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1. 发明授权

US09065109B2 Method for preparing a composite material comprising a polymeric matrix and a filler consisting in ion exchange inorganic particles 有权
标题翻译：制备复合材料的方法，所述复合材料包含聚合物基质和由离子交换无机颗粒组成的填料
公开(公告)号：US09065109B2
公开(公告)日：2015-06-23
申请号：US13704524
申请日：2011-06-15
申请人： Pierrick Buvat , Philippe Mazabraud , Herve Galiano , Jannick Bigarre , Veronique Bounor-Legare , Frederick Niepceron , Jean-Francois Gerard
发明人： Pierrick Buvat , Philippe Mazabraud , Herve Galiano , Jannick Bigarre , Veronique Bounor-Legare , Frederick Niepceron , Jean-Francois Gerard
IPC分类号： H01M8/10 , B01D69/14 , C08J5/22 , B01D67/00 , B01D71/02 , B01D71/32 , B01D71/82
CPC分类号： H01M8/1072 , B01D67/0048 , B01D67/0079 , B01D69/148 , B01D71/027 , B01D71/32 , B01D71/82 , B01D2323/40 , B01D2325/42 , C08J5/2275 , C08J5/2281 , C08J2327/16 , C08J2327/20 , H01M8/1039 , H01M8/1048 , H01M8/1074 , Y02E60/523
摘要： The invention relates to a method for preparing a composite material comprising a polymeric matrix and a filler consisting in ion exchange inorganic particles, comprising a step for synthesis in situ of said particles within the polymeric matrix.
摘要翻译：本发明涉及一种用于制备复合材料的方法，所述复合材料包含聚合物基质和由离子交换无机颗粒组成的填料，包括用于在聚合物基体内原位合成所述颗粒的步骤。

2. 发明申请

US20130092873A1 METHOD FOR PREPARING A COMPOSITE MATERIAL COMPRISING A POLYMERIC MATRIX AND A FILLER CONSISTING IN ION EXCHANGE INORGANIC PARTICLES 有权
标题翻译：制备包含聚合物基质的复合材料的方法和包含在离子交换无机颗粒中的填料
公开(公告)号：US20130092873A1
公开(公告)日：2013-04-18
申请号：US13704524
申请日：2011-06-15
申请人： Pierrick Buvat , Philippe Mazabraud , Herve Galiano , Jannick Bigarre , Veronique Bounor-Legare , Frederick Niepceron , Jean-Francois Gerard
发明人： Pierrick Buvat , Philippe Mazabraud , Herve Galiano , Jannick Bigarre , Veronique Bounor-Legare , Frederick Niepceron , Jean-Francois Gerard
IPC分类号： H01M8/10
CPC分类号： H01M8/1072 , B01D67/0048 , B01D67/0079 , B01D69/148 , B01D71/027 , B01D71/32 , B01D71/82 , B01D2323/40 , B01D2325/42 , C08J5/2275 , C08J5/2281 , C08J2327/16 , C08J2327/20 , H01M8/1039 , H01M8/1048 , H01M8/1074 , Y02E60/523
摘要： The invention relates to a method for preparing a composite material comprising a polymeric matrix and a filler consisting in ion exchange inorganic particles, comprising a step for synthesis in situ of said particles within the polymeric matrix.
摘要翻译：本发明涉及一种用于制备复合材料的方法，所述复合材料包含聚合物基质和由离子交换无机颗粒组成的填料，包括用于在聚合物基体内原位合成所述颗粒的步骤。

3. 发明申请

US20140113982A1 METHOD FOR PREPARING PROTON-CONDUCTING INORGANIC PARTICLES 有权
标题翻译：制备无机导电无机颗粒的方法
公开(公告)号：US20140113982A1
公开(公告)日：2014-04-24
申请号：US13990226
申请日：2011-11-28
申请人： Jannick Bigarre , Renaud Perrin , Pierrick Buvat , Herve Galiano
发明人： Jannick Bigarre , Renaud Perrin , Pierrick Buvat , Herve Galiano
IPC分类号： B01J39/20
CPC分类号： B01J39/20 , C08J5/2275 , H01B1/122
摘要： The invention relates to a method for functionalization of inorganic particles by polymers comprising at least one recurrent unit bearing at least one proton exchange group comprising the following steps: a) a step for functionalization of inorganic particles by an anionic polymerization termination agent comprising at least one group capable of being bound to the surface of said particles; b) a step for anionic polymerization of at least one monomer bearing at least one precursor group of a proton exchange group; c) a step for putting the particles obtained in step a) in contact with the polymers obtained in step b), in return for which the obtained particles are particles functionalized by said polymers by reaction between a reactive end of said polymeric polymers and at least one group of the aforementioned termination agent; and d) a step for transformation of the precursor group(s) of said proton exchange group(s).
摘要翻译：本发明涉及一种通过聚合物官能化无机颗粒的方法，所述聚合物包含至少一个具有至少一个质子交换基团的反应单元，该反应单元包括以下步骤：a）通过阴离子聚合终止剂官能化无机颗粒的步骤，所述阴离子聚合终止剂包含至少一个能够与所述颗粒的表面结合的基团; b）至少一种带有至少一个质子交换基团前体基团的单体进行阴离子聚合的步骤; c）将步骤a）中获得的颗粒与步骤b）中获得的聚合物接触的步骤，作为回报，所得颗粒是由所述聚合物官能化的颗粒，通过所述聚合物聚合物的反应性末端与至少一组上述终止剂; 和d）用于转化所述质子交换基团的前体基团的步骤。

4. 发明授权

US09227187B2 Method for preparing proton-conducting inorganic particles 有权
标题翻译：制备质子传导无机颗粒的方法
公开(公告)号：US09227187B2
公开(公告)日：2016-01-05
申请号：US13990226
申请日：2011-11-28
申请人： Jannick Bigarre , Renaud Perrin , Pierrick Buvat , Herve Galiano
发明人： Jannick Bigarre , Renaud Perrin , Pierrick Buvat , Herve Galiano
IPC分类号： B01J39/20 , H01B1/12 , C08J5/22
CPC分类号： B01J39/20 , C08J5/2275 , H01B1/122
摘要： The invention relates to a method for functionalization of inorganic particles by polymers comprising at least one recurrent unit bearing at least one proton exchange group comprising the following steps: a) a step for functionalization of inorganic particles by an anionic polymerization termination agent comprising at least one group capable of being bound to the surface of said particles; b) a step for anionic polymerization of at least one monomer bearing at least one precursor group of a proton exchange group; c) a step for putting the particles obtained in step a) in contact with the polymers obtained in step b), in return for which the obtained particles are particles functionalized by said polymers by reaction between a reactive end of said polymeric polymers and at least one group of the aforementioned termination agent; and d) a step for transformation of the precursor group(s) of said proton exchange group(s).
摘要翻译：本发明涉及一种通过聚合物官能化无机颗粒的方法，所述聚合物包含至少一个具有至少一个质子交换基团的反应单元，该反应单元包括以下步骤：a）通过阴离子聚合终止剂官能化无机颗粒的步骤，所述阴离子聚合终止剂包含至少一个能够与所述颗粒的表面结合的基团; b）至少一种带有至少一个质子交换基团前体基团的单体进行阴离子聚合的步骤; c）将步骤a）中获得的颗粒与步骤b）中获得的聚合物接触的步骤，作为回报，所得颗粒是由所述聚合物官能化的颗粒，通过所述聚合物聚合物的反应性末端与至少一组上述终止剂; 和d）用于转化所述质子交换基团的前体基团的步骤。

5. 发明授权

US09184459B2 Sulfonated polymers useful for forming fuel cell membranes 有权
标题翻译：用于形成燃料电池膜的磺化聚合物
公开(公告)号：US09184459B2
公开(公告)日：2015-11-10
申请号：US13823991
申请日：2011-09-21
申请人： Pierrick Buvat , Jannick Bigarre , Renaud Perrin , Bruno Ameduri , Aurelien Soules , Bernard Boutevin
发明人： Pierrick Buvat , Jannick Bigarre , Renaud Perrin , Bruno Ameduri , Aurelien Soules , Bernard Boutevin
IPC分类号： H01M8/10 , C08F8/36 , C08J3/24 , C08J5/22 , C08F8/30 , C08F112/08 , C08F112/14 , C08F12/08 , C08F12/30 , C08F293/00 , H01M8/02
CPC分类号： H01M8/1039 , C08F8/30 , C08F8/36 , C08F12/08 , C08F12/30 , C08F112/08 , C08F112/14 , C08F293/005 , C08F2438/00 , C08F2810/40 , C08J3/24 , C08J3/246 , C08J5/2237 , C08J2353/00 , H01M8/0289 , H01M8/1018 , H01M8/1023 , Y02E60/521 , C08F2/38
摘要： The invention relates to a polymer comprising at least one polymeric chain of a first type, the said chain comprising at least two blocks, the same or different, the said blocks comprising repeat units derived from the polymerisation of styrene monomers, the said units comprising at least one phenyl pendant group carrying at least one —SO3R group, R possibly being a hydrogen atom, an alkyl group or cationic counter-ion, the said two blocks being separated by a spacer group, the spacer group is a perfluorocarbon group.
摘要翻译：本发明涉及包含至少一种第一类聚合物链的聚合物，所述链包含至少两个嵌段，相同或不同的所述嵌段包含衍生自苯乙烯单体聚合的重复单元，所述单元包含在至少一个携带至少一个-SO 3 R基团的苯基侧基，R可能是氢原子，烷基或阳离子抗衡离子，所述两个嵌段被间隔基隔开，间隔基是全氟化碳基团。

6. 发明申请

US20050065285A1 Compositions with poly(ethynylene phenylene ethynylene silylenes) 审中-公开
标题翻译：聚（亚乙烯基亚苯基亚乙烯基甲硅烷基）
公开(公告)号：US20050065285A1
公开(公告)日：2005-03-24
申请号：US10490523
申请日：2003-03-06
申请人： Pierrick Buvat , Franck Jousse , Fabien Nony , Jean-Francois Gerard
发明人： Pierrick Buvat , Franck Jousse , Fabien Nony , Jean-Francois Gerard
IPC分类号： C08G77/60 , C08K5/00 , C08L83/05 , C08L83/14 , C08L83/16 , C08L101/00 , C08F8/00 , C08L63/00
CPC分类号： C08L83/14 , C08K5/0016 , C08L83/16 , C08L101/00 , C08L2666/02 , C08L83/00
摘要： Composition comprising a blend of at least one poly(ethynylene phenylene ethynylene silylene) polymer and of at least one compound capable of exerting a plasticizing effect in the blend, once this blend has been cured.
摘要翻译：一旦该共混物固化，组合物包含至少一种聚（亚乙烯基亚苯基亚乙烯基亚甲硅氧烷）聚合物和至少一种能够在共混物中发挥增塑作用的化合物的共混物。

7. 发明授权

US06919403B2 Poly(ethylene phenylene ethynylene silylenes) comprising an inert spacer and methods for preparing same 失效
标题翻译：包含惰性间隔基的聚（亚乙基亚苯基亚乙烯基甲硅烷基）及其制备方法
公开(公告)号：US06919403B2
公开(公告)日：2005-07-19
申请号：US10415644
申请日：2001-11-09
申请人： Christian Levassort , Franck Jousse , Laurent Delnaud , Pierrick Buvat
发明人： Christian Levassort , Franck Jousse , Laurent Delnaud , Pierrick Buvat
IPC分类号： C08G77/52 , C08G77/60 , C08G77/48
CPC分类号： C08G77/60
摘要： The present invention relates to polymers of poly(ethynylene phenylene ethynylene silylene) type comprising an inert spacer in the main chain of the polymer.The invention also relates to processes for preparing said polymers and to the cured products that may be obtained by heat-treating said polymers.The polymers according to the invention may be used especially in matrices for composites.
摘要翻译：本发明涉及在聚合物主链中包含惰性间隔物的聚（亚乙烯基亚苯基亚乙烯基亚甲硅烷基）聚合物。本发明还涉及制备所述聚合物的方法和可通过热处理所述聚合物获得的固化产物的方法。根据本发明的聚合物可以特别用于复合材料的基质中。

8. 发明授权

US06872795B2 Poly (ethynylene phenylene ethynylene polysiloxene(silylene)) and methods for preparing same 失效
标题翻译：聚（亚乙烯基亚苯基亚乙烯基聚硅氧烷（亚甲硅烷基））及其制备方法
公开(公告)号：US06872795B2
公开(公告)日：2005-03-29
申请号：US10415340
申请日：2001-11-09
申请人： Christian Levassort , Franck Jousse , Laurent Delnaud , Pierrick Buvat
发明人： Christian Levassort , Franck Jousse , Laurent Delnaud , Pierrick Buvat
IPC分类号： C08G77/52 , C08G77/60
CPC分类号： C08G77/60 , C08G77/52
摘要： Heat-stable poly(ethynylene phenylene ethynylene polysiloxene(silylene)) polymers preferably of determined molecular mass, optionally bearing at the end of the chain groups derived from a chain-limiting agent. Processes for preparing these polymers, cured products obtained by heat-treating these polymers, and composite matrices comprising these polymers.
摘要翻译：优选具有确定分子量的热稳定聚（亚乙烯基亚苯基亚乙烯基聚硅氧烷（亚甲硅烷基））聚合物，任选地在衍生自限定链的链的末端带有。制备这些聚合物的方法，通过热处理这些聚合物获得的固化产物，以及包含这些聚合物的复合基质。

9. 发明授权

US06703519B1 Poly (ethynylene phenylene ethynylene silylene)s and method for preparation thereof 失效
标题翻译：聚（亚乙烯基亚苯基亚乙烯基亚甲硅烷基）及其制备方法
公开(公告)号：US06703519B1
公开(公告)日：2004-03-09
申请号：US10088167
申请日：2002-03-15
申请人： Pierrick Buvat , Christian Levassort , Franck Jousse
发明人： Pierrick Buvat , Christian Levassort , Franck Jousse
IPC分类号： C07F708
CPC分类号： C08G77/60
摘要： Heat stable poly(ethynylene phenylene ethynylene silylene) polymers with a determined molecular weight bearing at the chain end, groups derived from a chain limiter. Methods for preparing these polymers, hardened products obtained by heat treatment of these polymers, and matrices for composites comprising these polymers.
摘要翻译：在链端具有确定的分子量的热稳定聚（亚乙烯基亚苯基亚乙烯基亚甲硅烷基）聚合物，衍生自链限制剂的基团。制备这些聚合物的方法，通过热处理这些聚合物获得的硬化产物，以及包含这些聚合物的复合材料基体聚合物。

10. 发明授权

US08993700B2 Fluorescent polymers of 7-hydroxycoumarin compounds, chemical sensors comprising them, and polymerizable fluorescent compound of 7-hydroxycoumarin 有权
标题翻译： 7-羟基香豆素化合物的荧光聚合物，包含它们的化学传感器和7-羟基香豆素的可聚合荧光化合物
公开(公告)号：US08993700B2
公开(公告)日：2015-03-31
申请号：US13498090
申请日：2010-09-24
申请人： Pierrick Buvat , Lucie Malosse , Alain Siove , Dominique Ades
发明人： Pierrick Buvat , Lucie Malosse , Alain Siove , Dominique Ades
IPC分类号： C08F24/00 , C07D311/00 , C09B69/10 , C09B57/02 , G01N33/52
CPC分类号： G01N21/64 , C08F220/68 , C09B57/02 , C09B69/109 , G01N33/0037 , G01N33/0047 , G01N33/0057 , G01N33/52 , G01N2201/06113 , G01N2201/068 , Y02A50/245 , Y10T428/2982 , Y10T436/163333 , Y10T436/173076
摘要： Polymers and copolymers of polymerizable fluorescent compounds of 7-hydroxycoumarin such as Ethyl-2-methacrylate Umbelliferone-4-acetate are provided. In addition, a sensor comprising this polymer notably for detecting and/or assaying nitrated and organophosphorus compounds, explosives, and toxic compounds is provided.
摘要翻译：提供了7-羟基香豆素的可聚合荧光化合物如2-乙基-2-甲基丙烯酸甲基松香酮-4-乙酸酯的聚合物和共聚物。此外，提供了包含该聚合物的传感器，其特别用于检测和/或测定硝化和有机磷化合物，爆炸物和有毒化合物。

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