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1. 发明申请

US20080226995A1 Thermally controlled particulate core migration within polymer matrix 有权
标题翻译：聚合物基体内的热控粒子芯迁移
公开(公告)号：US20080226995A1
公开(公告)日：2008-09-18
申请号：US11717069
申请日：2007-03-13
申请人： Philip J. Costanzo , Frederick L. Beyer
发明人： Philip J. Costanzo , Frederick L. Beyer
IPC分类号： C08L87/00 , A61K47/48 , G03C5/00
CPC分类号： G03F7/0388
摘要： A composition is provided that includes a polymer matrix. A core having a core surface is embedded within the polymer matrix. A polymeric ligand passivates the core surface and has a moiety Y, where Y is a Diels-Alder group of a diene or dienophile. A polymeric linker has a complementary Diels-Alder group diene or dienophile to moiety Y and forms a Diels-Alder bond with the moiety Y. A composition is also provided that includes polymer matrix having a matrix surface. A core having a core surface is present on the matrix surface. A polymeric ligand passivates the core surface and has a moiety Y, where Y is Diels-Alder group of a diene or dienophile. The polymer matrix and polymeric ligand together define a matrix-ligand Flory-Huggins binary interaction function greater than 0.
摘要翻译：提供了包含聚合物基质的组合物。具有芯表面的芯嵌入聚合物基质内。聚合物配体钝化核心表面并具有部分Y，其中Y是二烯或亲二烯体的Diels-Alder基团。聚合物接头与Y部分具有互补的Diels-Alder族二烯或亲双烯体，并与部分Y形成Diels-Alder键。还提供了包含具有基质表面的聚合物基质的组合物。具有芯表面的芯存在于基体表面上。聚合物配体钝化核心表面并具有部分Y，其中Y是二烯或亲二烯体的Diels-Alder基团。聚合物基质和聚合物配体一起定义了大于0的矩阵 - 配体Flory-Huggins二元相互作用函数。

2. 发明授权

US07863376B2 Thermally controlled particulate core migration within polymer matrix 有权
标题翻译：聚合物基体内的热控粒子芯迁移
公开(公告)号：US07863376B2
公开(公告)日：2011-01-04
申请号：US11717069
申请日：2007-03-13
申请人： Philip J. Costanzo , Frederick L. Beyer
发明人： Philip J. Costanzo , Frederick L. Beyer
IPC分类号： C08F290/14 , C04B24/38
CPC分类号： G03F7/0388
摘要： A composition is provided that includes a polymer matrix. A core having a core surface is embedded within the polymer matrix. A polymeric ligand passivates the core surface and has a moiety Y, where Y is a Diels-Alder group of a diene or dienophile. A polymeric linker has a complementary Diels-Alder group diene or dienophile to moiety Y and forms a Diels-Alder bond with the moiety Y. A composition is also provided that includes polymer matrix having a matrix surface. A core having a core surface is present on the matrix surface. A polymeric ligand passivates the core surface and has a moiety Y, where Y is Diels-Alder group of a diene or dienophile. The polymer matrix and polymeric ligand together define a matrix-ligand Flory-Huggins binary interaction function greater than 0.
摘要翻译：提供了包含聚合物基质的组合物。具有芯表面的芯嵌入聚合物基质内。聚合物配体钝化核心表面并具有部分Y，其中Y是二烯或亲二烯体的Diels-Alder基团。聚合物接头与Y部分具有互补的Diels-Alder族二烯或亲双烯体，并与部分Y形成Diels-Alder键。还提供了包含具有基质表面的聚合物基质的组合物。具有芯表面的芯存在于基体表面上。聚合物配体钝化核心表面并具有部分Y，其中Y是二烯或亲二烯体的Diels-Alder基团。聚合物基质和聚合物配体一起定义了大于0的矩阵 - 配体Flory-Huggins二元相互作用函数。

3. 发明授权

US07812069B2 Reversible viscosity reducing polymer 有权
标题翻译：可逆降粘聚合物
公开(公告)号：US07812069B2
公开(公告)日：2010-10-12
申请号：US12254214
申请日：2008-10-20
申请人： Philip J. Costanzo , Frederick L. Beyer, III , Robert E. Jensen
发明人： Philip J. Costanzo , Frederick L. Beyer, III , Robert E. Jensen
IPC分类号： C06B23/00
CPC分类号： C08F222/40 , C06B23/009 , C06B45/10
摘要： A reversible viscosity reducing polymer is provided that has a crosslinkage between subunits inclusive of a single Diels-Alder Such a reversible viscosity reducing polymer is particularly well suited as a matrix material for a heterogeneous propellant. A process for forming a reversible viscosity reducing polymer inclusive of a single Diels-Alder linkage includes reacting a native crosslinkable moiety with a crosslinker moiety having a Diels-Alder reactive moiety of a diene or dienophile to form a Diels-Alder reactive moiety capped polymer subunit. The Diels-Alder reactive moiety capped polymer subunit is then exposed to a Diels-Alder reactant inclusive of a complementary Diels-Alder reactive moiety where the reactant also includes at least one conventional crosslinkable moiety to form a crosslinkable moiety capped polymer subunit. Reaction of the crosslinkable moiety capped polymer subunit is then reacted with a conventional multifunctional crosslinking agent.
摘要翻译：提供了可逆的降粘聚合物，其具有包含单个Diels-Alder的亚基之间的交联。这种可逆粘度降低的聚合物特别适合作为非均相推进剂的基质材料。用于形成包含单个Diels-Alder连接的可逆降粘聚合物的方法包括使天然可交联部分与具有二烯或亲二烯体的Diels-Alder反应性部分的交联剂部分反应以形成Diels-Alder反应性部分封端的聚合物亚基。然后将Diels-Alder反应性部分封端的聚合物亚单位暴露于Diels-Alder反应物，包括互补的Diels-Alder反应性部分，其中反应物还包括至少一个常规的可交联部分以形成可交联部分封端的聚合物亚基。然后使可交联部分封端的聚合物亚单元的反应与常规的多功能交联剂反应。

4. 发明申请

US20100099798A1 REVERSIBLE VISCOSITY REDUCING POLYMER 有权
标题翻译：可逆粘度降低聚合物
公开(公告)号：US20100099798A1
公开(公告)日：2010-04-22
申请号：US12254214
申请日：2008-10-20
申请人： Philip J. Costanzo , Frederick L. Beyer, III , Robert E. Jensen
发明人： Philip J. Costanzo , Frederick L. Beyer, III , Robert E. Jensen
IPC分类号： C06B23/00 , C08F222/40
CPC分类号： C08F222/40 , C06B23/009 , C06B45/10
摘要： A reversible viscosity reducing polymer is provided that has a crosslinkage between subunits inclusive of a single Diels-Alder Such a reversible viscosity reducing polymer is particularly well suited as a matrix material for a heterogeneous propellant. A process for forming a reversible viscosity reducing polymer inclusive of a single Diels-Alder linkage includes reacting a native crosslinkable moiety with a crosslinker moiety having a Diels-Alder reactive moiety of a diene or dienophile to form a Diels-Alder reactive moiety capped polymer subunit. The Diels-Alder reactive moiety capped polymer subunit is then exposed to a Diels-Alder reactant inclusive of a complementary Diels-Alder reactive moiety where the reactant also includes at least one conventional crosslinkable moiety to form a crosslinkable moiety capped polymer subunit. Reaction of the crosslinkable moiety capped polymer subunit is then reacted with a conventional multifunctional crosslinking agent.
摘要翻译：提供了可逆的降粘聚合物，其具有包含单个Diels-Alder的亚基之间的交联。这种可逆粘度降低的聚合物特别适合作为非均相推进剂的基质材料。用于形成包含单个Diels-Alder连接的可逆降粘聚合物的方法包括使天然可交联部分与具有二烯或亲二烯体的Diels-Alder反应性部分的交联剂部分反应以形成Diels-Alder反应性部分封端的聚合物亚基。然后将Diels-Alder反应性部分封端的聚合物亚单位暴露于Diels-Alder反应物，包括互补的Diels-Alder反应性部分，其中反应物还包括至少一个常规的可交联部分以形成可交联部分封端的聚合物亚基。然后使可交联部分封端的聚合物亚单元的反应与常规的多功能交联剂反应。

5. 发明申请

US20160059235A1 Reagent-Loaded Pencils and Methods 审中-公开
标题翻译：试剂加载的铅笔和方法
公开(公告)号：US20160059235A1
公开(公告)日：2016-03-03
申请号：US14839661
申请日：2015-08-28
申请人： Andres W. Martinez , Haydn T. Mitchell , Chad E. Immoos , Nathaniel W. Martinez , Philip J. Costanzo , Samantha J. Carlton
发明人： Andres W. Martinez , Haydn T. Mitchell , Chad E. Immoos , Nathaniel W. Martinez , Philip J. Costanzo , Samantha J. Carlton
IPC分类号： B01L3/00 , B29C43/18
CPC分类号： B01L3/52 , B01L2200/087 , B01L2300/069 , B29C43/184 , B29K2071/00 , B29K2507/04 , B29L2031/7254 , B43K19/16
摘要： A reagent-loaded pencil, method of preparing a reagent-loaded pencil, and a system that uses reagent-loaded pencils are disclosed. The reagent-loaded pencil or pencils include a matrix of at least a soluble carrier, a hardening substance, and a reagent. The pencils also include a sheath disposed around at least a portion of the matrix. The soluble carrier may include poly(ethylene glycol) methyl ether. The hardening substance may leave a visible mark when abraded against a writing surface. One example of such a substance includes graphite. The sheath may be the outside of a wooden pencil or a mechanical pencil. A system that uses reagent-loaded pencils or compressed matrices may include a computer-controlled plotter that holds and plots with at least one of the reagent-loaded pencils or matrices.
摘要翻译：公开了一种试剂负载铅笔，制备试剂负载铅笔的方法和使用试剂负载铅笔的系统。试剂负载的铅笔或铅笔包括至少可溶性载体，硬化物质和试剂的基质。铅笔还包括围绕矩阵的至少一部分设置的护套。可溶性载体可以包括聚（乙二醇）甲基醚。硬化物质在与书写表面磨擦时可能留下可见痕迹。这种物质的一个例子包括石墨。护套可以是木制铅笔或机械铅笔的外部。使用试剂加载的铅笔或压缩矩阵的系统可以包括计算机控制的绘图仪，其保存并绘制至少一个试剂加载的铅笔或矩阵。

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