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1. 发明授权

US5767210A Process for controlled radical polymerization or copolymerization of (meth)acrylic and vinyl monomers and (co)polymers obtained 失效
标题翻译：获得的（甲基）丙烯酸和乙烯基单体和（共）聚合物的受控自由基聚合或共聚方法
公开(公告)号：US5767210A
公开(公告)日：1998-06-16
申请号：US827386
申请日：1997-03-27
申请人： Philippe Lecomte , Philippe Dubois , Robert Jerome , Philippe Teyssie , Thierry Senninger
发明人： Philippe Lecomte , Philippe Dubois , Robert Jerome , Philippe Teyssie , Thierry Senninger
IPC分类号： C08F2/24 , C08F2/02 , C08F2/38 , C08F4/00 , C08F4/04 , C08F4/26 , C08F4/28 , C08F4/72 , C08F4/80 , C08F20/00 , C08F20/14 , C08F2/00 , C08F20/06
CPC分类号： C08F4/00 , C08F4/80
摘要： This process is characterized by the fact that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature that can be as low as 0.degree. C., in the presence of an initiation system including: at least one compound generating radicals, other than bromofluorene, and at least one catalyst consisting of a complex of palladium in the 0 oxidation state, denoted by the following formula (I): Pd(0)L.sup.1 L.sup.2 L.sup.3 L.sup.4 in which each of L.sup.1, L.sup.2, L.sup.3 and L.sup.4, which are identical or different, denotes a ligand which may be a chiral ligand, which is chosen from PRR'R", P(OR)(OR')(OR"), NRR'R", ORR', SRR', SeRR', AsRR'R", SbRR'R", where each of R, R' and R" independently denotes a C.sub.1 -C.sub.14 alkyl group, optionally substituted, or an optionally substituted aromatic group, it being possible for at least two of these ligands to be joined to one another by one or more divalent radicals.
摘要翻译：该方法的特征在于，在起始系统存在下，至少一种所述单体在本体，溶液，乳液或悬浮液中在可低至0℃的温度下聚合或共聚，包括：除了溴芴之外，至少一种产生自由基的化合物和至少一种由O型氧化态的钯络合物组成的催化剂，由下式（I）表示：Pd（0）L1L2L3L4，其中L1，L2 表示可以是手性配体的配体，其选自PRR'R“，P（OR）（OR'）（OR”）（OR“），NRR'R” ，ORR'，SRR'，SeRR'，AsRR'R“，SbRR'R”，其中R，R'和R“各自独立地表示任选取代的C 1 -C 14烷基或任选取代的芳族这些配体中的至少两个可能通过一个或多个二价基团彼此连接。

2. 发明授权

US5811500A Process for the controlled radical (CO) polymerization of (Meth) acrylic vinyl vinylidene and diene monomers in the presence of an Rh Co OR Ir 失效
标题翻译：（甲基）丙烯酸乙烯基亚乙烯基和二烯单体在Rh Co OR Ir存在下的受控自由基（CO）聚合方法
公开(公告)号：US5811500A
公开(公告)日：1998-09-22
申请号：US884219
申请日：1997-06-27
申请人： Philippe Dubois , Georges Moineau , Philippe Teyssie , Robert Jerome , Thierry Senninger
发明人： Philippe Dubois , Georges Moineau , Philippe Teyssie , Robert Jerome , Thierry Senninger
IPC分类号： C08F2/24 , C08F2/38 , C08F4/00 , C08F4/04 , C08F4/28 , C08F4/60 , C08F4/72 , C08F4/80 , C08F12/08 , C08F14/00 , C08F18/08 , C08F20/10 , C08F20/14 , C08F297/06 , C08F4/06
CPC分类号： C08F4/00
摘要： This process is characterized in that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature which may be as low as 0.degree. C., in the presence of an initiator system comprising at least one non-peroxy radical-generator compound and at least one catalyst consisting of a metal complex represented by formula Ma.sub.a (L).sub.n in which M represents Rh, Co or Ir; A represents, a halogen or a pseudohalogen; the groups L, which may be identical or different, each represent a ligand which may be a chiral ligand, which is chosen from cyclooctadiene, PRR'R", P(OR) (OR') (OR"), NRR'R", ORR', SRR', SeRR', AsRR'R", SbRR'R", each radical R, R' and R" independently representing an optionally substituted C.sub.1 -C.sub.14 alkyl group or an optionally substituted aromatic group, it being possible for at least two of these ligands to be joined together by one or more divalent radicals; a is an integer such that 1.ltoreq.a.ltoreq.3 ; n is an integer such that 1.ltoreq.n.ltoreq.5, and in the absence of activator.
摘要翻译：该方法的特征在于，至少一种所述单体在本体，溶液，乳液或悬浮液中，在可能低至0℃的温度下，在至少包含至少一种非过氧自由基产生剂化合物和至少一种由式Ma（L）n表示的金属配合物组成的催化剂，其中M表示Rh，Co或Ir; A表示卤素或假卤素; 可以相同或不同的基团L各自表示可以是手性配体的配体，其选自环辛二烯，PRR'R“，P（OR）（OR'）（OR”），NRR' R“，ORR'，SRR'，SeRR'，AsRR'R”，SbRR'R“，每个基团R，R'和R”独立地表示任选取代的C 1 -C 14烷基或任选取代的芳族这些配体中的至少两个可能通过一个或多个二价基团连接在一起; a是整数，使得1

3. 发明授权

US06348564B1 Cyclic esterketone compounds, processes for the synthesis thereof and process for the preparation of poly (esterketone) polymers 失效
标题翻译：环状酯酮化合物，其合成方法和制备聚（酯酮）聚合物的方法
公开(公告)号：US06348564B1
公开(公告)日：2002-02-19
申请号：US09595030
申请日：2000-06-16
申请人： Henri Wautier , Jean-Pierre Latere , Philippe Lecomte , Robert Jerome , Philippe Dubois
发明人： Henri Wautier , Jean-Pierre Latere , Philippe Lecomte , Robert Jerome , Philippe Dubois
IPC分类号： C08G6308
CPC分类号： C07D313/04 , C08G6/02 , C08G63/08
摘要： Unsubstituted oxepane-diones useful as monomers for the production of polymers, process for the synthesis thereof by oxidation of unsubstituted cyclohexanediones, process for the preparation of polyesterketone polymers by polymerization of cyclic esterketones and polyesterketone polymers so obtained.
摘要翻译：可用作生产聚合物的单体的未取代的氧杂环庚烷二酮，通过未取代的环己二酮的氧化合成的方法，通过如此获得的环状酯酮和聚酯酮聚合物的聚合制备聚酯酮聚合物的方法。

4. 发明授权

US06375821B1 Method for coating electrically conductive particles by grafting a polymer layer 失效
标题翻译：通过接枝聚合物层涂覆导电颗粒的方法
公开(公告)号：US06375821B1
公开(公告)日：2002-04-23
申请号：US09529643
申请日：2000-06-19
申请人： Robert Jerome , Lucien Martinot , Marc Mertens , Isabelle Bodart , Philippe Dubois
发明人： Robert Jerome , Lucien Martinot , Marc Mertens , Isabelle Bodart , Philippe Dubois
IPC分类号： C25D902
CPC分类号： C09D5/4476
摘要： The invention concerns a method for forming a coating on conductive particles by grafting a polymer and/or a copolymer of the particles from a bath containing at least a monomer from which the polymer and/or copolymer is formed. The method consists of producing the grafting by electrochemical reduction of the monomer in an electrolytic solution, where at least a cathode and an anode are provided, and containing an aprotic solvent, a support electrolyte and the monomer(s) required for polymerizing or copolymerizing the coating, by suspending the particles and moving the solution so as to produce an intermittent contact between the particles and the cathode, and to form, by polymerization or copolymerization, the coating on the particles by applying an electric potential.
摘要翻译：本发明涉及一种通过从至少含有形成聚合物和/或共聚物的单体的浴接枝颗粒的聚合物和/或共聚物而在导电颗粒上形成涂层的方法。该方法包括通过在电解液中电化学还原单体进行接枝，其中至少提供阴极和阳极，并且含有非质子溶剂，载体电解质和聚合或共聚所需的单体通过使颗粒悬浮并移动溶液以在颗粒和阴极之间产生间歇接触，并通过施加电势而在颗粒上聚合或共聚而形成涂层。

5. 发明授权

US6166169A Aliphatic polyesters and/or copolyesters and a process for the production thereof 有权
标题翻译：脂族聚酯和/或共聚酯及其制备方法
公开(公告)号：US6166169A
公开(公告)日：2000-12-26
申请号：US232144
申请日：1999-01-15
申请人： Hans-Gerhard Fritz , Sven Jacobsen , Robert Jerome , Philippe Degee , Philippe Dubois
发明人： Hans-Gerhard Fritz , Sven Jacobsen , Robert Jerome , Philippe Degee , Philippe Dubois
IPC分类号： C08G63/78 , C08G63/82 , C08K5/13 , C08K5/524 , C08G63/02
CPC分类号： C08K5/13 , C08G63/78 , C08G63/823 , C08K5/524 , C08L67/00
摘要： An aliphatic polyester and/or copolyester, obtained from a polyreaction of at least one monomer from the group comprising lactides, lactones, cyclic carbonates and cyclic anhydrides. To be able to prepare the aliphatic polyester and/or copolyester a reaction mixture is used which contains at least one catalyst of the general formula (M) (X.sub.1, X.sub.2 . . . X), M being a metal selected from the group 3 to 12 of the periodic system (X.sub.1, X.sub.2 . . . X.sub.m) being a substituent selected from one of the families of alkyls, aryls, oxides, carboxylates, halogenides, alkoxides and compounds with elements from group 15 and/or 16 of the periodic system, m being an integer in the range of from 1 to 6, and n being an integer in the range of from 0 to 6, and which also contains a co-catalyst of the general formula (Y) (R.sub.1, R.sub.2 . . . R.sub.q).sub.p, Y being an element selected from the group 15 or 16 of the periodic system. (R.sub.1, R.sub.2 . . . R.sub.q) being a substituent selected from one of the families of the alkyls, aryls, oxides, halogenides, oxyalkyls, aminoalkyls, thiolkyls, phenoxides, aminioaryls, thioaryls, and q and p corresponding to the values for m and n.
摘要翻译：由至少一种包含丙交酯，内酯，环状碳酸酯和环状酸酐的单体的多元反应获得的脂族聚酯和/或共聚酯。为了能够制备脂肪族聚酯和/或共聚酯，使用含有至少一种通式（M）的催化剂（X1，X2 ... X）的反应混合物，M是选自组3 周期性系统（X1，X2 ... Xm）的12位是选自烷基，芳基，氧化物，羧酸盐，卤化物，醇盐和具有周期系统的第15和/或16族元素的化合物之一的取代基 m为1〜6的整数，n为0〜6的整数，并且还含有通式（Y）（R1，R2，...）的助催化剂。 R q）p，Y是选自周期系统的组15或16的元素。（R1，R2 ... Rq）是选自烷基，芳基，氧化物，卤化物，烷氧基，氨基烷基，硫代烷基，苯氧基，氨基芳基，硫代芳基中的一个族的取代基，对应于m的值的q和p 和n。

6. 发明授权

US09249253B2 Polylactide-urethane copolymers 有权
标题翻译：聚丙交酯 - 聚氨酯共聚物
公开(公告)号：US09249253B2
公开(公告)日：2016-02-02
申请号：US12442481
申请日：2007-09-27
申请人： Philippe Dubois , Philippe Coszach , Gloria Vendrell , Philippe Degee , Michael Alexandre , Ibrahim Barakat , Jean Marie Raquez
发明人： Philippe Dubois , Philippe Coszach , Gloria Vendrell , Philippe Degee , Michael Alexandre , Ibrahim Barakat , Jean Marie Raquez
IPC分类号： C08G18/42 , C08G18/32 , C08G18/08 , C08G18/10
CPC分类号： C08G18/4283 , C08G18/0895 , C08G18/10 , C08G18/3206 , C08G18/3228 , C08G18/3231 , C08G18/428 , C08G2230/00 , C08G18/3225
摘要： The process of obtaining a polylactide-urethane copolymer is described which includes contacting an α, ω dihydroxyl polylactide prepolymer of general formula I wherein X is NH or O, R is an alkyl or an aryl group, n and n′ are integer numbers which are substantially the same and are in the range from 20 to 140, with a diisocyanate compound of general formula II O═C═N—R′—N═C═O wherein R′ is an alkyl or an aryl group and with an amine or an alcohol of general formula III R″X′]2 wherein R″ is an alkyl or an aryl group and X′ is NH2 or OH, and with the proviso that at least one of R or R″ is an aryl group.
摘要翻译：描述了获得聚丙交酯 - 氨基甲酸酯共聚物的方法，该方法包括使通式I的α，ω二羟基聚丙交酯预聚物，其中X是NH或O，R是烷基或芳基，n和n'是整数，基本相同并且在20至140的范围内，与通式II的二异氰酸酯化合物O = C = N-R'-N = C = O，其中R'为烷基或芳基，并与胺或通式III R“X”] 2的醇，其中R“是烷基或芳基，X'是NH 2或OH，条件是R”或R“中的至少一个是芳基。

7. 发明申请

US20110125108A1 SURGICAL INSTRUMENT PREFERABLY WITH TEMPERATURE CONTROL 审中-公开
标题翻译：手术仪器优先采用温度控制
公开(公告)号：US20110125108A1
公开(公告)日：2011-05-26
申请号：US12992248
申请日：2009-05-18
申请人： Jacques Deviere , Alain Delchambre , Nicolas Cauche , Sonia Dugardeyn , Philippe Dubois , Jean-Marie Raquez
发明人： Jacques Deviere , Alain Delchambre , Nicolas Cauche , Sonia Dugardeyn , Philippe Dubois , Jean-Marie Raquez
IPC分类号： A61M5/32
CPC分类号： A61B17/06066 , A61B18/082 , A61B18/1445 , A61B2017/00084 , A61B2017/00092 , A61B2017/0034 , A61B2017/00398 , A61B2017/00871 , A61B2017/2926 , A61B2018/00011 , A61B2018/0022 , A61B2018/00702 , A61B2018/00791 , A61B2218/002
摘要： A surgical needle has shape memory. An endoscope tool controls the temperature of a foreign body or surgical instrument such as an endoscopic needle.
摘要翻译：手术针头有形状记忆。内窥镜工具控制诸如内窥镜针的异物或外科器械的温度。

8. 发明申请

US20090298994A1 Polymer-Based Composites Comprising Carbon Nanotubes As A Filler, Method for Producing Said Composites, And Associated Uses 有权
标题翻译：包含作为填料的碳纳米管的聚合物基复合材料，生产所述复合材料的方法及相关用途
公开(公告)号：US20090298994A1
公开(公告)日：2009-12-03
申请号：US12482240
申请日：2009-06-10
申请人： Philippe Dubois , Michael Alexandre , Daniel Bonduel , Michael Mainil
发明人： Philippe Dubois , Michael Alexandre , Daniel Bonduel , Michael Mainil
IPC分类号： C08K3/04
CPC分类号： C08K7/24 , B01J21/185 , B01J31/2295 , B01J2531/48 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B2202/06 , C08F2/44 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F110/02 , C08J5/005 , C08J2323/06 , C08K2201/011 , C08F4/02 , C08F4/65916 , C08F4/70
摘要： This invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a co-catalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in a field of polymers, especially that of nanotechnologies.
摘要翻译：本发明涉及分散状态的碳纳米管的制造方法。该方法包括在催化体系存在下由至少一种所谓的目的单体进行聚合的阶段。催化体系包括由对应于所述碳纳米管的催化剂载体负载的助催化剂/催化剂催化剂。本发明还涉及通过所述方法获得的复合材料以及用于实现所述方法的催化体系。本发明还涉及本发明的方法和产品在聚合物领域，特别是纳米技术领域中的应用。

9. 发明授权

US07550543B2 Polymer-based composites comprising carbon nanotubes as a filler, method for producing said composites, and associated uses 失效
标题翻译：包含碳纳米管作为填料的聚合物基复合材料，所述复合材料的制造方法和相关用途
公开(公告)号：US07550543B2
公开(公告)日：2009-06-23
申请号：US10567197
申请日：2004-08-05
申请人： Philippe Dubois , Michael Alexandre , Daniel Bonduel , Michael Mainil
发明人： Philippe Dubois , Michael Alexandre , Daniel Bonduel , Michael Mainil
IPC分类号： C08F4/608 , C08F4/602 , C08F4/6192 , B01J31/22
CPC分类号： C08K7/24 , B01J21/185 , B01J31/2295 , B01J2531/48 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B2202/06 , C08F2/44 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F110/02 , C08J5/005 , C08J2323/06 , C08K2201/011 , C08F4/02 , C08F4/65916 , C08F4/70
摘要： The invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a cocatalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in the field of polymers, especially that of nanotechnologies.
摘要翻译：本发明涉及分散状态的碳纳米管的制造方法。该方法包括在催化体系存在下由至少一种所谓的目的单体进行聚合的阶段。催化体系包括由对应于所述碳纳米管的催化剂载体负载的助催化剂/催化剂催化剂。本发明还涉及通过所述方法获得的复合材料以及用于实现所述方法的催化体系。本发明还涉及本发明的方法和产品在聚合物领域，特别是纳米技术领域中的应用。

10. 发明申请

US20070203261A1 Reactively blended polyester and filler composite compositions and process 审中-公开
标题翻译：反应性混合聚酯和填料复合组合物和工艺
公开(公告)号：US20070203261A1
公开(公告)日：2007-08-30
申请号：US11362381
申请日：2006-02-24
申请人： Ramani Narayan , Yogaraj Nabar , Jean-Marie Raquez , Philippe Dubois
发明人： Ramani Narayan , Yogaraj Nabar , Jean-Marie Raquez , Philippe Dubois
IPC分类号： C08K9/00
CPC分类号： C08K9/08
摘要： High-performance inorganic filled thermoplastic polyester composites are provided, and the process for preparing thereof. Biodegradable inorganic filled thermoplastic polyester composites are provided by reactive melt-blending of biodegradable thermoplastic polyesters with inorganic fillers using a reactive extrusion processing.
摘要翻译：提供高性能无机填充热塑性聚酯复合材料及其制备方法。可生物降解的无机填充热塑性聚酯复合材料是通过使用反应性挤出加工将可生物降解的热塑性聚酯与无机填料进行反应性熔融共混来提供的。

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