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1. 发明授权

US5326791A Process for separation of hydrolyzable from non-hydrolyzable waste plastics for recovery of starting materials and other conversion processes, respectively 失效
标题翻译：分离可水解与不可水解废塑料的回收原料和其他转化方法的方法
公开(公告)号：US5326791A
公开(公告)日：1994-07-05
申请号：US812176
申请日：1991-12-20
申请人： Ramzi Y. Saleh , William E. Wellman
发明人： Ramzi Y. Saleh , William E. Wellman
IPC分类号： C08F6/00 , C08F6/06 , C08F8/12 , C08G85/00 , C08J11/00 , C08J11/14
CPC分类号： C08J11/14 , C08J2367/02 , Y02W30/704
摘要： The present invention relates to a process for reactively separating hydrolyzable polymers, such as PET, in mixtures of the polymer and certain non-hydrolyzable polymers, specifically polyolefins by converting the hydrolyzable polymers to their corresponding water soluble components (e.g., PET to ethylene glycol and terephthalic acid) in the presence of liquid water at temperatures from about 200.degree. C. up to the critical temperature of water and autogenous pressure. The process has utility in recycling and waste material separation processes.
摘要翻译：本发明涉及通过将可水解聚合物转化成其相应的水溶性组分（例如，PET至乙二醇和/或其衍生物）的聚合物和某些不可水解的聚合物，特别是聚烯烃的混合物，将可水解聚合物如PET，对苯二甲酸）在液态水存在下，在约200℃至临界温度和自生压力的温度下进行。该方法在回收和废料分离过程中具有实用价值。

2. 发明授权

US08859821B2 Polyketone plasticizers 有权
标题翻译：聚酮增塑剂
公开(公告)号：US08859821B2
公开(公告)日：2014-10-14
申请号：US13345014
申请日：2012-01-06
申请人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
发明人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
IPC分类号： C07C45/00 , C07C45/27 , C08L101/00 , C08G67/00 , C08G67/02 , C08L73/00
CPC分类号： C08G67/02 , C08L73/00 , C08L101/00 , C08L2666/14
摘要： The invention relates to polyketone compounds and the at least partially hydrogenated products thereof, the use of said polyketone compounds and/or the at least partially hydrogenated products thereof as plasticizers, processes of making polyketone compounds and the at least partially hydrogenated products thereof, compositions comprising the polyketone compounds and/or the at least partially hydrogenated products thereof, and to articles formed from products of the invention.
摘要翻译：本发明涉及聚酮化合物及其至少部分氢化的产物，所述聚酮化合物和/或其至少部分氢化产物作为增塑剂的用途，制备聚酮化合物的方法及其至少部分氢化的产物，包含聚酮化合物和/或其至少部分氢化的产物，以及由本发明的产物形成的制品。

3. 发明申请

US20080242895A1 Polyketone Plasticizers 失效
标题翻译：聚酮增塑剂
公开(公告)号：US20080242895A1
公开(公告)日：2008-10-02
申请号：US12058397
申请日：2008-03-28
申请人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
发明人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
IPC分类号： C07C45/27
CPC分类号： C08G67/02 , C08L73/00 , C08L101/00 , C08L2666/14
摘要： The invention relates to polyketone compounds and the at least partially hydrogenated products thereof, the use of said polyketone compounds and/or the at least partially hydrogenated products thereof as plasticizers, processes of making polyketone compounds and the at least partially hydrogenated products thereof, compositions comprising the polyketone compounds and/or the at least partially hydrogenated products thereof, and to articles formed from products of the invention.
摘要翻译：本发明涉及聚酮化合物及其至少部分氢化的产物，所述聚酮化合物和/或其至少部分氢化产物作为增塑剂的用途，制备聚酮化合物的方法及其至少部分氢化的产物，包含聚酮化合物和/或其至少部分氢化的产物，以及由本发明的产物形成的制品。

4. 发明授权

US5453561A Reactive separation process 失效
标题翻译：反应分离过程
公开(公告)号：US5453561A
公开(公告)日：1995-09-26
申请号：US187673
申请日：1994-01-27
申请人： Ramzi Y. Saleh , Michael Siskin , Glen B. Brons , Stephen N. Vaughn , Richard H. Schlosberg
发明人： Ramzi Y. Saleh , Michael Siskin , Glen B. Brons , Stephen N. Vaughn , Richard H. Schlosberg
IPC分类号： B01D17/025 , C07C7/148 , C07C11/02 , C07C29/10 , C10G50/00 , C07C7/00
CPC分类号： C07C29/10 , C07C7/148
摘要： The invention concerns a method for reactive separation of mixtures containing hydrocarbons and oxygenated hydrocarbons, by contacting a mixture of hydrocarbons such as C.sub.2 to C.sub.26 hydrocarbons and mixtures thereof and oxygenated hydrocarbons, such as C.sub.2 to C.sub.40 oxygenated hydrocarbons and mixtures thereof to form a mixture of hydrocarbons and lower molecular weight oxygenated hydrocarbons and heating the mixture in water at temperature typically from about and pressure sufficient to cleave the oxygenated hydrocarbons to lower molecular weight products to form a liquid layer containing water soluble reaction products and an organic layer containing primarily hydrocarbons.
摘要翻译：本发明涉及通过使烃类混合物例如C 2至C 26烃及其混合物和含氧烃如C2至C40含氧烃及其混合物的混合物与烃和氧化烃的混合物进行反应分离的方法，以形成混合物碳氢化合物和较低分子量的氧化烃，并将混合物在水中加热，其温度通常为足以将氧化烃切割成较低分子量产物的温度，形成含有水溶性反应产物和主要含有烃的有机层的液体层。

5. 发明授权

US5169824A Catalyst comprising amorphous NiO on silica/alumina support 失效
标题翻译：包含在二氧化硅/氧化铝载体上的无定形NiO的催化剂
公开(公告)号：US5169824A
公开(公告)日：1992-12-08
申请号：US644998
申请日：1991-01-22
申请人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
发明人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
IPC分类号： B01J23/755 , B01J37/02 , B01J37/03
CPC分类号： B01J37/0217 , B01J23/755 , B01J37/031
摘要： The present invention provides for a catalyst composition which is effective for use in the production of dimer products and higher olefin products from lower olefins such as propylene and butene in high yields and with an average degree of branching in the dimer products of less than about 1.6 methyl groups per molecule, generally in the range of from about 1.0 to 1.4 methyl groups per molecule. The present invention also provides a process for producing such dimer and higher olefin products using the catalyst composition of this invention. The catalyst of the invention comprises an amorphous nickel oxide (NiO) present as a disperse substantial monolayer on the surfaces of a silica (SiO.sub.2) support, which support also contains minor amounts of an oxide of aluminum, gallium or indium such that the ratio of NiO to metal oxide present in the catalyst is within the range of from about 4:1 to about 100:1. The catalyst may be prepared by precipitating a water insoluble nickel salt onto the surfaces of a silica support which has been impregnated with the metal oxide or onto a silica-alumina support which has been dealuminized such that the resulting nickel oxide/alumina ratio will fall within the ranges set forth above. The catalyst may then be activated by calcination in the presence of oxygen at a temperature within the range of from about 500.degree. to 700.degree. C.
摘要翻译：本发明提供了一种催化剂组合物，其有效用于以高产率从低级烯烃如丙烯和丁烯生产二烯体产物和高级烯烃产物，并且二聚体产物中的平均支化度小于约1.6 每个分子的甲基基团，通常在每分子约1.0至1.4个甲基的范围内。本发明还提供了使用本发明的催化剂组合物生产这种二聚物和较高级烯烃产物的方法。本发明的催化剂包括在二氧化硅（SiO 2）载体的表面上作为分散实质单层存在的无定形氧化镍（NiO），该载体还含有少量的铝，镓或铟的氧化物，存在于催化剂中的NiO与金属氧化物在约4:1至约100:1的范围内。催化剂可以通过将水不溶性镍盐沉淀到已经浸渍有金属氧化物的二氧化硅载体的表面上或已经脱铝的二氧化硅 - 氧化铝载体上，使得所得到的氧化镍/氧化铝比落入上述范围。催化剂然后可以在氧的存在下在约500-700℃的温度下煅烧来活化。

6. 发明授权

US5043486A Aquathermolytic cleavage of ethers 失效
标题翻译：醚水解裂解
公开(公告)号：US5043486A
公开(公告)日：1991-08-27
申请号：US572485
申请日：1990-08-23
申请人： Michael Siskin , Glen B. Brons , Ramzi Y. Saleh , Stephen N. Vaughn
发明人： Michael Siskin , Glen B. Brons , Ramzi Y. Saleh , Stephen N. Vaughn
IPC分类号： C07C29/10 , C07C31/02 , C07C31/10 , C07C31/12
CPC分类号： C07C29/10
摘要： The present invention provides for a simplified process for converting ethers into their corresponding alcohols comprising forming an aqueous mixture of the ether and at least about 50% by weight water and heating the mixture under autogeneous pressure at a temperature of from about 250.degree. to 450.degree. C., more preferably from about 250.degree. C. up to the critical temperature of water which is about 374.degree. C. Heating is continued for a period of time sufficient to convert at least about 20% by weight of the ether, usually from about 5 up to about 120 minutes, depending on temperature and the amount of water present, and the identity of the starting ether feedstock.The process may be characterized as an aquathermolysis reaction wherein the reaction proceeds in water primarily through ionic routes rather than through free radical routes. Accordingly, relatively high conversion rates and good yields of alcohol and other reaction by-products may be obtained without the necessity of using a catalyst in the process.
摘要翻译：本发明提供了将醚转化成其相应的醇的简化方法，包括形成醚的水性混合物和至少约50重量％的水，并在约250-450℃的温度下在自主压力下加热混合物更优选约250℃至约374℃的水的临界温度。继续加热足够的时间以使至少约20重量％的乙醚转化成通常为约 5至约120分钟，这取决于温度和存在的水的量以及起始醚原料的特性。该方法可以表征为水解溶解反应，其中反应在水中主要通过离子路线而不是通过自由基途径进行。因此，可以获得醇和其它反应副产物的相对高的转化率和良好的产率，而不需要在该方法中使用催化剂。

7. 发明授权

US08115034B2 Polyketone plasticizers 失效
标题翻译：聚酮增塑剂
公开(公告)号：US08115034B2
公开(公告)日：2012-02-14
申请号：US12058397
申请日：2008-03-28
申请人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
发明人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
IPC分类号： C07C45/00 , C07C45/27 , C08G67/00 , C08G67/02
CPC分类号： C08G67/02 , C08L73/00 , C08L101/00 , C08L2666/14
摘要： The invention relates to polyketone compounds and the at least partially hydrogenated products thereof, the use of said polyketone compounds and/or the at least partially hydrogenated products thereof as plasticizers, processes of making polyketone compounds and the at least partially hydrogenated products thereof, compositions comprising the polyketone compounds and/or the at least partially hydrogenated products thereof, and to articles formed from products of the invention.
摘要翻译：本发明涉及聚酮化合物及其至少部分氢化的产物，所述聚酮化合物和/或其至少部分氢化产物作为增塑剂的用途，制备聚酮化合物的方法及其至少部分氢化的产物，包含聚酮化合物和/或其至少部分氢化的产物，以及由本发明的产物形成的制品。

8. 发明申请

US20100022802A1 Preparation of Alkylaromatic Hydrocarbons and Alkylaryl Sulfonates 失效
标题翻译：烷基芳烃和烷基芳基磺酸盐的制备
公开(公告)号：US20100022802A1
公开(公告)日：2010-01-28
申请号：US12575948
申请日：2009-10-08
申请人： Carolyn B. Duncan , David Wayne Turner , Jane C. Cheng , Charles M. Yarbrough , Raphael Frans Caers , Ramzi Y. Saleh , James L. Propp
发明人： Carolyn B. Duncan , David Wayne Turner , Jane C. Cheng , Charles M. Yarbrough , Raphael Frans Caers , Ramzi Y. Saleh , James L. Propp
IPC分类号： C07C315/00 , C07C15/00
CPC分类号： C07C2/66 , C07C15/107 , C07C303/06 , C07C2527/1206 , C07C2527/126 , C07C2527/173 , C07C2529/70 , C07C309/31
摘要： An alkylaromatic hydrocarbon composition prepared by the process which comprises oligomerizing an olefin selected from the group consisting of propylene, n-butene and mixtures thereof over an oligomerization catalyst, to form a oligomerization product comprising at least 95% by weight of mono-olefin oligomers of the empirical formula: CnH2n wherein n is greater than or equal to 10, the mono-olefin oligomers comprise at least 20% by weight of olefins having at least 12 carbon atoms, and the olefins having at least 12 carbon atoms having an average of from 0.8 to 2.0 C1-C3 alkyl branches per carbon chain. Sulfonation of the alkylaromatic hydrocarbon product produces an alkylaryl sulfonate mixture that exhibits advantageous properties, such as biodegradability and hard and cold water performance.
摘要翻译：通过该方法制备的烷基芳族烃组合物，其包括在低聚催化剂上使选自丙烯，正丁烯及其混合物的烯烃低聚，形成低聚产物，其包含至少95重量％的单烯烃低聚物经验式：C n H 2n其中n大于或等于10，单烯烃低聚物包含至少20重量％的具有至少12个碳原子的烯烃，并且具有至少12个碳原子的烯烃具有平均为每个碳链0.8至2.0个C1-C3烷基支链。烷基芳族烃产物的磺化产生显示出有利性质的烷基芳基磺酸盐混合物，例如生物降解性和冷水和冷水性能。

9. 发明授权

US07425662B2 Oligomerization of olefins 有权
标题翻译：烯烃的低聚
公开(公告)号：US07425662B2
公开(公告)日：2008-09-16
申请号：US10509356
申请日：2003-03-28
申请人： Jon E. Stanat , Georges M. K. Mathys , David Wayne Turner , Jane C. Cheng , Stephen W. Beadle , Cesar M. Cheng Guajardo , Roger Eijkhoudt , Allen D. Godwin , Ernest E. Green , Charles M. Yarbrough , Raphael Frans Caers , Carolyn B. Duncan , Ramzi Y. Saleh
发明人： Jon E. Stanat , Georges M. K. Mathys , David Wayne Turner , Jane C. Cheng , Stephen W. Beadle , Cesar M. Cheng Guajardo , Roger Eijkhoudt , Allen D. Godwin , Ernest E. Green , Charles M. Yarbrough , Raphael Frans Caers , Carolyn B. Duncan , Ramzi Y. Saleh
IPC分类号： C07C2/20
CPC分类号： C07C2/64 , C07C2/12 , C07C45/28 , C07C51/16 , C07C2529/70 , C08F10/00 , C08F210/10 , C10G50/00 , C10M129/68 , C10M129/95 , C10M2207/28 , C11D1/667 , C11D3/2093 , C07C15/107 , C08F4/12 , C08F4/18 , C08F2500/02
摘要： A selectivated molecular sieve, e.g., ZSM-22 or ZSM-23, is used as olefin oligomerization catalyst to provide product, e.g., octenes and dodecenes from butene, having a low degree of branching and hindered double bonds.
摘要翻译：使用选择性分子筛，例如ZSM-22或ZSM-23作为烯烃低聚催化剂，以提供具有低支化度和受阻双键的产物，例如丁烯中的辛烯和十二碳烯。

10. 发明授权

US4831164A Process of preparing carboxylic anhydride 失效
标题翻译：制备羧酸酐的方法
公开(公告)号：US4831164A
公开(公告)日：1989-05-16
申请号：US180061
申请日：1988-04-11
申请人： Ramzi Y. Saleh , Israel E. Wachs
发明人： Ramzi Y. Saleh , Israel E. Wachs
IPC分类号： B01J23/22 , C07C51/215 , C07C51/25 , C07C51/265 , C07C51/31
CPC分类号： C07C51/313 , B01J23/22 , C07C51/215 , C07C51/25 , C07C51/252 , C07C51/265
摘要： In accordance with the process of this invention, an improved catalyst for molecular oxidation of hydrocarbons to form the corresponding carboxylic anhydrides is prepared by the steps of forming a catalyst precursor by depositing on titanium dioxide catalyst solids in the anatase form a continuous monolayer amount of at least one source of titanium oxide, calcining the thus-formed catalyst percursor under conditions sufficient to convert the titanium oxide source into the oxide form, depositing upon the calcined catalyst precursor a continuous monolayer amount of at least one vanadium compound which is convertible into vanadium oxide upon heating and calcining the vanadium-deposited solids under conditions sufficient to convert the vanadium compound into vanadium oxide.
摘要翻译：根据本发明的方法，通过以下步骤制备用于分子氧化烃形成相应的羧酸酐的改进的催化剂：通过在锐钛矿上沉积二氧化钛催化剂固体形成连续单层量的至少一种氧化钛来源，在足以将氧化钛源转化为氧化物形式的条件下煅烧由此形成的催化剂过氧化物，在煅烧的催化剂前体上沉积连续的单层量的至少一种可转化为氧化钒的钒化合物在足以将钒化合物转化为氧化钒的条件下加热和煅烧钒沉积固体。

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