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1. 发明授权

US07439401B2 Process for preparing acylphosphanes and derivatives thereof 有权
标题翻译：制备酰基磷烷及其衍生物的方法
公开(公告)号：US07439401B2
公开(公告)日：2008-10-21
申请号：US10564711
申请日：2004-07-09
申请人： Reinhard H. Sommerlade , Souâd Boulmaâz , Jean-Pierre Wolf , Jens Geier , Hansjörg Grützmacher , Markus Scherer , Hartmut Schönberg , Daniel Stein , Peter Murer , Stephan Burkhardt
发明人： Reinhard H. Sommerlade , Souâd Boulmaâz , Jean-Pierre Wolf , Jens Geier , Hansjörg Grützmacher , Markus Scherer , Hartmut Schönberg , Daniel Stein , Peter Murer , Stephan Burkhardt
IPC分类号： C07F9/02
CPC分类号： C07F9/5036 , C07F9/5337
摘要： The present invention relates to a new, selective process for the preparation of mono- and bisacylphosphanes of formula (I) n and m are each independently of the other 1 or 2; R1, if n=1, is e.g. phenyl R1, if n=2, is e.g. C1-C18alkylene or phenylene; R2 is e. g. C1-C18alkyl, phenyl or substituted phenyl; R3 is e. g. C1-C18alkyl, by (1) reacting a phosphorous halide of formula IIa or a phosphorous halide oxide of formula (IIb) or a phosphorous halide sulfide of formula (IIc) with an alkali metal in a solvent in the presence of a proton source; (2) subsequent reaction with m acid halides of formula (III) An oxidation step may follow to obtain mono- and bisacylphosphane oxides or mono- and bisacylphosphane sulfides.
摘要翻译：本发明涉及制备式（I）的单 - 和双酰基磷烷的新的选择性方法，n和m各自独立地为1或2; 如果n = 1，则为R 1。苯基R 1，如果n = 2，则为例如。 C 1 -C 18亚烷基或亚苯基; R 2是e。 G。 C 1 -C 18烷基，苯基或取代的苯基; R 3是e。 G。通过（1）使式IIa的卤化磷或式（IIb）的卤化磷氧化物或式（IIb）的卤化磷化物或式（IIb） IIc）与碱金属在溶剂中在质子源存在下反应; （2）随后与式（III）的酰卤反应可以进行氧化步骤以获得单酰基和双酰基氧化膦或单酰基和双酰基磷烷硫化物。

2. 发明授权

US07230137B2 Process for the synthesis of cycloorganylphosphanes and di(alkyli metal/alkaline earth metal) oligophosphanediides 有权
标题翻译：合成环亚烷基磷烷和二（烷基金属/碱土金属）低聚二氧化膦的方法
公开(公告)号：US07230137B2
公开(公告)日：2007-06-12
申请号：US10535372
申请日：2003-11-24
申请人： Hansjörg Grützmacher , Jens Geier , Hartmut Schönberg , Markus Scherer , Daniel Stein , Souâd Boulmaâz
发明人： Hansjörg Grützmacher , Jens Geier , Hartmut Schönberg , Markus Scherer , Daniel Stein , Souâd Boulmaâz
IPC分类号： C07F9/547
CPC分类号： C07F9/6568 , C07F9/6596
摘要： The invention relates to a process for the preparation of cycloorganylphosphanes of formula 1 (R1P)n by reaction of dihalo(organyl)phosphanes of formula R1PHal2 with: a) activated zinc in an organic solvent, or with: b) an alkali metal or alkaline earth metal in a non-polar organic solvent in the presence of an activator, wherein R1 is C1–C12alkyl; C3–C12 cycloalkyl, aryl or heteroaryl, Hal is F, Cl, Br or I, and n is a number from 3 to 20. The invention relates also to novel di(alkali metal/alkaline earth metal) oligophosphanediides and to the use thereof in the preparation of organophosphorus compounds.
摘要翻译：本发明涉及通过式R 1的二卤代（有机基）磷烷的反应来制备式1的环状有机基磷烷（R 1 P 1）n的方法，其中：a）活化的锌在有机溶剂中，或与：b）碱金属或碱土金属在非极性有机溶剂中，在活化剂存在下，其中 R 1是C 1 -C 12烷基; R 1是C 1 -C 12烷基; C 3 -C 12环烷基，芳基或杂芳基，Hal是F，Cl，Br或I，n是3至20的数。本发明还涉及新型二（碱金属/碱土金属）低聚二氧化膦及其在制备有机磷化合物中的应用。

3. 发明授权

US07687657B2 Process for preparing acylphosphanes and derivatives thereof 有权
标题翻译：制备酰基磷烷及其衍生物的方法
公开(公告)号：US07687657B2
公开(公告)日：2010-03-30
申请号：US11667780
申请日：2005-11-14
申请人： Peter Murer , Jean-Pierre Wolf , Stephan Burkhardt , Hansjörg Grützmacher , Daniel Stein , Kurt Dietliker
发明人： Peter Murer , Jean-Pierre Wolf , Stephan Burkhardt , Hansjörg Grützmacher , Daniel Stein , Kurt Dietliker
IPC分类号： C07C69/76 , C07C69/95
CPC分类号： G03F7/029 , C07F9/5036 , C07F9/5337 , C07F9/5537 , C07F9/65515 , C07F9/6552
摘要： The invention relates to a process for the preparation of (bis)acylphosphanes of formula I, wherein n and m are each independently of the other 1 or 2; R1 if n=1, is e.g. unsubstituted or substituted C1-C18alkyl or C2-C18alkenyl, or phenyl, R1 if n=2, is e.g. a divalent radical of the monovalent radical defined above; R2 is e.g. C1-C18alkyl, C3-C12cycloalkyl, C2-C18alkenyl, mesityl, phenyl, naphthyl; R3 is one of the radicals defined under R1; the process comprises the steps a) contacting e.g. elemental phosphorous [P]∞, P(Hal)3 with a reducing metal optionally in the presence of a catalyst or an activator in a solvent to obtain metal phosphides Me3P or Me′3P2, wherein Me is an alkali metal and Me′ is an earth alkali metal or to obtain metal polyphosphides b) optionally adding a proton source, optionally in the presence of a catalyst or an activator to obtain metal dihydrogen phosphides MePH2; c) subsequent acylation reaction with m acid halides of formula III or m carboxylic acid esters of formula IV or, in case that in formula I m=1, with one carboxylic ester of formula IV followed by one acid halide of formula III or vice versa, wherein R is the residue of an alcohol and R2 is as defined above; d) alkylation reaction subsequent reaction with an electrophilic agent R1Hal or other electrophilic agents to obtain the compounds of formula I. An oxidation step may follow to obtain mono- and bisacylphosphane oxides or mono- and bisacylphosphane sulfides, which are used as photoinitiators.
摘要翻译：本发明涉及制备式（I）的（双）酰基磷烷的方法，其中n和m各自独立地为1或2; 如果n = 1，则为R1。未取代或取代的C1-C18烷基或C2-C18链烯基，或苯基，如果n = 2，则为R1。上述定义的一价基团的二价基团; R2是例如 C 1 -C 18烷基，C 3 -C 12环烷基，C 2 -C 18烯基，三甲苯基，苯基，萘基; R3是R1下定义的基团之一; 该方法包括以下步骤：a）元素磷[P]∞，P（Hal）3与还原金属，任选在催化剂或活化剂存在下在溶剂中，得到金属磷化物Me3P或Me'3P2，其中Me为碱金属，Me'为碱土金属或获得金属多磷酸盐b）任选地在催化剂或活化剂存在下加入质子源以获得金属二磷化磷MePH2; c）随后与式III的酰基卤或式IV的羧酸酯的酰化反应，或在式I中m = 1的情况下，与一种式IV的羧酸酯接触，然后加入式III的酰卤，反之亦然其中R是醇的残基，R 2如上所定义; d）烷基化反应随后与亲电子试剂R1Hal或其他亲电子试剂反应以获得式I化合物。随后可以进行氧化步骤以获得用作光引发剂的单酰基和双酰基膦烷氧化物或单酰基和双酰基磷烷硫化物。

4. 发明授权

US06441243B1 Process for the selective oxidation of alcohols using readily removable nitroxyl radicals 失效
标题翻译：使用易于除去的硝酰基选择性氧化醇的方法
公开(公告)号：US06441243B1
公开(公告)日：2002-08-27
申请号：US09713277
申请日：2000-11-15
申请人： Reinhard Sommerlade , Hansjörg Grützmacher , Souâd Boulmaâz
发明人： Reinhard Sommerlade , Hansjörg Grützmacher , Souâd Boulmaâz
IPC分类号： C07C4500
CPC分类号： C08G79/025 , C07C45/30 , C07F9/59 , C07F9/65815 , Y02P20/584 , C07C49/784 , C07C49/82 , C07C49/14
摘要： The invention relates to a process for the selective oxidation of alcohols to ketones or to aldehydes by means of an alkali hypohalite under alkaline conditions, which comprises carrying out the oxidation in the presence of a heterogeneous oxidation catalyst that is insoluble in the reaction medium and is selected from the group comprising the compounds of formula (I) (III), wherein n is a number from 3 to 3000; or a 4-oxy-2,2,6,6-tetramethylpiperidin-1-oxyl that is 4-oxy-bound to a Merrifield polymer. The invention relates also to the compounds of formulae (II) and (III) and to the use of the above-mentioned oxidation catalysts for the oxidation of alcohols.
摘要翻译：本发明涉及在碱性条件下通过碱性次卤酸盐将醇选择性氧化成酮或醛的方法，其包括在不溶于反应介质的非均相氧化催化剂存在下进行氧化，并且是选自包含式（I）（III）的化合物的基团，其中n为3至3000的数; 或与Merrifield聚合物4-氧结合的4-氧-2,2,6,6-四甲基哌啶-1-氧基。本发明还涉及式（II）和（III）的化合物以及上述氧化催化剂用于醇的氧化的用途。

5. 发明授权

US06660860B2 Process for the selective oxidation of alcohols using readily removable nitroxyl radicals 失效
标题翻译：使用易于除去的硝酰基选择性氧化醇的方法
公开(公告)号：US06660860B2
公开(公告)日：2003-12-09
申请号：US10164768
申请日：2002-06-07
申请人： Reinhard Sommerlade , Hansjörg Grützmacher , Souâd Boulmaâz
发明人： Reinhard Sommerlade , Hansjörg Grützmacher , Souâd Boulmaâz
IPC分类号： C07F906
CPC分类号： C08G79/025 , C07C45/30 , C07F9/59 , C07F9/65815 , Y02P20/584 , C07C49/784 , C07C49/82 , C07C49/14
摘要： The invention relates to a process for the selective oxidation of alcohols to ketones or to aldehydes by means of an alkali hypohalite under alkaline conditions, which comprises carrying out the oxidation in the presence of a heterogeneous oxidation catalyst that is insoluble in the reaction medium and is selected from the group comprising the compounds of formula (I) wherein n is a number from 3 to 3000; or a 4-oxy-2,2,6,6-tetramethylpiperidin-1-oxyl that is 4-oxy-bound to a Merrifield polymer. The invention relates also to the compounds of formulae (II) and (III) and to the use of the above-mentioned oxidation catalysts for the oxidation of alcohols.
摘要翻译：本发明涉及在碱性条件下通过碱性次卤酸盐将醇选择性氧化成酮或醛的方法，其包括在不溶于反应介质的非均相氧化催化剂存在下进行氧化，并且是选自包含其中n为3至3000的数的式（I）化合物的基团; 与Merrifield聚合物4-氧结合的4-氧基-2,2,6,6-四甲基哌啶-1-氧基。本发明还涉及式（II）和（III）的化合物及其用途的上述用于氧化醇的氧化催化剂。

6. 发明授权

US07777062B2 Method for production of a B/N/C/Si ceramic from a borazine precursor, ceramics made by said method and use of the ceramic made by said method 失效
标题翻译：从硼嗪前体生产B / N / C / Si陶瓷的方法，由所述方法制成的陶瓷和由所述方法制成的陶瓷的使用方法
公开(公告)号：US07777062B2
公开(公告)日：2010-08-17
申请号：US10544211
申请日：2004-02-02
申请人： Reinhard Nesper , Hansjörg Grützmacher , Jörg Haberecht
发明人： Reinhard Nesper , Hansjörg Grützmacher , Jörg Haberecht
IPC分类号： C04B35/563 , C04B35/571 , C04B35/583 , C04B35/589 , C07F5/05 , C07F7/08
CPC分类号： C04B35/571 , C04B35/563 , C04B35/583 , C04B35/589
摘要： B-tris(silylvinyl)borazine is pyrolysed as a borazine precursor for the production of a B/N/C/Si ceramic. A high-temperature ceramic is obtained by means of a further pyrolysis at higher temperatures after a pre-pyrolysis, which is of high purity and essentially free of pores. The ceramic furthermore contains essentially no oxygen and is particularly suitable as a coating material and for the production of heating elements.
摘要翻译： B-三（甲硅烷基乙烯基）环硼氮烷作为生产B / N / C / Si陶瓷的环硼氮烷前体热解。通过在预热解之后的较高温度下进一步热解获得高温陶瓷，其具有高纯度并且基本上没有孔。陶瓷基本上不含有氧，并且特别适合作为涂料和用于制造加热元件。

7. 发明申请

US20050283014A1 Bistropylidenediamines and use thereof 审中-公开
标题翻译：二亚丙基二胺及其用途
公开(公告)号：US20050283014A1
公开(公告)日：2005-12-22
申请号：US11145839
申请日：2005-06-06
申请人： Hansjörg Grützmacher , Pascal Maire
发明人： Hansjörg Grützmacher , Pascal Maire
IPC分类号： B01J31/22 , C07B53/00 , C07C211/42 , C07C211/63 , C07F15/00
CPC分类号： C07C211/42 , B01J31/1805 , B01J2231/643 , B01J2231/645 , B01J2531/822 , B01J2531/827 , C07B53/00 , C07B2200/07 , C07C211/63
摘要： The present invention relates to bistropylidenediamines, to a process for their preparation and to the use thereof in catalysis.
摘要翻译：本发明涉及双丙烯二胺，其制备方法及其在催化中的应用。

8. 发明授权

US07112696B2 Preparation of phosphorus compounds 失效
标题翻译：磷化合物的制备
公开(公告)号：US07112696B2
公开(公告)日：2006-09-26
申请号：US10839652
申请日：2004-05-05
申请人： Hansjörg Grützmacher , Elisabetta Piras
发明人： Hansjörg Grützmacher , Elisabetta Piras
IPC分类号： C07F9/50 , C07F9/53
CPC分类号： C07F9/5018 , C07F7/08 , C07F9/42 , C07F9/532
摘要： The present invention relates to a process for preparing phosphorus compounds and intermediates.
摘要翻译：本发明涉及磷化合物和中间体的制备方法。

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