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    • 1. 发明授权
    • Styling agents and compositions containing the same
    • 造型剂和含有它的组合物
    • US4963348A
    • 1990-10-16
    • US433409
    • 1989-11-03
    • Raymond E. Bolich, Jr.Peter M. Torgerson
    • Raymond E. Bolich, Jr.Peter M. Torgerson
    • A61K8/81A61Q5/02A61Q5/06A61Q5/12
    • A61Q5/02A61K8/8158A61Q5/06A61Q5/12Y10S424/01Y10S424/02Y10S424/13
    • The present invention relates to styling agents comprising adhesive copolymers along with a volatile diluent useful in products such as shampoos and conditioners which provide hair styling hold. The monomer components in these copolymers are randomly distributed in the copolymer chain, preferably to form a substantially linear chain. Preferably, at least one of the monomer components is selected from vinyl pyridine, acrylate amides and methacrylate amides and one of the other monomer components is selected from butadiene, isoprene, isobutene, acrylate esters, methacrylate esters, vinyl alkyl ethers, alkyl-substituted butadienes, and chloroprene. These copolymers also have a single glass transition temperature within the temperature range of from about 0.degree. C. to about 150.degree. C. The volatile diluents useful in these styling agents can be hydrocarbons, esters, ethers, amines, alkyl alcohols, or volatile silicon derivatives.
    • 本发明涉及包含粘合剂共聚物以及可用于诸如洗发剂和调理剂的产品的挥发性稀释剂的造型剂,其提供头发造型保持。 这些共聚物中的单体组分随机分布在共聚物链中,优选形成基本上线性的链。 优选地,至少一种单体组分选自乙烯基吡啶,丙烯酰胺和甲基丙烯酸酰胺,其它单体组分之一选自丁二烯,异戊二烯,异丁烯,丙烯酸酯,甲基丙烯酸酯,乙烯基烷基醚,烷基取代的丁二烯 ,和氯丁二烯。 这些共聚物在约0℃至约150℃的温度范围内也具有单一玻璃化转变温度。用于这些定型剂的挥发性稀释剂可以是烃,酯,醚,胺,烷基醇或挥发性硅 衍生品
    • 5. 发明授权
    • Hair styling compositions containing a silicone grafted polymer and low
level of a volatile hydrocarbon solvent
    • 包含硅酮接枝聚合物和低水平挥发性烃溶剂的头发定型组合物
    • US5565193A
    • 1996-10-15
    • US273289
    • 1994-07-11
    • Sanjeev MidhaPeter M. TorgersonChristine Hall
    • Sanjeev MidhaPeter M. TorgersonChristine Hall
    • A61K8/00A61K20060101A61K8/31A61K8/34A61K8/37A61K8/89A61K8/891A61K8/895A61K8/91A61K9/12A61Q5/06C08F30/08C08F130/08C08F230/08C08G77/00C08L83/12A61K7/11A61K7/09
    • A61Q5/06A61K8/895
    • Provided hair styling compositions comprising: (a) from about 0.1% to about 15%, by weight, of a silicone grafted adhesive polymer, said polymer being characterized by an organic polymeric backbone having silicone macromers grafted to said backbone; (b) from about 0.5% to about 15%, by weight, of a hydrocarbon solvent selected from the group consisting of C.sub.10 -C.sub.14 branched chain hydrocarbons, and mixtures thereof; (c) a polar solvent phase comprising from about 80% to about 98.9%, by weight of the composition, of a polar solvent selected from the group consisting of water and C.sub.2 -C.sub.3 monohydric alcohols, and mixtures thereof, wherein said composition contains no more than about 15%, by weight, of C.sub.3 monohydric alcohol; wherein said organic polymer backbone is soluble in said polar solvent phase, and said silicone macromers of said hair setting polymer are soluble in said hydrocarbon solvent and insoluble in said polar solvent. In preferred embodiments, the compositions hereof additionally comprise a plasticizer for the silicone grafted hair setting polymer. Especially preferred plasticizers include acetyl tri-C.sub.2 -C.sub.8 alkyl citrates, particularly acetyl triethyl citrate.
    • 提供的头发定型组合物包含:(a)约0.1重量%至约15重量%的硅氧烷接枝的粘合剂聚合物,所述聚合物的特征在于具有接枝到所述骨架上的硅氧烷大分子单体的有机聚合物骨架; (b)约0.5%至约15%重量的选自C 10 -C 14支链烃的烃溶剂及其混合物; (c)包含按组合物重量计约80%至约98.9%的极性溶剂相,选自水和C 2 -C 3一元醇的极性溶剂及其混合物,其中所述组合物不含 大于约15重量%的C3一元醇; 其中所述有机聚合物主链可溶于所述极性溶剂相,并且所述毛发固化聚合物的所述硅氧烷大分子可溶于所述烃溶剂中并且不溶于所述极性溶剂。 在优选的实施方案中,本发明的组合物另外包含用于硅氧烷接枝的固化聚合物的增塑剂。 特别优选的增塑剂包括乙酰基三-C 2 -C 8烷基柠檬酸盐,特别是乙酰基柠檬酸三乙酯。
    • 6. 发明授权
    • Low glass transistion temperature adhesive copolymers for use in hair
styling products
    • 用于头发造型产品的低玻璃化转移温度粘合剂共聚物
    • US5019377A
    • 1991-05-28
    • US379516
    • 1989-07-13
    • Peter M. Torgerson
    • Peter M. Torgerson
    • A61K8/81A61Q5/02A61Q5/06A61Q5/12C08F220/12C08F220/54C09J133/06C09J133/26
    • A61Q5/06A61K8/8158A61Q5/02A61Q5/12C08F220/12C08F220/54C09J133/062C09J133/26
    • The present invention relates to low glass transition temperature adhesive copolymers useful in products such as those which provide hair styling hold, e.g., aerosol mousses, shampoos and conditioners. The monomer components in these copolymers are randomly distributed in the copolymer chain, preferably to form a substantially linear chain. At least one of the monomer components is selected from acrylate amides and methacrylate amides; and furthermore at least one of the other monomer components is selected from acrylate esters and methacrylate esters. These copolymers have a single glass transition temperature within the temperature range of from about 0.degree. C. to about 80.degree. C. The present invention further relates to hair styling compositions (e.g., aerosol mousses, shampoos, conditioners) comprising these adhesive copolymers, and to methods for providing styling hold to hair by using an adhesive copolymer or composition of the present invention.
    • 本发明涉及可用于诸如提供发型保持的产品(例如气溶胶摩丝,洗发剂和调理剂)的产品中的低玻璃化转变温度的粘合剂共聚物。 这些共聚物中的单体组分随机分布在共聚物链中,优选形成基本上线性的链。 单体组分中的至少一种选自丙烯酸酯酰胺和甲基丙烯酸酰胺; 此外,其它单体组分中的至少一种选自丙烯酸酯和甲基丙烯酸酯。 这些共聚物在约0℃至约80℃的温度范围内具有单一玻璃化转变温度。本发明还涉及包含这些粘合剂共聚物的毛发定型组合物(例如,气溶胶摩丝,洗发剂,调理剂)和 涉及通过使用本发明的粘合剂共聚物或组合物为头发提供造型保持的方法。