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1. 发明授权

US06353085B1 Method for producing polyamides 失效
标题翻译：生产聚酰胺的方法
公开(公告)号：US06353085B1
公开(公告)日：2002-03-05
申请号：US09622321
申请日：2000-08-16
申请人： Ralf Mohrschladt , Volker Hildebrandt , Gunter Pipper , Eberhard Fuchs
发明人： Ralf Mohrschladt , Volker Hildebrandt , Gunter Pipper , Eberhard Fuchs
IPC分类号： C08G6914
CPC分类号： C08G69/20 , C08G69/18
摘要： In a process for producing polyamides by polymerization of lactams in the presence of metal oxides as heterogeneous catalysts, the metal oxides are used in a form which permits mechanical removal from the reaction mixture and are removed from the reaction mixture in the course of or on completion of the polymerization.
摘要翻译：在作为非均相催化剂的金属氧化物存在下通过内酰胺聚合制备聚酰胺的方法中，金属氧化物以允许从反应混合物中机械除去并在完成过程中从反应混合物中除去的形式使用金属氧化物的聚合。

2. 发明授权

US06316588B1 Continuous preparation of polyamides from aminonitriles 有权
标题翻译：从氨基腈连续制备聚酰胺
公开(公告)号：US06316588B1
公开(公告)日：2001-11-13
申请号：US09600957
申请日：2000-07-25
申请人： Ralf Mohrschladt , Volker Hildebrandt , Eberhard Fuchs
发明人： Ralf Mohrschladt , Volker Hildebrandt , Eberhard Fuchs
IPC分类号： C08G6900
CPC分类号： C08G69/00 , C08G69/04 , C08G69/08 , C08G69/16 , C08G69/28 , C08K3/011
摘要： A continuous process for preparing a polyamide by reacting at least one aminonitrile with water comprises: (1) reacting at least one aminonitrile with water at a temperature from 90 to 400° C. and a pressure from 0.1 to 35×106 Pa in a flow tube containing a Brönsted acid catalyst selected from a beta-zeolite catalyst, a sheet-silicate catalyst or a titanium dioxide catalyst comprising from 70 to 100% by weight of anatase and from 0 to 30% by weight of rutile and in which up to 40% by weight of the titanium dioxide may be replaced by tungsten oxide to obtain a reaction mixture, (2) further reacting the reaction mixture at a temperature from 150 to 400° C. and a pressure which is lower than the pressure in step 1, in the presence of a Brönsted acid catalyst as in (1), the temperature and pressure being selected so as to obtain a first gas phase and a first liquid or a first solid phase or a mixture of first solid and first liquid phase, and the first gas phase is separated from the first liquid or the first solid phase or from the mixture of first liquid and first solid phase, and (3) admixing the first liquid or the first solid phase or the mixture of first liquid and first solid phase with a gaseous or liquid phase comprising water at a temperature from 150 to 370° C. and a pressure from 0.1 to 30×106 Pa to obtain a product mixture.
摘要翻译：通过使至少一种氨基腈与水反应制备聚酰胺的连续方法包括：（1）在90-400℃的温度和0.1至35×10 6 Pa的压力下使至少一种氨基腈与水反应，选自β-沸石催化剂，片状硅酸盐催化剂或二氧化钛催化剂的布朗斯台德酸催化剂，其包含70至100重量％的锐钛矿和0至30重量％的金红石，其中至多40重量％二氧化钛的重量可以被氧化钨代替以获得反应混合物，（2）使反应混合物在150-400℃的温度和低于步骤1的压力的压力下反应，在存在如（1）中所述的布朗斯台德酸催化剂，选择温度和压力以获得第一气相和第一液体或第一固相或第一固体和第一液相的混合物，并且第一气体相与杉木分离第一液体或第一固相或第一液体和第一固相的混合物，和（3）将第一液体或第一固相或第一液体和第一固相的混合物与包含水的气相或液相混合温度为150〜370℃，压力为0.1〜30×10 6 Pa，得到产物混合物。

3. 发明授权

US06683177B1 Process for producing caprolactam 失效
标题翻译：己内酰胺的制备方法
公开(公告)号：US06683177B1
公开(公告)日：2004-01-27
申请号：US08952208
申请日：1997-11-06
申请人： Eberhard Fuchs , Johann-Peter Melder , Werner Schnurr , Rolf Fischer
发明人： Eberhard Fuchs , Johann-Peter Melder , Werner Schnurr , Rolf Fischer
IPC分类号： C07D20108
CPC分类号： C07D201/08 , C07D223/12
摘要： A process for preparing caprolactam by reacting 6-aminocapronitrile with water in the presence of catalysts comprises using a starting mixture of 6-aminocapronitrile and the tetrahydroazepine derivative of the formula and conducting the reaction in liquid phase in the presence of a heterogeneous catalyst. Also describes a process for preparing said tetrahydroazepine derivative I and its use for preparing caprolactam and polycaprolactam.
摘要翻译：在催化剂存在下使6-氨基己腈与水反应制备己内酰胺的方法包括使用6-氨基己腈和下式的四氢氮杂衍生物的起始混合物，并在非均相催化剂存在下进行液相反应。还描述了制备所述四氢氮杂衍生物I的方法及其制备己内酰胺和聚己内酰胺的用途。

4. 发明授权

US5952493A Method of purifying .epsilon.-caprolactam 失效
标题翻译： ε-己内酰胺的纯化方法
公开(公告)号：US5952493A
公开(公告)日：1999-09-14
申请号：US202094
申请日：1998-12-09
申请人： Eberhard Fuchs
发明人： Eberhard Fuchs
IPC分类号： C07D201/08 , C07D201/16 , C07D223/10
CPC分类号： C07D201/16
摘要： Crude caprolactam is purified by reaction with a complex hydride of boron or of aluminum.
摘要翻译： PCT No.PCT / EP98 / 03098 371 1998年12月9日第 102（e）日期1998年12月9日PCT提交1997年6月13日PCT公布。公开号WO97 / 47596 日期1997年12月18日粗制己内酰胺通过与硼或铝的复合氢化物反应而纯化。

5. 发明授权

US5496941A Process for continuous purification of crude caprolactam prepared from 6-aminocapronitrile 失效
标题翻译：从6-氨基己腈制备的己内酰胺的连续纯化方法
公开(公告)号：US5496941A
公开(公告)日：1996-03-05
申请号：US375410
申请日：1995-01-18
申请人： Josef Ritz , Rolf Fischer , Werner Schnurr , Gu/ nther Achhammer , Hermann Luyken , Eberhard Fuchs
发明人： Josef Ritz , Rolf Fischer , Werner Schnurr , Gu/ nther Achhammer , Hermann Luyken , Eberhard Fuchs
IPC分类号： C07D201/08 , C07D201/16
CPC分类号： C07D201/16 , Y02P20/52
摘要： Crude capronitrile is purified by hydrogenation, subsequent treatment in an acidic medium and subsequent distillation in an alkaline medium, by a process in which(a) 6-aminocapronitrile is converted into crude caprolactam by reaction with water,(b) high boilers and low boilers are separated off from the crude caprolactam from step (a),(c) the crude caprolactam from step (b) is treated with hydrogen at from 50.degree. to 150.degree. C. and from 1.5 to 250 bar in the presence of a hydrogenation catalyst and, if desired, of a solvent to give a mixture A,(d1) mixture A in a solvent is passed, at from 30.degree. to 80.degree. C. and from 1 to 5 bar, over an ion exchanger containing terminal acid groups to give a mixture B1, or(d2) mixture A is distilled in the presence of sulfuric acid, any solvent present being removed before the addition of the sulfuric acid, to give a mixture B2, and(e) mixture B1 or mixture B2 is distilled in the presence of a base to give pure caprolactam.
摘要翻译：通过氢化纯化粗碳腈，随后在酸性介质中处理，随后在碱性介质中进行蒸馏，其中（a）通过与水反应将（a）6-氨基己腈转化为粗己内酰胺，（b）高锅炉和低锅炉与步骤（a）中的粗己内酰胺分离，（c）步骤（b）中的粗己内酰胺在氢化催化剂存在下在50-150℃和1.5-250巴下用氢处理并且如果需要，得到溶剂以得到混合物A，（d1）溶剂中的混合物A在30℃至80℃和1至5巴条件下通过含有末端酸基团的离子交换剂得到混合物B1，或（d2）在硫酸存在下蒸馏混合物A，在加入硫酸之前，除去存在的任何溶剂，得到混合物B2，并且（e）蒸馏出混合物B1或混合物B2 在碱的存在下得到纯己内酰胺。

6. 发明授权

US06198002B1 Preparation of secondary and tertiary 2-methyl-1, 5-pentanediamines 失效
标题翻译：二级和叔级2-甲基-1,5-戊二胺的制备
公开(公告)号：US06198002B1
公开(公告)日：2001-03-06
申请号：US09324715
申请日：1999-06-03
申请人： Karsten Eller , Bernd Fiege , Stefan Rittinger , Eberhard Fuchs
发明人： Karsten Eller , Bernd Fiege , Stefan Rittinger , Eberhard Fuchs
IPC分类号： C07C20948
CPC分类号： C07C211/09 , C07C209/48
摘要： A process for preparing a secondary or tertiary 2-methyl-1,5-pen-tanediamine of the formula I where R1 and R2 are H, C1-C20-alkyl, C3-C8-cycloalkyl, aryl, C7-C20-arylalkyl, where the radicals R1 and R2 may bear substituents selected from the group consisting of C1-C20-alkyl, C1-C20-alkoxy, C6-C20-aryloxy and hydroxy, and R1 and R2 are not simultaneously hydrogen, or R1 and R2 are together an unsubstituted or C1-C20-alkyl- and/or C1-C20-alkoxy-substituted C3-C7-alkylene chain which may, if desired, be interrupted by one or two O or NR3 groups, where R3 is H or C1-C20-alkyl comprises reacting 2-methylglutarodinitrile with a primary or secondary amine of the formula R1R2NH and hydrogen at from 50 to 250° C. and pressures of from 0.5 to 35 MPa in the presence of an oxidic supported catalyst comprising one or more noble metals which has been treated with hydrogen at from 50 to 300° C. for at least 0.5 hour before use. The compound 1,5-bis(dimethylamino)-2-methylpentane is also claimed.
摘要翻译：制备式I其中R 1和R 2的仲或叔2-甲基-1,5-辛烷二胺的方法是H，C 1 -C 20 - 烷基，C 3 -C 8 - 环烷基，芳基，C 7 -C 20 - 芳烷基，其中基团R 1和R 2可以具有选自C 1 -C 20 - 烷基，C 1 -C 20 - 烷氧基，C 6 -C 20 - 芳氧基和羟基的取代基，并且R 1和R 2不同时为氢，或者R 1和R 2一起为未取代或未取代的 C 1 -C 20烷基 - 和/或C 1 -C 20 - 烷氧基取代的C 3 -C 7 - 亚烷基链，如果需要，可以被一个或两个O或NR 3基团中断，其中R 3是H或C 1 -C 20烷基， - 甲基戊二腈与式R1R2NH的伯胺或仲胺和50-250℃的氢气和0.5-35MPa的压力在包含一种或多种已经用氢处理过的贵金属的氧化载体催化剂存在下在使用前至少0.5小时，从50至300℃。还要求化合物1,5-双（二甲基氨基）-2-甲基戊烷。

7. 发明授权

US6153748A Method for hydrogenating compounds from the group of imines or enamines 失效
标题翻译：从亚胺或烯胺类中氢化化合物的方法
公开(公告)号：US6153748A
公开(公告)日：2000-11-28
申请号：US367069
申请日：1999-08-09
申请人： Eberhard Fuchs , Frank Ohlbach
发明人： Eberhard Fuchs , Frank Ohlbach
IPC分类号： B01J23/44 , C07D295/02 , C07D295/023 , C07D223/02 , C07C253/34 , C07C255/24
CPC分类号： C07D295/023
摘要： A process for hydrogenating a compound in the group of the imines or enamines I to an amine II in the presence of a nitrile III, said nitrile III being essentially not hydrogenated comprises reacting a mixture comprising a compound I and a nitrile III with a gas comprising molecular hydrogen in the presence of a catalyst IV.
摘要翻译： PCT No.PCT / EP98 / 00414 Sec。 371日期1999年8月9日 102（e）日期1999年8月9日PCT提交1998年1月26日PCT公布。第WO98 / 34899号公报日期1998年8月13日在腈III存在下氢化亚胺中的化合物或使胺I化合到胺II上的方法，所述腈III基本上未氢化，包括将包含化合物I和腈 III在催化剂IV存在下具有包含分子氢的气体。

8. 发明授权

US5502185A Preparation of lactams 失效
标题翻译：内酰胺的制备
公开(公告)号：US5502185A
公开(公告)日：1996-03-26
申请号：US358413
申请日：1994-12-19
申请人： Eberhard Fuchs , Tom Witzel
发明人： Eberhard Fuchs , Tom Witzel
IPC分类号： C07D201/08
CPC分类号： C07D201/08 , Y02P20/52
摘要： Cyclic lactams are prepared by reacting an aminocarboxylic acid compound of the formula IH.sub.2 N--(CH.sub.2).sub.m --COR.sup.1 Iwhere R.sup.1 is --OH, --O--C.sub.1 -C.sub.12 -alkyl or --NR.sup.2 R.sup.3 and R.sup.2 and R.sup.3, independently of one another, are each hydrogen, C.sub.1 -C.sub.12 -alkyl or C.sub.5 -C.sub.8 -cycloalkyl and m is an integer from 3 to 12, with water by a process in which the reaction is carried out in the liquid phase using a heterogeneous catalyst.
摘要翻译：环状内酰胺是通过使式ⅠH2N-（CH2）m-COR1I的氨基羧酸化合物，其中R1是-OH，-O-C1-C12-烷基或-NR2R3，R2和R3彼此独立地进行反应，各自为氢，C 1 -C 12 - 烷基或C 5 -C 8 - 环烷基，m为3至12的整数，通过使用多相催化剂在液相中进行反应的方法与水反应。

9. 发明授权

US5495014A Preparation of caprolactam 失效
标题翻译：己内酰胺的制备
公开(公告)号：US5495014A
公开(公告)日：1996-02-27
申请号：US358412
申请日：1994-12-19
申请人： Eberhard Fuchs , Tom Witzel
发明人： Eberhard Fuchs , Tom Witzel
IPC分类号： C07D201/12
CPC分类号： C07D201/12
摘要： Caprolactam is prepared by cleaving oligomers or polymers containing essentially the repeating unit --[--N(H)-(CH.sub.2).sub.5 --C(O)--]- in the presence of a catalyst at elevated temperatures by a process in which the cleavage is carried out in the liquid phase in the presence of a heterogeneous catalyst and of an organic solvent.
摘要翻译：己内酰胺通过在催化剂存在下在升高的温度下裂解基本上含有重复单元 - [ - N（H） - （CH 2）5 -C（O） - ] - 的低聚物或聚合物来制备，在非均相催化剂和有机溶剂的存在下在液相中进行。

10. 发明授权

US5463130A Preparation of peralkylated amines 失效
标题翻译：全烷基化胺的制备
公开(公告)号：US5463130A
公开(公告)日：1995-10-31
申请号：US395596
申请日：1995-02-28
申请人： Tom Witzel , Eberhard Fuchs , Horst Zimmermann
发明人： Tom Witzel , Eberhard Fuchs , Horst Zimmermann
IPC分类号： B01J23/44 , B01J23/58 , B01J23/63 , C07B61/00 , C07C209/48 , C07C209/60 , C07C211/09 , C07C213/02 , C07C215/08 , C08G18/18 , C08G59/68
CPC分类号： C07C209/48 , C08G18/1808 , C08G18/1825 , C08G59/686
摘要： A process for the preparation of peralkylated amines of the general formula I ##STR1## in which R.sup.1, R.sup.2 denote C.sub.1 -C.sub.200 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.4 -C.sub.20 alkylcycloalkyl, C.sub.4 -C.sub.20 cycloalkylalkyl, C.sub.2 -C.sub.20 alkoxyalkyl, aryl, C.sub.7 -C.sub.20 alkylaryl, C.sub.7 -C.sub.20 aralkyl, C.sub.2 -C.sub.8 hydroxyalkyl, C.sub.2 -C.sub.8 mercaptoalkyl, C.sub.8 -C.sub.20 phenoxyalkyl, C.sub.2 -C.sub.8 aminoalkyl, C.sub.2 -C.sub.8 (NHR.sup.4)alkyl, C.sub.2 -C.sub.8 (NR.sup.4 R.sup.5)alkyl or together form a saturated or unsaturated C.sub.2 -C.sub.6 alkylene chain optionally mono- to tri-substituted by C.sub.1 -C.sub.4 alkyl and optionally interrupted by oxygen or nitrogenX denotes a C.sub.2 -C.sub.20 alkylene or C.sub.2 -C.sub.20 alkenylene or C.sub.4 -C.sub.8 cycloalkylene chain optionally mono- to penta-substituted by R.sup.3, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.1 -C.sub.8 dialkylamino, phenoxy, diphenylamino and/or C.sub.2 -C.sub.8 alkoxycarbonyl,A denotes hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.4 -C.sub.20 alkylcycloalkyl, C.sub.4 -C.sub.20 cycloalkylalkyl, C.sub.2 -C.sub.20 alkoxyalkyl, aryl, C.sub.7 -C.sub.20 alkylaryl, C.sub.7 -C.sub.20 aralkyl, C.sub.1 -C.sub.20 alkoxy, hydroxy, C.sub.1 -C.sub.20 hydroxyalkyl, amino, C.sub.1 -C.sub.20 alkylamino, C.sub.2 -C.sub.20 dialkylamino, C.sub.3 -C.sub.12 alkenyleneamino, C.sub.3 -C.sub.8 cycloalkylamino, arylamino, aryl-C.sub.1 -C.sub.12 alkylamino, halogen, mercapto, C.sub.2 -C.sub.20 alkenylenoxy, C.sub.3 -C.sub.8 cycloalkoxy and aryloxyR.sup.3 denotes CH.sub.2 --NR.sup.1 R.sup.2,R.sup.4, R.sup.5 denote C.sub.1 -C.sub.20 alkylby the reaction of a nitrile of the general formula IIA--X--CN (II),in which R.sup.1, R.sup.2, R.sup.4, R.sup.5, X and A have the aforementioned meanings and R.sup.3 stands for --CH.sub.2 --NR.sup.1 R.sup.2 or cyano, with a secondary amine of the general formula III ##STR2## and hydrogen at temperatures ranging from 50.degree. to 250.degree. C. and pressures ranging from 5 to 350 bar in the presence of a catalyst, wherein the catalyst used is palladium on an oxidic support.
摘要翻译：制备通式I（I）的全烷基胺的方法，其中R 1，R 2表示C 1 -C 20烷基，C 3 -C 8环烷基，C 4 -C 20烷基环烷基，C 4 -C 20环烷基烷基，C 2 -C 20烷氧基烷基，芳基，C 7 -C 20烷基芳基 C 7 -C 20烷基，C 2 -C 8羟烷基，C 2 -C 8巯基烷基，C 8 -C 20苯氧烷基，C 2 -C 8氨基烷基，C 2 -C 8（NHR 4）烷基，C 2 -C 8（NR 4 R 5）烷基或一起形成饱和或不饱和的C 2 -C 6亚烷基链，被C1-C4烷基三取代并且任选地被氧或氮中断X表示任选被R 3，C 1 -C 8烷基，C 1 -C 8烷氧基，C 1 -C 8烷氧基取代的C 2 -C 20亚烷基或C 2 -C 20亚烯基或C 4 -C 8亚烷基链， C 2 -C 20烷基氨基，苯氧基，二苯基氨基和/或C 2 -C 8烷氧基羰基，A表示氢，C 1 -C 20烷基，C 3 -C 8环烷基，C 4 -C 20烷基环烷基，C 4 -C 20环烷基烷基，C 2 -C 20烷氧基烷基，芳基，C 7 -C 20烷基芳基，C 7 -C 20芳烷基，C 1 -C 20烷氧基，羟基，C 1 -C 20羟烷基，氨基，C 1 -C 20烷基氨基，C 2 -C 20二烷基氨基，C 3 -C 12亚烯基氨基， C 3 -C 8环烷基氨基，芳基氨基，芳基-C 1 -C 12烷基氨基，卤素，巯基，C 2 -C 20烯基烯氧基，C 3 -C 8环烷氧基和芳氧基R 3表示CH 2 -NR 1 R 2，R 4，R 5表示通过通式II的腈反应的C 1 -C 20烷基 -CN（II），其中R1，R2，R4，R5，X和A具有上述含义，R3代表-CH2-NR1R2或氰基，与通式III的仲胺（III）和氢气在50至250℃的温度和5至350巴的压力范围内，在催化剂存在下，其中使用的催化剂是氧化载体上的钯。

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