone imine groups and (ii) blocked isocyanate groups, wherein about 10 to 90% of the isocyanate groups of an organic polyisocyanate are blocked by reaction with a monofunctional blocking agent for isocyanate groups, and subsequently about 65 to 100% of the free isocyanate groups still remaining are converted into carbodiimide groups with elimination of the carbodiimide. The present invention also relates to the organic compounds obtainable by this process and to their use for the production of plastics by reaction with compounds containing isocyanate-reactive groups by the isocyanate polyaddition process.
摘要翻译：本发明涉及一种生产含有（i）碳二亚胺和/或脲酮亚胺基团和（ii）封端异氰酸酯基团的有机化合物的方法，其中有机多异氰酸酯的约10至90％的异氰酸酯基团被反应阻断与异氰酸酯基团的单官能封端剂反应，随后剩余的约65-100％的游离异氰酸酯基团被除去碳二亚胺转化为碳二亚胺基团。本发明还涉及通过该方法获得的有机化合物及其通过与通过异氰酸酯加聚方法含有异氰酸酯反应性基团的化合物反应来生产塑料的用途。

5. 发明授权

US4851531A Isocyanurate group-containing polyisocyanates 失效
标题翻译：含异氰脲酸酯基的多异氰酸酯
公开(公告)号：US4851531A
公开(公告)日：1989-07-25
申请号：US74380
申请日：1987-07-16
申请人： Reinhard Halpaap , Gerhard Klein , Roland Richter , Hanns P. Muller , Josef Pedain , Hans-Joachim Kreuder
发明人： Reinhard Halpaap , Gerhard Klein , Roland Richter , Hanns P. Muller , Josef Pedain , Hans-Joachim Kreuder
IPC分类号： C08G18/00 , C07D251/34 , C08G18/02 , C08G18/79 , C09D5/46 , C09D175/00 , C09D175/12
CPC分类号： C08G18/792 , C07D251/34 , C08G2150/20
摘要： The present invention is directed to isocyanato isocyanurates prepared from diisocyanates which contain a sterically unhindered isocyanate group bound to a primary aliphatic carbon atom and a sterically hindered isocyanate group which is bound to a tertiary carbon atom forming part of a cycloaliphatic ring system, said diisocyanate having an NCO content of about 20 to 50% by weight. The present invention is further directed to a process for preparing these isocyanato isocyanurates by catalytic trimerization and the use of the isocyanato isocyanurates in a process for the production of polyisocyanate polyaddition products, preferably two-component polyurethane stoving lacquers.
摘要翻译：本发明涉及由二异氰酸酯制备的异氰酸根合异氰脲酸酯，该二异氰酸酯包含与主要脂族碳原子结合的空间上不受阻碍的异氰酸酯基团和与形成脂环族环系的一部分的叔碳原子结合的空间位阻异氰酸酯基团，所述二异氰酸酯具有约20至50重量％的NCO含量。本发明还涉及一种通过催化三聚制备这些异氰酸酯异氰脲酸酯的方法，以及在制备多异氰酸酯加聚产物的方法中使用异氰酸酯基异氰脲酸酯的方法，优选为双组分聚氨酯烘烤漆。

6. 发明授权

US4748242A Tertiary polyisocyanate derivatives 失效
标题翻译：三元多异氰酸酯衍生物
公开(公告)号：US4748242A
公开(公告)日：1988-05-31
申请号：US930584
申请日：1986-11-12
申请人： Reinhard Halpaap , Josef Pedain , Hans-Joachim Kreuder , Gerhard Klein , Dieter Arlt
发明人： Reinhard Halpaap , Josef Pedain , Hans-Joachim Kreuder , Gerhard Klein , Dieter Arlt
IPC分类号： C08G18/00 , C08G18/02 , C08G18/06 , C08G18/79 , C08G63/52 , C07D251/30 , C07D251/32
CPC分类号： C08G18/792 , C08G2150/20
摘要： The present invention is directed to a process for the production of polyisocyanates containing isocyanurate groups by trimerizing a mixture of aliphatic-cycloaliphatic diisocyanates having a sterically unhindered isocyanate group bound to a primary aliphatic carbon atom and a sterically hindered isocyanate group bound to a tertiary carbon atom which forms a part of a cycloaliphatic ring system and 1,6-diisocyanatohexane. The present invention is also directed to the polyisocyanates containing isocyanurate groups produced according to this process and to their use, optionally in blocked form, as an isocyanate component in the production of polyisocyanate polyaddition products, preferably polyurethane lacquers.
摘要翻译：本发明涉及一种制备含有异氰脲酸酯基团的多异氰酸酯的方法，该方法是将具有与伯脂肪族碳原子结合的空间上不受阻碍的异氰酸酯基团和与叔碳原子结合的位阻异氰酸酯基团的脂族 - 脂环族二异氰酸酯的混合物三聚其形成脂环族环系的一部分和1,6-二异氰酸根合己烷。本发明还涉及根据该方法制备的含有异氰脲酸酯基团的多异氰酸酯基团，以及它们在多异氰酸酯加聚产物（优选聚氨酯漆）生产中作为异氰酸酯组分的用途，任选地以封闭形式使用。

7. 发明授权

US4481345A Process for the production of combinations of organic polyisocyanates and at least partly blocked polyamines, the combinations obtainable by this process and their use for the production of lacquers, coating or sealing compositions 失效
标题翻译：用于生产有机多异氰酸酯和至少部分封闭的多胺的组合的方法，可通过该方法获得的组合及其用于生产漆，涂料或密封组合物的用途
公开(公告)号：US4481345A
公开(公告)日：1984-11-06
申请号：US583918
申请日：1984-02-27
申请人： Klaus Nachtkamp , Manfred Bock , Reinhard Halpaap , Josef Pedain
发明人： Klaus Nachtkamp , Manfred Bock , Reinhard Halpaap , Josef Pedain
IPC分类号： C09K3/10 , C08G18/10 , C08G18/32 , C08G18/65 , C09D175/00 , C09D175/02 , C09D175/04 , C08G18/38
CPC分类号： C08G18/3256 , C08G18/10
摘要： Process for the production of water-hardenable compositions of organic polyisocyanates and polyamines containing at least partly blocked amino groups present as ketimines, the combinations essentially representing mixtures and optionally reaction products containing urea groups by mixing the organic polyisocyanates with the polyamines in such quantities that the equivalent ratio of isocyanate groups to blocked and free amino groups is between about 0.9:1 and 4:1 and reacting any free amino groups present with some of the isocyanate groups in the polyisocyanate to form ureas, characterized in that the polyamines containing at least partly blocked amino groups used are mixtures comprising(a) from about 50 to 95 amine equivalent percent of organic compounds which are free from primary and secondary amino groups and which contain at least two ketimine groups corresponding to the following formula ##STR1## in which R.sup.1 represents an alkyl or cycloalkyl radical and R.sup.2 represents hydrogen or an alkyl or cycloalkyl radical or in which R.sup.1 and R.sup.2 form a cycloaliphatic hydrocarbon radical together with the two carbon atoms of the ketimine group and(b) from about 5 to 40 amine equivalent percent of organic compounds which are free from primary and secondary amino groups and which contain at least two ketimine groups of which one corresponds to the formula ##STR2## in which R.sup.1 and R.sup.2 are as defined above, the other ketimine group(s) present correspond(s) to the formula shown in (a).
摘要翻译：用于生产有机多异氰酸酯和含有至少部分封闭的胺基的多胺的水可硬化组合物作为酮亚胺存在的方法，所述组合基本上代表混合物和任选的含有尿素基团的反应产物，通过将有机多异氰酸酯与多胺混合，异氰酸酯基与封端和游离氨基的当量比为约0.9:1至4:1，并使与多异氰酸酯中存在的一些异氰酸酯基团存在的任何游离氨基反应形成脲，其特征在于，含有至少部分使用的封闭氨基是包含（a）约50至95胺当量百分比的不含伯和仲氨基并且含有至少两个对应于下式的酮亚胺基的有机化合物的混合物：其中R 1表示烷基或环烷基，R 2表示氢或a n烷基或环烷基，或其中R1和R2与酮亚胺基团的两个碳原子一起形成脂环族烃基，和（b）约5至40胺当量百分比的不含伯和仲氨基的有机化合物并且其包含至少两个酮亚胺基，其中一个对应于式（Ia）其中R 1和R 2如上所定义的式“IMAGE”，其它酮亚胺基与（a）所示的式表示。

8. 发明授权

US5821326A Process for preparing mono and polyaspartates 失效
标题翻译：制备单和聚天冬氨酸的方法
公开(公告)号：US5821326A
公开(公告)日：1998-10-13
申请号：US883478
申请日：1997-06-25
申请人： Gerald Kurek , Josef Pedain , Reinhard Halpaap , Michael Sonntag
发明人： Gerald Kurek , Josef Pedain , Reinhard Halpaap , Michael Sonntag
IPC分类号： B01J31/02 , C07B61/00 , C07C227/08 , C07C227/18 , C07C229/24 , C08G18/32 , C08G18/38 , C09D175/04 , C09D175/12 , C08G69/26
CPC分类号： C07C227/18 , C08G18/3821 , C09D175/12
摘要： The present invention relates to a new process for preparing mono and polyaspartates from primary mono and polyamines and maleates in presence of five-membered aromatic ring compounds containing nitrogen atoms in the ring structure as catalysts and use of these mono and polyaspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers.
摘要翻译：本发明涉及一种在环结构中含有氮原子的五元芳环化合物作为催化剂和由单个和多聚天冬氨酸作为多异氰酸酯的反应性组分的用途制备单和聚胺和马来酸酯的单和聚天冬氨酸的新方法在双组分聚氨酯涂料组合物中并用于制备聚氨酯预聚物。

9. 发明授权

US06392001B1 Process for the production of light-stable polyisocyanates containing allophanate groups 失效
标题翻译：用于生产含有脲基甲酸酯基的光稳定多异氰酸酯的方法
公开(公告)号：US06392001B1
公开(公告)日：2002-05-21
申请号：US08432285
申请日：1995-05-01
申请人： Harald Mertes , Josef Pedain , Reinhard Halpaap
发明人： Harald Mertes , Josef Pedain , Reinhard Halpaap
IPC分类号： C08G1810
CPC分类号： C08G18/7837 , C07C273/1836 , C07C275/60
摘要： The present invention relates to a process for the production of polyisocyanates containing allophanate groups and having aliphatically and/or cycloaliphatically bound isocyanate groups by reacting organic compounds containing urethane groups with organic polyisocyanates containing aliphatically and/or cycloaliphatically bound isocyanate groups in the presence of tin compounds and to the use of these polyisocyanates, optionally blocked with blocking agents for isocyanate groups, as an isocyanate component in the production of polyurethanes, in particular polyurethane coatings.
摘要翻译：本发明涉及通过在锡化合物的存在下使含有氨基甲酸酯基团的有机化合物与含有脂族和/或环状结合的异氰酸酯基团的有机多异氰酸酯反应来生产含有脲基甲酸酯基并具有脂族和/或环脂键结的异氰酸酯基团的多异氰酸酯的方法以及在聚氨酯生产中尤其是聚氨酯涂料中使用这些多异氰酸酯，任选地被异氰酸酯基封端剂封闭，作为异氰酸酯组分。

10. 发明授权

US5750629A Uretdione diisocyanates and a process for their production 失效
标题翻译：脲二异氰酸酯及其制备方法
公开(公告)号：US5750629A
公开(公告)日：1998-05-12
申请号：US788726
申请日：1997-01-23
申请人： Hans-Josef Laas , Reinhard Halpaap , Josef Pedain , Klaus Konig
发明人： Hans-Josef Laas , Reinhard Halpaap , Josef Pedain , Klaus Konig
IPC分类号： B01D3/28 , B01J31/24 , C07B61/00 , C07D229/00 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04
CPC分类号： C08G18/8016 , C07D229/00 , C08G18/798
摘要： The present invention relates to a process for preparing pure bis(isocyanatoalkyl)monouretdiones corresponding to formula (I) ##STR1## wherein R represents identical or different, linear or branched alkyl groups having 4 to 9 carbon atoms, by oligomerizing at least a portion of the isocyanate groups of aliphatic diisocyanates in the presence of catalysts which accelerate the dimerization of isocyanate groups, terminating the reaction at the desired degree of oligomerization, removing unreacted excess diisocyanate by extraction or thin film distillation to obtain a distillation residue, subjecting the distillation residue to thin film distillation at a temperature of 160.degree. to 220.degree. C. and a pressure of 0.01 to 1.0 mbar and obtaining bis(isocyanato-alkyl)monouretdiones corresponding to formula (I) as the distillate. The present invention also relates to the resulting bis(isocyanato-alkyl)monouretdiones corresponding to formula I and to their use for the production of polyisocyanate addition products, in particular as the isocyanate components in polyurethane coatings compositions, in which the isocyanate groups may optionally be present in blocked form.
摘要翻译：本发明涉及一种制备对应于式（I）的纯双（异氰酸根合烷基）单脲基的方法，其中R表示相同或不同的具有4至9个碳原子的直链或支链烷基，至少通过低聚一部分脂族二异氰酸酯的异氰酸酯基团在催化剂存在下加速异氰酸酯基团的二聚反应，以期望的低聚程度终止反应，通过萃取或薄膜蒸馏除去未反应的过量二异氰酸酯，得到蒸馏残渣，蒸馏残渣，在160〜220℃的温度和0.01〜1.0mbar的压力下进行薄膜蒸馏，得到与式（I）相应的作为馏出物的双（异氰酸基 - 烷基）单脲。本发明还涉及所得到的对应于式I的双（异氰酸根合 - 烷基）单脲基团，以及其用于制备多异氰酸酯加成产物的用途，特别是作为聚氨酯涂料组合物中的异氰酸酯组分，其中异氰酸酯基团可任选地为以阻塞形式存在。

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