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    • 1. 发明授权
    • Powder coating compositions and their use for coating heat-resistant
substrates
    • 粉末涂料组合物及其用于涂覆耐热基材的用途
    • US5852101A
    • 1998-12-22
    • US958227
    • 1997-10-27
    • Reinhard HalpaapChristian WamprechtHans-Joachim KreuderWolfgang SchultzManfred BockRainer Rettig
    • Reinhard HalpaapChristian WamprechtHans-Joachim KreuderWolfgang SchultzManfred BockRainer Rettig
    • C08G18/62C08G18/75C08G18/78C08G18/80C09D5/03C09D5/46C09D175/00C09D175/04C08J3/00C08F8/30C08K3/00C08L75/00
    • C08G18/8074C08G18/6229C08G18/6254C08G18/758C08G18/8016C08G2150/20Y10T428/31551
    • The present invention relates to a powder coating composition for the production of non-yellowing flexible coatings which is solid below 30.degree. C. and liquid above 120.degree. C. and contains a mixture of A) a polyisocyanate component which i) has a content of blocked isocyanate groups (expressed as NCO, molecular weight=42) of 3.0 to 14.0% by weight, ii) has a functionality, based on the blocked isocyanate groups, of 1.9 to 2.3 and iii) and contains at least one .epsilon.-caprolactam-blocked polyisocyanate based on the reaction product of 4,4'-diisocyanatodicyclohexyl methane with a polyol component having an average molecular weight of 90 to 400 and containing at least 50% by weight, based on the weight of the polyol component, of one or more (cyclo)aliphatic diols containing 4 to 12 carbon atoms, B) a polyol component containing at least one polyhydroxy polyacrylate having an OH number of 40 to 120 and C) an organotin catalyst for the reaction between hydroxyl groups and blocked isocyanate groups, wherein components A) and B) are present in quantities which correspond to an equivalent ratio of blocked polyisocyanate groups to hydroxyl groups of 0.5:1 to 1.2:1. The present invention also relates to the a heat-resistant substrate which is coated with this powder coating composition.
    • 本发明涉及一种粉末涂料组合物,用于生产低于30℃的固体和高于120℃的液体的非黄变柔性涂层,并且含有A)多异氰酸酯组分的混合物,i)多异氰酸酯组分的含量 封闭的异氰酸酯基团(表示为NCO,分子量= 42)为3.0至14.0重量%,ii)基于封端异氰酸酯基团的官能度为1.9至2.3和iii)并且包含至少一个ε-己内酰胺 - 封端的多异氰酸酯基于4,4'-二异氰酸二环己基甲烷与平均分子量为90至400的多元醇组分的反应产物和基于多元醇组分重量的至少50重量%的一种或多种 含有4至12个碳原子的(环)脂族二醇,B)含有至少一种羟值为40至120的多羟基聚丙烯酸酯的多元醇组分,C)用于羟基与封端异氰酸酯反应的有机锡催化剂 te基团,其中组分A)和B)以对应于封端多异氰酸酯基团与羟基的当量比为0.5:1至1.2:1的量存在。 本发明还涉及涂覆有该粉末涂料组合物的耐热基材。
    • 5. 发明授权
    • Powder coating compositions, a process for their preparation, and their
use for the coating of heat resistant substrates
    • 粉末涂料组合物,其制备方法及其用于涂覆耐热基材的用途
    • US5508337A
    • 1996-04-16
    • US238563
    • 1994-05-05
    • Christian WamprechtReinhard HalpaapHans-Ulrich Meier-WesthuesWolfgang Schultz
    • Christian WamprechtReinhard HalpaapHans-Ulrich Meier-WesthuesWolfgang Schultz
    • C08G18/40C08G18/78C08G18/79C08G18/80C09D5/46C08J3/00C08F8/30C08K3/20C08L75/00
    • C08G18/7831C08G18/4063C08G18/792C08G18/8077C08G2150/20Y10T428/31551
    • The present invention relates to a powder coating composition having a glass transition temperature of 20.degree. to 80.degree. C. and containing(A) 56 to 86.9% by weight of a polyacrylate polyol component having a hydroxyl number of 30 to 155 and a glass transition temperature of 30.degree. to 120.degree. C.,(B) 0.1 to 9% by weight of a polyester polyol component having a hydroxyl number of 40 to 180 and a glass transition temperature of -40.degree. to 80.degree. C.,(C) 13 to 35% by weight of a polyisocyanate component having a glass transition temperature of -40.degree. to 60.degree. C. and containing at least one ketoxime-blocked polyisocyanate selected from (i) polyisocyanate derivatives prepared from 1,6-diisocyanatohexane and containing biuret, isocyanurate, uretdione, and/or urethane groups, (ii) polyisocyanate derivatives prepared from mixtures of 1,6-diisocyanatohexane and 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane and containing isocyanurate groups and optionally uretdione groups and (iii) polyisocyanate derivatives prepared from 4,4'-diisocyanato-dicyclohexylmethane and containing urethane groups, and(D) at least one catalyst for the reaction between blocked isocyanate groups and hydroxyl groups,wherein i) the percentages of components (A), (B), and (C) are based on the total weight of these components and ii) components (A), (B), and (C) are present in amounts sufficient to provide an equivalent ratio of blocked isocyanate groups to hydroxyl groups of 0.5:1 to 1.5:1.The present invention is also relates to a process for the preparation of this powder coating composition and to heat-resistant substrates, particularly automotive body parts, coated with this powder coating composition.
    • 本发明涉及玻璃化转变温度为20〜80℃,含有(A)56〜86.9重量%的羟基数为30〜155的聚丙烯酸酯多元醇成分和玻璃化转变温度的粉末涂料组合物 温度为30〜120℃,(B)0.1〜9重量%的羟值为40〜180,玻璃化转变温度为-40〜80℃的聚酯多元醇成分,(C) 13至35重量%的玻璃化转变温度为-40至60℃的多异氰酸酯组分,并含有至少一种酮肟封闭的多异氰酸酯,其选自(i)由1,6-二异氰酸根合己烷制备并含有缩二脲 ,异氰脲酸酯,脲二酮和/或氨基甲酸酯基团,(ii)由1,6-二异氰酸根合己烷和1-异氰酸根合-3,3,5-三甲基-5-异氰酸甲酯基环己烷的混合物制备并含有异氰脲酸酯基团和任选的脲二酮基团的多异氰酸酯衍生物, (iii )由4,4'-二异氰酸根合二环己基甲烷制备并含有氨基甲酸酯基团的多异氰酸酯衍生物,和(D)至少一种用于封端异氰酸酯基和羟基之间反应的催化剂,其中i)组分(A),(B )和(C)基于这些组分的总重量,和ii)组分(A),(B)和(C)以足以提供封端异氰酸酯基与羟基的当量比为0.5的量存在 :1〜1.5:1。 本发明还涉及这种粉末涂料组合物的制备方法以及涂覆有该粉末涂料组合物的耐热基材,特别是汽车车身部件。
    • 8. 发明授权
    • Powder lacquer and its use for coating heat-resistant substrates
    • 粉末漆及其用于涂覆耐热基材的用途
    • US4900800A
    • 1990-02-13
    • US73927
    • 1987-07-15
    • Reinhard HalpaapJosef PedainHans-Joachim KreuderGerhard KleinWalter SchaferDieter Arlt
    • Reinhard HalpaapJosef PedainHans-Joachim KreuderGerhard KleinWalter SchaferDieter Arlt
    • C08G18/72C08G18/02C08G18/16C08G18/73C08G18/79C08G18/80C09D5/03C09D5/46C09D175/00C09D175/04
    • C08G18/8058C08G18/791C08G18/8009C08G2150/20
    • The present invention relates to a powder lacquer containing a mixture of(A) a polyisocyanate component in power form which is solid below about 40.degree. C. and liquid above about 150.degree. C. and(B) a organic polyhydroxyl component in powder form which is solid below about 40.degree. C. and liquid above about 150.degree. C.,components (A) and (B) being present in quantities corresponding to an equivalent ratio of isocyanate groups to hydroxyl groups of about 0.6:1 to 1.2:1, characterized in that component (A) is based on a polyisocyanate or polyisocyanate mixture which(a) does not contain any blocking agents for isocyanate groups,(b) has a content of free isocyanate groups (expressed as NCO) attached to tertiary, aliphatic or cycloaliphatic carbon atoms of about 8 to 24% by weight and an average NCO functionality of at least 2.1,(c) has a urethane group content (expressed as --NH--CO--O--) of about 3 to 30% by weight and(d) has an isocyanurate group content (expressed as C.sub.3 N.sub.3 O.sub.3) of 0 to about 30% by weight.The present invention also relates to the use of this powder lacquer for the production of coatings on heat-resistant substrates by methods known in powder lacquer technology.
    • 本发明涉及一种粉末漆,其含有(A)固体低于约40℃的功率形式的多异氰酸酯组分和高于约150℃的液体的混合物和(B)粉末形式的有机多羟基组分, 固体低于约40℃,液体高于约150℃,组分(A)和(B)的存在量相当于异氰酸酯基与羟基的当量比为约0.6:1至1.2:1, 其特征在于组分(A)是基于多异氰酸酯或多异氰酸酯混合物,其中(a)不含任何异氰酸酯基团的封端剂,(b)具有连接到叔脂族或叔碳原子上的游离异氰酸酯基团(表示为NCO) 约8至24重量%的脂环族碳原子和平均NCO官能度至少为2.1,(c)具有约3至30重量%的氨基甲酸酯基含量(表示为-NH-CO-O-)和( d)具有0至约的异氰脲酸酯基含量(表示为C 3 N 3 O 3) 30重量%。 本发明还涉及这种粉末漆用于通过粉末漆技术中已知的方法在耐热基材上生产涂层的用途。