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1. 发明授权

US6022095A Curable compositions 有权
标题翻译：可固化组合物
公开(公告)号：US6022095A
公开(公告)日：2000-02-08
申请号：US221024
申请日：1998-12-23
申请人： Ram S. Narang , Timothy J. Fuller , Thomas W. Smith , David J. Luca , Ralph A. Mosher
发明人： Ram S. Narang , Timothy J. Fuller , Thomas W. Smith , David J. Luca , Ralph A. Mosher
IPC分类号： B41J2/16 , C08F2/46 , C08F299/02 , C08L71/00 , C08L71/08 , C08L81/06 , G03F7/038 , H01L21/027 , B41J2/015 , B41J2/04 , G01D15/18 , G03C1/72
CPC分类号： B41J2/1628 , B41J2/1604 , B41J2/1623 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1635 , B41J2/1642 , B41J2/1645 , G03F7/038 , G03F7/0388 , Y10S522/904 , Y10S522/905
摘要： Disclosed is an improved composition comprising a photopatternable polymer containing at least some monomer repeat units with photosensitivity-imparting substituents, said photopatternable polymer being of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer and a thermal ink jet printhead containing therein a layer of a crosslinked or chain extended polymer of the above formula.
摘要翻译：公开了一种改进的组合物，其包含含有至少一些具有赋予光敏性的取代基的单体重复单元的光图案化聚合物，所述光致图案化聚合物具有以下通式：其中x为0或1的整数，A为若干指定基团之一，例如 B是若干指定基团之一，例如其混合物，n为代表重复单体单元数的整数。还公开了一种用上述聚合物和热喷墨打印头制备具有上述式的交联或链延长聚合物层的热喷墨打印头的方法。

2. 发明授权

US5994425A Curable compositions containing photosensitive high performance aromatic ether polymers 失效
标题翻译：含有光敏高性能芳香族醚聚合物的固化组合物
公开(公告)号：US5994425A
公开(公告)日：1999-11-30
申请号：US705375
申请日：1996-08-29
申请人： Ram S. Narang , Timothy J. Fuller , Thomas W. Smith , David J. Luca , Ralph A. Mosher
发明人： Ram S. Narang , Timothy J. Fuller , Thomas W. Smith , David J. Luca , Ralph A. Mosher
IPC分类号： B41J2/16 , C08F2/46 , C08F299/02 , C08L71/00 , C08L71/08 , C08L81/06 , G03F7/038 , H01L21/027 , C08L63/00 , C08L71/12 , G03F7/004
CPC分类号： B41J2/1628 , B41J2/1604 , B41J2/1623 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1635 , B41J2/1642 , B41J2/1645 , G03F7/038 , G03F7/0388 , Y10S522/904 , Y10S522/905
摘要： Disclosed is an improved composition comprising a photopatternable polymer containing at least some monomer repeat units with photosensitivity-imparting substituents, said photopatternable polymer being of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer and a thermal ink jet printhead containing therein a layer of a crosslinked or chain extended polymer of the above formula.
摘要翻译：公开了一种改进的组合物，其包含含有至少一些具有赋予光敏性的取代基的单体重复单元的光图案化聚合物，所述光致图案化聚合物具有以下通式：其中x为0或1的整数，A为若干指定基团之一，例如 B是若干指定基团之一，例如其混合物，n为代表重复单体单元数的整数。还公开了一种用上述聚合物和热喷墨打印头制备具有上述式的交联或链延长聚合物层的热喷墨打印头的方法。

3. 发明授权

US06323301B1 High performance UV and heat crosslinked or chain extended polymers 失效
标题翻译：高性能UV和热交联或链延长聚合物
公开(公告)号：US06323301B1
公开(公告)日：2001-11-27
申请号：US09635913
申请日：2000-08-10
申请人： Thomas W. Smith , Timothy J. Fuller , Ram S. Narang , David J. Luca
发明人： Thomas W. Smith , Timothy J. Fuller , Ram S. Narang , David J. Luca
IPC分类号： C08F246
CPC分类号： B41J2/14032 , B41J2/14129 , B41J2202/03 , G03F7/038 , G03F7/0388 , Y10S522/904 , Y10S522/905
摘要： Disclosed is a composition comprising a polymer with a weight average molecular weight of from about 1,000 to about 100,000, said polymer containing at least some monomer repeat units with a first, photosensitivity-imparting substituent which enables crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer also containing a second, thermal sensitivity-imparting substituent which enables further crosslinking or chain extension of the polymer upon exposure to temperatures of about 140° C. and higher, wherein the first substituent is not the same as the second substituent, said polymer being selected from the group consisting of polysulfones, polyphenylenes, polyether sulfones, polyimides, polyamide imides, polyarylene ethers, polyphenylene sulfides, polyarylene ether ketones, phenoxy resins, polycarbonates, polyether imides, polyquinoxalines, polyquinolines, polybenzimidazoles, polybenzoxazoles, polybenzothiazoles, polyoxadiazoles, copolymers thereof, and mixtures thereof.
摘要翻译：公开了一种组合物，其包含重均分子量为约1,000至约100,000的聚合物，所述聚合物含有至少一些单体重复单元，其具有第一，赋予光敏性的取代基，其能够在暴露于聚合物时交联或延伸聚合物所述聚合物还含有第二个赋予热敏感性的第二取代基，该取代基在暴露于约140℃以上的温度下能够进一步交联或链延伸聚合物，其中第一取代基与第二取代基不同所述聚合物选自聚砜，聚苯醚，聚醚砜，聚酰亚胺，聚酰胺酰亚胺，聚亚芳基醚，聚苯硫醚，聚芳醚酮，苯氧基树脂，聚碳酸酯，聚醚酰亚胺，聚喹喔啉，聚喹啉，聚苯并咪唑，聚苯并恶唑，聚苯并噻唑，聚唑，共聚物的，及其混合物。

4. 发明授权

US6151042A High performance polymer compositions 有权
标题翻译：高性能聚合物组合物
公开(公告)号：US6151042A
公开(公告)日：2000-11-21
申请号：US221690
申请日：1998-12-23
申请人： Thomas W. Smith , Timothy J. Fuller , Ram S. Narang , David J. Luca
发明人： Thomas W. Smith , Timothy J. Fuller , Ram S. Narang , David J. Luca
IPC分类号： B41J2/14 , C08F2/46 , C08F2/50 , C08L101/02 , G03F7/038 , H01L21/027 , B41J2/178 , B41J2/235
CPC分类号： B41J2/14032 , B41J2/14129 , G03F7/038 , G03F7/0388 , B41J2202/03 , Y10S522/904 , Y10S522/905
摘要： Disclosed is a composition comprising a polymer with a weight average molecular weight of from about 1,000 to about 100,000, said polymer containing at least some monomer repeat units with a first, photosensitivity-imparting substituent which enables crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer also containing a second, thermal sensitivity-imparting substituent which enables further crosslinking or chain extension of the polymer upon exposure to temperatures of about 140.degree. C. and higher, wherein the first substituent is not the same as the second substituent, said polymer being selected from the group consisting of polysulfones, polyphenylenes, polyether sulfones, polyimides, polyamide imides, polyarylene ethers, polyphenylene sulfides, polyarylene ether ketones, phenoxy resins, polycarbonates, polyether imides, polyquinoxalines, polyquinolines, polybenzimidazoles, polybenzoxazoles, polybenzothiazoles, polyoxadiazoles, copolymers thereof, and mixtures thereof.
摘要翻译：公开了一种组合物，其包含重均分子量为约1,000至约100,000的聚合物，所述聚合物含有至少一些单体重复单元，其具有第一，赋予光敏性的取代基，其能够在暴露于聚合物时交联或延伸聚合物所述聚合物还含有第二个赋予热敏感度的第二取代基，其在暴露于约140℃以上的温度下能够进一步交联或链延伸聚合物，其中第一取代基与第二取代基不相同所述聚合物选自聚砜，聚苯醚，聚醚砜，聚酰亚胺，聚酰胺酰亚胺，聚亚芳基醚，聚苯硫醚，聚芳醚酮，苯氧基树脂，聚碳酸酯，聚醚酰亚胺，聚喹喔啉，聚喹啉，聚苯并咪唑，聚苯并恶唑，聚苯并噻唑，聚唑，共聚物 reof，及其混合物。

5. 发明授权

US5889077A Process for direct substitution of high performance polymers with unsaturated ester groups 失效
标题翻译：用不饱和酯基直接取代高性能聚合物的方法
公开(公告)号：US5889077A
公开(公告)日：1999-03-30
申请号：US697761
申请日：1996-08-29
申请人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
发明人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
IPC分类号： B41J2/16 , C08G65/40 , C08G65/48 , C08G75/23 , C08L71/00 , C08L71/10 , G03F7/038 , H01L21/027 , C08J3/28
CPC分类号： G03F7/038 , B41J2/1604 , B41J2/1623 , B41J2/1628 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1635 , B41J2/1642 , B41J2/1645 , C08G65/4012 , C08G65/4018 , C08G65/48 , C08G75/23 , G03F7/0388 , C08G2650/20 , C08G2650/64 , C08L2312/00 , Y10S522/904 , Y10S522/905
摘要： Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units, with (i) a formaldehyde source, and (ii) an unsaturated acid in the presence of an acid catalyst, thereby forming a curable polymer with unsaturated ester groups. Also disclosed is a process for preparing an ink jet printhead with the above polymer.
摘要翻译：公开了一种方法，其包括使通式为“IMAGE”或“IMAGE”的聚合物与其中x为0或1的整数反应，A为若干指定基团之一，例如“IMAGE”B为若干指定基团之一，例如或其混合物，n是表示重复单体单元数的整数，（i）甲醛源，和（ii）在酸存在下的不饱和酸催化剂，从而形成具有不饱和酯基的可固化聚合物。还公开了用上述聚合物制备喷墨打印头的方法。

6. 发明授权

US5761809A Process for substituting haloalkylated polymers with unsaturated ester, ether, and alkylcarboxymethylene groups 失效
标题翻译：用不饱和酯，醚和烷基羧基亚甲基取代卤代烷基化聚合物的方法
公开(公告)号：US5761809A
公开(公告)日：1998-06-09
申请号：US705479
申请日：1996-08-29
申请人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
发明人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
IPC分类号： B41J2/16 , C08G65/40 , C08G65/48 , C08L71/00 , C08L71/10 , G03F7/038 , H01L21/027 , H01R43/00 , C08G63/00 , C03C1/005
CPC分类号： B41J2/1628 , B41J2/1604 , B41J2/1623 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1642 , B41J2/1645 , C08G65/48 , G03F7/038 , G03F7/0388 , Y10T29/49401 , Y10T428/31551 , Y10T428/31794
摘要： Disclosed is a process which comprises reacting a haloalkylated aromatic polymer with a material selected from the group consisting of unsaturated ester salts, alkoxide salts, alkylcarboxylate salts, and mixtures thereof, thereby forming a curable polymer having functional groups corresponding to the selected salt. Another embodiment of the present invention is directed to a process for preparing an ink jet printhead with the curable polymer thus prepared.
摘要翻译：公开了一种方法，其包括使卤代烷基化芳族聚合物与选自不饱和酯盐，醇盐，烷基羧酸盐及其混合物的材料反应，从而形成具有与所选择的盐相应的官能团的可固化聚合物。本发明的另一个实施方案涉及用如此制备的可固化聚合物制备喷墨打印头的方法。

7. 发明授权

US6124372A High performance polymer compositions having photosensitivity-imparting substituents and thermal sensitivity-imparting substituents 失效
标题翻译：具有赋予感光性的取代基和赋予热敏感性的取代基的高性能聚合物组合物
公开(公告)号：US6124372A
公开(公告)日：2000-09-26
申请号：US705488
申请日：1996-08-29
申请人： Thomas W. Smith , Timothy J. Fuller , Ram S. Narang , David J. Luca
发明人： Thomas W. Smith , Timothy J. Fuller , Ram S. Narang , David J. Luca
IPC分类号： B41J2/14 , C08F2/46 , C08F2/50 , C08L101/02 , G03F7/038 , H01L21/027 , B41J2/015 , G03F7/004
CPC分类号： B41J2/14032 , B41J2/14129 , G03F7/038 , G03F7/0388 , B41J2202/03 , Y10S522/904 , Y10S522/905
摘要： Disclosed is a composition comprising a polymer with a weight average molecular weight of from about 1,000 to about 100,000, said polymer containing at least some monomer repeat units with a first, photosensitivity-imparting substituent which enables crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer also containing a second, thermal sensitivity-imparting substituent which enables further crosslinking or chain extension of the polymer upon exposure to temperatures of about 140.degree. C. and higher, wherein the first substituent is not the same as the second substituent, said polymer being selected from the group consisting of polysulfones, polyphenylenes, polyether sulfones, polyimides, polyamide imides, polyarylene ethers, polyphenylene sulfides, polyarylene ether ketones, phenoxy resins, polycarbonates, polyether imides, polyquinoxalines, polyquinolines, polybenzimidazoles, polybenzoxazoles, polybenzothiazoles, polyoxadiazoles, copolymers thereof, and mixtures thereof.
摘要翻译：公开了一种组合物，其包含重均分子量为约1,000至约100,000的聚合物，所述聚合物含有至少一些单体重复单元，其具有第一，赋予光敏性的取代基，其能够在暴露于聚合物时交联或延伸聚合物所述聚合物还含有第二个赋予热敏感度的第二取代基，其在暴露于约140℃以上的温度下能够进一步交联或链延伸聚合物，其中第一取代基与第二取代基不相同所述聚合物选自聚砜，聚苯醚，聚醚砜，聚酰亚胺，聚酰胺酰亚胺，聚亚芳基醚，聚苯硫醚，聚芳醚酮，苯氧基树脂，聚碳酸酯，聚醚酰亚胺，聚喹喔啉，聚喹啉，聚苯并咪唑，聚苯并恶唑，聚苯并噻唑，聚唑，共聚物 reof，及其混合物。

8. 发明授权

US6087414A Process for direct substitution of high performance polymers with unsaturated ester groups 失效
标题翻译：用不饱和酯基直接取代高性能聚合物的方法
公开(公告)号：US6087414A
公开(公告)日：2000-07-11
申请号：US221278
申请日：1998-12-23
申请人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
发明人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
IPC分类号： B41J2/16 , C08G65/40 , C08G65/48 , C08G75/23 , C08L71/00 , C08L71/10 , G03F7/038 , H01L21/027 , C08J3/28 , C08G65/38 , C08G73/06 , C08G85/00
CPC分类号： G03F7/038 , B41J2/1604 , B41J2/1623 , B41J2/1628 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1635 , B41J2/1642 , B41J2/1645 , C08G65/4012 , C08G65/4018 , C08G65/48 , C08G75/23 , G03F7/0388 , C08G2650/20 , C08G2650/64 , C08L2312/00 , Y10S522/904 , Y10S522/905
摘要： Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3##
摘要翻译：公开了一种方法，其包括使通式为的聚合物其中x为0或1的整数，A为若干指定基团之一，例如B为若干指定基团之一，例如

9. 发明授权

US5739254A Process for haloalkylation of high performance polymers 失效
公开(公告)号：US5739254A
公开(公告)日：1998-04-14
申请号：US705463
申请日：1996-08-29
申请人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Grandall
发明人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Grandall
IPC分类号： C08F8/24 , C08G65/40 , C08G65/48 , C08G75/23 , C08L71/00 , C08L71/10 , G03F7/038 , C08G8/02 , C08G14/00
CPC分类号： C08G65/48 , C08F8/24 , C08G65/40 , C08G65/4012 , C08G75/23 , G03F7/038 , G03F7/0388 , C08G2650/20 , C08L2312/00
摘要： Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units, with an acetyl halide and dimethoxymethane in the presence of a halogen-containing Lewis acid catalyst and methanol, thereby forming a haloalkylated polymer. In a specific embodiment, the haloalkylated polymer is then reacted further to replace at least some of the haloalkyl groups with photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer.

10. 发明授权

US5753783A Process for haloalkylation of high performance polymers 失效
标题翻译：高性能聚合物的卤代烷基化方法
公开(公告)号：US5753783A
公开(公告)日：1998-05-19
申请号：US920240
申请日：1997-08-28
申请人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
发明人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
IPC分类号： C08F8/24 , C08G65/40 , C08G65/48 , C08G75/23 , C08L71/00 , C08L71/10 , G03F7/038 , C08F283/00 , C08G14/00
CPC分类号： C08G65/48 , C08F8/24 , C08G65/40 , C08G65/4012 , C08G75/23 , G03F7/038 , G03F7/0388 , C08G2650/20 , C08L2312/00
摘要： Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units, with an acetyl halide and dimethoxymethane in the presence of a halogen-containing Lewis acid catalyst and methanol, thereby forming a haloalkylated polymer. In a specific embodiment, the haloalkylated polymer is then reacted further to replace at least some of the haloalkyl groups with photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer.
摘要翻译：公开了一种方法，其包括使通式为“IMAGE”或“IMAGE”的聚合物与其中x为0或1的整数反应，A为若干指定基团之一，例如“IMAGE”B为若干指定基团之一，例如或其混合物，n是表示重复单体单元数的整数，在含卤素的路易斯酸催化剂和甲醇的存在下与乙酰卤和二甲氧基甲烷反应，由此形成卤代烷基化聚合物。在一个具体实施方案中，然后使卤代烷基化的聚合物进一步反应以用感光性赋予基团代替至少一些卤代烷基。还公开了一种用上述聚合物制备热喷墨打印头的方法。

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