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1. 发明申请

US20180237573A1 POLYESTER POLYOLS FROM RECYCLED POLYMERS AND WASTE STREAMS 审中-公开
公开(公告)号：US20180237573A1
公开(公告)日：2018-08-23
申请号：US15959596
申请日：2018-04-23
申请人： RESINATE MATERIALS GROUP, INC.
发明人： Rick Tabor , Eric David Vrabel , Matthew J. Beatty , Gary E. Spilman , Kevin Anthony Rogers , Michael Robert Christy , Matthew Thomas Brown , Jack Rogers Kovsky , Woo-Sung Bae , Shakti L. Mukerjee
IPC分类号： C08G18/08 , C08G18/76 , C09D175/06 , C09D175/04 , C08G64/40 , C08G18/42 , C08G18/66 , C09D167/02 , C08G18/09 , C08J11/24 , C08G63/89 , C08G63/91 , C09D5/03 , C08F20/10 , C08G18/72 , C08G63/553 , C08J9/04 , C08G63/183 , C08G18/44 , C09D167/00 , C08J3/03 , C08G101/00
CPC分类号： C08G18/0866 , C08F20/10 , C08G18/092 , C08G18/4213 , C08G18/4288 , C08G18/44 , C08G18/664 , C08G18/722 , C08G18/7671 , C08G63/183 , C08G63/553 , C08G63/89 , C08G63/916 , C08G64/403 , C08G2101/0025 , C08G2150/20 , C08J3/03 , C08J9/04 , C08J11/24 , C08J2201/022 , C08J2205/06 , C08J2205/10 , C08J2367/02 , C08J2375/06 , C09D5/03 , C09D167/00 , C09D167/02 , C09D175/04 , C09D175/06 , Y02W30/706
摘要： The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

2. 发明授权

US10030099B2 Digestion of keratin 有权
公开(公告)号：US10030099B2
公开(公告)日：2018-07-24
申请号：US15084737
申请日：2016-03-30
申请人： Resinate Materials Group, Inc.
发明人： Rick Tabor , Eric David Vrabel , Matthew J Beatty , Jack Rogers Kovsky
IPC分类号： C08G18/28 , C08G63/91 , C08G63/183 , C08G18/66 , C08G18/72 , C09D175/04 , C08J11/24 , C07C29/09 , C07C31/18 , C08G18/08 , C08J9/14 , C08F20/10 , C08G18/42 , C08G18/76 , C09D5/03 , C09D175/06 , C08G101/00
摘要： The present invention relates to the chemical digestion of keratin, such as avian feathers and wool. The digestion product is made by heating the feathers or wool with a solvent selected from glycols, alkanolamines, polyamines, and combinations thereof. The resulting digested keratin product is a keratin-derived polyol useful for making polymeric materials such as polyurethanes. The digestion products provide a sustainable alternative to petrochemical based intermediates.

3. 发明申请

US20170029561A1 POLYESTER POLYOLS FROM RECYCLED POLYMERS AND WASTE STREAMS 有权
标题翻译：来自回收聚合物和废物流的聚酯多元醇
公开(公告)号：US20170029561A1
公开(公告)日：2017-02-02
申请号：US15205235
申请日：2016-07-08
申请人： Resinate Materials Group, Inc.
发明人： Rick Tabor , Eric David Vrabel , Matthew J. Beatty , Gary E. Spilman , Kevin Anthony Rogers , Michael Robert Christy , Matthew Thomas Brown , Jack Rogers Kovsky , Woo-Sung Bae , Shakti L. Mukerjee
IPC分类号： C08G63/91 , C08G18/42 , C08F20/10 , C09D175/06 , C09D5/03 , C08G18/76 , C08G63/183
CPC分类号： C08G63/916 , C07C29/09 , C07C31/18 , C08F20/10 , C08F291/08 , C08G18/14 , C08G18/28 , C08G18/4213 , C08G18/664 , C08G18/722 , C08G18/7671 , C08G63/183 , C08G2101/00 , C08G2101/0025 , C08G2150/20 , C08J9/141 , C08J11/24 , C08J2203/14 , C08J2205/10 , C08J2367/02 , C08J2375/04 , C09D5/03 , C09D167/00 , C09D175/04 , C09D175/06 , Y02W30/706
摘要： The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.
摘要翻译：本发明涉及由芳族多酸源如热塑性聚酯制成的聚酯多元醇。多元醇可以通过将热塑性聚酯如原始聚对苯二甲酸乙二醇酯，再循环的聚对苯二甲酸乙二醇酯或其混合物与二醇加热来制备，从而得到消化的中间体，然后与可消化的聚合物反应，该可消化的聚合物可以从各种循环废物流。聚酯多元醇包含二醇消化的多酸源和另外的可消化的聚合物。聚酯多元醇提供石油化学或生物化学基聚酯多元醇的可持续替代品。

4. 发明授权

US09522976B2 Cycloaliphatic polyester polyols from thermoplastic polyesters 有权
标题翻译：来自热塑性聚酯的脂环族聚酯多元醇
公开(公告)号：US09522976B2
公开(公告)日：2016-12-20
申请号：US15083491
申请日：2016-03-29
申请人： RESINATE MATERIALS GROUP, INC.
发明人： Rick Tabor , Eric David Vrabel , Matthew Beatty
IPC分类号： C08G18/42 , C08G63/91 , C09D175/06
CPC分类号： C08G63/916 , C08G18/242 , C08G18/246 , C08G18/34 , C08G18/4202 , C08G18/423 , C08G18/4233 , C08G18/4238 , C08G18/722 , C08G18/73 , C08G18/755 , C09D175/06
摘要： Cycloaliphatic polyester polyols and processes for making them from thermoplastic polyesters are disclosed. One process comprises heating a thermoplastic polyester with a glycol to give a digested intermediate and hydrogenating aromatic rings in the digested intermediate to produce the cycloaliphatic polyester polyol. Optionally, the digested intermediate is reacted with a hydrophobe to give a modified polyol prior to hydrogenation, and the modified polyol is hydrogenated to give the cycloaliphatic polyester polyol. The high-recycle-content cycloaliphatic polyester polyols have desirable attributes for formulating polyurethane dispersions, two-component polyurethane coatings, mono- or poly(meth)acrylates, polyisocyanurates, flexible and rigid foams, coatings, adhesives, sealants, and elastomers, and they provide a sustainable alternative to petrochemical-based polyols.
摘要翻译：公开了环脂族聚酯多元醇及其由热塑性聚酯制备它们的方法。一种方法包括用二醇加热热塑性聚酯以在消化的中间体中产生消化的中间体和氢化芳环以制备脂环族聚酯多元醇。任选地，将消化的中间体与疏水物反应以在氢化之前得到改性的多元醇，并将改性的多元醇氢化得到环脂族聚酯多元醇。高回收含量的脂环族聚酯多元醇具有用于配制聚氨酯分散体，双组分聚氨酯涂料，单或多（甲基）丙烯酸酯，聚异氰脲酸酯，柔性和刚性泡沫，涂料，粘合剂，密封剂和弹性体的所需属性，并且它们为石化多元醇提供可持续的替代方案。

5. 发明申请

US20190010303A1 INTEGRATED PROCESS FOR TREATING RECYCLED PET AND PTT MATERIALS 审中-公开
公开(公告)号：US20190010303A1
公开(公告)日：2019-01-10
申请号：US16127423
申请日：2018-09-11
申请人： RESINATE MATERIALS GROUP, INC.
发明人： Rick Tabor , Shakti L. Mukerjee , Kevin Rogers , Eric David Vrabel , Adam W. Emerson , Brian Douglas Phillips
IPC分类号： C08J11/24 , C08G18/42 , C08G18/10 , C08G18/36 , C08G18/08 , C08K5/12 , C08J5/24 , C08G63/91
摘要： A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.

6. 发明授权

US09951171B2 Polyester polyols from recycled polymers and waste streams 有权
公开(公告)号：US09951171B2
公开(公告)日：2018-04-24
申请号：US14882584
申请日：2015-10-14
申请人： Resinate Materials Group, Inc.
发明人： Rick Tabor , Eric David Vrabel , Matthew J Beatty , Gary E. Spilman , Kevin Anthony Rogers , Michael Robert Christy , Matthew Thomas Brown , Jack Rogers Kovsky , Woo-Sung Bae , Shakti L Mukerjee
IPC分类号： C08G18/08 , C08G63/183 , C08G63/91 , C08G18/42 , C08F20/10 , C09D5/03 , C08J3/03 , C09D167/00 , C09D175/06 , C08G63/553 , C08G18/72 , C08G18/76 , C08G63/89 , C08G18/66 , C08G64/40 , C08G18/44 , C09D167/02 , C08J9/04 , C08J11/24 , C08G18/09 , C09D175/04 , C08G101/00
CPC分类号： C08G18/0866 , C08F20/10 , C08G18/092 , C08G18/4213 , C08G18/4288 , C08G18/44 , C08G18/664 , C08G18/722 , C08G18/7671 , C08G63/183 , C08G63/553 , C08G63/89 , C08G63/916 , C08G64/403 , C08G2101/0025 , C08G2150/20 , C08J3/03 , C08J9/04 , C08J11/24 , C08J2201/022 , C08J2205/06 , C08J2205/10 , C08J2367/02 , C08J2375/06 , C09D5/03 , C09D167/00 , C09D167/02 , C09D175/04 , C09D175/06 , Y02W30/706
摘要： The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

7. 发明申请

US20160229981A1 INTEGRATED PROCESS FOR TREATING RECYCLED STREAMS OF PET AND PTT 审中-公开
标题翻译：用于处理PET和PTT的回收流的综合过程
公开(公告)号：US20160229981A1
公开(公告)日：2016-08-11
申请号：US15099794
申请日：2016-04-15
申请人： Resinate Materials Group, Inc.
发明人： Brian Douglas Phillips , Rick Tabor , Shakti L. Mukerjee , Kevin Rogers , Eric David Vrabel , Woo-Sung Bae , Adam W. Emerson
IPC分类号： C08J11/24 , C08K5/12
CPC分类号： C08J11/24 , C08G18/0823 , C08G18/10 , C08G18/36 , C08G18/42 , C08G18/4288 , C08G18/7664 , C08G63/16 , C08G63/916 , C08J5/24 , C08J2367/02 , C08J2375/04 , C08J2375/06 , C08J2423/02 , C08J2467/02 , C08J2475/04 , C08K5/12 , Y02P20/125
摘要： A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.
摘要翻译：一种生产聚酯多元醇的方法，包括使选自回收的PET地毯，地毯纤维，容器，织物，制品或其混合物的循环料流与反应器中的二醇反应，从而形成包含多元醇的消化产物流和未消化的流 ; 然后将消化的产物流与选自二聚脂肪酸，三聚体脂肪酸，油酸，蓖麻油酸，桐油，玉米油，菜籽油，大豆油，向日葵油，细菌油，酵母油，藻油，蓖麻油，甘油三酸酯或具有饱和或不饱和C6-C36脂肪酸单元，饱和或不饱和C6-C36脂肪酸，烷氧基化蓖麻油，饱和或不饱和C 9 -C 18二羧酸或二醇的羟基甘油酯或烷基羧酸酯，基于腰果酚的产品，再循环烹饪油，支链或直链C6-C36脂肪醇，衍生自环氧化，臭氧化或加氢甲酰化脂肪酯或酸的羟基官能材料，或其混合物。

8. 发明申请

US20190169397A1 INTEGRATED PROCESS FOR TREATING RECYCLED STREAMS OF PET AND PTT 审中-公开
公开(公告)号：US20190169397A1
公开(公告)日：2019-06-06
申请号：US16272040
申请日：2019-02-11
申请人： RESINATE MATERIALS GROUP, INC.
发明人： Rick Tabor , Shakti L. Mukerjee , Kevin Anthony Rogers , Adam W. Emerson , Eric David Vrabel , Brian Douglas Phillips
IPC分类号： C08J11/24 , C08G18/42 , C08G18/08 , C08G18/10 , C08G18/36 , C08J5/24 , C08G63/91 , C08K5/12 , C08G18/76 , C08G63/16
摘要： A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.

9. 发明授权

US10040899B2 Cycloaliphatic polyester polyols from thermoplastic polyesters 有权
公开(公告)号：US10040899B2
公开(公告)日：2018-08-07
申请号：US15347924
申请日：2016-11-10
申请人： Resinate Materials Group, Inc.
发明人： Rick Tabor , Eric David Vrabel , Matthew Beatty
IPC分类号： C08G18/24 , C08G18/34 , C08G18/42 , C08G18/73 , C08G18/75 , C08G63/91 , C09D175/06
摘要： Cycloaliphatic polyester polyols and processes for making them from thermoplastic polyesters are disclosed. One process comprises heating a thermoplastic polyester with a glycol to give a digested intermediate and hydrogenating aromatic rings in the digested intermediate to produce the cycloaliphatic polyester polyol. Optionally, the digested intermediate is reacted with a hydrophobe to give a modified polyol prior to hydrogenation, and the modified polyol is hydrogenated to give the cycloaliphatic polyester polyol. The high-recycle-content cycloaliphatic polyester polyols have desirable attributes for formulating polyurethane dispersions, two-component polyurethane coatings, mono- or poly(meth)acrylates, polyisocyanurates, flexible and rigid foams, coatings, adhesives, sealants, and elastomers, and they provide a sustainable alternative to petrochemical-based polyols.

10. 发明申请

US20160229980A1 INTEGRATED PROCESS FOR TREATING RECYCLED STREAMS OF PET AND PTT 审中-公开
公开(公告)号：US20160229980A1
公开(公告)日：2016-08-11
申请号：US15099700
申请日：2016-04-15
申请人： Resinate Materials Group, Inc.
发明人： Brian Douglas Phillips , Rick Tabor , Shakti L. Mukerjee , Kevin Rogers , Eric David Vrabel , Woo-Sung Bae , Adam W. Emerson
IPC分类号： C08J11/24
CPC分类号： C08J11/24 , C08G18/0823 , C08G18/10 , C08G18/36 , C08G18/42 , C08G18/4288 , C08G63/916 , C08J5/24 , C08J2367/02 , C08J2375/06 , C08J2423/02 , C08K5/12 , Y02P20/125
摘要： A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.

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