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1. 发明授权

US08580027B1 Sprayed on superoleophobic surface formulations 有权
标题翻译：喷涂在超疏油表面配方上
公开(公告)号：US08580027B1
公开(公告)日：2013-11-12
申请号：US13207562
申请日：2011-08-11
申请人： Raymond Campos , Andrew J. Guenthner , Timothy S. Haddad , Joseph M. Mabry
发明人： Raymond Campos , Andrew J. Guenthner , Timothy S. Haddad , Joseph M. Mabry
IPC分类号： C08K9/08 , C08K9/06
CPC分类号： C08K9/08 , C09D127/18 , C08K9/06 , C08L27/18
摘要： Fluoroalkylsilane-treated metal oxide particles and a fluoroelastomeric binder are dispersed in a fluorinated solvent with a low boiling point and applied to a substrate via spray deposition. The spray deposition process rapidly produces a conformal coating that features low surface energy and surface topography with a large range of characteristic length scales and re-entrant curvature, thereby imparting superoleophobicity. The degree of superoleophobicity is readily adjusted by means of altering the ratio of particles to binder. The choice of particle and binder result in coatings with thermal stability for thousands of hours at temperatures up to 200 degrees Celsius as well as desirable mechanical characteristics.
摘要翻译：将氟烷基硅烷处理的金属氧化物颗粒和含氟弹性体粘合剂分散在具有低沸点的氟化溶剂中，并通过喷雾沉积施加到基材上。喷涂沉积过程快速产生具有低表面能和表面形貌的共形涂层，其具有大范围的特征长度尺度和重入曲率，从而赋予超疏水性。通过改变颗粒与粘合剂的比例容易地调节超亲水性的程度。颗粒和粘合剂的选择导致在高达200摄氏度的温度下具有热稳定性数千小时的涂层以及期望的机械特性。

2. 发明授权

US08741432B1 Fluoroalkylsilanated mesoporous metal oxide particles and methods of preparation thereof 有权
标题翻译：氟烷基硅烷化介孔金属氧化物颗粒及其制备方法
公开(公告)号：US08741432B1
公开(公告)日：2014-06-03
申请号：US13206994
申请日：2011-08-10
申请人： Raymond Campos , Timothy Haddad , Joseph M. Mabry , Andrew J. Guenthner
发明人： Raymond Campos , Timothy Haddad , Joseph M. Mabry , Andrew J. Guenthner
IPC分类号： B32B5/16 , B05D7/00 , B05D3/02
CPC分类号： C09C3/12 , C01P2006/10 , C01P2006/11 , C01P2006/12 , Y10T428/2991 , Y10T428/2995
摘要： Coated particles comprise a core of fumed or precipitated inorganic metal oxide having a surface area of about 50 to about 500 square meters per gram and a shell consisting of an array of fluoroalkyl molecular chains at a density of at least 1 chain per square nanometer, joined to the core by covalent chemical bonds and with a total organic content of at least 9.9 percent by weight. These particles are formed by the chemical attachment of fluoroalkyl-alkylsilanes after exposure to an alkylamine and followed by an extraction to remove any organic material not covalently bound. The dense packing of molecular chains in the fluoroalkyl shell combined with a mesoporous structure imparts a very low surface energy, a very high specific surface area, and surface texture over a wide range of length scales. Such features are highly desirable for the creation of, for example, superhydrophobic and superoleophobic surfaces, separation media, and release films.
摘要翻译：涂覆的颗粒包括表面积为约50至约500平方米/克的热解或沉淀的无机金属氧化物的核心和由至少1个链每平方毫米的密度的氟代烷基分子链阵列组成的壳，通过共价化学键到达核心，总有机含量为至少9.9重量％。这些颗粒是在暴露于烷基胺之后通过氟代烷基 - 烷基硅烷的化学连接形成的，然后进行萃取以去除未共价结合的任何有机材料。结合中孔结构的氟烷基壳中的分子链的密集填料在宽范围的长度尺度上赋予非常低的表面能，非常高的比表面积和表面纹理。这种特征对于产生例如超疏水和超疏油表面，分离介质和脱模膜是非常需要的。

3. 发明申请

US20100144226A1 Thermally-Activated Heat Resistant insulating Apparatus 审中-公开
标题翻译：耐热绝缘耐热绝缘设备
公开(公告)号：US20100144226A1
公开(公告)日：2010-06-10
申请号：US12171133
申请日：2008-07-10
申请人： Andrew J. Guenthner , Michael E. Wright , Stephen Fallis
发明人： Andrew J. Guenthner , Michael E. Wright , Stephen Fallis
IPC分类号： B32B5/00
CPC分类号： A62C2/065 , Y10T442/2656 , Y10T442/2672
摘要： A firefighting and protection apparatus being thermally-activated and/or heat resistant when subjected to a temperature above a pre-determined limit thermally set chemical reactions occur within the apparatus which causes the apparatus to expand in volume for multifunctional purposes including acting as an insulator against heat, an absorbent for diminishing contact between fuel and oxygen, and release inert gases and flame retardants for disrupting chemical reactions that sustain a fire.
摘要翻译：当受到高于预定极限热定形化学反应的温度时，热活化和/或耐热的消防和保护装置发生在装置内，这导致装置体积膨胀以用于多功能目的，包括用作绝缘体热，用于减少燃料和氧气之间的接触的吸收剂，以及释放惰性气体和阻燃剂以破坏持续火灾的化学反应。

4. 发明授权

US06861497B2 Polyimides having an unusually low and tunable electrical resistivity useful for electrical and optical applications 失效
标题翻译：聚酰亚胺具有非常低的可调电阻率，可用于电气和光学应用
公开(公告)号：US06861497B2
公开(公告)日：2005-03-01
申请号：US10282307
申请日：2002-10-28
申请人： Geoffrey A. Lindsay , Richard A. Hollins , Peter Zaras , Andrew J. Guenthner , Andrew P. Chafin , Mathew C. Davis , Stephen Fallis
发明人： Geoffrey A. Lindsay , Richard A. Hollins , Peter Zaras , Andrew J. Guenthner , Andrew P. Chafin , Mathew C. Davis , Stephen Fallis
IPC分类号： C08G73/06 , C08G73/10 , C08L79/08 , C09K11/06 , H01L51/00 , H01L51/30 , C08G69/28 , B32B27/00
CPC分类号： C08G73/06 , C08G73/1085 , C08L79/08 , C09K11/06 , H01L51/0035 , H01L51/0043 , Y10T428/31504 , Y10T428/31721
摘要： A polyimide is disclosed of the formula: CG1 and CG2 are independently electron-accepting and/or electron-donating groups; x is an integer from about 3 to about 3000; ODAH is any of a number of known dianhydride residues; ODAM is any of a number of known diamine residues; and m, n, o, and p cumulatively add to 1.0, with the sum of m and n ranging from about 0.05 to about 1.0, the sum of o and p ranging from about 0 to about 0.95, the sum of m and o being about 0.5 and the sum of n and p being about 0.5. In addition, a film structure comprising the polyimide and devices utilizing the film structure are disclosed.
摘要翻译：公开了下式的聚酰亚胺：CG1和CG2独立地是电子接受和/或给电子基团; x为约3至约3000的整数; ODAH是许多已知的二酐残基中的任何一种; ODAM是许多已知二胺残基中的任何一种; 并且m，n，o和p累积加到1.0，m和n的总和范围为约0.05至约1.0，o和p的总和范围为约0至约0.95，m和o的和为约0.5，n和p的和为约0.5。此外，公开了包含聚酰亚胺的膜结构和利用膜结构的装置。

5. 发明授权

US08354052B1 Process for manufacturing microconduit networks formed by electrospinning techniques 有权
标题翻译：用于制造由静电纺丝技术形成的微型管道网络的方法
公开(公告)号：US08354052B1
公开(公告)日：2013-01-15
申请号：US12694090
申请日：2010-01-26
申请人： Andrew J. Guenthner , David Michael Hess
发明人： Andrew J. Guenthner , David Michael Hess
IPC分类号： B29C67/20 , D06M10/00 , H05B7/00
CPC分类号： C08J9/26 , B29C39/18 , B29C67/20 , B29C67/202 , B32B33/00 , C08J2325/06 , D01D5/0061 , D04H1/728 , D06M15/233 , D10B2321/121
摘要： A microconduit network structure and methods for making the same. One aspect of the invention relates to a microconduit network structure, including: a solid or semi-solid matrix having at least one interconnected web of filaments formed within the matrix; and wherein at least one interconnected web of filaments having diameters of about 10 nm to about 1 mm.
摘要翻译：微型网络结构及其制作方法。本发明的一个方面涉及一种微通道网络结构，其包括：固体或半固体基体，其具有形成在所述基体内的至少一个互连的细丝网; 并且其中至少一个互连的细丝网具有约10nm至约1mm的直径。

6. 发明申请

US20100139931A1 Thermally-activated heat resistant insulating apparatus 审中-公开
标题翻译：热活化耐热绝缘装置
公开(公告)号：US20100139931A1
公开(公告)日：2010-06-10
申请号：US11148573
申请日：2005-05-27
申请人： Andrew J. Guenthner , Michael E. Wright , Stephen Fallis
发明人： Andrew J. Guenthner , Michael E. Wright , Stephen Fallis
IPC分类号： A62C2/06
CPC分类号： A62C2/065
摘要： A firefighting and protection apparatus being thermally-activated and/or heat resistant when subjected to a temperature above a pre-determined limit thermally set chemical reactions occur within the apparatus which causes the apparatus to expand in volume for multifunctional purposes including acting as an insulator against heat, an absorbent for diminishing contact between fuel and oxygen, and release inert gases and flame retardants for disrupting chemical reactions that sustain a fire.
摘要翻译：当受到高于预定极限热定形化学反应的温度时，热活化和/或耐热的消防和保护装置发生在装置内，这导致装置体积膨胀以用于多功能目的，包括用作绝缘体热，用于减少燃料和氧气之间的接触的吸收剂，以及释放惰性气体和阻燃剂以破坏持续火灾的化学反应。

7. 发明授权

US07462681B1 Polycyanurate compositions 有权
标题翻译：聚氰脲酸盐组合物
公开(公告)号：US07462681B1
公开(公告)日：2008-12-09
申请号：US11239443
申请日：2005-09-19
申请人： Andrew J. Guenthner , Gregory R. Yandek , David J. Irvin
发明人： Andrew J. Guenthner , Gregory R. Yandek , David J. Irvin
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08L69/00 , C08L79/04 , C08L2666/20 , C08L2666/18
摘要： A polycyanurate composition (I), wherein “n” is a positive integer of about 1 to about 10, and wherein R, R′, and R″ comprising at least one of C, H, N, O, F, Si, P, S, Cl, Br, I, and any combination thereof. A method of making a polycyanurate composition (I) including, providing at least one semi-aliphatic polycarbonate (V), wherein R comprises at least one of C, H, N, O, F, Si, P, S, Cl, Br, I, providing at least one uncured reactive thermoset monomer, dissolving the polycarbonate in a solvent with a high vapor pressure or suspending the polycarbonate directly into the reactive monomer, mixing the liquefied polycarbonate with the uncured reactive thermoset monomer into a homogeneous liquid component, curing the liquid component into a viscous component, and exposing the cured component to temperatures of about 50° C. to about 400° C. forming tricyanurate linkages in the polycyanurate composition (I).
摘要翻译：一种聚氰尿酸酯组合物（I），其中“n”为约1至约10的正整数，并且其中R，R'和R“包含C，H，N，O，F，Si， P，S，Cl，Br，I及其任何组合。一种制备聚氰脲酸盐组合物（I）的方法，包括提供至少一种半脂族聚碳酸酯（V），其中R包含C，H，N，O，F，Si，P，S，Cl，Br I提供至少一种未固化的反应性热固性单体，将聚碳酸酯溶解在具有高蒸气压的溶剂中或将聚碳酸酯直接悬浮于反应性单体中，将液化的聚碳酸酯与未固化的反应性热固性单体混合成均匀的液体组分，固化将液体组分变成粘性组分，并将固化的组分暴露于约50℃至约400℃的温度，在聚氰化脲组合物（I）中形成三氰脲酸酯键。

8. 发明授权

US09006371B1 Synthesis of oligomeric silsesquioxane monomers for high performance polymers 有权
标题翻译：用于高性能聚合物的低聚倍半硅氧烷单体的合成
公开(公告)号：US09006371B1
公开(公告)日：2015-04-14
申请号：US12892124
申请日：2010-09-28
申请人： Michael E. Wright , Brian J. Petteys , Andrew J. Guenthner , Sandra J. Tomczak
发明人： Michael E. Wright , Brian J. Petteys , Andrew J. Guenthner , Sandra J. Tomczak
IPC分类号： C08G77/26 , C07F7/08
CPC分类号： C07F7/081 , C08G69/32 , C08G69/42 , C08G73/1042 , C08G73/105 , C08G73/1071 , C08G77/045 , C08G77/26
摘要： A formulation and methods for making formulation of a series of oligomeric silsesesquioxane (OS) diamine monomers which have been synthesized and purified in a highly time, energy, and atom efficient manner.
摘要翻译：已经以高度时间，能量和原子效率的方式合成和纯化的一系列低聚倍半硅氧烷（OS）二胺单体的配制和制备方法。

9. 发明申请

US20100139933A1 Thermally-Activated Heat Resistant Insulating Apparatus 审中-公开
标题翻译：耐热绝缘绝热设备
公开(公告)号：US20100139933A1
公开(公告)日：2010-06-10
申请号：US12172825
申请日：2008-07-14
申请人： Andrew J. Guenthner , Michael E. Wright , Stephen Fallis
发明人： Andrew J. Guenthner , Michael E. Wright , Stephen Fallis
IPC分类号： A62C2/00 , B32B3/06 , A62C5/00
CPC分类号： A62C2/065 , Y10T442/2656 , Y10T442/2672
摘要： A firefighting and protection apparatus being thermally-activated and/or heat resistant when subjected to a temperature above a pre-determined limit thermally set chemical reactions occur within the apparatus which causes the apparatus to expand in volume for multifunctional purposes including acting as an insulator against heat, an absorbent for diminishing contact between fuel and oxygen, and release inert gases and flame retardants for disrupting chemical reactions that sustain a fire.
摘要翻译：当受到高于预定极限热定形化学反应的温度时，热活化和/或耐热的消防和保护装置发生在装置内，这导致装置体积膨胀以用于多功能目的，包括用作绝缘体热，用于减少燃料和氧气之间的接触的吸收剂，以及释放惰性气体和阻燃剂以破坏持续火灾的化学反应。

10. 发明申请

US20100139932A1 Thermally-Activated Heat Resistant Insulating Apparatus 审中-公开
公开(公告)号：US20100139932A1
公开(公告)日：2010-06-10
申请号：US12172797
申请日：2008-07-14
申请人： Andrew J. Guenthner , Michael E. Wright , Stephen Fallis
发明人： Andrew J. Guenthner , Michael E. Wright , Stephen Fallis
IPC分类号： A62C2/00 , B32B3/26 , A62C5/00
CPC分类号： A62C2/065 , Y10T442/2656 , Y10T442/2672
摘要： A firefighting and protection apparatus being thermally-activated and/or heat resistant when subjected to a temperature above a pre-determined limit thermally set chemical reactions occur within the apparatus which causes the apparatus to expand in volume for multifunctional purposes including acting as an insulator against heat, an absorbent for diminishing contact between fuel and oxygen, and release inert gases and flame retardants for disrupting chemical reactions that sustain a fire.

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