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1. 发明授权

US5055617A Process for the preparation of N-alkylated anilines 失效
标题翻译： N-烷基化苯胺的制备方法
公开(公告)号：US5055617A
公开(公告)日：1991-10-08
申请号：US552277
申请日：1990-07-12
申请人： Peter Wimmer , Hans-Josef Buysch , Lothar Puppe , Christian Froehlich
发明人： Peter Wimmer , Hans-Josef Buysch , Lothar Puppe , Christian Froehlich
IPC分类号： C07C209/18 , C07C211/48
CPC分类号： C07C209/18
摘要： Anilines or N-alkyl-anilines are advantageously reacted with alkyl alcohols or the associated dialkyl ethers at elevated temperature in the gas phase, if a .gamma.-Al.sub.2 O.sub.3 is used that is prepared by dehydration of an aluminum oxide/hydroxide hydrate and has a BET surface area from 50 to 400 m.sup.2 /g and a surface acidity of 5 to 600 mmol H.sup.+ /kg.
摘要翻译：如果使用通过氧化铝/氢氧化物水合物的脱水制备并具有BET表面的γ-Al 2 O 3，则苯胺或N-烷基苯胺有利地在气相中在升高的温度下与烷基醇或相关联的二烷基醚反应面积为50〜400m2 / g，表面酸度为5〜600mmol H + / kg。

2. 发明授权

US5087754A Process for the preparation of N,N-dialkylaniline 失效
标题翻译：制备N，N-二甲基兰酰胺的方法
公开(公告)号：US5087754A
公开(公告)日：1992-02-11
申请号：US567478
申请日：1990-08-13
申请人： Hans-Josef Buysch , Heinrich Pelster , Lothar Puppe , Peter Wimmer
发明人： Hans-Josef Buysch , Heinrich Pelster , Lothar Puppe , Peter Wimmer
IPC分类号： B01J29/06 , B01J29/70 , C07B61/00 , C07C209/14 , C07C209/18 , C07C211/48
CPC分类号： C07C209/18
摘要： N,N-dialkylanilines can be prepared by reacting the anilines on which they are based with lower alcohols or with the corresponding ethers, at an increased temperature in the gas phase in the presence of a proton-containing zeolite catalyst of the pentasil type having an SiO.sub.2 /Al.sub.2 O.sub.3 ratio of >60, it being advantageous to carry out the alkylation process under a pressure of 2-30 bar.
摘要翻译： N，N-二烷基苯胺可以通过使它们所基于的苯胺与低级醇或相应的醚反应，在气相中升高的温度下，在具有五 SiO 2 / Al 2 O 3比> 60，有利的是在2-30巴的压力下进行烷基化工艺。

3. 发明授权

US5030770A Process for the preparation of thymol 失效
标题翻译：制备百里酚的方法
公开(公告)号：US5030770A
公开(公告)日：1991-07-09
申请号：US375751
申请日：1989-07-05
申请人： Peter Wimmer , Hans-Josef Buysch , Lothar Puppe
发明人： Peter Wimmer , Hans-Josef Buysch , Lothar Puppe
IPC分类号： B01J29/06 , C07B61/00 , C07C37/14 , C07C39/06
CPC分类号： C07C37/14
摘要： Thymol can be prepared by reaction of m-cresol with propene at elevated temperature and at atmospheric to superatmospheric pressure by using wide- and medium-pored zeolites which have a pore diameter of at least 5 .ANG. as heterogeneous catalysts.
摘要翻译：通过使用孔径至少为5 ANGSTROM的多孔和中等沸石作为非均相催化剂，可以通过间甲酚与丙烯在升高的温度和大气压至超大气压下反应制备百里酚。

4. 发明授权

US5053566A Process for the preparation of oligophenyls dihalogenated in the 4,4'-position 失效
标题翻译：制备4,4'-位二卤代低聚苯基的方法
公开(公告)号：US5053566A
公开(公告)日：1991-10-01
申请号：US571956
申请日：1990-08-23
申请人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
发明人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
IPC分类号： C07C41/22 , B01J29/50 , B01J29/60 , B01J29/70 , C07B61/00 , C07C17/12 , C07C25/18 , C07C41/38 , C07C43/225
CPC分类号： C07C17/12
摘要： Oligophenyls dihalogenated in the 4,4'-position, of the formula ##STR1## can be prepared by catalyzed halogenation of oligophenyls of the formula ##STR2## wherein, in the formulae, X.sup.1 and X.sup.2 independently of one another represent chlorine or bromine, preferably chlorine,X.sup.3 denotes hydrogen, chlorine or bromine, preferably hydrogen or chlorine and particularly preferably hydrogen,R.sup.1, R.sup.2 and R.sup.3 independently of one another represent hydrogen, C.sub.1 -C.sub.4 -alkyl (preferably methyl or ethyl and particularly preferably methyl), C.sub.1 -C.sub.4 -alkoxy (preferably methoxy or ethoxy and particularly preferably methoxy), fluorine, chlorine or bromine anda assumes the value zero or one,with halogenating agents, the preparation being carried out in the presence of methylene chloride or solvent mixtures essentially containing methylene chloride and in the presence of zeolites of the L structure type which contain metal cations.
摘要翻译：在式（Ⅰ）的4,4'-位上二卤代的低级苯基可以通过式（II）的低聚苯基的催化卤化来制备，其中在式中X1和X2彼此独立地代表氯或溴，优选氯，X3表示氢，氯或溴，优选氢或氯，特别优选氢，R 1，R 2和R 3彼此独立地表示氢，C 1 -C 4烷基（优选甲基或乙基，特别优选甲基），C1-C4-烷氧基（优选甲氧基或乙氧基，特别优选甲氧基），氟，氯或溴，并且与卤化剂呈现零或一个值，该制剂在二氯甲烷或溶剂存在下进行基本上含有二氯甲烷的混合物和在含有金属阳离子的L结构类型的沸石的存在下。

5. 发明授权

US5053565A Process for the preparation of p-chlorotoluene 失效
标题翻译：制备对氯甲苯的方法
公开(公告)号：US5053565A
公开(公告)日：1991-10-01
申请号：US572526
申请日：1990-08-23
申请人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
发明人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
IPC分类号： B01J29/60 , B01J29/50 , C07B61/00 , C07C17/12 , C07C25/02
CPC分类号： C07C17/12
摘要： p-Chlorotoluene can be prepared in an improved manner by catalyzed reaction of toluene with a chlorinating agent if a zeolite L containing metal cations is employed as the catalyst and the reaction is carried out in the presence of methylene chloride and/or chloroform.
摘要翻译：如果使用含有金属阳离子的沸石作为催化剂，并且在二氯甲烷和/或氯仿的存在下进行反应，则可以通过甲苯与氯化剂的催化反应以改进的方式制备对 - 氯甲苯。

6. 发明授权

US4940817A Process for the preparation of n-alkylanilines 失效
标题翻译：制备正烷基苯胺的方法
公开(公告)号：US4940817A
公开(公告)日：1990-07-10
申请号：US301672
申请日：1989-01-25
申请人： Gunter Klug , Hans-Josef Buysch , Lothar Puppe
发明人： Gunter Klug , Hans-Josef Buysch , Lothar Puppe
IPC分类号： B01J29/06 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/22 , C07C209/64 , C07C211/48 , C07C211/52 , C07C213/02 , C07C217/84
CPC分类号： C07C209/64
摘要： N-Alkylanilines can be prepared by reaction of anilines with N,N-dialkylanilines in the gas or liquid phase at elevated temperature by carrying out the reaction in the presence of zeolites.
摘要翻译： N-烷基苯胺可以通过在沸石存在下进行反应而在升高的温度下将苯胺与N，N-二烷基苯胺在气相或液相中反应来制备。

7. 发明授权

US4918232A Process for separating aniline derivatives 失效
标题翻译：苯胺衍生物分离方法
公开(公告)号：US4918232A
公开(公告)日：1990-04-17
申请号：US213069
申请日：1988-06-29
申请人： Hans-Josef Buysch , Michael Hullmann , Lothar Puppe
发明人： Hans-Josef Buysch , Michael Hullmann , Lothar Puppe
IPC分类号： C07C209/86 , C07C67/00 , C07C209/00 , C07C211/46
CPC分类号： C07C209/86
摘要： A process for separating from each other aniline and aniline derivatives having different numbers of C atoms bound to the N atoms is disclosed herein, this process being characterized in that a mixture of the substances mentioned is treated in liquid phase with zeolites of the faujasite type at a temperature from 0.degree. C. to 190.degree. C.
摘要翻译：本文公开了一种彼此分离的苯胺和与N原子结合的C原子数不同的苯胺衍生物的方法，该方法的特征在于所述物质的混合物用八面沸石沸石沸石处理温度为0℃至190℃

8. 发明授权

US5386067A Process for separating mixtures of m- and p-dichlorobenzene 失效
标题翻译：分离对 - 二氯苯混合物的方法
公开(公告)号：US5386067A
公开(公告)日：1995-01-31
申请号：US252154
申请日：1994-06-01
申请人： Ursula Pentling , Hans-Josef Buysch , Lothar Puppe , Kai Rohlk , Rolf Grosser , Hans-Ingolf Paul
发明人： Ursula Pentling , Hans-Josef Buysch , Lothar Puppe , Kai Rohlk , Rolf Grosser , Hans-Ingolf Paul
IPC分类号： B01D15/00 , B01D15/04 , C07C17/38 , C07C17/389 , C07C25/08
CPC分类号： C07C17/389
摘要： Mixtures of m- and p-dichlorobenzene can be separated by treating such mixtures in the liquid phase with a pentasil zeolite at from 20.degree. to 250.degree. C., a filtrate enriched in m-dichlorobenzene being removed and the p-dichlorobenzene being obtained by desorption of the pentasil zeolite. The pentasil zeolites may contain, as exchangeable cations, protons, cations of the first or second main group of the Mendeleev Periodic System, cations of the rare earth metals or a mixture of a plurality thereof. In order to prepare the liquid phase a solvent is used that belongs to the group of cyclic saturated hydrocarbons having 5 to 15 carbon atoms, alkyl-substituted aromatic hydrocarbons having 8 to 12 carbon atoms, and halogen-substituted aromatic hydrocarbons having 6 to 10 carbon atoms and 1 to 3 halogen atoms. The solvents ethylbenzene, chlorobenzene, p-xylene, p-chlorotoluene and dichlorobenzene are excepted. A mixture of a plurality of these solvents may also be used.
摘要翻译：可以通过在20至250℃下用pentasil沸石处理液相中的这种混合物来分离对 - 二氯苯的混合物，除去富含间二氯苯的滤液，将对二氯苯由五硅沸石的解吸。戊二烯沸石可以包含作为可交换阳离子的质子，门多列夫周期系统的第一或第二主要组分的阳离子，稀土金属的阳离子或其多个混合物。为了制备液相，使用属于具有5至15个碳原子的环状饱和烃基团，具有8至12个碳原子的烷基取代的芳族烃和具有6至10个碳原子的卤素取代的芳族烃的溶剂原子和1至3个卤素原子。溶剂乙苯，氯苯，对二甲苯，对氯甲苯和二氯苯除外。也可以使用多种这些溶剂的混合物。

9. 发明授权

US5072017A Process for the preparation of P-substituted O-benzylphenols 失效
标题翻译：制备O-取代的苄氧基苯酚的方法
公开(公告)号：US5072017A
公开(公告)日：1991-12-10
申请号：US505799
申请日：1990-04-06
申请人： Hans-Josef Buysch , Gunter Klug , Peter Mues , Lothar Puppe
发明人： Hans-Josef Buysch , Gunter Klug , Peter Mues , Lothar Puppe
IPC分类号： C07C43/23 , B01J29/08 , C07B61/00 , C07C27/00 , C07C37/11 , C07C37/16 , C07C37/18 , C07C39/15 , C07C41/00 , C07C41/30 , C07C67/00 , C07C67/343 , C07C69/76 , C07C69/92 , C07C255/53 , C07C313/00 , C07C319/20 , C07C323/20 , C07C323/62
CPC分类号： B01J29/08 , C07C37/16 , C07C37/18
摘要： Para-substituted o-benzylphenols are prepared by reacting p-substituted phenols with benzylating agents in the presence of zeolites of the faujasite type at elevated temperature.
摘要翻译：对位取代的邻 - 苄基苯酚是通过在升高的温度下在八面沸石型沸石存在下使对取代的酚与苄化剂反应来制备的。

10. 发明授权

US5338861A Process for the preparation of N-substituted lactams 失效
标题翻译：制备N-取代的内酰胺的方法
公开(公告)号：US5338861A
公开(公告)日：1994-08-16
申请号：US919818
申请日：1992-07-24
申请人： Artur Botta , Hans-Josef Buysch , Otto Immel , Lothar Puppe
发明人： Artur Botta , Hans-Josef Buysch , Otto Immel , Lothar Puppe
IPC分类号： B01J21/04 , B01J23/20 , C07B61/00 , C07D201/02 , C07D207/267 , C07D211/76 , C07D213/64 , C07D215/22 , C07D223/10 , C07D201/04
CPC分类号： C07D201/02 , Y02P20/52
摘要： Substituted lactams of the formula ##STR1## can be prepared from lactam N-carboxylates or lactim O-carboxylates of the formulae ##STR2## by thermal or mixed thermal and catalysed CO.sub.2 elimination at 80.degree.-450.degree. C. Lactams substituted on the N atom by aliphatic groups such as those produced herein are useful as industrial aprotic solvents.
摘要翻译：式（I）的取代的内酰胺可以通过热或混合的热和催化的二氧化碳消除从制备式“IMAGE”（II）或（IMAGE）（III）的内酰胺N-羧酸盐或内酰胺酸O-羧酸盐制备。 80°-450℃。通过脂族基团（例如本文制备的那些）在N原子上取代的内酰胺可用作工业非质子溶剂。

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