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    • 4. 发明授权
    • Lead-acid cells and batteries
    • 铅酸电池和电池
    • US5874186A
    • 1999-02-23
    • US872811
    • 1997-06-11
    • Purushothama RaoThomas F. Uhlemann
    • Purushothama RaoThomas F. Uhlemann
    • C22C11/06H01M4/68H01M4/74
    • H01M4/685C22C11/06H01M4/745
    • A lead-acid cell or battery includes positive plates made from a lead-based alloy containing calcium, tin, and silver in amounts selected based upon the type of application and the plate fabrication method utilized, starting, lighting and ignition battery grids being directly cast and having calcium present in an amount of 0.03% to 0.050%, tin in an amount of 0.65% to 1.25%, and silver in an amount of from 0.018% to 0.030%, and the grids used in sealed, lead-acid cells comprising, when made by gravity casting, from about 0.035% to 0.055% calcium, 0.95% to 1.45% tin, and 0.018% to 0.030% silver, and, when made by continuous strip casting, calcium in the range of from 0.030% to 0.050%, tin in the range of from 0.95% to 1.25%, and silver in the range of from 0.017% to 0.030%, all of the alloy percentages being based upon the total weight of the grid.
    • 铅酸电池或电池包括由包含钙,锡和银的铅基合金制成的正极板,其基于应用的类型和使用的板制造方法选择的量,起始,照明和点火电池网格直接铸造 并且具有0.03%至0.050%的钙,0.65%至1.25%的锡和0.018%至0.030%的量的银,以及用于密封的铅酸电池中的电池,包括 当通过重力铸造制成时,约0.035%至0.055%的钙,0.95%至1.45%的锡和0.018%至0.030%的银,并且当通过连续带铸造制成时,钙在0.030%至0.050的范围内 %,锡在0.95%至1.25%的范围内,银在0.017%至0.030%的范围内,所有合金百分比均基于电网的总重量。
    • 8. 发明授权
    • Bipolar lead-acid battery
    • 双极铅酸电池
    • US5348817A
    • 1994-09-20
    • US72414
    • 1993-06-02
    • Purushothama RaoJing-Yih Cherng
    • Purushothama RaoJing-Yih Cherng
    • H01M4/14H01M4/68H01M10/18
    • H01M10/18H01M4/14H01M4/68Y02E60/126
    • A bipolar lead-acid is disclosed in which a conductive metal substrate is used for the bipolar plates which may comprise either a multi-layer metallic substrate defined as C/A/B/D, layer C having a layer of positive active material adhered thereto and layer D having a layer of negative active material adhered thereto, C can be lead or lead alloy or a conductive tin, titanium dioxide or ruthenium oxide, A is titanium or tin, B is copper or tin, and D is lead, a lead alloy or tin, or a conductive metal substrate-fiber or mesh composite in which the fiber may be glass fibers or the like. A preferred embodiment provides a bipolar lead-acid battery having enhanced capacity by utilizing a central bi-negative or bi-positive plate so that the capacity can be increased without increasing the size of the plates.
    • 公开了一种双极性铅酸,其中导电金属基板用于双极板,其可以包括定义为C / A / B / D的多层金属基板,具有粘附到其上的正极活性材料层的层C 和具有粘附到其上的负极活性物质层的层D,C可以是铅或铅合金或导电锡,二氧化钛或氧化钌,A是钛或锡,B是铜或锡,D是铅,铅 合金或锡,或其中纤维可以是玻璃纤维等的导电金属基材纤维或网状复合物。 一个优选的实施方案提供了一种通过利用中央双阴极或双正极板而具有增强的容量的双极铅酸电池,使得容量可以增加而不增加板的尺寸。
    • 9. 发明授权
    • Calcium-tin-silver lead-based alloys, and battery grids and lead-acid
batteries made using such alloys
    • 钙 - 锡 - 铅铅基合金,以及使用这种合金制成的电池网格和铅酸电池
    • US5298350A
    • 1994-03-29
    • US852803
    • 1992-03-17
    • Purushothama Rao
    • Purushothama Rao
    • C22C11/06H01M4/62H01M4/68H01M4/82H01M10/12H01M10/34
    • H01M4/627C22C11/06H01M4/685H01M4/82H01M10/342
    • Automotive SLI lead-acid batteries are disclosed which are characterized by enhanced resistance to positive grid corrosion, even when exposed to the current, relatively high under-the-hood service temperatures in use with recent model automobiles. The grids are formed from either a cast lead-based alloy including from about 0.025 to 0.06% calcium, from about 0.3 to 0.7% tin and from about 0.015 to 0.045% silver, the percentages being based upon the weight of the alloy prior to casting or a wrought lead-based alloy including from about 0.02 to 0.05% calcium, from about 0.3 to 0.5% tin and 0.02 to 0.045% silver, the percentages being based upon the weight of the alloy. Aluminum in an amount of from about 0.008 to about 0.012%, based upon the as-added total weight of the alloy may be used to maintain the desired calcium content during casting.
    • 公开了汽车SLI铅酸电池,其特征在于对正电网腐蚀具有增强的抵抗力,即使当暴露于与最近的模型汽车一起使用的当前相对较高的引擎盖下服务温度时。 栅格由包括约0.025至0.06%的钙,约0.3至0.7%的锡和约0.015至0.045%的银的铸造铅基合金形成,其百分比基于铸造前合金的重量 或包含约0.02至0.05%的钙,约0.3至0.5%的锡和0.02至0.045%的银的锻造铅基合金,所述百分比基于合金的重量。 可以使用约0.008至约0.012%的铝,基于合金的添加总重量,以在铸造期间保持所需的钙含量。
    • 10. 发明授权
    • Method of preparing lead-acid battery plates and lead-acid batteries
containing plates so prepared
    • 制备铅酸蓄电池板和铅酸蓄电池的方法
    • US4713304A
    • 1987-12-15
    • US875800
    • 1986-06-18
    • Purushothama RaoFrederick L. Marsh
    • Purushothama RaoFrederick L. Marsh
    • H01M4/20H01M4/22H01M4/23
    • H01M4/20H01M4/22
    • A method for preparing lead-acid battery positive and negative plates for use in lead-acid batteries, comprising (a) providing battery grids, (b) applying wet leady oxide paste to the grids to form plates, (c) optionally wrapping the freshly pasted plates with an absorbent material, and (d) initiating formation of the lead-acid battery plates while the plates contain more than about 5 wt. % free lead in the paste and are generally damp from moisture existing in the paste from the time of plate pasting. Although conventional curing and drying of the plates is obviated and the plate formation is initiated merely hours after plate pasting, instead of a day or more after plate pasting as is the case with conventional battery plate processing, the cells and batteries containing plates prepared in accordance with the present invention exhibit a mechanical strength and deliver an overall electrical performance equivalent or superior to cells and batteries containing conventionally prepared plates.
    • 一种铅酸蓄电池用铅酸蓄电池正极板和负极板的制造方法,其特征在于,包括:(a)提供蓄电池栅格,(b)将湿铅氧化铅膏施加到栅格上形成板,(c) 具有吸收材料的粘贴板,以及(d)当板含有大于约5重量%时,引发铅酸电池板的形成。 在糊状物中,游离铅的含量通常比糊料中存在的水分潮湿。 虽然消除了板的常规固化和干燥,并且在板粘贴之后仅仅几个小时开始板形成,而不是如常规电池板处理那样在平板粘贴之后的一天或更多天,但是根据 本发明显示出机械强度并且提供等同于或优于含有常规制备的板的电池和电池的整体电性能。