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1. 发明授权

US08729179B1 Moisture curable polyacrylates 有权
标题翻译：可湿固化聚丙烯酸酯
公开(公告)号：US08729179B1
公开(公告)日：2014-05-20
申请号：US13738348
申请日：2013-01-10
申请人： Philip T. Klemarczyk , Anthony F. Jacobine , Joel D. Schall
发明人： Philip T. Klemarczyk , Anthony F. Jacobine , Joel D. Schall
IPC分类号： C08L57/10 , C07F7/02 , C07F7/08
CPC分类号： C08F220/18 , C07F7/1804 , C07F7/1892 , C08F8/42 , C08F120/18 , C08F2438/01 , C08F2800/10 , C08F2810/20 , C08F2810/40 , C09J133/08 , C08F2220/1825 , C08F2220/1808 , C08F2220/285
摘要： A process for preparing moisture curable compounds and moisture curable compositions prepared from the product of that process is provided.
摘要翻译：提供了由该方法的产物制备的可湿气固化的化合物和可湿气固化的组合物的方法。

2. 发明授权

US08030401B1 Photoinitiated cationic epoxy compositions 失效
标题翻译：光引发的阳离子环氧组合物
公开(公告)号：US08030401B1
公开(公告)日：2011-10-04
申请号：US11498422
申请日：2006-08-03
申请人： Philip T. Klemarczyk , Anthony F. Jacobine
发明人： Philip T. Klemarczyk , Anthony F. Jacobine
IPC分类号： C08G59/68 , C08F8/18 , C08L27/06 , C08L63/02
CPC分类号： C08G59/687 , C08K5/1515 , C09D163/00 , C08L27/06
摘要： The present invention is directed to photoinitiated cationic epoxy compositions including: (a) at least one substantially saturated epoxy material comprising at least two glycidyl ether groups; (b) about 0.1 to about 20 weight percent on a basis of total weight of the composition of at least one polymer comprising at least one vinyl chloride segment and at least one vinyl acetate segment; and (c) at least one cationic photoinitiator; and bonded substrates and methods of bonding including the same.
摘要翻译：本发明涉及光引发的阳离子环氧组合物，其包括：（a）至少一种包含至少两个缩水甘油醚基团的基本上饱和的环氧材料; （b）基于组合物的总重量为约0.1至约20重量％的至少一种包含至少一个氯乙烯链段和至少一个乙酸乙烯酯链段的聚合物; 和（c）至少一种阳离子光引发剂; 和粘合基材和包括其的粘合方法。

3. 发明申请

US20110290418A1 HYDROGEN PEROXIDE COMPLEXES AND THEIR USE IN THE CURE SYSTEM OF ANAEROBIC ADHESIVES 有权
标题翻译：过氧化氢复合物及其在厌氧粘合剂固化体系中的应用
公开(公告)号：US20110290418A1
公开(公告)日：2011-12-01
申请号：US13177921
申请日：2011-07-07
申请人： Philip T. Klemarczyk , David Birkett , David Farrell , Peter Wrobel , Ciaran McArdle , Greg Clarke
发明人： Philip T. Klemarczyk , David Birkett , David Farrell , Peter Wrobel , Ciaran McArdle , Greg Clarke
IPC分类号： B32B37/12 , C07C233/31 , C07C275/02 , C07D207/26 , C09J4/02 , C09K3/00
CPC分类号： C07C275/02 , C07C275/06 , C09J4/00 , C09J5/06
摘要： Provided is a complex of hydrogen peroxide and at least one compound represented by Formula I: wherein X is: —C(R3)3, —C≡C(R3), —O(R3), —N(R3)2, or —S(R3); and R1, R2, and R3 are each independently selected from H, alkyl, alkenyl, alkynyl, aralkyl, aryl, heteroaryl heteroarylalkyl, heterocyclyl, and cycloalkyl, or R2 and an R3 are optionally taken together to form an alicyclic ring. Also provided are anaerobic cure systems and curable compositions employing the complexes described herein.
摘要翻译：提供了过氧化氢和至少一种由式I表示的化合物的络合物：其中X是：-C（R 3）3，-C≡C（R 3），-O（R 3），-N（R 3）2或 -S（R 3）; 并且R 1，R 2和R 3各自独立地选自H，烷基，烯基，炔基，芳烷基，芳基，杂芳基杂芳基烷基，杂环基和环烷基，或者R 2和R 3任选地一起形成脂环族环。还提供了使用本文所述复合物的厌氧固化体系和可固化组合物。

4. 发明授权

US06255500B1 Process for the epoxidation of diene esters 失效
标题翻译：二烯酯环氧化方法
公开(公告)号：US06255500B1
公开(公告)日：2001-07-03
申请号：US09488833
申请日：2000-01-21
申请人： Philip T. Klemarczyk
发明人： Philip T. Klemarczyk
IPC分类号： C07D30114
CPC分类号： C08G59/027 , C07D303/44 , C08G59/24
摘要： Process for the preparation of aliphatic diene ester diepoxides comprising the steps of a) reacting an aliphalic diene ester with a peracid at a temperature at or below 15° C. in the absence of a pH control agent to epoxidize the double bonds of the diene ester; and b) isolating the epoxidized diene ester form the resulting reaction mixture.
摘要翻译：用于制备脂族二烯烃二环氧化物的方法，包括以下步骤：a）在不存在pH控制剂的情况下，在等温或低于15℃的温度下，将脂族二烯烃与过酸反应，以环氧化二烯酯的双键; 和b）从得到的反应混合物中分离环氧化二烯酯。

5. 发明授权

US5585414A Filament winding compositions for fiber/resin composites 失效
标题翻译：纤维/树脂复合材料的丝卷绕组合物
公开(公告)号：US5585414A
公开(公告)日：1996-12-17
申请号：US478893
申请日：1995-06-07
申请人： Philip T. Klemarczyk , Yoshihisa Okamoto , James P. Moran, Jr.
发明人： Philip T. Klemarczyk , Yoshihisa Okamoto , James P. Moran, Jr.
IPC分类号： C08F2/50 , C08F283/10 , C08J3/24 , C08J5/04 , B29C35/10 , C08L63/00
CPC分类号： C08J5/24 , C08F283/10 , C08J3/243 , C08J5/04 , C08J2363/00 , Y10T428/1314 , Y10T428/1321 , Y10T428/1362 , Y10T428/1369 , Y10T428/2936
摘要： Resin compositions useful for filament winding applications comprising an epoxy component including at least one polyepoxide resin curable by heat, an olefinicially unsaturated monomer component including at least one polyolefinically unsaturated monomer curable by actinic radiation, at least one photoinitiator, at least one organic peroxide, and a heat activated curing agent for epoxides. The compositions have a viscosity less than about 2000 centipoise (cps) and are capable of retaining this viscosity for at least about 2 hours at a temperature of from about ambient temperature to about 60.degree. C. The resins are capable of being immobilized by actinic radiation exposure and further heat cured without substantial resin drip. One or more organic peroxides are employed, selected from the group of organic peroxides having 10 hour decomposition half lives at temperatures of from about 50.degree. C. to less than about 104.degree. C. Also, fiber resin composites comprising fiber substrates impregnated with the dual-curing resin compositions. Also the process for coating fiber substrates with the dual-curing resin compositions is disclosed.
摘要翻译：用于长丝缠绕应用的树脂组合物包括包含至少一种可热固化的聚环氧树脂的环氧组分，包含至少一种可通过光化辐射固化的聚烯烃不饱和单体的烯属不饱和单体组分，至少一种光引发剂，至少一种有机过氧化物和用于环氧化物的热活化固化剂。该组合物的粘度小于约2000厘泊（cps），并且能够在约环境温度至约60℃的温度下保持该粘度至少约2小时。树脂能够通过光化辐射固定暴露并进一步加热固化，而没有实质的树脂滴落。使用一种或多种有机过氧化物，选自在约50℃至小于约104℃的温度下具有10分钟分解半衰期的有机过氧化物。此外，包含浸渍有双重的纤维基材的纤维树脂复合材料固化树脂组合物。还公开了用双重固化树脂组合物涂布纤维基材的方法。

6. 发明授权

US5066743A Two-part composition comprising a cyanoacrylate adhesive and a primer comprising a tertiary ammonium carboxylate compound 失效
标题翻译：包含氰基丙烯酸酯粘合剂和包含叔羧酸铵化合物的底漆的两部分组合物
公开(公告)号：US5066743A
公开(公告)日：1991-11-19
申请号：US568386
申请日：1990-08-16
申请人： Yoshihisa Okamoto , Philip T. Klemarczyk
发明人： Yoshihisa Okamoto , Philip T. Klemarczyk
IPC分类号： B05D3/10 , C08F2/00 , C08J5/12
CPC分类号： C08J5/124
摘要： The invention relates to a tertiary ammonium alkyl carboxylate primer for bonding surface with cyanoacrylate adhesives, and to a method of bonding low surface energy surfaces using such tertiary ammonium alkyl carboxylates. A preferred primer is tridodecylammonium stearate and preferred solvents for the tertiary ammonium alkyl carboxylate are non-aqueous, low surface tension organic solvents.
摘要翻译：本发明涉及用氰基丙烯酸酯粘合剂粘合表面的叔烷基羧酸烷基酯底漆，以及使用这种烷基羧酸叔铵键合低表面能表面的方法。优选的底漆是十三烷基硬脂酸铵，优选的叔烷基羧酸烷基酯的溶剂是非水的低表面张力的有机溶剂。

7. 发明授权

US4487701A Process of augmenting or enhancing the aroma of fabric softeners and detergents using cyclohexenyl-alpha-alkyl acrolein derivatives 失效
标题翻译：使用环己烯基-α-烷基丙烯醛衍生物增强或增强织物柔软剂和洗涤剂的香气的方法
公开(公告)号：US4487701A
公开(公告)日：1984-12-11
申请号：US609350
申请日：1984-05-11
申请人： Mark A. Sprecker , Philip T. Klemarczyk , Robert P. Belko
发明人： Mark A. Sprecker , Philip T. Klemarczyk , Robert P. Belko
IPC分类号： A24B15/34 , C07C45/74 , C07C45/82 , C07C47/225 , C11B9/00 , C11D3/50
CPC分类号： C07C403/14 , A24B15/34 , C07C45/74 , C07C45/82 , C07C47/225 , C11B9/0034 , C07C2101/16
摘要： Described are cyclohexenyl-alpha-alkyl acrolein derivatives defined according to the generic structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen or methyl with the proviso that one, two or three of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent methyl; wherein R.sub.5 represents methyl or ethyl; wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond; wherein the wavy lines represent the "cis" or "trans" juxtaposition of the moieties hydrogen, R.sub.5, cyclohexenyl and carboxaldehyde about the carbon-carbon double bond; or represented by the structures: ##STR2## and processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, perfumed articles, colognes, smoking tobaccos and smoking tobacco articles using as the essential ingredient at least one of said cyclohexenyl-alpha-alkyl acrolein derivatives.
摘要翻译：描述了根据通用结构定义的环己烯基-α-烷基丙烯醛衍生物：其中R 1，R 2，R 3和R 4表示氢或甲基，条件是R 1，R 2，R 3和R 4中的一个，两个或三个表示甲基 ; 其中R 5表示甲基或乙基; 其中一条虚线表示碳 - 碳双键，另一条虚线表示碳 - 碳单键; 其中波浪线表示碳 - 碳双键周围部分氢，R5，环己烯基和甲醛的“顺式”或“反式”并置; 或由以下结构表示：＆lt; IMAGE＆gt;图像＆gt;以及用于增强或增强消费材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，香料制品，古龙水，烟草烟草和烟草制品，其中使用至少一种所述环己烯基-α-烷基丙烯醛衍生物作为必需成分。

8. 发明授权

US4451403A Substituted methyl isopropyl oxocyclohexane derivatives, organoleptic uses thereof and process for preparing same 失效
标题翻译：取代甲基异丙基氧代环己烷衍生物，其感官用途及其制备方法
公开(公告)号：US4451403A
公开(公告)日：1984-05-29
申请号：US343571
申请日：1982-04-26
申请人： Philip T. Klemarczyk
发明人： Philip T. Klemarczyk
IPC分类号： C07C35/18 , C07C45/62 , C07C45/72 , C07C49/203 , C07C49/647 , C11B9/00 , C07C50/02 , C07C69/025
CPC分类号： C11B9/0034 , C07C35/18 , C07C45/62 , C07C45/72 , C07C49/203 , C07C49/647
摘要： Described is the genus of compounds defined according to the structure: ##STR1## wherein at least one of the lines:[++++]represents a carbon-carbon single bond and the other of the lines:[++++]represents a carbon-carbon double bond or a carbon-carbon single bond; wherein the moiety X represents one of the moieties: ##STR2## wherein when the moiety X has the structure: ##STR3## then one of the lines:[++++]is a carbon-carbon double bond and the other of the lines:[++++]is a carbon-carbon single bond and when the moiety X has the structure: ##STR4## then both of the lines:[++++]represent carbon-carbon single bonds; wherein, one of R.sub.1, R.sub.2 and R.sub.3 represent 2-methyl-1-propenyl or 2-methyl-1-propylidenyl; and the other of R.sub.1, R.sub.2 and R.sub.3 represent hydrogen; with the provisos that:(i) when the line:[++++] at the 3-4 position is a double bond, then R.sub.3 is hydrogen or 2-methyl-1-propenyl; and(ii) when the line:[++++] at the 2-3 position is a double bond, then R.sub.2 is hydrogen or 2-methyl-1-propenyl.with the members of said genus being novel compounds useful in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, colognes and perfumed articles (e.g., solid or liquid anionic, cationic, nonionic or zwitterionic detergents, cosmetic powder compositions, fabric softener compositions and fabric softener articles).
摘要翻译：描述根据以下结构定义的化合物属：其中至少一行：[++++]表示碳 - 碳单键，另一行：[++++]表示碳 - 碳双键或碳 - 碳单键; 其中部分X表示以下部分之一：其中当部分X具有以下结构时：其中一行：[++++]是碳 - 碳双键，另一条线：[++++]是碳 - 碳单键，当X部分具有以下结构时：，则两行：[++++]表示碳 - 碳单键; 其中，R 1，R 2和R 3中的一个表示2-甲基-1-丙烯基或2-甲基-1-亚丙基; R1，R2和R3中的另一个表示氢; 条件是：（i）当3-4位上的线：[++++]是双键时，则R3是氢或2-甲基-1-丙烯基; 和（ii）当2-3位上的线：[++++]是双键时，则R2是氢或2-甲基-1-丙烯基。所述属的成员是用于增强或增强消耗材料（包括香料组合物，古龙水和香料制品）（例如固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，化妆品粉末组合物，织物柔软剂）的香味或味道的新化合物组合物和织物柔软剂制品）。

9. 发明授权

US4424379A Cyclohexenyl-alpha-alkyl acrolein derivatives 失效
标题翻译：环己烯基-α-烷基丙烯醛衍生物
公开(公告)号：US4424379A
公开(公告)日：1984-01-03
申请号：US398953
申请日：1982-07-16
申请人： Mark A. Sprecker , Philip T. Klemarczyk , Robert P. Belko
发明人： Mark A. Sprecker , Philip T. Klemarczyk , Robert P. Belko
IPC分类号： A24B15/34 , C07C45/74 , C07C45/82 , C07C47/225 , C11B9/00
CPC分类号： C11B9/0034 , A24B15/34 , C07C403/14 , C07C45/74 , C07C45/82 , C07C47/225 , C07C2101/16
摘要： Described are cyclohexenyl-alpha-alkyl acrolein derivatives defined according to the generic structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen or methyl with the proviso that one, two or three of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent methyl; wherein R.sub.5 represents methyl or ethyl; wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond; wherein the wavy lines represent the "cis" or "trans" juxtaposition of the moieties hydrogen, R.sub.5, cyclohexenyl and carboxaldehyde about the carbon-carbon double bond; or represented by the structures: ##STR2## and processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, perfumed articles, colognes, smoking tobaccos and smoking tobacco articles using as the essential ingredient at least one of said cyclohexenyl-alpha-alkyl acrolein derivatives.
摘要翻译：描述了根据通用结构定义的环己烯基-α-烷基丙烯醛衍生物：其中R 1，R 2，R 3和R 4表示氢或甲基，条件是R 1，R 2，R 3和R 4中的一个，两个或三个表示甲基 ; 其中R 5表示甲基或乙基; 其中一条虚线表示碳 - 碳双键，另一条虚线表示碳 - 碳单键; 其中波浪线表示碳 - 碳双键周围部分氢，R5，环己烯基和甲醛的“顺式”或“反式”并置; 或由以下结构表示：＆lt; IMAGE＆gt;图像＆gt;以及用于增强或增强消费材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，香料制品，古龙水，烟草烟草和烟草制品，其中使用至少一种所述环己烯基-α-烷基丙烯醛衍生物作为必需成分。

10. 发明授权

US4374053A Unsaturated aldehydes, organoleptic uses thereof and process for preparing same 失效
标题翻译：不饱和醛，感官用途及其制备方法
公开(公告)号：US4374053A
公开(公告)日：1983-02-15
申请号：US303011
申请日：1981-09-17
申请人： Philip T. Klemarczyk , Robert P. Belko , Richard M. Boden
发明人： Philip T. Klemarczyk , Robert P. Belko , Richard M. Boden
IPC分类号： C07C33/02 , C07C45/38 , C07C47/21 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0015 , C07C33/02 , C07C45/38 , C07C47/21 , C07C67/00 , Y02P20/582
摘要： Described is a mixture containing a major proportion of unsaturated aldehydes defined according to the structure: ##STR1## wherein in the mixture in each of the molecules thereof one of the dashed lines represents a carbon-carbon double bond and each of the other of the dashed lines represent carbon-carbon single bonds, prepared by first reacting a diisoamylene compound defined according to the structure: ##STR2## wherein one of the dashed lines represents a carbon-carbon double bond and each of the other of the dashed lines represent carbon-carbon single bonds or defined according to one of the structures: ##STR3## with formaldehyde or a formaldehyde source such as trioxane or paraformaldehyde in the presence of an alkanoic acid anhydride and an acid catalyst; then hydrolyzing the resulting ester or mixture of esters to form an alcohol or mixture of alcohols and finally oxidizing the resulting alcohol or mixture of alcohols to form a mixture of aldehydes; the organoleptic uses of such oxidation products in the field of perfumery, colognes and perfumed articles (e.g., solid or liquid anionic, cationic, nonionic, zwitterionic detergents, fabric softener compositions or dryer-added fabric softener articles).
摘要翻译：描述了根据以下结构限定的主要比例的不饱和醛的混合物：其中在每个分子的混合物中，虚线之一表示碳 - 碳双键，并且每个虚线线代表碳 - 碳单键，其通过首先使根据以下结构定义的二异戊烯化合物反应制备：其中虚线中的一条代表碳 - 碳双键，另一条虚线表示碳 - 碳或者在链烷酸酐和酸催化剂存在下，根据以下结构之一定义：与甲醛或甲醛源如三恶烷或多聚甲醛反应; 然后水解所得的酯或酯的混合物以形成醇或醇的混合物，并最终氧化得到的醇或醇的混合物以形成醛的混合物; 在香料，古龙水和香水制品（例如固体或液体阴离子，阳离子，非离子，两性离子洗涤剂，织物柔软剂组合物或干燥剂添加的织物柔软剂制品）领域中的这种氧化产物的感官用途。

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