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    • 1. 发明授权
    • Solid particle dispersions for imaging elements
    • 用于成像元件的固体颗粒分散体
    • US5750323A
    • 1998-05-12
    • US698378
    • 1996-08-15
    • Raymond Peter ScaringeDavid Darrell MillerMary Christine BrickLeslie ShuttleworthMargaret Jones HelberSteven Evans
    • Raymond Peter ScaringeDavid Darrell MillerMary Christine BrickLeslie ShuttleworthMargaret Jones HelberSteven Evans
    • B01J13/00G03C1/005G03C1/83G03C7/388G03C1/06G03C1/10G03C1/38
    • G03C1/83G03C1/005G03C7/388G03C1/832
    • Solid particle dispersions of compounds useful in imaging elements can be made with substantially improved stability to particle growth by dispersing the compound of interest in the presence of a relatively small amount of a second compound that is structurally similar to the compound of interest. This second compound is combined with the compound of interest prior to dispersing the compound of interest, i.e., prior to milling in the case of milled dispersions, and prior to precipitation in the case of pH or solvent precipitated dispersions. While being distinct, the second compound has a similar chemical structure to the main compound. More specifically, the second compound and first compound each comprise an identical structural section thereof which makes up at least 75% of the total molecular weight of the first compound, and the second compound has at least one substituent bonded to the identical structural section which has a molecular weight higher than the corresponding substituent of the first compound. In preferred embodiments of the invention, the compound useful in imaging elements is a compound useful in photographic or thermal transfer printing elements, and the resulting stabilized dispersion is used in preparing a photographic or thermal transfer printing element.
    • 用于成像元件的化合物的固体颗粒分散体可以通过在相当少量的结构上类似于感兴趣的化合物的相对少量的第二化合物的存在下分散感兴趣的化合物,从而具有显着提高的颗粒生长稳定性。 在分散感兴趣的化合物之前,即在研磨的分散体的情况下,在研磨之前,并且在pH或溶剂沉淀分散体的情况下,在沉淀之前,将该第二化合物与感兴趣的化合物组合。 虽然不同,第二化合物与主要化合物具有相似的化学结构。 更具体地,第二化合物和第一化合物各自包含相同的结构部分,其占第一化合物的总分子量的至少75%,并且第二化合物具有至少一个与相同结构部分键合的取代基,其具有 分子量高于第一化合物的相应取代基。 在本发明的优选实施方案中,可用于成像元件的化合物是用于照相或热转印打印元件的化合物,所得稳定的分散体用于制备照相或热转印打印元件。
    • 3. 发明授权
    • Combination of yellow filter dye and 4-equivalent pyrazolone magenta
coupler
    • 黄色过滤染料和4-当量吡唑啉酮品红色成色剂的组合
    • US5695917A
    • 1997-12-09
    • US561677
    • 1995-11-22
    • John Victor NelsonMargaret Jones HelberMary Christine Brick
    • John Victor NelsonMargaret Jones HelberMary Christine Brick
    • G03C7/00G03C1/83G03C3/00G03C7/30G03C7/384G03C1/06G03C1/815G03C1/825
    • G03C7/3008G03C1/832G03C3/00G03C7/384
    • A photographic element contains a four-equivalent pyrazolone magenta coupler and a yellow filter dye represented by Formula I. ##STR1## wherein: A is an acidic nucleus selected from the group consisting of benzoylacetonitrile, 2-phenyl-1,1,3-tricyanopropene, 5-pyrazolone, isooxazolone, barbituric acid, thiobarbituric acid, rhodanine, hydantoin, thiohydantoin, oxazolidindione, pyrazolidindione, indandione, pyrazolopyridone, 1,2,3,4-tetrahydroquinolin-2,4-dione, 3-oxo-2,3-dihydrobenzo�d!thiophene-1,1-dioxide and 3-dicynaomethine-2,3-dihydroxybenzo�d!thiophene-1,1-dioxide; L.sup.1-3 each independently represents a substituted or unsubstituted methine group; n is 0 or 1; R.sup.1-2 each independently represents hydrogen or an alkyl, aryl or acyl groups (including, for example,alkoxycarbonyl, amido and carboxyl); Y represents non-metal atoms which form a five membered heterocyclic ring optionally comprising a fused substituted or unsubstituted benzene ring; and wherein the dye comprises at least one ionizable group with a pKa value between 4-11 such as a carboxyl group, a sulfonamido group or a sulfamoyl group.
    • 照相元件含有四等价的吡唑啉酮品红成色剂和由式I表示的黄色滤光染料。其中:A是选自苯甲酰基乙腈,2-苯基-1,1, 3-三氯丙烯,5-吡唑啉酮,异恶唑酮,巴比妥酸,硫代巴比妥酸,绕丹宁,乙内酰脲,硫代乙内酰脲,恶唑烷二酮,吡唑烷二酮,茚二酮,吡唑并吡啶酮,1,2,3,4-四氢喹啉-2,4-二酮, 2,3-二氢苯并[d]噻吩-1,1-二氧化物和3-二甲基甲烷-2,3-二羟基苯并[d]噻吩-1,1-二氧化物; L1-3各自独立地表示取代或未取代的次甲基; n为0或1; R1-2各自独立地表示氢或烷基,芳基或酰基(包括例如烷氧基羰基,酰氨基和羧基); Y表示形成任选包含稠合取代或未取代的苯环的五元杂环的非金属原子; 并且其中所述染料包含pKa值在4-11之间的至少一个可离子化基团,例如羧基,亚磺酰氨基或氨磺酰基。