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1. 发明授权

US5268517A Stereoselective preparation of Z-1,2-diarylallyl chlorides and the conversion thereof into azolylmethyloxiranes, and novel intermediates 失效
标题翻译： Z-1,2-二芳基烯丙基氯的立体选择性制备及其转化为唑基甲基环氧乙烷，以及新型中间体
公开(公告)号：US5268517A
公开(公告)日：1993-12-07
申请号：US987078
申请日：1992-12-07
申请人： Reiner Kober , Rainer Seele , Heinz Isak , Eckhard Hichmann , Norbert Goetz , Thomas Zierke
发明人： Reiner Kober , Rainer Seele , Heinz Isak , Eckhard Hichmann , Norbert Goetz , Thomas Zierke
IPC分类号： C07C17/35 , C07C25/24 , C07C43/225 , C07C43/29 , C07D303/08 , C07D521/00 , C07C17/24
CPC分类号： C07D249/08 , C07C17/35 , C07C25/24 , C07C43/225 , C07C43/29 , C07D231/12 , C07D233/56 , C07D303/08
摘要： The preparation of Z-1,2-diarylallyl chlorides of the general formula I ##STR1## in which R.sup.1 and R.sup.2, independently of one another, are hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or a substituted aromatic radical, and n and m are 1, 2 or 3, by dehydrating chlorohydrins of the formula II ##STR2## in which the radicals are as defined above, at up to 50.degree. C. in an inert ether or carboxylic acid ester as solvent and in the presence of a carboxylic anhydride and an organic or inorganic acid, the conversion thereof into azolylmethyloxiranes, and novel intermediates are described.
摘要翻译：制备通式I（I）的Z-1,2-二芳基烯丙基氯，其中R 1和R 2彼此独立地为氢，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或取代的芳族基团，并且n和m为1,2或3，通过在惰性醚或羧酸酯中在高达50℃下使式II的氯代醇（II）脱水，其中自由基如上所定义，作为溶剂，在羧酸酐和有机或无机酸的存在下，将其转化为唑基甲基环氧乙烷和新的中间体。

2. 发明授权

US5093046A Preparation of ethereal solutions of arylmethyl-magnesium halides 失效
标题翻译：亚甲基山梨糖醇的方法的制备
公开(公告)号：US5093046A
公开(公告)日：1992-03-03
申请号：US575803
申请日：1990-08-31
申请人： Reiner Kober , Rainer Seele , Thomas Zierke , Heinz Isak , Stefan Karbach , Guenter Wegner
发明人： Reiner Kober , Rainer Seele , Thomas Zierke , Heinz Isak , Stefan Karbach , Guenter Wegner
IPC分类号： C07F3/02 , C07F7/08
CPC分类号： C07F3/02 , C07F7/0827
摘要： Ethereal solutions of arylmethylmagnesium halidesAr--CH.sub.2 --Mg--Hal I(where Ar is unsubstituted or substituted aryl and Hal is Cl or Br) are prepared by the Grignard method from an arylmethyl halide IIAr--CH.sub.2 --Hal IIand magnesium in an ether IIItert-butyl--O--R III(where R is C.sub.1 -C.sub.3 -alkyl) as solvent.
摘要翻译：芳基甲基卤化镁Ar-CH2-Mg-Hal1（其中Ar为未取代或取代的芳基，Hal为Cl或Br）的芳烃溶液通过Grignard法由芳基甲基卤化物II Ar-CH2-HalII和乙醚中的镁制备。丁基-O-RIII（其中R是C 1 -C 3 - 烷基）作为溶剂。

3. 发明授权

US5245042A Preparation of cis-2-(1H-1,2,4-triazol-1-ylmethyl)-2-(halopheny)-3-(halophenyl) oxirane 失效
标题翻译：顺式-2-（1H-1,2,4-三唑-1-基甲基）-2-（卤代苯基）-3-（卤苯基）环氧乙烷的制备
公开(公告)号：US5245042A
公开(公告)日：1993-09-14
申请号：US874227
申请日：1992-04-27
申请人： Eckhard Hickmann , Rainer Seele , Reiner Kober , Heinz Isak
发明人： Eckhard Hickmann , Rainer Seele , Reiner Kober , Heinz Isak
IPC分类号： C07D249/08 , C07D521/00
CPC分类号： C07D249/08 , C07D231/12 , C07D233/56
摘要： A process is described for the preparation of cis-2-(1H-1,2,4-triazol-1-ylmethyl)-2-(halophenyl)-3-(halophenyl)oxirane I ##STR1## by epoxidizing Z-3-(1H-1,2,4-triazol-1-yl)-2-(halophenyl)-1-halophenyl)propene II, ##STR2## where halogen is in each case fluorine, chlorine or bromine, which comprises reacting the crude product of the epoxidation with one or more reducing agents, which are added to the reaction mixture in a considerable excess over the amount necessary to destroy any peroxide compounds present.
摘要翻译：描述了通过环氧化Z-3-（1H-1,2,4-三唑-1-基甲基）-2-（卤代苯基）-3-（卤代苯基）环氧乙烷I （1H-1,2,4-三唑-1-基）-2-（卤代苯基）-1-卤代苯基）丙烯II，其中卤素在各种情况下为氟，氯或溴，其包括使粗产物与一种或多种还原剂进行环氧化反应，其以相当多的过量加入反应混合物中超过破坏存在的任何过氧化物化合物所需的量。

4. 发明授权

US5081317A 1-bromo-3-chloro-1,2-diaryl-2-propanols, the stereo-selective preparation of erythro-1-bromo-3-chloro-1,2-diaryl-2-propanols and the conversion thereof into azolylmethyloxiranes 失效
标题翻译： 1-溴-3-氯-1,2,2-二胺-2-丙醇，硫代-1-溴-3-氯-1,2,2-二胺-2-丙醇的立体选择性制备及其转化为三羟甲基纤维素
公开(公告)号：US5081317A
公开(公告)日：1992-01-14
申请号：US623578
申请日：1990-12-07
申请人： Reiner Kober , Heinz Isak , Rainer Seele
发明人： Reiner Kober , Heinz Isak , Rainer Seele
IPC分类号： C07C29/62 , C07C33/46 , C07D405/06 , C07D521/00
CPC分类号： C07D249/08 , C07C29/62 , C07C33/46 , C07D231/12 , C07D233/56 , C07B2200/07
摘要： 1-Bromo-3-chloro-1,2-diaryl-2-propanols of the general formula I ##STR1## where n and m are each 1, 2 or 3, and R.sup.1 and R.sup.2 are each hydrogen, haloalkyl, alkoxy, haloalkoxy, t-butyl or an aromatic radical which may be substituted, are prepared and converted into azolylmethyloxiranes.
摘要翻译：通式I的1-溴-3-氯-1,2-二芳基-2-丙醇，其中n和m各自为1,2或3，R 1和R 2各自为氢，卤代烷基，烷氧基，卤代烷氧基，叔丁基或可被取代的芳基，并被转化为唑基甲基环氧乙烷。

5. 发明授权

US5159117A Preparation of .alpha.,.alpha.-dialkoxy ketones 失效
标题翻译：（ALPHA），（ALPHA） - 二羟基酮的制备
公开(公告)号：US5159117A
公开(公告)日：1992-10-27
申请号：US747575
申请日：1991-08-20
申请人： Guenter Wegner , Stefan Karbach , Hubert Smuda , Eckhard Hickmann , Reiner Kober , Rainer Seele , Thomas Zierke
发明人： Guenter Wegner , Stefan Karbach , Hubert Smuda , Eckhard Hickmann , Reiner Kober , Rainer Seele , Thomas Zierke
IPC分类号： C07C45/68 , C07C45/71 , C07C49/175 , C07C49/255 , C07C49/517 , C07C49/84 , C07D307/46 , C07D333/22
CPC分类号： C07D333/22 , C07C45/68 , C07C45/71 , C07C49/175 , C07C49/255 , C07C49/517 , C07C49/84 , C07D307/46
摘要： A process for preparing .alpha.,.alpha.-dialkoxy ketones of the formula I ##STR1## where R.sup.1 and R.sup.2 are each, independently of one another, hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.30 -cycloalkylakyl, C.sub.9 -C.sub.30 -alkylcycloalkyl, unsubstituted or C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy-, halogen-, C.sub.1 -C.sub.4 -haloalkyl-, C.sub.1 -C.sub.4 -haloalkoxy-, phenyl-, phenoxy-, halophenyl-, halophenoxy- and/or cyano-substituted aryl, C.sub.7 -C.sub.20 -aralkyl or heterocyclyl,R.sup.2 is also ##STR2## R.sup.3 and R.sup.4 are each, independently of one another, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.20 -cycloalkyl, aryl, C.sub.7 -C.sub.20 -arylalkyl, or together are an unsubstituted or C.sub.1-C.sub.4 -alkyl- substituted C.sub.2 -C.sub.7 -alkylene chain andR.sup.5 is R.sup.1 or together with R.sup.1 is an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.7 -alkylene chain,which entails reacting ketones or aldehydes of the formula II ##STR3## with nitrites of the formula IIIR.sup.3/4 --(NO.sub.2).sub.n (III)where n is 1 or 2, and n is 2 when R.sup.3 and R.sup.4 together are an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.7 -alkylene chain, with the proviso that the nitrite radicals are located at the termini, or with a mixture of alcohol of the formula IVR.sup.3/4 --(OH).sub.n IVwhere n is 1 or 2, and n is 2 when R.sup.3 and R.sup.4 together are an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.7 -alkylene chain, with the proviso that the hydroxyl group is located at the terminus, and dinitrogen trioxide in a molar ratio of 2:1 in the presence of an acid catalyst at from 0.degree. to 170.degree. C.
摘要翻译：制备式I的α，α-二烷氧基酮的方法，其中R 1和R 2各自独立地为氢，C 1 -C 20 - 烷基，C 3 -C 20 - 环烷基，C 4 -C 30 - 环烷基，C 9 -C 30 - 烷基环烷基，未取代的或C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基 - ，卤素 - ，C 1 -C 4卤代烷基 - ，C 1 -C 4 - 卤代烷氧基 - ，苯基 - ，苯氧基 - ，卤代苯基 - ，卤代苯氧基 - 和/或氰基取代的芳基，C 7 -C 20 - 芳烷基或杂环基，R 2也是R 3和R 4彼此独立地为C 1 -C 20 - 烷基，C 3 -C 20 - 环烷基，芳基，或者一起是未取代的或C 1 -C 4烷基取代的C 2 -C 7亚烷基链，R 5是R 1或与R 1一起是未取代的或C 1 -C 4烷基取代的C 2 -C 7亚烷基链，其中需要使式II（II）的酮或醛与式III R3 / 4-（NO2）n（III）的亚硝酸盐反应，其中n为1或2，n为2，当R3和R4一起为未取代的或C 1 -C 4烷基取代的C 2 -C 7 - 亚烷基链条件是亚硝酸根自由基位于末端，或与式IV R3 / 4-（OH）n IV的醇的混合物，其中n为1或2，n为2，当R 3和R 4一起为未取代的或 C1-C4烷基取代的C2-C7-亚烷基链，条件是羟基位于末端，二氧化二氮在摩尔比为2:1的酸催化剂存在下，0℃至 170℃

6. 发明授权

US5164408A 1,2-dihaloazolylethane derivatives and crop protection agents containing them 失效
标题翻译： 1,2-DIHALOAZOLYLETHANE DORIVATIVES和作物保护剂含有它们
公开(公告)号：US5164408A
公开(公告)日：1992-11-17
申请号：US552037
申请日：1990-07-13
申请人： Rainer Seele , Norbert Goetz , Walter Himmele , Reiner Kober , Wolfgang Rohr , Eberhard Ammermann , Gisela Lorenz , Wilhelm Rademacher , Johann Jung
发明人： Rainer Seele , Norbert Goetz , Walter Himmele , Reiner Kober , Wolfgang Rohr , Eberhard Ammermann , Gisela Lorenz , Wilhelm Rademacher , Johann Jung
IPC分类号： A01N43/50 , A01N43/653 , C07D233/56 , C07D233/60 , C07D233/61 , C07D249/08 , C07D401/06 , C07D407/06 , C07D409/06 , C07D413/06 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： 1,2-Dihaloazolylethane derivatives of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each substituted or unsubstituted phenyl, biphenyl, naphthyl or hetaryl, Z is chlorine or bromine, and X is CH or N, and their plant-tolerated acid addition salts and metal complexes, and fungicides and growth regulators containing these compounds.
摘要翻译：其中R 1和R 2各自为取代或未取代的苯基，联苯基，萘基或杂芳基，Z为氯或溴，X为CH或N，并且它们的植物耐受性为酸加成盐和金属配合物，以及含有这些化合物的杀真菌剂和生长调节剂。

7. 发明授权

US5017594A 1-halo-1-azolylpropenes and -methyloxiranes and fungicides containing these compounds 失效
标题翻译： 1-卤代-1-氮杂环丙烷和含有这些化合物的甲基环氧乙烷和杀真菌剂
公开(公告)号：US5017594A
公开(公告)日：1991-05-21
申请号：US376429
申请日：1989-07-07
申请人： Rainer Seele , Reiner Kober , Norbert Goetz , Eberhard Ammermann , Gisela Lorenz
发明人： Rainer Seele , Reiner Kober , Norbert Goetz , Eberhard Ammermann , Gisela Lorenz
IPC分类号： A01N43/50 , A01N43/653 , C07D233/56 , C07D233/58 , C07D233/60 , C07D233/61 , C07D249/08 , C07D405/06 , C07D405/14 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： 1-Halo-1-azolylpropenes and -methyloxiranes of the formula I ##STR1## where R.sup.1 and R.sup.2 are alkyl, cycloalkyl, cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenyl or phenyl, A is oxygen or a single bond, R.sup.3 is F, Cl or Br, X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.
摘要翻译：其中R 1和R 2为烷基，环烷基，环烯基，四氢吡喃基，降冰片基，吡啶基，萘基，联苯基或苯基，A为氧或单键，R3为卤素，是F，Cl或Br，X是CH或N，它们的植物耐受的酸加成盐和金属络合物，以及含有这些化合物的杀真菌剂。

8. 发明授权

US5162357A Fungicidal azolylmethyloxiranes 失效
标题翻译：杀真菌剂
公开(公告)号：US5162357A
公开(公告)日：1992-11-10
申请号：US578400
申请日：1990-09-07
申请人： Rainer Seele , Norbert Goetz , Reiner Kober , Bernhard Zipperer , Eberhard Ammermann , Gisela Lorenz , Joachim Gebhardt
发明人： Rainer Seele , Norbert Goetz , Reiner Kober , Bernhard Zipperer , Eberhard Ammermann , Gisela Lorenz , Joachim Gebhardt
IPC分类号： C07D303/08 , A01N43/50 , A01N43/653 , C07D213/48 , C07D249/08 , C07D303/12 , C07D303/16 , C07D303/34 , C07D405/04 , C07D405/06 , C07D405/14 , C07D409/14 , C07D413/14 , C07D417/14 , C07D521/00
CPC分类号： C07D249/08 , A01N43/50 , A01N43/653 , C07D213/48 , C07D231/12 , C07D233/56 , C07D303/16 , C07D405/04
摘要： and their acid addition salts and metal complexes,with the exception of 2-(imidazol-1-ylmethyl)-2-(4-fluorophenyl)-3-(pyrid-3-yl)-oxirane.The compounds I are suitable as fungicides.
摘要翻译：取代基A和R 1为未取代的或带有多至三个其它基团的前提条件，其中条件是（A，R 1）= 5 / 6-元杂芳基，环烷基，四氢吡喃基，四氢噻喃基，苯基，联苯基，萘基或苄基，除非R1是邻甲基苯基，否则至少一个取代基A和R1是杂芳基; Z = CH，N）和它们的酸加成盐和金属络合物，除了2-（咪唑-1-基甲基）-2-（4-氟苯基）-3-（吡啶-3-基） - 环氧乙烷外。化合物I适合作为杀真菌剂。

9. 发明授权

US5084471A 1-halovinylazoles and fungicides and growth regulators containing these 失效
标题翻译：含有这些的1-羟基吡唑类和杀真菌剂和生长调节剂
公开(公告)号：US5084471A
公开(公告)日：1992-01-28
申请号：US500728
申请日：1990-03-28
申请人： Rainer Seele , Reiner Kober , Norbert Goetz , Thomas Saupe , Eberhard Ammermann , Gisela Lorenz , Wilhelm Rademacher , Johann Jung
发明人： Rainer Seele , Reiner Kober , Norbert Goetz , Thomas Saupe , Eberhard Ammermann , Gisela Lorenz , Wilhelm Rademacher , Johann Jung
IPC分类号： A01N43/50 , A01N43/54 , A01N43/653 , C07D233/60 , C07D233/61 , C07D233/64 , C07D249/08 , C07D303/32 , C07D401/06 , C07D401/14 , C07D405/06 , C07D405/14 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： 1-Halovinylazoles of the general formula I ##STR1## where A and R are each alkyl, cycloalkyl, cycloalkenyl, pyridyl, tetrahydropyranyl, naphthyl, biphenyl or phenyl, each of these radicals being substituted or unsubstituted, D is chlorine or bromine, and X is CH or N, acid addition salts and metal complexes thereof which are tolerated by plants, and fungicides and growth regulators containing these compounds.
摘要翻译：其中A和R各自为烷基，环烷基，环烯基，吡啶基，四氢吡喃基，萘基，联苯基或苯基，这些基团各自为取代或未取代的，D为氯或溴，以及 X是被植物耐受的CH或N，其酸加成盐和金属络合物，以及含有这些化合物的杀真菌剂和生长调节剂。

10. 发明授权

US5204362A Fungicidal azolylethane derivatives 失效
标题翻译：杀真菌药物衍生物
公开(公告)号：US5204362A
公开(公告)日：1993-04-20
申请号：US675170
申请日：1991-03-26
申请人： Rainer Seele , Norbert Goetz , Wolfgang Brox , Reiner Kober , Eberhard Ammermann , Gisela Lorenz
发明人： Rainer Seele , Norbert Goetz , Wolfgang Brox , Reiner Kober , Eberhard Ammermann , Gisela Lorenz
IPC分类号： A01N43/50 , A01N43/653 , C07D233/56 , C07D233/60 , C07D249/08 , C07D401/06 , C07D403/06 , C07D405/06 , C07D409/06 , C07D417/06 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Azolylethane derivatives of the formula I ##STR1## where A and R.sup.1 are each alkyl, phenyl, biphenyl, naphthyl, benzyl, cycloalkyl, alkoxy, alkylthio, phenoxy, benzyloxy, phenylthio, methoxycarbonylethyl or hetaryl, these radicals being substituted or unsubstituted,D is halogen, alkoxy, alkylthio, phenylthio or phenoxy, these radicals being substituted or unsubstituted,X is CH or N,plant-tolerated acid addition salts and metal complex compounds thereof, and fungicides containing these compounds.
摘要翻译：苯基，联苯基，萘基，苄基，环烷基，烷氧基，烷硫基，苯氧基，苄氧基，苯硫基，甲氧基羰基乙基或杂芳基，这些基团是取代或未取代的，D 是卤素，烷氧基，烷硫基，苯硫基或苯氧基，这些基团是取代或未取代的，X是CH或N，植物耐受的酸加成盐和金属络合物，以及含有这些化合物的杀真菌剂。

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