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    • 1. 发明授权
    • Method of preparing fiber/resin composites
    • 制备纤维/树脂复合材料的方法
    • US5679719A
    • 1997-10-21
    • US473730
    • 1995-06-07
    • Philip T. KlemarczykYoshihisa OkamotoJames P. Moran, Jr.Susan LevandoskiVeronica Hanlon
    • Philip T. KlemarczykYoshihisa OkamotoJames P. Moran, Jr.Susan LevandoskiVeronica Hanlon
    • C08F2/50C08F283/10C08J3/24C08J5/04C08L63/02C08L63/04
    • C08F283/10C08J3/243C08J5/04C08J5/24C08J2363/00Y10T428/2918Y10T428/2936
    • Resin compositions useful for filament winding applications comprising an epoxy component including at least one polyepoxide resin curable by heat, an olefinicially unsaturated monomer component including at least one polyolefinically unsaturated monomer curable by actinic radiation, at least one photoinitiator which is not a peroxide, at least one organic peroxide, and a heat activated curing agent for epoxides. The compositions have a viscosity less than about 2000 centipoise (cps) and are capable of retaining this viscosity for at least about 2 hours at a temperature of from about ambient temperature to about 60.degree. C. The resins are capable of being immobilized by actinic radiation exposure and further heat cured without substantial resin drip. One or more organic peroxides are employed, selected from the group of organic peroxides having 10 hour decomposition half lives at temperatures of from about 50.degree. C. to less than about 104.degree. C. Also, fiber resin composites comprising fiber substrates impregnated with the dual-curing resin compositions is disclosed. Also the process for coating fiber substrates with the dual-curing resin compositions is disclosed.
    • 用于长丝缠绕应用的树脂组合物,其包含包含至少一种可热固化的聚环氧树脂的环氧组分,包含至少一种可通过光化辐射固化的聚烯烃不饱和单体的烯属不饱和单体组分,至少一种不是过氧化物的光引发剂,至少 一种有机过氧化物和用于环氧化物的热活化固化剂。 该组合物的粘度小于约2000厘泊(cps),并且能够在约环境温度至约60℃的温度下保持该粘度至少约2小时。树脂能够通过光化辐射固定 暴露并进一步加热固化,而没有实质的树脂滴落。 使用一种或多种有机过氧化物,选自在约50℃至小于约104℃的温度下具有10分钟分解半衰期的有机过氧化物。此外,包含浸渍有双重的纤维基材的纤维树脂复合材料 公开了固化树脂组合物。 还公开了用双重固化树脂组合物涂布纤维基材的方法。
    • 2. 发明授权
    • Filament winding compositions for fiber/resin composites
    • 纤维/树脂复合材料的丝卷绕组合物
    • US5585414A
    • 1996-12-17
    • US478893
    • 1995-06-07
    • Philip T. KlemarczykYoshihisa OkamotoJames P. Moran, Jr.
    • Philip T. KlemarczykYoshihisa OkamotoJames P. Moran, Jr.
    • C08F2/50C08F283/10C08J3/24C08J5/04B29C35/10C08L63/00
    • C08J5/24C08F283/10C08J3/243C08J5/04C08J2363/00Y10T428/1314Y10T428/1321Y10T428/1362Y10T428/1369Y10T428/2936
    • Resin compositions useful for filament winding applications comprising an epoxy component including at least one polyepoxide resin curable by heat, an olefinicially unsaturated monomer component including at least one polyolefinically unsaturated monomer curable by actinic radiation, at least one photoinitiator, at least one organic peroxide, and a heat activated curing agent for epoxides. The compositions have a viscosity less than about 2000 centipoise (cps) and are capable of retaining this viscosity for at least about 2 hours at a temperature of from about ambient temperature to about 60.degree. C. The resins are capable of being immobilized by actinic radiation exposure and further heat cured without substantial resin drip. One or more organic peroxides are employed, selected from the group of organic peroxides having 10 hour decomposition half lives at temperatures of from about 50.degree. C. to less than about 104.degree. C. Also, fiber resin composites comprising fiber substrates impregnated with the dual-curing resin compositions. Also the process for coating fiber substrates with the dual-curing resin compositions is disclosed.
    • 用于长丝缠绕应用的树脂组合物包括包含至少一种可热固化的聚环氧树脂的环氧组分,包含至少一种可通过光化辐射固化的聚烯烃不饱和单体的烯属不饱和单体组分,至少一种光引发剂,至少一种有机过氧化物和 用于环氧化物的热活化固化剂。 该组合物的粘度小于约2000厘泊(cps),并且能够在约环境温度至约60℃的温度下保持该粘度至少约2小时。树脂能够通过光化辐射固定 暴露并进一步加热固化,而没有实质的树脂滴落。 使用一种或多种有机过氧化物,选自在约50℃至小于约104℃的温度下具有10分钟分解半衰期的有机过氧化物。此外,包含浸渍有双重的纤维基材的纤维树脂复合材料 固化树脂组合物。 还公开了用双重固化树脂组合物涂布纤维基材的方法。
    • 3. 发明授权
    • Filament-winding compositions for fiber/resin composites
    • 纤维/树脂复合材料的丝缠绕组合物
    • US5565499A
    • 1996-10-15
    • US468550
    • 1995-06-06
    • Philip T. KlemarczykYoshihisa OkamotoJames P. Moran, Jr.
    • Philip T. KlemarczykYoshihisa OkamotoJames P. Moran, Jr.
    • C08F2/50C08F283/10C08J3/24C08J5/04B29C35/10C08L63/00
    • C08J5/24C08F283/10C08J3/243C08J5/04C08J2363/00Y10T428/1314Y10T428/1321Y10T428/1362Y10T428/1369Y10T428/2936
    • Resin compositions useful for filament winding applications comprising an epoxy component including at least one polyepoxide resin curable by heat, an olefinicially unsaturated monomer component including at least one polyolefinically unsaturated monomer curable by actinic radiation, at least one photoinitiator, at least one organic peroxide, and a heat activated curing agent for epoxides. The compositions have a viscosity less than about 2000 centipoise (cps) and are capable of retaining this viscosity for at least about 2 hours at a temperature of from about ambient temperature to about 60.degree. C. The resins are capable of being immobilized by actinic radiation exposure and further heat cured without substantial resin drip. One or more organic peroxides are employed, selected from the group of organic peroxides having 10 hour decomposition half lives at temperatures of from about 50.degree. C. to less than about 104.degree. C. Also, fiber resin composites comprising fiber substrates impregnated with the dual-curing resin compositions. Also the process for coating fiber substrates with the dual-curing resin compositions is disclosed.
    • 用于长丝缠绕应用的树脂组合物包括包含至少一种可热固化的聚环氧树脂的环氧组分,包含至少一种可通过光化辐射固化的聚烯烃不饱和单体的烯属不饱和单体组分,至少一种光引发剂,至少一种有机过氧化物和 用于环氧化物的热活化固化剂。 该组合物的粘度小于约2000厘泊(cps),并且能够在约环境温度至约60℃的温度下保持该粘度至少约2小时。树脂能够通过光化辐射固定 暴露并进一步加热固化,而没有实质的树脂滴落。 使用一种或多种有机过氧化物,选自在约50℃至小于约104℃的温度下具有10分钟分解半衰期的有机过氧化物。此外,包含浸渍有双重的纤维基材的纤维树脂复合材料 固化树脂组合物。 还公开了用双重固化树脂组合物涂布纤维基材的方法。
    • 5. 发明授权
    • Aromatic vinyl ether compounds and compositions, and method of making
the same
    • 芳族乙烯基醚化合物和组合物及其制备方法
    • US5070117A
    • 1991-12-03
    • US615205
    • 1990-11-19
    • Philip T. KlemarczykYoshihisa Okamoto
    • Philip T. KlemarczykYoshihisa Okamoto
    • C07C43/215C07C43/315C07C69/92C08F2/46C08F16/32
    • C07C43/215C07C43/315C07C69/92C08F16/32
    • An aromatic vinyl ether of the formula: ##STR1## wherein: R.sup.1, R.sub.2, R.sub.4, R.sub.5, R.sub.6, R.sub.8, R.sub.9, and R.sup.10 are independently selected from hydrogen, halogen, and C.sub.1 -C.sub.8 alkyl radicals;R.sub.3 and R.sub.7 are independently selected from C.sub.1 -C.sub.8 alkylene radicals; andR.sub.11 and R.sub.12 are independently selected from allyl and methallyl.Also disclosed are various other aromatic vinyl ether compounds, chain-extended derivatives thereof, and liquid vinyl ether blends, and a method of making the aromatic vinyl ether compounds at high yield. The aromatic vinyl ether compounds, chain-extended vinyl derivatives, and/or liquid vinyl ether blends of the invention may be employed as vinyl ether components together with cationic photoinitiators, to provide cationically polymerizable vinyl ether compositions having utility in applications such as coatings, adhesives, and sealants.
    • 下式的芳族乙烯基醚其中:R 1,R 2,R 4,R 5,R 6,R 8,R 9和R 10独立地选自氢,卤素和C 1 -C 8烷基; R 3和R 7独立地选自C 1 -C 8亚烷基; R 11和R 12独立地选自烯丙基和甲代烯丙基。 还公开了各种其它芳族乙烯基醚化合物,其链延伸的衍生物和液体乙烯基醚共混物,以及以高产率制备芳族乙烯基醚化合物的方法。 本发明的芳族乙烯基醚化合物,链延长的乙烯基衍生物和/或液体乙烯基醚共混物可以与阳离子光引发剂一起用作乙烯基醚组分,以提供可用于例如涂料,粘合剂 ,和密封剂。
    • 6. 发明授权
    • Fiber/resin composites and method of preparation
    • 纤维/树脂复合材料及其制备方法
    • US5539012A
    • 1996-07-23
    • US108437
    • 1993-08-18
    • Philip T. KlemarczykYoshihisa Okamoto
    • Philip T. KlemarczykYoshihisa Okamoto
    • C08F2/50C08F283/10C08J3/24C08J5/04C08L63/00
    • C08J3/243C08F283/10C08J5/04Y10T428/1314Y10T428/1321Y10T428/1362
    • Resin compositions useful for filament winding applications comprising an epoxy component including at least one polyepoxide resin curable by heat, an olefinicially unsaturated monomer component including at least one polyolefinically unsaturated monomer curable by actinic radiation, a cyanate ester component including at least one cyanate ester compound having at least two cyanate functional groups per molecule, at least one organic peroxide, at least one photoinitiator, and a heat activated curing agent for epoxides. The compositions have a viscosity less than about 2000 centipoise (cps) and are capable of retaining this viscosity for at least about 6 months at about ambient temperature. The resins are capable of being immobilized by actinic radiation exposure and further heat cured without substantial resin drip. One or more organic peroxides are employed, selected from the group of organic peroxides having 10 hour decomposition half-lives at temperatures of from about 50.degree. C. to less than about 104.degree. C. Also, fiber resin composites comprising fiber substrates impregnated with the dual-curing resin compositions. Also the process for coating fiber substrates with the dual-curing resin compositions is disclosed.
    • 可用于长丝缠绕应用的树脂组合物包括包含至少一种可热固化的聚环氧树脂的环氧组分,包含至少一种可通过光化辐射固化的聚烯烃不饱和单体的烯属不饱和单体组分,包含至少一种氰酸酯化合物的氰酸酯组分, 每分子至少两个氰酸酯官能团,至少一种有机过氧化物,至少一种光引发剂和用于环氧化物的热活化固化剂。 组合物的粘度小于约2000厘泊(cps),并且能够在约环境温度下保持该粘度至少约6个月。 树脂能够通过光化辐射暴露固定,并进一步热固化而没有大量的树脂滴落。 使用一种或多种有机过氧化物,其选自在约50℃至小于约104℃的温度下具有10小时分解半衰期的有机过氧化物。此外,纤维树脂复合材料包含浸渍有 双固化树脂组合物。 还公开了用双重固化树脂组合物涂布纤维基材的方法。