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1. 发明申请

US20120010426A1 Processes Related to the Hydroformylation of Butenes 有权
标题翻译：与丁烯加氢甲酰化有关的工艺
公开(公告)号：US20120010426A1
公开(公告)日：2012-01-12
申请号：US13239004
申请日：2011-09-21
申请人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Marie Mathys , John Richard Shutt
发明人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Marie Mathys , John Richard Shutt
IPC分类号： C07C69/003 , C07C31/125 , C07C53/126 , C07C47/02
CPC分类号： C07C29/141 , C07C29/175 , C07C31/125 , C07C45/50 , C07C47/02 , C07C53/126 , C07C69/003 , C07C69/22 , C07C69/80
摘要： Mixed butene streams containing butene-1 and isobutylene and optionally butene-2 are hydroformylated under conditions that hydroformylates all the monomers to yield a mixture of valeraldehydes
摘要翻译：含有丁烯-1和异丁烯和任选的丁烯-2的混合丁烯流在加氢甲酰化所有单体以产生戊醛混合物的条件下加氢甲酰化

2. 发明申请

US20120253059A1 Hydroformylation Of Butenes 有权
标题翻译：丁烯加氢甲酰化
公开(公告)号：US20120253059A1
公开(公告)日：2012-10-04
申请号：US13439231
申请日：2012-04-04
申请人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Marie Mathys , John Richard Shutt
发明人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Marie Mathys , John Richard Shutt
IPC分类号： C07C69/80 , C09K3/00
CPC分类号： C07C29/141 , C07C29/175 , C07C31/125 , C07C45/50 , C07C47/02 , C07C53/126 , C07C69/003 , C07C69/22 , C07C69/80
摘要： Mixed butene streams containing butene-1 and isobutylene and optionally butene-2 are hydroformylated under conditions that hydroformylates all the monomers to yield a mixture of valeraldehydes. Higher temperatures and/or longer residence times and/or higher partial pressure of carbon monoxide than in conventional processes are used to ensure hydroformylation of all the monomers.
摘要翻译：在加氢甲酰化所有单体以产生戊醛混合物的条件下，将含有丁烯-1和异丁烯和任选的丁烯-2的混合丁烯流加氢甲酰化。使用比常规方法更高的温度和/或更长的停留时间和/或更高的一氧化碳分压来确保所有单体的加氢甲酰化。

3. 发明授权

US08921607B2 Hydroformylation of butenes 有权
标题翻译：丁烯的羰基化
公开(公告)号：US08921607B2
公开(公告)日：2014-12-30
申请号：US13439231
申请日：2012-04-04
申请人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Marie Mathys , John Richard Shutt
发明人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Marie Mathys , John Richard Shutt
IPC分类号： C07C45/00 , C07C29/141 , C07C31/125 , C07C69/80 , C07C29/17 , C07C47/02 , C07C69/22 , C07C69/003 , C07C45/50 , C07C53/126
CPC分类号： C07C29/141 , C07C29/175 , C07C31/125 , C07C45/50 , C07C47/02 , C07C53/126 , C07C69/003 , C07C69/22 , C07C69/80
摘要： Mixed butene streams containing butene-1 and isobutylene and optionally butene-2 are hydroformylated under conditions that hydroformylates all the monomers to yield a mixture of valeraldehydes. Higher temperatures and/or longer residence times and/or higher partial pressure of carbon monoxide than in conventional processes are used to ensure hydroformylation of all the monomers.
摘要翻译：在加氢甲酰化所有单体以产生戊醛混合物的条件下，将含有丁烯-1和异丁烯和任选的丁烯-2的混合丁烯流加氢甲酰化。使用比常规方法更高的温度和/或更长的停留时间和/或更高的一氧化碳分压来确保所有单体的加氢甲酰化。

4. 发明授权

US08178730B2 Processes related to the hydroformylation of butenes 有权
标题翻译：与丁烯加氢甲酰化相关的方法
公开(公告)号：US08178730B2
公开(公告)日：2012-05-15
申请号：US13239004
申请日：2011-09-21
申请人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Marie Mathys , John Richard Shutt
发明人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Marie Mathys , John Richard Shutt
IPC分类号： C07C45/00
CPC分类号： C07C29/141 , C07C29/175 , C07C31/125 , C07C45/50 , C07C47/02 , C07C53/126 , C07C69/003 , C07C69/22 , C07C69/80
摘要： Mixed butene streams containing butene-1 and isobutylene and optionally butene-2 are hydroformylated under conditions that hydroformylates all the monomers to yield a mixture of valeraldehydes.
摘要翻译：在加氢甲酰化所有单体以产生戊醛混合物的条件下，将含有丁烯-1和异丁烯和任选的丁烯-2的混合丁烯流加氢甲酰化。

5. 发明授权

US08022256B2 Hydroformylation of butenes comprising isobutylene 有权
标题翻译：包含异丁烯的丁烯的羰基化
公开(公告)号：US08022256B2
公开(公告)日：2011-09-20
申请号：US10572011
申请日：2004-09-17
申请人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Maria Mathys , John Richard Shutt
发明人： Raphael F. Caers , Eddy Theophile Van Driessche , Hubertus J. Beckers , Luc Roger Marc Martens , Georges Maria Mathys , John Richard Shutt
IPC分类号： C07C45/00
CPC分类号： C07C29/141 , C07C29/175 , C07C31/125 , C07C45/50 , C07C47/02 , C07C53/126 , C07C69/003 , C07C69/22 , C07C69/80
摘要： Mixed butene streams containing butene-1 and isobutylene and optionally butene-2 are hydroformylated under conditions that hydroformylates all the monomers to yield a mixture of valeraldehydes. Higher temperatures and/or longer residence times and/or higher partial pressure of carbon monoxide than in conventional processes are used to ensure hydroformylation of all the monomers.
摘要翻译：在加氢甲酰化所有单体以产生戊醛混合物的条件下，将含有丁烯-1和异丁烯和任选的丁烯-2的混合丁烯流加氢甲酰化。使用比常规方法更高的温度和/或更长的停留时间和/或更高的一氧化碳分压来确保所有单体的加氢甲酰化。

6. 发明授权

US07582802B2 Propylene hydroformylation 有权
标题翻译：丙烯加氢甲酰化
公开(公告)号：US07582802B2
公开(公告)日：2009-09-01
申请号：US10591306
申请日：2005-01-28
申请人： Raphael Frans Caers , Hubertus Joseph Beckers , Eddy Theophyle Andrea Van Driessche , Luc Roger Marc Martens , John Stephen Godsmark , John Richard Shutt
发明人： Raphael Frans Caers , Hubertus Joseph Beckers , Eddy Theophyle Andrea Van Driessche , Luc Roger Marc Martens , John Stephen Godsmark , John Richard Shutt
IPC分类号： C07C45/50
CPC分类号： C07C51/252 , C07C2/66 , C07C45/50 , C07C253/00 , Y02P20/582 , Y02P30/20 , C07C15/085 , C07C57/04 , C07C255/16 , C07C47/02
摘要： Propylene streams obtained by the conversion of oxygenates to olefins are used as feeds for hydroformylation. The streams may contain measurable amounts of dimethyl ether without adversely impacting the hydroformylation.
摘要翻译：通过将含氧化合物转化为烯烃获得的丙烯流用作加氢甲酰化的进料。流可以含有可测量的二甲醚，而不会不利地影响加氢甲酰化。

7. 发明授权

US07015174B2 Maintaining molecular sieve catalytic activity under water vapor conditions 有权
标题翻译：在水汽条件下维持分子筛催化活性
公开(公告)号：US07015174B2
公开(公告)日：2006-03-21
申请号：US10600123
申请日：2003-06-20
申请人： Peter N. Loezos , Shun Chong Fung , Stephen Neil Vaughn , Kenneth Ray Clem , James H. Beech , Nicolas P. Coute , Marcel Johannes Janssen , Luc Roger Marc Martens , Karl G. Strohmaier
发明人： Peter N. Loezos , Shun Chong Fung , Stephen Neil Vaughn , Kenneth Ray Clem , James H. Beech , Nicolas P. Coute , Marcel Johannes Janssen , Luc Roger Marc Martens , Karl G. Strohmaier
IPC分类号： B01J29/02 , B01J27/18 , B01J27/182
CPC分类号： B01J29/85 , B01J29/84 , B01J37/10 , B01J2229/24 , B01J2229/36 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2300/807 , C10G2400/20 , Y02P30/20 , Y02P30/42 , Y10S585/906 , Y10S585/951 , C07C11/02
摘要： The invention is directed to methods for protecting metalloaluminophosphate molecular sieves, particularly silicoaluminophosphate (SAPO) molecular sieves, from loss of catalytic activity due to contact with a gas containing water. The methods of the invention provide procedures that enable activated sieve to contact water vapor, within a certain range of time, temperature, and water partial pressure conditions, before the sieve becomes substantially deactivated.
摘要翻译：本发明涉及用于保护金属铝磷酸盐分子筛，特别是硅铝磷酸盐（SAPO）分子筛的方法，这是由于与含有气体的气体接触导致的催化活性丧失。本发明的方法提供了在筛子基本上失活之前，在一定时间，温度和水分压条件下使活化筛接触水蒸汽的方法。

8. 发明授权

US06656345B1 Hydrocarbon conversion to propylene with high silica medium pore zeolite catalysts 失效
标题翻译：烃转化为丙烯与高二氧化硅中孔沸石催化剂
公开(公告)号：US06656345B1
公开(公告)日：2003-12-02
申请号：US09304657
申请日：1999-05-04
申请人： Tan-Jen Chen , Mechilium (Marcel) Johannes Gerardus Janssen , Luc Roger Marc Martens , Machteld Maria Mertens , Philip Andrew Ruziska , Lynn L. Zhao , Jannetje Maatje van den Berge
发明人： Tan-Jen Chen , Mechilium (Marcel) Johannes Gerardus Janssen , Luc Roger Marc Martens , Machteld Maria Mertens , Philip Andrew Ruziska , Lynn L. Zhao , Jannetje Maatje van den Berge
IPC分类号： C10G1102
CPC分类号： C10G11/05 , C10G2400/20
摘要： The invention provides a method for converting a hydrocarbon feedstock to propylene comprising: contacting an olefinic hydrocarbon feedstock boiling in the naphtha range with a catalyst comprising a zeolitic catalyst selected from the group consisting of medium pore zeolites having a ratio of silica to alumina above 200 and pore diameter less than 0.7 nm under cracking conditions to selectively produce propylene. The preferred catalyst comprises of a zeolite having an 8, 10, or 12 membered ring pore structure. The preferred catalysts are selected from the group consisting of zeolites from the families MFI, MEL, MTW, TON, MTT, FER, MFS, and the zeolites ZSM-21, ZSM-38 and ZSM-48. Preferably the method is carried out to produce propylene with greater than 50% specificity, more preferably, the propylene to butylene ratio is at least 2:1 or a propylene to ethylene ratio of at least 4:1. The olefinic hydrocarbon feedstock consists essentially of hydrocarbons boiling within the range of 18° to 220° C. (65° F. to 430° F.). The olefinic hydrocarbon feedstock comprises from about 10 wt % to about 70 wt % olefins. Preferably the olefinic hydrocarbon feedstock comprises from about 5 wt % to about 35 wt % paraffins. The catalyst is contacted in the range of 400° C. to 700° C., a weight hourly space velocity (“WHSV”) of 1 to 1,000 hr−1 and a pressure of 0.1 to 30 atm. absolute.
摘要翻译：本发明提供了一种用于将烃原料转化成丙烯的方法，包括：使在石脑油范围沸腾的烯烃原料与包含沸石催化剂的催化剂接触，所述催化剂选自二氧化硅与氧化铝的比例大于200的中孔沸石，孔径小于0.7nm，在选择性地生产丙烯。优选的催化剂包括具有8,10或12元环孔结构的沸石。优选的催化剂选自族MFI，MEL，MTW，TON，MTT，FER，MFS和沸石ZSM-21，ZSM-38和ZSM-48的沸石。优选地，该方法进行以产生具有大于50％特异性的丙烯，更优选丙烯与丁烯的比率为至少2:1或丙烯与乙烯的比率为至少4:1。烯烃原料基本上由沸点在18°至220℃（65°F至430°F）范围内的烃组成。烯烃原料包含约10重量％至约70重量％的烯烃。优选地，烯烃原料包含约5重量％至约35重量％的链烷烃。催化剂在400℃至700℃的范围内接触，1至1,000小时-1的重时空速（“WHSV”）和0.1至30大气压的压力。绝对。

9. 发明授权

US6033555A Sequential catalytic and thermal cracking for enhanced ethylene yield 失效
标题翻译：连续催化和热裂解提高乙烯产率
公开(公告)号：US6033555A
公开(公告)日：2000-03-07
申请号：US872660
申请日：1997-06-10
申请人： Tan-Jen Chen , Luc Roger Marc Martens
发明人： Tan-Jen Chen , Luc Roger Marc Martens
IPC分类号： C07C4/02 , C10G51/02
CPC分类号： C07C4/02 , C10G2400/20
摘要： The invention provides a process for improving the conversion of a hydrocarbon feedstock to light olefins comprising the steps of first contacting the hydrocarbon feedstock with a light olefin producing cracking catalyst and subsequently thermally cracking the unseparated stream to produce additional ethylene. Preferably the zeolite catalyst is selected from the group consisting of ferrierite, heulandite, phillipsite, faujasite, chabazite, erionite, mordenite, offretite, gmelinite, analcite, ZSM-5, ZSM-11, ZSM-25, gallium silicate zeolite, zeolite Beta, zeolite rho, ZK5, titanosilicate, zeolites having a silica to alumina molar ratio within the range of about 2.0:1 to 2000:1 ferrosilicate; zeolites such as those described in U.S. Pat. No. 4,238,318; borosilicate zeolites such as those described in Belgian Pat. No. 859656; zeolites designated by the Linde Division of Union Carbide by the letters of X, Y, A, L; zeolites such as those described in U.S. Pat. No. 5,552,035; and zeolites such as those described in U.S. Pat. No. 5,348,924. Preferably the catalyst is contacted at a temperature within the range of about 500.degree. C. to about 750.degree. C. and the feedstock flows at a weight hourly space velocity in the range of about 0.1 Hr.sup.-1 WHSV to about 100 Hr.sup.-1 WHSV. The trim thermal cracking is carried out between 650.degree. C. to 900.degree. C. for 0.1 to 20 seconds.
摘要翻译：本发明提供了一种改进烃原料转化成轻质烯烃的方法，包括首先使烃原料与轻质烯烃生成裂化催化剂接触，随后热裂裂未分离的流以产生额外的乙烯。优选地，沸石催化剂选自镁碱沸石，胡萝卜石，氯化石，八面沸石，菱沸石，毛沸石，丝光沸石，白云母，绿泥石，anal石，ZSM-5，ZSM-11，ZSM-25，硅酸镓沸石，β沸石，沸石rho，ZK5，钛硅酸盐，二氧化硅与氧化铝摩尔比在约2.0:1至2000:1的硅酸铝的范围内的沸石; 沸石如美国专利No. 第4,238,318号; 硼硅酸盐沸石，如比利时专利中描述的那些。 No. 859656; 由联合碳化物林德分公司以X，Y，A，L的字母指定的沸石; 沸石如美国专利No. 第5,552,035号; 和沸石，例如美国专利No. 第5,348,924号。优选地，催化剂在约500℃至约750℃范围内的温度下接触，并且原料以约0.1Hr-1WHSV至约100Hr-1WHSV的重时空速流动。修整热裂化在650℃至900℃之间进行0.1至20秒。

10. 发明授权

US5739076A Catalysts and their use in oxidation of saturated hydrocarbons 失效
标题翻译：催化剂及其在饱和烃氧化中的应用
公开(公告)号：US5739076A
公开(公告)日：1998-04-14
申请号：US374588
申请日：1995-04-19
申请人： Diane Renata Cornelia Huybrechts , Philip Luc Buskens , Georges Marie Karel Mathys , Luc Roger Marc Martens
发明人： Diane Renata Cornelia Huybrechts , Philip Luc Buskens , Georges Marie Karel Mathys , Luc Roger Marc Martens
IPC分类号： B01J29/70 , B01J29/74 , B01J29/89 , B01J31/02 , C01B37/00 , C01B39/04 , C01B39/06 , C01B39/48 , C07B41/00 , C07B61/00 , C07C37/01 , C07C51/285 , C07C51/31 , C07C55/14 , C07D301/19 , C07C55/00 , B01J23/00
CPC分类号： C07D301/19 , B01J29/7007 , B01J29/7415 , B01J29/89 , C01B37/005 , C01B39/04 , C01B39/065 , C01B39/48 , C07B41/00 , C07C37/50 , C07C37/60 , C07C51/285 , C07C51/313 , B01J2229/36 , Y02P20/52
摘要： New titanium zeolite Beta catalysts which have been found to be useful as catalysts for the oxidation of organic compounds using organic hydroperoxides as oxidation catalysts. They are particularly useful as ring opening oxidation catalysts and may be used to produce adipic acid from cyclohexane.
摘要翻译： PCT No.PCT / EP93 / 01972 Sec。 371日期1995年04月19日 102（e）1995年4月19日PCT PCT 1993年7月23日PCT公布。出版物WO94 / 02245 日期1994年2月3日新的钛沸石β-催化剂已被发现可用作有机氢过氧化物作为氧化催化剂氧化有机化合物的催化剂。它们特别用作开环氧化催化剂，并且可用于从环己烷产生己二酸。

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