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1. 发明授权

US08865843B2 Fluorinated sag control agent and use thereof 有权
标题翻译：氟化松弛控制剂及其用途
公开(公告)号：US08865843B2
公开(公告)日：2014-10-21
申请号：US13496224
申请日：2010-09-16
申请人： Rajesh Gopalan Saliya , Ayumu Yokoyama , Sheau-Hwa Ma , Axel Hans-Joachim Herzog
发明人： Rajesh Gopalan Saliya , Ayumu Yokoyama , Sheau-Hwa Ma , Axel Hans-Joachim Herzog
IPC分类号： C08G18/00 , C08G18/28 , C08G75/00 , B05D3/00
CPC分类号： C07C319/20 , C08G18/3814 , C08G18/6229 , C08G18/73 , C08G18/792 , C08K5/21 , C09D7/43 , C09D7/47 , C09D7/63 , C09D167/00 , C09D175/04 , Y10T428/269 , Y10T428/31855 , C07C323/41
摘要： The present disclosure is directed to a sag control agent comprising a reaction product of an isocyanate and a fluorinated amine. This disclosure is further directed to a coating composition comprising the sag control agent. This disclosure is also directed to a process of forming a sag-free coating layer on a substrate.
摘要翻译：本公开涉及包含异氰酸酯和氟化胺的反应产物的流挂控制剂。本公开进一步涉及包含松弛控制剂的涂料组合物。本公开还涉及在基材上形成无卷曲涂层的方法。

2. 发明申请

US20120171478A1 FLUORINATED SAG CONTROL AGENT AND USE THEREOF 有权
标题翻译：氟化SAG控制剂及其用途
公开(公告)号：US20120171478A1
公开(公告)日：2012-07-05
申请号：US13496224
申请日：2010-09-16
申请人： Rajesh Gopalan Saliya , Ayumu Yokoyama , Sheau-Hwa Ma , Axel Hans-Joachim Herzog
发明人： Rajesh Gopalan Saliya , Ayumu Yokoyama , Sheau-Hwa Ma , Axel Hans-Joachim Herzog
IPC分类号： B32B27/18 , C08K5/16 , B05D3/00 , C09D167/00 , C09D171/08 , B05D5/00 , C07C265/14 , C09D133/00
CPC分类号： C07C319/20 , C08G18/3814 , C08G18/6229 , C08G18/73 , C08G18/792 , C08K5/21 , C09D7/43 , C09D7/47 , C09D7/63 , C09D167/00 , C09D175/04 , Y10T428/269 , Y10T428/31855 , C07C323/41
摘要： The present disclosure is directed to a sag control agent comprising a reaction product of an isocyanate and a fluorinated amine. This disclosure is further directed to a coating composition comprising the sag control agent. This disclosure is also directed to a process of forming a sag-free coating layer on a substrate.
摘要翻译：本公开涉及包含异氰酸酯和氟化胺的反应产物的流挂控制剂。本公开进一步涉及包含松弛控制剂的涂料组合物。本公开还涉及在基材上形成无卷曲涂层的方法。

3. 发明授权

US08420826B2 Fluoroalkyl silanes 有权
标题翻译：氟烷基硅烷
公开(公告)号：US08420826B2
公开(公告)日：2013-04-16
申请号：US13242365
申请日：2011-09-23
申请人： Axel Hans-Joachim Herzog , Gerald Oronde Brown
发明人： Axel Hans-Joachim Herzog , Gerald Oronde Brown
IPC分类号： C07D231/00 , C07F7/04
CPC分类号： C07F7/1804
摘要： The present invention is directed to a fluorosilane represented by (L)3-Si—(CH2)n—(Z1)a—[C(X1)]x—(Z2)l-Q1-Rf where each n is independently an integer from 1 to 12; L is independently chosen from a hydrolysable or non-hydrolysable monovalent group; Rf is chosen from a C2-C12 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl can be optionally replaced by hydrogen, and/or ii) the perfluoroalkyl can be optionally interrupted by at least one oxygen, methylene, or ethylene; Q1 is chosen from the group consisting of a C2-C12 hydrocarbylene optionally interrupted by at least one divalent organic group; X1 is chosen from O or S; —Z2 is —NH— and Z1 is from the group consisting of —O—, and —S—; each R1 is independently chosen from hydrogen, phenyl, or a monovalent C1-C8 alkyl optionally terminated by —C6H5, preferably H or CH3.
摘要翻译：本发明涉及由（L）3-Si-（CH2）n-（Z1）a- [C（X1）] x-（Z2）1-Q1-Rf表示的氟硅烷，其中每个n独立地为整数从1到12; L独立地选自可水解或不可水解的一价基团; Rf选自C 2 -C 12全氟烷基，条件是：i）全氟烷基的一个氟原子可以任选被氢替代，和/或ii）全氟烷基可以任选被至少一个氧，亚甲基或亚乙基所取代; Q1选自任选被至少一个二价有机基团中断的C 2 -C 12亚烃基; X1选自O或S; -Z 2为-NH-，Z 1为-O-和-S-; 每个R 1独立地选自氢，苯基或任选被-C 6 H 5，优选H或CH 3终止的一价C 1 -C 8烷基。

4. 发明申请

US20120022267A1 FLUOROALKYL SILANES 有权
标题翻译：氟烷基硅烷
公开(公告)号：US20120022267A1
公开(公告)日：2012-01-26
申请号：US13242434
申请日：2011-09-23
申请人： Axel Hans-Joachim Herzog , Gerald Oronde Brown
发明人： Axel Hans-Joachim Herzog , Gerald Oronde Brown
IPC分类号： C07F7/18
CPC分类号： C07F7/1804
摘要： The present invention is directed to a fluorosilane represented by (L)3-Si—(CH2)n—N(-Q3-Rf)-Q1-Rf where each n is independently an integer from 1 to 12; L is independently chosen from a hydrolysable or non-hydrolysable monovalent group Rf is chosen from a C2-C12 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl can be optionally replaced by hydrogen, and/or ii) the perfluoroalkyl can be optionally interrupted by at least one oxygen, methylene, or ethylene; Q1 is chosen from the group consisting of a C2-C12 hydrocarbylene optionally interrupted by at least one divalent organic group; X1 is chosen from O or S; and b) Q1 and Q3 are independently chosen from the group consisting of a C2-C12 hydrocarbylene interrupted by at least one of —C(O)—O— or —O—C(O)—, and optionally further interrupted by at least one divalent organic group.
摘要翻译：本发明涉及由（L）3-Si-（CH2）n-N（-Q3-Rf）-Q1-Rf表示的氟硅烷，其中每个n独立地为1至12的整数; L独立地选自可水解或不可水解的一价基团，Rf选自C 2 -C 12全氟烷基，条件是：i）全氟烷基的一个氟原子可任选被氢替代，和/或ii）全氟烷基可任选地被至少一个氧，亚甲基或乙烯中断; Q1选自任选被至少一个二价有机基团中断的C 2 -C 12亚烃基; X1选自O或S; 和b）Q1和Q3独立地选自被-C（O）-O-或-O-C（O） - 中的至少一个间隔的C 2 -C 12亚烃基，并且任选进一步被至少中断一个二价有机基团。

5. 发明授权

US07964552B2 Fluorosurfactant with disproportionate effect 失效
标题翻译：含氟表面活性剂具有不成比例的作用
公开(公告)号：US07964552B2
公开(公告)日：2011-06-21
申请号：US11983858
申请日：2007-11-13
申请人： Axel Hans-Joachim Herzog , Shaun Raymond Rinehimer
发明人： Axel Hans-Joachim Herzog , Shaun Raymond Rinehimer
IPC分类号： C11D3/37 , D06M15/263 , C07C43/00 , A61K8/72
CPC分类号： C09D11/03 , C09D7/47 , C09D11/38
摘要： This invention relates to surfactant compositions comprising a fluorosurfactant and a siloxane surfactant wherein the fluorosurfactant exhibits a disproportionate effect upon the resulting surfactant composition's ability to lower equilibrium surface tension. The fluorosurfactants and siloxane surfactants identified by the present invention exhibit a desirable disproportionate effect from the fluorosurfactant acting upon the resulting surfactant composition's ability to lower equilibrium surface tension. Because of this disproportionate effect, surfactant compositions of the present invention with no more than 21 weight percent fluorosurfactant have nearly identical ability to lower equilibrium surface tensions compared with surfactant compositions having higher amounts of fluorosurfactant. Such a disproportionate effect is desirable because it permits the use of lower amounts of the more costly fluorosurfactant and higher amounts of the less costly siloxane without significantly deteriorating equilibrium surface tension.
摘要翻译：本发明涉及包含含氟表面活性剂和硅氧烷表面活性剂的表面活性剂组合物，其中氟表面活性剂对所得表面活性剂组合物降低平衡表面张力的能力表现出不成比例的影响。由本发明鉴定的含氟表面活性剂和硅氧烷表面活性剂表现出对所得表面活性剂组合物降低平衡表面张力的能力的氟表面活性剂的所需不成比例的影响。由于这种不成比例的影响，具有不超过21重量％含氟表面活性剂的本发明的表面活性剂组合物与具有较高量的含氟表面活性剂的表面活性剂组合物相比，具有几乎相同的降低平衡表面张力的能力。这种不成比例的效果是期望的，因为它允许使用较少量的更昂贵的含氟表面活性剂和更高量的较低成本的硅氧烷，而不会显着降低平衡表面张力。

6. 发明授权

US08153834B2 Surface modified inorganic particles 有权
标题翻译：表面改性无机颗粒
公开(公告)号：US08153834B2
公开(公告)日：2012-04-10
申请号：US12328122
申请日：2008-12-04
申请人： Gerald Oronde Brown , Axel Hans-Joachim Herzog
发明人： Gerald Oronde Brown , Axel Hans-Joachim Herzog
IPC分类号： C07F7/04 , C07D231/00
CPC分类号： C09C3/12 , C01P2002/86 , C09C1/043 , C09C1/3081 , C09C1/3684 , C09C1/407 , Y10T428/2991
摘要： The present invention relates to particles, i.e., oxides of Si, Ti, Zn, Zr, Mn, Al and combinations thereof, where at least one particle has a surface covalently bonded to at least one fluorosilane group. The particle is first bonded to a divalent organic linking group which in turn is bonded to a perfluoroalkyl group. It has been discovered that incorporation of the aforementioned divalent organic linking group can improve the ability of the resulting hydrophobized inorganic particles to impart hydrophobic and oleophobic properties.
摘要翻译：本发明涉及其中至少一个颗粒具有与至少一个氟硅烷基团共价键合的表面的Si，Ti，Zn，Zr，Mn，Al及其组合的颗粒。该颗粒首先与二价有机连接基团键合，二价有机连接基团又与全氟烷基键合。已经发现，引入上述二价有机连接基团可以提高所得疏水化无机颗粒赋予疏水性和疏油性的能力。

7. 发明申请

US20080145552A1 Fluorochemical and polyoxyalkylene siloxane additive for coatings 审中-公开
公开(公告)号：US20080145552A1
公开(公告)日：2008-06-19
申请号：US11899238
申请日：2007-09-05
申请人： Mia Genevieve Berrettini , Axel Hans-Joachim Herzog , John Gavenonis , Donald Douglas May , Xianjun Meng
发明人： Mia Genevieve Berrettini , Axel Hans-Joachim Herzog , John Gavenonis , Donald Douglas May , Xianjun Meng
IPC分类号： B05D3/00 , C08K5/5419
CPC分类号： C09D5/024 , C09D7/47
摘要： Coating compositions comprise a coating base, a polyoxyalkylene siloxane additive and a fluorochemical wherein the polyoxyalkylene siloxane is of Formulae 1A, 1B, 1C, or 2: (R2)3SiO[Si(R2)2O]y[Si(R2)(R1)O]x[Si(R2)2O]zSi(R2)3Formula 1A (R2)3SiO[Si(R2)2O]x[Si(R2)2R1Formula 1B R1(R2)2SiO[Si(R2)2O]x[Si(R2)2O]Si(R2)2R1Formula 1C wherein each R2 is independently H, alkyl, or aryl; each R1 is a polyoxyalkylene group having the formula 3 as follows: —CnR4pH2n−pQCmR5pH2m−pOZR3Formula 3 wherein each R4 and R5 is independently H, alkyl, or aryl; Q is CnHR4, aryl, CH2CH(OR4), CH2(CH2OR4), S, O, SO, SO2, SO2NR4, OC(O), OC(NR4), NHC(X)NH, or OC(X)NH or triazole; Z is [C2H4O]a and [C3H6O]b in block or random order; X is O or S; m and n are each independently an integer of 2 to 8; a is an integer of 0 to about 30; b is an integer of 0 to about 20; provided that a+b is from 1 to about 50; each R3 is independently H, acyl, CH3, or a linear or branched alkyl or aryl group having 1 to about 20 carbon atoms; w is an integer of from 1 to 3; x is an integer of from 1 to about 20; y is an integer of from 0 to about 20; and z is an integer of from 0 to about 10; and the fluorochemical is selected from the group consisting of a perfluoroalkyl ester, fluorinated urethane, fluoroalkyl phosphate or salt thereof, fluoroalkyl phosphate ester or salt thereof, a mixture of a fluoroalkyl phosphate and a glycol ester, and fluoroalkylpolyoxyethylene.

8. 发明授权

US07638589B2 Triazole-containing fluorocarbon-grafted polysiloxanes 失效
标题翻译：含三氟乙烯的氟碳接枝聚硅氧烷
公开(公告)号：US07638589B2
公开(公告)日：2009-12-29
申请号：US11311077
申请日：2005-12-19
申请人： Erick Jose Acosta , Axel Hans-Joachim Herzog , Martial Jean-Jacques Pabon
发明人： Erick Jose Acosta , Axel Hans-Joachim Herzog , Martial Jean-Jacques Pabon
IPC分类号： C08G77/08
CPC分类号： C08G77/26 , C08G77/24 , C08G77/388 , Y10T428/31663
摘要： A polymer for imparting repellency and stain resistance to substrates is disclosed of Formula 1: (W)a(R2)bSi(R1)2—O—[Si(R1)2—O]n—[Si(W)c(R1)d(R2)e—O]m—Si(R1)2—(W)f(R2)g 1 wherein: a, b, c, d, e, f and g are each independently 0 or 1, provided that (a+b) is 1, (f+g) is 1, and (c+d+e) is 2, each R1 is a C1 to C8 alkyl, each R2 is independently H or C1 to C8 alkyl, optionally containing oxygen, nitrogen, or sulfur, or a combination thereof, and n=0 to 500, m=1 to 100, each W is independently (Rf—X—A—X)p—Y—X— wherein: Rf is a straight or branched perfluoroalkyl group having from about 2 to about 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, each X is independently an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing oxygen, nitrogen, or sulfur, or a combination thereof, A is a 1,2,3-triazole, p=1 to 2, Y is O, N, or NR wherein R is H or C1 to C20 alkyl, optionally containing oxygen, nitrogen, or sulfur, or a combination thereof.
摘要翻译：式（1）公开了：（W）a（R2）bSi（R1）2-O- [Si（R1）2-O] n- [Si（W）c（R1））d（R2）eO] m-Si（R1）2-（W）f（R2）g1其中：a，b，c，d，e，f和g各自独立地为0或1，条件是（a + b）为1，（f + g）为1，（c + d + e）为2，每个R 1为C 1至C 8烷基，每个R 2独立地为H或C 1至C 8烷基，任选地含有氧，氮，或硫，或其组合，n = 0〜500，m = 1〜100，各W独立地为（Rf-XAX）pYX-，其中：Rf为直链或支链的全氟烷基，其具有约2至约20 碳原子或其混合物，其任选被至少一个氧原子间隔，每个X独立地为具有约1至约20个碳原子的有机二价连接基团，任选地含有氧，氮或硫，或组合其中A为1,2,3-三唑，p = 1至2，Y为O，N或NR，其中R为H或C 1至C 20烷基，任选含有氧，硝基烯或硫，或其组合。

9. 发明申请

US20090148654A1 FLUOROPOLYMER COMPOSITIONS AND TREATED SUBSTRATES 审中-公开
标题翻译：氟聚合物组合物和处理的基材
公开(公告)号：US20090148654A1
公开(公告)日：2009-06-11
申请号：US12268766
申请日：2008-11-11
申请人： Gerald Oronde Brown , Axel Hans-Joachim Herzog , Timothy Edward Hopkins
发明人： Gerald Oronde Brown , Axel Hans-Joachim Herzog , Timothy Edward Hopkins
IPC分类号： B32B33/00 , C08L75/04 , B32B27/40 , B32B27/36 , B32B27/30 , B32B27/32 , B32B27/34 , C08L83/06
CPC分类号： C08G18/2885 , C08G18/3895 , C08G18/8087 , D06M11/44 , D06M11/45 , D06M11/46 , D06M11/485 , D06M11/79 , D06M15/576 , D06M23/08 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/2933 , Y10T428/2969 , Y10T428/31504 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31583 , Y10T442/2172
摘要： A composition comprising a polymer prepared by: reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf1-L-X (I) whereinRf1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having 2 to 100 carbon atoms; optionally interrupted by 1 to 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least 2:1 and no oxygen atoms are bonded to each other;L is a bond or a linear or branched divalent linking group having 1 15 to 20 carbon atoms, said linking group optionally interrupted by 1 to 4 hetero-radicals selected from the group consisting or —O—, —NR—, —S—, —SO—, —SO2—, —N(R)C(O)— wherein R is H or C1-C6 alkyl, and said linking group optionally substituted with CH2Cl;X is an isocyanate-reactive group selected from the group consisting of —OH, —N(R)H, and —SH wherein R is H or C1-C6 alkyl;and thereafter reacting with (c) water and (d) an isocyanate-reactive non-fluorinated particulate component.
摘要翻译：一种包含聚合物的组合物，其通过：（a）至少一种具有异氰酸酯基团的二异氰酸酯，多异氰酸酯或其混合物，和（b）至少一种选自式（I）的氟化化合物：公式描述=“在线公式”end =“lead”？> Rf1-LX（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Rf1是一价，具有2至100个碳原子的部分或完全氟化的直链或支链烷基; 任选地被1至50个氧原子中断; 其中碳原子与氧原子的比例为至少2:1，并且没有氧原子彼此键合; L是具有15至20个碳原子的键或直链或支链二价连接基团，所述连接基团任选被1-4个选自-O - ， - NR - ， - S - -SO - ， - SO 2 - ， - N（R）C（O） - ，其中R是H或C 1 -C 6烷基，所述连接基团任选地被CH 2 Cl取代; X是选自-OH，-N（R）H和-SH的异氰酸酯反应性基团，其中R是H或C 1 -C 6烷基; 然后与（c）水和（d）异氰酸酯反应性非氟化颗粒组分反应。

10. 发明申请

US20090143608A1 SULFUR CONTAINING FLUOROALKYL AMINES AND ISOCYANATES 失效
标题翻译：含有氟代氨基甲酸酯和异氰酸酯的硫磺
公开(公告)号：US20090143608A1
公开(公告)日：2009-06-04
申请号：US12273091
申请日：2008-11-18
申请人： Axel Hans-Joachim Herzog , Hollis Thomas Warren , Brent Ryan Gonska
发明人： Axel Hans-Joachim Herzog , Hollis Thomas Warren , Brent Ryan Gonska
IPC分类号： C07C255/10 , C07C315/00 , C07C317/28
CPC分类号： C07C315/02 , C07C317/28 , C07C319/16 , C07C319/18 , C07C319/20 , C07C323/25 , C07C331/20 , C07D207/27 , C07C323/41
摘要： The present invention provides a method of making sulfur containing fluoroalkyl amines which overcomes the problems previously known methods. Unlike previously known methods, the method of the present invention can achieve higher yields of sulfur containing fluoroalkyl amines without resorting to costly solvents. Furthermore, unlike previously known methods, the method of the present invention can produce oxidized forms of sulfur containing fluoroalkyl amines wherein the sulfur atom thereof is oxidized.
摘要翻译：本发明提供一种制备含硫氟烷基胺的方法，其克服了以前已知方法的问题。与先前已知的方法不同，本发明的方法可以实现更高产率的含硫氟烷基胺，而不需要使用昂贵的溶剂。此外，与以前已知的方法不同，本发明的方法可以产生其硫原子被氧化的含氧氟烷基胺的氧化形式。

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