专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US5053566A Process for the preparation of oligophenyls dihalogenated in the 4,4'-position 失效
标题翻译：制备4,4'-位二卤代低聚苯基的方法
公开(公告)号：US5053566A
公开(公告)日：1991-10-01
申请号：US571956
申请日：1990-08-23
申请人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
发明人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
IPC分类号： C07C41/22 , B01J29/50 , B01J29/60 , B01J29/70 , C07B61/00 , C07C17/12 , C07C25/18 , C07C41/38 , C07C43/225
CPC分类号： C07C17/12
摘要： Oligophenyls dihalogenated in the 4,4'-position, of the formula ##STR1## can be prepared by catalyzed halogenation of oligophenyls of the formula ##STR2## wherein, in the formulae, X.sup.1 and X.sup.2 independently of one another represent chlorine or bromine, preferably chlorine,X.sup.3 denotes hydrogen, chlorine or bromine, preferably hydrogen or chlorine and particularly preferably hydrogen,R.sup.1, R.sup.2 and R.sup.3 independently of one another represent hydrogen, C.sub.1 -C.sub.4 -alkyl (preferably methyl or ethyl and particularly preferably methyl), C.sub.1 -C.sub.4 -alkoxy (preferably methoxy or ethoxy and particularly preferably methoxy), fluorine, chlorine or bromine anda assumes the value zero or one,with halogenating agents, the preparation being carried out in the presence of methylene chloride or solvent mixtures essentially containing methylene chloride and in the presence of zeolites of the L structure type which contain metal cations.
摘要翻译：在式（Ⅰ）的4,4'-位上二卤代的低级苯基可以通过式（II）的低聚苯基的催化卤化来制备，其中在式中X1和X2彼此独立地代表氯或溴，优选氯，X3表示氢，氯或溴，优选氢或氯，特别优选氢，R 1，R 2和R 3彼此独立地表示氢，C 1 -C 4烷基（优选甲基或乙基，特别优选甲基），C1-C4-烷氧基（优选甲氧基或乙氧基，特别优选甲氧基），氟，氯或溴，并且与卤化剂呈现零或一个值，该制剂在二氯甲烷或溶剂存在下进行基本上含有二氯甲烷的混合物和在含有金属阳离子的L结构类型的沸石的存在下。

2. 发明授权

US5053565A Process for the preparation of p-chlorotoluene 失效
标题翻译：制备对氯甲苯的方法
公开(公告)号：US5053565A
公开(公告)日：1991-10-01
申请号：US572526
申请日：1990-08-23
申请人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
发明人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
IPC分类号： B01J29/60 , B01J29/50 , C07B61/00 , C07C17/12 , C07C25/02
CPC分类号： C07C17/12
摘要： p-Chlorotoluene can be prepared in an improved manner by catalyzed reaction of toluene with a chlorinating agent if a zeolite L containing metal cations is employed as the catalyst and the reaction is carried out in the presence of methylene chloride and/or chloroform.
摘要翻译：如果使用含有金属阳离子的沸石作为催化剂，并且在二氯甲烷和/或氯仿的存在下进行反应，则可以通过甲苯与氯化剂的催化反应以改进的方式制备对 - 氯甲苯。

3. 发明授权

US5338861A Process for the preparation of N-substituted lactams 失效
标题翻译：制备N-取代的内酰胺的方法
公开(公告)号：US5338861A
公开(公告)日：1994-08-16
申请号：US919818
申请日：1992-07-24
申请人： Artur Botta , Hans-Josef Buysch , Otto Immel , Lothar Puppe
发明人： Artur Botta , Hans-Josef Buysch , Otto Immel , Lothar Puppe
IPC分类号： B01J21/04 , B01J23/20 , C07B61/00 , C07D201/02 , C07D207/267 , C07D211/76 , C07D213/64 , C07D215/22 , C07D223/10 , C07D201/04
CPC分类号： C07D201/02 , Y02P20/52
摘要： Substituted lactams of the formula ##STR1## can be prepared from lactam N-carboxylates or lactim O-carboxylates of the formulae ##STR2## by thermal or mixed thermal and catalysed CO.sub.2 elimination at 80.degree.-450.degree. C. Lactams substituted on the N atom by aliphatic groups such as those produced herein are useful as industrial aprotic solvents.
摘要翻译：式（I）的取代的内酰胺可以通过热或混合的热和催化的二氧化碳消除从制备式“IMAGE”（II）或（IMAGE）（III）的内酰胺N-羧酸盐或内酰胺酸O-羧酸盐制备。 80°-450℃。通过脂族基团（例如本文制备的那些）在N原子上取代的内酰胺可用作工业非质子溶剂。

4. 发明授权

US4960943A Process for the preparation of phenylketones etherified in the 4-position 失效
标题翻译：在4-位上醚化的苯基酮的制备方法
公开(公告)号：US4960943A
公开(公告)日：1990-10-02
申请号：US318088
申请日：1989-03-02
申请人： Artur Botta , Hans-Josef Buysch , Lothar Puppe , Dieter Arlt
发明人： Artur Botta , Hans-Josef Buysch , Lothar Puppe , Dieter Arlt
IPC分类号： C07C45/45 , C07B61/00 , C07C45/00 , C07C45/46 , C07C49/84 , C07C67/00
CPC分类号： C07C49/84 , C07C45/46
摘要： Phenylketones etherified in the 4-position can be prepared by reaction of aromatic ethers which have a free 4-position with acylating agents, the acylation being carried out in the presence of zeolite catalysts having pore sizes of at least 5 .ANG..
摘要翻译：醚化4-位的苯基酮可以通过使具有游离4-位的芳族醚与酰化剂的反应制备，酰化在孔径至少为5安士的沸石催化剂的存在下进行。

5. 发明授权

US4950817A Process for the preparation of 4,4'-dihalobiphenyls 失效
标题翻译：制备4,4'-二卤代联苯的方法
公开(公告)号：US4950817A
公开(公告)日：1990-08-21
申请号：US318087
申请日：1989-03-02
申请人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
发明人： Artur Botta , Hans-Josef Buysch , Lothar Puppe
IPC分类号： B01J29/06 , B01J29/18 , B01J29/40 , B01J29/60 , B01J29/65 , B01J29/86 , C07B31/00 , C07B39/00 , C07B61/00 , C07C17/00 , C07C17/12 , C07C17/20 , C07C25/18 , C07C27/00 , C07C37/62 , C07C39/15 , C07C41/00 , C07C41/22 , C07C43/225 , C07C67/00
CPC分类号： C07C17/12
摘要： 4,4'-dihalobiphenyls can be prepared by catalyzed halogenation of biphenyls with halogenating agents, the catalysts used being zeolites having pore sizes of at least 5 .ANG..
摘要翻译： 4,4'-二卤代联苯可以通过用卤化剂催化联苯联苯来制备，所用的催化剂是孔径至少为5安士的沸石。

6. 发明授权

US4377670A Copolymers based on aliphatic polycarbonates and lactams 失效
标题翻译：基于脂肪族聚碳酸酯和内酰胺的共聚物
公开(公告)号：US4377670A
公开(公告)日：1983-03-22
申请号：US314242
申请日：1981-10-23
申请人： Heinrich Krimm , Hans-Josef Buysch , Artur Botta
发明人： Heinrich Krimm , Hans-Josef Buysch , Artur Botta
IPC分类号： C08G69/00 , C08G63/00 , C08G64/00 , C08G64/42 , C08G69/18 , C08G69/44 , C08G71/00 , C08G71/04 , C08G63/62 , C08G69/16
CPC分类号： C08G69/44 , C08G71/04
摘要： Anionic copolymers of lactams and aliphatic polycarbonates having urethane and carboxylic acid ester groups, preferably having recurring structural units of the formula:--NH--CO--O--Y--O--CO--(CR.sub.2).sub.n --whereinR represents hydrogen or C.sub.1 -C.sub.4 -alkyl;n represents an integer of from 2 to 13;Y represents the residue of an alcohol of the following formula:HO--X--OH,whereinX represents an open-chain, cyclic or mixed open-chain-cyclic alkylene radical having from 2 to 12 carbon atoms which is optionally substituted by C.sub.1 -C.sub.4 -alkyl and optionally interrupted by from 1 to 3 oxygen atoms, or a polyethylene glycol having a molecular weight up to 10,000 or an alkoxylation product of bifunctional phenols.
摘要翻译：具有氨基甲酸酯和羧酸酯基的内酰胺和脂族聚碳酸酯的阴离子共聚物，优选具有下式的重复结构单元：-NH-CO-O-Y-O-CO-（CR2）n-，其中R表示氢或C1-C4-烷基; n表示2〜13的整数， Y表示下式的醇的残基：HO-X-OH，其中X表示具有2至12个碳原子的开链，环状或混合的开链 - 环状亚烷基，其任选被C1- C4烷基，任选地被1至3个氧原子间隔，或分子量高达10,000的聚乙二醇或双功能酚的烷氧基化产物。

7. 发明授权

US4431795A Copolymers of cyclic carbonic acid esters and lactams and their production 失效
标题翻译：环状碳酸酯和内酰胺的共聚物及其制备
公开(公告)号：US4431795A
公开(公告)日：1984-02-14
申请号：US384566
申请日：1982-06-03
申请人： Heinrich Krimm , Hans-Josef Buysch , Artur Botta
发明人： Heinrich Krimm , Hans-Josef Buysch , Artur Botta
IPC分类号： C08G69/00 , C08G63/00 , C08G64/00 , C08G69/44 , C08G71/00 , C08G71/04 , C08G69/14
CPC分类号： C08G69/44 , C08G71/04
摘要： A process for producing an anionic copolymer containing urethane and carboxylic acid ester moieties with or without carbonate moieties, carbonamide moieties, or both carbonate and carbonamide moieties, having weight average molecular weights from 1,000 to 150,000, determined by light diffusion method, which comprises heating an anhydrous mixture of 20 to 80% by weight of lactam and 80 to 20% by weight of a cyclic carbonate at temperatures between 100.degree. and 250.degree. C. in the presence of 0.001 to 1% by weight, based on the quantity of monomers, of an alkaline catalyst and copolymers produced thereby which are useful as adhesives, plasticizers and lacquers.
摘要翻译：一种含有具有或不具有碳酸酯部分的氨基甲酸酯和羧酸酯部分的阴离子共聚物的方法，碳酸酯部分的碳酰胺部分或碳酸酯和碳酰胺部分，重均分子量为1,000至150,000，通过光漫射法测定，其包括加热基于单体的量，在0.001至1重量％的存在下，在100至250℃的温度下，将20至80重量％的内酰胺和80至20重量％的环状碳酸酯的无水混合物，的碱性催化剂和由此制备的共聚物，其可用作粘合剂，增塑剂和漆。

8. 发明授权

US5723694A Process for preparing monomethylated or dimethylated phenols 失效
标题翻译：制备单甲基化或二甲基化酚的方法
公开(公告)号：US5723694A
公开(公告)日：1998-03-03
申请号：US755513
申请日：1996-11-22
申请人： Artur Botta , Hans-Josef Buysch
发明人： Artur Botta , Hans-Josef Buysch
IPC分类号： C07C37/50 , C07C37/00 , C07C37/20 , C07C39/07 , C07C69/007
CPC分类号： C07C69/007 , C07C37/50
摘要： Phenols monomethylated or dimethylated in the ortho or para position to the OH group and having the formula ##STR1## can be prepared by reaction of tert-alkyl-substituted phenols of the formula ##STR2## in which at least one free ortho or para position to the OH group is present, in three reaction steps a), b) and c). In a), (II) is reacted with formaldehyde or its polymers and a carboxylic acid of the formula R.sup.3 --COOH, (III) which gives a mixture of substituted phenols of the formulae ##STR3## In b) the mixture of (IV)/(V) is hydrogenated using catalytically activated hydrogen to give the substituted phenols of the formula ##STR4## which, if m=0, are reacted in c) in the presence of an acid cleavage catalyst with elimination of tert-alkenes to give the methylated phenols of the formula (I). Before or during the hydrogenation, the phenols of the formulae (IV) and (V) can be reacted with the aid of an alcohol of the formula R.sup.4 --OH (VII) to give a mixture of the etherified substituted phenols of the formulae ##STR5## which can then, in the manner indicated, be hydrogenated and freed of the tert-alkyl groups.
摘要翻译：在OH基上邻位或对位甲基化或二甲基化的酚可以通过式（II）的叔烷基取代的酚与其中至少一个在三个反应步骤a），b）和c）中存在OH基的游离的邻位或对位。在a）中，（II）与甲醛或其聚合物和式R3-COOH（III）的羧酸反应，得到式IMA（IV）和（VI）的取代酚的混合物）b）使用催化活化氢氢化（IV）/（V）的混合物，得到式（VI）的取代苯酚，如果m = 0，则在c）具有消除叔烯烃的酸裂解催化剂，得到式（I）的甲基化酚。在氢化之前或期间，式（Ⅳ）和（Ⅴ）的酚可以借助于式R 4 -OH（Ⅶ）的醇进行反应，得到下列化学式的醚化取代酚的混合物（VIII）化合物，氢化并除去叔烷基。

9. 发明授权

US5087754A Process for the preparation of N,N-dialkylaniline 失效
标题翻译：制备N，N-二甲基兰酰胺的方法
公开(公告)号：US5087754A
公开(公告)日：1992-02-11
申请号：US567478
申请日：1990-08-13
申请人： Hans-Josef Buysch , Heinrich Pelster , Lothar Puppe , Peter Wimmer
发明人： Hans-Josef Buysch , Heinrich Pelster , Lothar Puppe , Peter Wimmer
IPC分类号： B01J29/06 , B01J29/70 , C07B61/00 , C07C209/14 , C07C209/18 , C07C211/48
CPC分类号： C07C209/18
摘要： N,N-dialkylanilines can be prepared by reacting the anilines on which they are based with lower alcohols or with the corresponding ethers, at an increased temperature in the gas phase in the presence of a proton-containing zeolite catalyst of the pentasil type having an SiO.sub.2 /Al.sub.2 O.sub.3 ratio of >60, it being advantageous to carry out the alkylation process under a pressure of 2-30 bar.
摘要翻译： N，N-二烷基苯胺可以通过使它们所基于的苯胺与低级醇或相应的醚反应，在气相中升高的温度下，在具有五 SiO 2 / Al 2 O 3比> 60，有利的是在2-30巴的压力下进行烷基化工艺。

10. 发明授权

US4940817A Process for the preparation of n-alkylanilines 失效
标题翻译：制备正烷基苯胺的方法
公开(公告)号：US4940817A
公开(公告)日：1990-07-10
申请号：US301672
申请日：1989-01-25
申请人： Gunter Klug , Hans-Josef Buysch , Lothar Puppe
发明人： Gunter Klug , Hans-Josef Buysch , Lothar Puppe
IPC分类号： B01J29/06 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/22 , C07C209/64 , C07C211/48 , C07C211/52 , C07C213/02 , C07C217/84
CPC分类号： C07C209/64
摘要： N-Alkylanilines can be prepared by reaction of anilines with N,N-dialkylanilines in the gas or liquid phase at elevated temperature by carrying out the reaction in the presence of zeolites.
摘要翻译： N-烷基苯胺可以通过在沸石存在下进行反应而在升高的温度下将苯胺与N，N-二烷基苯胺在气相或液相中反应来制备。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式