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    • 8. 发明授权
    • Paint and coating remover
    • 油漆和涂料去除剂
    • US06169061A
    • 2001-01-02
    • US09335596
    • 1999-06-18
    • James R. Machac, Jr.Edward T. MarquisSusan A. Woodrum
    • James R. Machac, Jr.Edward T. MarquisSusan A. Woodrum
    • C11D718
    • C11D3/2093C09D9/00C11D3/3947C11D3/43C11D7/263C11D7/264
    • This invention concerns a composition useful as a paint remover, comprising: alkylene carbonate such as propylene carbonate or ethylene carbonate, hydrogen peroxide, and water, and optionally an alcohol such as benzyl alcohol. In another broad respect, his invention concerns a process for removing paint, comprising: applying a composition containing alkylene carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. In another broad respect, this invention is a composition useful as a paint remover, comprising: dialkyl carbonate, hydrogen peroxide, and water, optionally containing an alcohol, optionally containing a glycol ether. In another broad respect, this invention is a process for removing paint, comprising: applying a composition containing dialkyl carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. Advantageously, the composition of this invention may include a dibasic ester (DBE).
    • 本发明涉及可用作除漆剂的组合物,其包括:碳酸亚烃酯如碳酸亚丙酯或碳酸亚乙酯,过氧化氢和水,以及任选的醇如苄醇。 在另一个广泛的方面,他的发明涉及一种除去油漆的方法,其包括:将含有碳酸亚烷基酯,过氧化氢和水的组合物在有效引起油漆起泡或起泡的条件下,一段时间和在有条件的条件下涂覆到涂漆表面上。 在另一个广泛的方面,本发明是一种可用作除漆剂的组合物,其包括:任选含有任选含有二醇醚的醇的碳酸二烷基酯,过氧化氢和水。 在另一个广泛的方面,本发明是一种除去油漆的方法,其包括:将含有碳酸二烷基酯,过氧化氢和水的组合物在有效引起油漆起泡或起泡的条件下,一段时间和时间施加到涂漆表面上。 有利地,本发明的组合物可以包括二元酯(DBE)。
    • 10. 发明授权
    • Process for the production of carbonates that melt at a high temperature
    • 用于生产在高温下熔化的碳酸酯的方法
    • US06515145B2
    • 2003-02-04
    • US09752118
    • 2000-12-29
    • James R. Machac, Jr.Edward T. MarquisHoward P. Klein
    • James R. Machac, Jr.Edward T. MarquisHoward P. Klein
    • C07D31712
    • C07C68/04Y02P20/142C07C69/96
    • A method for preparing carbonates includes reacting an alkylene oxide with carbon dioxide in the presence of a catalyst and a non-protic solvent. The method further includes having the boiling point of the solvent greater than about 70 ° C., and removing the solvent from the reaction product. The solvent used in the various forms of the present invention can be glyme, diglyme, tetraglyme, cumene, toluene, tetrahydofuran, cyclohexanone, ethylbenzene, aromatic hydrocarbons, or ethers. The catalyst used can be a tetraalkyl ammonium halide, such as tetraethyl ammonium bromide. The alkylene oxide that can be used in the invention can include Bisphenol A, Bisphenol B, Bisphenol F, alkylene oxides that have alkyl substituent groups, alkylene oxides that have aryl substituent groups, and alkylene oxides that contain both alkyl and aryl substituent groups. An essentially solvent free carbonate can be prepared by flash removal of the solvent.
    • 制备碳酸酯的方法包括在催化剂和非质子溶剂的存在下使烯化氧与二氧化碳反应。 该方法还包括使溶剂的沸点大于约70℃,并从反应产物中除去溶剂。 用于本发明各种形式的溶剂可以是甘醇二甲醚,二甘醇二甲醚,四甘醇二甲醚,枯烯,甲苯,四氢呋喃,环己酮,乙苯,芳烃或醚。 所使用的催化剂可以是四烷基卤化铵,例如四乙基溴化铵。 可用于本发明的环氧烷可以包括双酚A,双酚B,双酚F,具有烷基取代基的烯化氧,具有芳基取代基的烯化氧和含有烷基和芳基取代基的烯化氧。 可以通过快速除去溶剂来制备基本上无溶剂的碳酸盐。