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1. 发明授权

US5968494A Polyurethanes with carboxylate functionality for hair fixative applications 失效
标题翻译：用于头发固定剂应用的具有羧酸酯官能团的聚氨酯
公开(公告)号：US5968494A
公开(公告)日：1999-10-19
申请号：US28826
申请日：1998-02-24
申请人： Pravin K. Kukkala , Sharon P. Lee , Andrew J. Kielbania, Jr. , Melissa J. Vitale
发明人： Pravin K. Kukkala , Sharon P. Lee , Andrew J. Kielbania, Jr. , Melissa J. Vitale
IPC分类号： A61K8/30 , A61K8/00 , A61K8/02 , A61K8/06 , A61K8/34 , A61K8/36 , A61K8/365 , A61K8/49 , A61K8/72 , A61K8/87 , A61Q5/06 , C08G18/00 , C08G18/08 , C08G18/12 , C08G18/32 , C08G18/66 , C08L75/04 , A61K7/06 , A61K7/00
CPC分类号： C08G18/6692 , A61K8/87 , A61Q5/06 , C08G18/0823 , C08G18/12 , C08G2170/80
摘要： A polyurethane, soluble or dispersible in water, prepared from organic diisocyanate diols or other isocyanate reactive materials and a 2,2-hydroxymethyl-substituted carboxylic acid diol neutralized with a cosmetically acceptable organic or inorganic base and formulated into a hair fixative composition containing low amounts of volatile organic solvent. The present invention is also directed to a process for the preparation of polyurethanes comprising dispersing the polyurethane after at least 70% of the theoretical isocyanate reaction has taken place, but before completion of the reaction.
摘要翻译：由有机二异氰酸酯二醇或其它异氰酸酯反应性物质制备的可溶于或分散于水中的聚氨酯，和用化妆品可接受的有机或无机碱中和的2,2-羟甲基取代的羧酸二醇，并配制成含有少量的头发定型组合物的挥发性有机溶剂。本发明还涉及一种制备聚氨酯的方法，包括在理论异氰酸酯反应的至少70％发生，但在反应完成之前分散聚氨酯。

2. 发明授权

US06291580B1 Polyurethanes with carboxylate functionality for hair fixative applications 有权
标题翻译：用于头发固定剂应用的具有羧酸酯官能团的聚氨酯
公开(公告)号：US06291580B1
公开(公告)日：2001-09-18
申请号：US09340332
申请日：1999-06-25
申请人： Pravin K. Kukkala , Sharon P. Lee , Andrew J. Kielbania, Jr. , Melissa J. Vitale
发明人： Pravin K. Kukkala , Sharon P. Lee , Andrew J. Kielbania, Jr. , Melissa J. Vitale
IPC分类号： C08G1865
CPC分类号： C08G18/6692 , A61K8/87 , A61Q5/06 , C08G18/0823 , C08G18/12 , C08G2170/80 , C08G18/3821 , C08G18/302 , C08G18/50 , C08G18/64
摘要： A polyurethane, soluble or dispersible in water, prepared from organic diisocyanate diols or other isocyanate reactive materials and a 2,2-hydroxymethyl-substituted carboxylic acid diol neutralized with a cosmetically acceptable organic or inorganic base and formulated into a hair fixative composition containing low amounts of volatile organic solvent. The present invention is also directed to a process for the preparation of polyurethanes comprising dispersing the polyurethane after at least 70% of the theoretical isocyanate reaction has taken place, but before completion of the reaction.
摘要翻译：由有机二异氰酸酯二醇或其它异氰酸酯反应性物质制备的可溶于或分散于水中的聚氨酯，和用化妆品可接受的有机或无机碱中和的2,2-羟甲基取代的羧酸二醇，并配制成含有少量的头发定型组合物的挥发性有机溶剂。本发明还涉及一种制备聚氨酯的方法，包括在理论异氰酸酯反应的至少70％发生，但在反应完成之前分散聚氨酯。

3. 发明授权

US6051646A Thermosetting binder prepared with (hydroxyalkyl)urea crosslinking agent for abrasive articles 有权
标题翻译：用（研磨制品）的（羟基烷基）脲交联剂制备的热固性粘合剂
公开(公告)号：US6051646A
公开(公告)日：2000-04-18
申请号：US181192
申请日：1998-10-28
申请人： David R. Nass , Andrew J. Kielbania, Jr. , Sharon P. Lee
发明人： David R. Nass , Andrew J. Kielbania, Jr. , Sharon P. Lee
IPC分类号： C08K5/21 , C08L33/02 , C08L67/00 , C08L101/02 , C09D167/00 , B32B19/02 , C08K3/14 , C08L29/04 , C08L31/04
CPC分类号： C08K5/21 , C09D167/00 , Y10T428/24628
摘要： Abrasive articles comprising a cured thermosetting binder and abrasive grains. The binder is prepared with a poly-functional molecule which contains at least two functional groups selected from the group consisting of carboxyl, anhydride and amine, and a (hydroxyalkyl)urea crosslinking agent containing a single urea group, at least two hydroxyl groups, and have at least two carbon atoms disposed between the urea group and each of the hydroxyl groups. The abrasive articles comprise bonded, nonwoven or coated abrasive articles.
摘要翻译：包含固化的热固性粘合剂和磨料颗粒的磨料制品。粘合剂是由含有至少两个选自羧基，酸酐和胺的官能团的多官能分子和含有单个脲基，至少两个羟基的（羟烷基）脲交联剂和在尿素基团和每个羟基之间具有至少两个碳原子。研磨制品包括粘合的，非织造的或涂覆的磨料制品。

4. 发明授权

US6140388A Thermosetting binder prepared with mono(hydroxyalkyl)urea and oxazolidone crosslinking agents 有权
标题翻译：用单（羟烷基）脲和恶唑烷酮交联剂制备的热固性粘合剂
公开(公告)号：US6140388A
公开(公告)日：2000-10-31
申请号：US197804
申请日：1998-11-23
申请人： David R. Nass , Andrew J. Kielbania, Jr. , Sharon P. Lee , Steven P. Pauls, Sr.
发明人： David R. Nass , Andrew J. Kielbania, Jr. , Sharon P. Lee , Steven P. Pauls, Sr.
IPC分类号： C08K5/21 , C08G71/00 , C08G71/02 , C08K5/353 , C08L101/06 , B22C1/00 , B22C1/22 , B22C3/00 , C09K3/18
CPC分类号： C08G71/02 , Y10S428/932 , Y10T428/24372 , Y10T428/24405 , Y10T428/24421 , Y10T428/2443
摘要： Abrasive articles comprising a cured thermosetting binder and abrasive grains. The binder is prepared with a poly-functional molecule comprising at least two functional groups selected from the group consisting of carboxyl and anhydride, and a crosslinking agent which is selected from the group consisting of a mono(hydroxyalkyl)urea comprising a single urea group, a single hydroxyl group, and at least two carbon atoms disposed between the urea group and the hydroxyl group, and 2-oxazolidone. The abrasive articles comprise bonded, nonwoven or coated abrasive articles.
摘要翻译：包含固化的热固性粘合剂和磨料颗粒的磨料制品。粘合剂由包含至少两个选自羧基和酸酐的官能团的多官能分子和选自包含单一脲基的单（羟基烷基）脲的交联剂制备，设置在脲基和羟基之间的至少两个碳原子和2-恶唑烷酮。研磨制品包括粘合的，非织造的或涂覆的磨料制品。

5. 发明授权

US4288499A Polymers adherent to polyolefins 失效
标题翻译：聚合物粘附在聚烯烃上
公开(公告)号：US4288499A
公开(公告)日：1981-09-08
申请号：US037069
申请日：1979-05-08
申请人： Andrew J. Kielbania, Jr.
发明人： Andrew J. Kielbania, Jr.
IPC分类号： B32B27/30 , B05D7/02 , B32B27/32 , C08J7/04 , C09D133/14 , C09D133/26 , B32B27/08
CPC分类号： C08J7/047 , B05D7/02 , B32B37/12 , C09D133/14 , C09D133/26 , C08J2323/02 , C08J2433/00 , Y10T428/31855 , Y10T428/31913 , Y10T428/3192
摘要： This invention is concerned with an article comprising a polyolefin substrate and adherent thereto a vinyl addition polymer of monomers comprising at least 5% by weight a primary monomer selected from(a) monomers having the formula ##STR1## wherein X is --O--, --NH-- or --NR.sup.5 --;R.sup.1 and R.sup.7, individually, are H, methyl or ethyl;R.sup.2 is H or an organic radical, preferably --COOH, --CONH.sub.2 or --COOR.sup.6 ;R.sup.3 is H or an organic radical, preferably methyl, other alkyl having up to about five carbon atoms, --CH.sub.2 COOR.sup.6, --COOR.sup.6 or --CH.sub.2 COOH;R.sup.4 and R.sup.5, individually, are monocyclic alkyl having six or more carbon atoms, acyclic alkyl having nine or more carbon atoms, or alkaryl having nine or more carbon atoms;R.sup.6 is hydrocarbyl, preferably alkyl;n has a value from zero to about ten;(b) vinyl esters of alkanoic acids having at least eight carbon atoms;(c) substituted styrenes wherein the substituent group or groups have a total of three or more carbon atoms;and mixtures thereof; said polymer having surface energy properties such as to form a stable bond with said substrate.The polymer, used alone or in a blend, serves as a coating, a tiecoat, an adhesive or a binder.
摘要翻译：本发明涉及包含聚烯烃基材并与其粘合的单体的乙烯基加成聚合物的制品，所述单体包含至少5重量％的选自（a）具有下式的单体的主要单体：其中X为-O-， - NH-或-NR5-; R 1和R 7分别为H，甲基或乙基; R2是H或有机基团，优选-COOH，-CONH 2或-COOR 6; R3是H或有机基团，优选甲基，具有至多约5个碳原子的其它烷基，-CH 2 COOR 6，-COOR 6或-CH 2 COOH; R4和R5分别是具有6个或更多个碳原子的单环烷基，具有9个或更多个碳原子的无环烷基，或具有9个或更多个碳原子的烷芳基; R6是烃基，优选烷基; n具有从零到大约十的值; （b）具有至少8个碳原子的链烷酸的乙烯基酯; （c）取代苯乙烯，其中取代基或基团具有总共三个或更多个碳原子; 及其混合物; 所述聚合物具有表面能，例如与所述基材形成稳定的键合。单独使用或混合使用的聚合物用作涂层，粘结剂，粘合剂或粘合剂。

6. 发明授权

US5426129A Reactive coalescents 失效
标题翻译：活性聚结剂
公开(公告)号：US5426129A
公开(公告)日：1995-06-20
申请号：US262183
申请日：1994-06-20
申请人： William D. Emmons , Daniel A. Bors , Andrew J. Kielbania, Jr.
发明人： William D. Emmons , Daniel A. Bors , Andrew J. Kielbania, Jr.
IPC分类号： C09D7/12 , C08F2/48 , C08K5/101 , C08K5/17 , C09D5/02 , C09D133/04 , C09D157/00 , C08F8/30
CPC分类号： C09D133/04 , C08K5/101 , C08K5/17 , C09D157/00 , C09D5/024
摘要： A coating or impregnating composition containing an aqueous dispersion of a vinyl addition polymer and a reactive coalescent is provided. The reactive coalescent contains at least one acetoacetate grouping, or an enamine thereof. In one embodiment the reactive coalescent also functions as an emulsion polymer crosslinker.
摘要翻译：提供含有乙烯基加成聚合物和反应性聚结剂的水性分散体的涂料或浸渍组合物。反应性聚结剂含有至少一种乙酰乙酸酯基团或其烯胺。在一个实施方案中，反应性聚结剂还用作乳液聚合物交联剂。

7. 发明授权

US4424240A Polymers adherent to polyolefins 失效
标题翻译：聚合物粘附在聚烯烃上
公开(公告)号：US4424240A
公开(公告)日：1984-01-03
申请号：US282121
申请日：1981-07-10
申请人： Andrew J. Kielbania, Jr.
发明人： Andrew J. Kielbania, Jr.
IPC分类号： B05D7/02 , C08J7/04 , C09D133/14 , C09D133/26 , B05D3/02
CPC分类号： B05D7/02 , B32B37/12 , C08J7/047 , C09D133/14 , C09D133/26 , C08J2323/02 , C08J2433/12 , Y10T428/31909 , Y10T428/31928
摘要： This invention is concerned with an article comprising an untreated polyolefin substrate and adherent thereto a vinyl addition polymer of monomers comprising at least 5% by weight a primary monomer selected from (a) monomers having the formula ##STR1## wherein X is -O-, -NH- or -NR.sup.5 -; R.sup.1 and R.sup.7, individually, are H, methyl or ethyl; R.sup.2 is H or an organic radical, preferably -COOH, -CONH.sub.2 or -COOR.sup.6 ; R.sup.3 is H or an organic radical, preferably methyl, other alkyl having up to about five carbon atoms, -CH.sub.2 COOR.sup.6, -COOR.sup.6 or -CH.sub.2 COOH; R.sup.4 and R.sup.5, individually, are monocyclic alkyl having six or more carbon atoms, acyclic alkyl having nine or more carbon atoms, or alkaryl having nine or more carbon atoms; R.sup.6 is hydrocarbyl, preferably alkyl; n has a value from zero to about ten; (b) vinyl esters of alkanoic acids having at least eight carbon atoms; (c) alkyl substituted styrenes wherein the substituent group or groups have a total three or more carbon atoms; and mixtures thereof; said polymer having surface energy properties such as to form a stable bond with said substrate. The polymer, used alone or in a blend with other polymers, serves as a coating, a tiecoat, an adhesive or a binder.

8. 发明授权

US5349026A Reactive coalescents 失效
标题翻译：活性聚结剂
公开(公告)号：US5349026A
公开(公告)日：1994-09-20
申请号：US979118
申请日：1992-11-20
申请人： William D. Emmons , Daniel A. Bors , Andrew J. Kielbania, Jr.
发明人： William D. Emmons , Daniel A. Bors , Andrew J. Kielbania, Jr.
IPC分类号： C09D7/12 , C08F2/48 , C08K5/101 , C08K5/17 , C09D5/02 , C09D133/04 , C09D157/00 , C08F116/36 , C08F8/14 , C08F8/32 , C08F216/36
CPC分类号： C09D133/04 , C08K5/101 , C08K5/17 , C09D157/00 , C09D5/024
摘要： A coating or impregnating composition containing an aqueous dispersion of a vinyl addition polymer and a reactive coalescent is provided. The reactive coalescent contains at least one acetoacetate grouping, or an enamine thereof. In one embodiment the reactive coalescent also functions as an emulsion polymer crosslinker.
摘要翻译：提供含有乙烯基加成聚合物和反应性聚结剂的水性分散体的涂料或浸渍组合物。反应性聚结剂含有至少一种乙酰乙酸酯基团或其烯胺。在一个实施方案中，反应性聚结剂还用作乳液聚合物交联剂。

9. 发明授权

US5277979A Process for microencapsulation 失效
标题翻译：微胶囊化方法
公开(公告)号：US5277979A
公开(公告)日：1994-01-11
申请号：US882323
申请日：1992-05-13
申请人： Andrew J. Kielbania, Jr. , William D. Emmons , George H. Redlich
发明人： Andrew J. Kielbania, Jr. , William D. Emmons , George H. Redlich
IPC分类号： A01N25/28 , A61K9/50 , B01J13/16 , B41M5/165
CPC分类号： B01J13/16 , A01N25/28 , A61K9/5089 , B41M5/165 , Y10S514/963 , Y10T428/2985 , Y10T428/2987 , Y10T428/2989
摘要： A process for encapsulating a wide variety of target materials, including both hydrophilic and hydrophobic materials, employs condensation of two reactive compounds to form shells around core phase particles including target material dispersed in a continuous phase. One of the reactive compounds has at least two active methylene functional groups per molecule, the other being an active methylene-reactive crosslinking agent. Either type of the reactive compounds can be dispersed in the continuous phase, the other being dispersible in the core phase. Applications include controlled release microencapsulation of agriculture chemicals and biocides.
摘要翻译：用于封装各种目标材料（包括亲水和疏水材料两者）的方法使用两种反应性化合物的缩合形成核心相颗粒周围的壳体，包括分散在连续相中的靶材料。一种反应性化合物每分子具有至少两个活性亚甲基官能团，另一种是活性亚甲基反应性交联剂。任何一种类型的反应性化合物可以分散在连续相中，另一种可分散在核相中。应用包括农药和杀菌剂的控释微胶囊。

10. 发明授权

US06290867B1 Treatment composition which provides anti-wrinkling properties to textiles 有权
标题翻译：为织物提供抗皱性能的处理组合物
公开(公告)号：US06290867B1
公开(公告)日：2001-09-18
申请号：US09456358
申请日：1999-12-08
申请人： Andrew J. Kielbania, Jr. , Klein A. Rodrigues , Susanne Goodson , Christopher G. Gore
发明人： Andrew J. Kielbania, Jr. , Klein A. Rodrigues , Susanne Goodson , Christopher G. Gore
IPC分类号： D06M13322
CPC分类号： D06M13/432 , D06M15/3562 , D06M15/564 , D06M15/568 , D06M2200/20 , Y10T442/2393
摘要： A textile treatment composition which imparts anti-wrinkling properties to textiles treated therewith, said textile treatment composition comprising a polyhydroxyalkylurea crosslinking agent having at least two urea moieties. Textiles treated with the compositions of the invention display a significant reduction in wrinkles compared with nontreated textiles. Moreover, the treated textiles have a tactile sensation of feeling soft and retain their smoothness after laundering.
摘要翻译：一种纺织品处理组合物，其对经过处理的织物赋予抗皱性能，所述纺织品处理组合物包含具有至少两个脲部分的聚羟烷基脲交联剂。与未处理的纺织品相比，用本发明组合物处理的纺织品显示皱纹显着减少。此外，被处理的纺织品具有感觉柔软的触感，并在洗涤后保持其光滑度。

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