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1. 发明授权

US06331626B1 Triazinylaminostilbene compounds 有权
标题翻译：三嗪基氨基芪化合物
公开(公告)号：US06331626B1
公开(公告)日：2001-12-18
申请号：US09666768
申请日：2000-09-21
申请人： Peter Rohringer , André Geoffroy , Andreas Burkhard , Erwin Marti , Werner Schreiber , Josef Zelger
发明人： Peter Rohringer , André Geoffroy , Andreas Burkhard , Erwin Marti , Werner Schreiber , Josef Zelger
IPC分类号： C07D25170
CPC分类号： C07D251/68 , C09B67/0025 , D06L4/621 , Y10S8/919
摘要： The present invention provides a hydrate of the 4,4′-di-triazinylamino-2,2′-di-sulfostilbene compound having the formula: in which M and M1 independently represent hydrogen, an alkaline-, an alkaline earth metal or ammonium, x is a number within the range of from 1 to 30, and the crystal form of the hydrate (I) being characterised by an X-ray diffraction pattern which is essentially as set out in the accompanying FIGS. 1 to 11; or a mixture containing one or more of the hydrates of the 4,4′-di-triazinylamino-2,2′-di-sulfostilbene compound having the formula (I); processes for the preparation of the new hydrates; and the use of the new hydrates for the preparation of concentrated aqueous formulations of fluorescent whitening agents.
摘要翻译：本发明提供了具有下式的4,4'-二 - 三嗪基氨基-2,2'-二磺基芪化合物的水合物：其中M和M1独立地表示氢，碱金属，碱土金属或铵， x是1至30范围内的数字，并且水合物（I）的晶体形式的特征在于X射线衍射图，其基本上如附图中所示。 1至11; 或含有一种或多种具有式（I）的4,4'-二 - 三嗪基氨基-2,2'-二磺基芪化合物的水合物的混合物; 新水合物的制备过程; 以及使用新的水合物来制备荧光增白剂的浓缩水性制剂。

2. 发明授权

US6153122A Triazinylaminostilbene compounds 失效
标题翻译：三嗪基氨基芪化合物
公开(公告)号：US6153122A
公开(公告)日：2000-11-28
申请号：US081427
申请日：1998-05-19
申请人： Peter Rohringer , Andre Geoffroy , Andreas Burkhard , Erwin Marti , Werner Schreiber , Josef Zelger
发明人： Peter Rohringer , Andre Geoffroy , Andreas Burkhard , Erwin Marti , Werner Schreiber , Josef Zelger
IPC分类号： C07D251/54 , C07D251/68 , C08K5/3492 , C09B57/00 , C09B67/48 , D06L3/12 , C11D3/42 , C07D251/00 , C09K11/06 , D21H21/32
CPC分类号： C07D251/68 , C09B67/0025 , D06L3/1214 , Y10S8/919
摘要： The present invention provides a hydrate of the 4,4'-di-triazinylamino-2,2'-di-sulfostilbene compound having the formula: ##STR1## in which M and M.sub.1 independently represent hydrogen, an alkaline-, an alkaline earth metal or ammonium, x is a number within the range of from 1 to 30, and the crystal form of the hydrate (I) being characterized by an X-ray diffraction pattern which is essentially as set out in the accompanying FIGS. 1 to 11; or a mixture containing one or more of the hydrates of the 4,4'-di-triazinylamino-2,2'-di-sulfostilbene compound having the formula (I); processes for the preparation of the new hydrates; and the use of the new hydrates for the preparation of concentrated aqueous formulations of fluorescent whitening agents.
摘要翻译：本发明提供了具有下式的4,4'-二 - 三嗪基氨基-2,2'-二磺基芪化合物的水合物：其中M和M1独立地表示氢，碱金属，碱土金属或铵， x是1至30范围内的数字，并且水合物（I）的晶体形式的特征在于X射线衍射图，其基本上如附图中所示。 1至11; 或含有一种或多种具有式（I）的4,4'-二 - 三嗪基氨基-2,2'-二磺基芪化合物的水合物的混合物; 新水合物的制备过程; 以及使用新的水合物来制备荧光增白剂的浓缩水性制剂。

3. 发明授权

US06783698B1 Mixtures of fluorescent whitening agents 失效
标题翻译：荧光增白剂的混合物
公开(公告)号：US06783698B1
公开(公告)日：2004-08-31
申请号：US10111530
申请日：2002-04-23
申请人： Dieter Reinehr , Hanspeter Sauter , Hans Kramer , Werner Schreiber
发明人： Dieter Reinehr , Hanspeter Sauter , Hans Kramer , Werner Schreiber
IPC分类号： D06L312
CPC分类号： C07C255/51 , C11D3/42 , D06L4/636 , D06L4/65 , D06L4/664 , Y10S8/922
摘要： The present invention relates to a mixture of fluorescent whitening agents comprising 20 to 70% by weight of a compound of formula (1), 30 to 80% of a compound of formula (2) and 0.1 to 10% of a compound of formula (3), compositions containing the mixture and the user of the compositions for whitening synthetic fibers, in particular, polyester.
摘要翻译：本发明涉及一种荧光增白剂的混合物，其包含20至70重量％的式（1）化合物，30至80％的式（2）化合物和0.1至10％的式（1）化合物 3），含有混合物的组合物和用于使合成纤维增白的组合物，特别是聚酯的用户。

4. 发明授权

US4490562A Process for the preparation of a very pure commercial form of 4,2',4'-trichloro-2-hydroxydiphenyl ether 失效
标题翻译：用于制备非常纯的商业形式的4,2'，4'-三氯-2-羟基二苯醚的方法
公开(公告)号：US4490562A
公开(公告)日：1984-12-25
申请号：US462258
申请日：1983-01-31
申请人： Werner Schreiber , Michael Marky
发明人： Werner Schreiber , Michael Marky
IPC分类号： C07C41/30 , C07C41/00 , C07C41/26 , C07C41/34 , C07C41/40 , C07C43/295 , C07C67/00 , C07C41/38 , C07C41/42
CPC分类号： C07C41/26 , C07C41/38 , C07C41/40
摘要： A very pure, dust-free commercial form of 4,2',4'-trichloro-2-hydroxydiphenyl ether with little odor is prepared by diazotizing 4,2'4'-trichloro-2-aminodiphenyl ether, boiling the diazonium salt and purifying the reaction product. The pure, dust-free and odor-free commercial form is obtained by separating off the acid aqueous phase of the reaction mixture, rendering the mixture containing 4,2'4'-trichloro-2-hydroxydiphenyl ether and 2,4,8-trichlorodibenzofuran alkaline, extracting it several times with an inert water-immiscible solvent, either after removal of the organic solvent by steam distillation and precipitation of the by-product 2,4,8-trichlorodibenzofuran or directly, and then adjusting the pH to 3 to 10; subsequently, the highly volatile constituents are removed from the 4,2',4'-trichloro-2-hydroxydiphenyl ether melt which has separated out, the melt is subjected to molecular distillation and the distilled melt is introduced into an aqueous dispersion of crystalline 4,2',4'-trichloro-2-hydroxydiphenyl ether, this dispersion simultaneously being subjected to wet grinding. Filtration and drying gives a granular-like ready-to-use commercial form.
摘要翻译：通过重氮化4,2'4'-三氯-2-氨基二苯醚，沸腾重氮盐和重氮化物制备非常纯净，无尘的商业形式的4,2'，4'-三氯-2-羟基二苯醚，纯化反应产物。通过分离出反应混合物的酸性水相，得到纯的无尘，无臭味的商业形式，使含有4,2'-四氯-2-羟基二苯醚和2,4,8-三氯-2-羟基二苯醚的混合物，三氯二苯并呋喃碱性，用惰性水不混溶溶剂萃取数次，无论是通过蒸汽蒸馏除去有机溶剂并沉淀副产物2,4,8-三氯二苯并呋喃或直接，然后将pH调节至3〜 10; 随后，从分离出的4,2'，4'-三氯-2-羟基二苯醚熔体中除去高挥发性成分，熔融物进行分子蒸馏，将蒸馏的熔体引入结晶4的水分散体，2'，4'-三氯-2-羟基二苯醚，该分散体同时进行湿磨。过滤和干燥得到颗粒状的即用型商业形式。

5. 发明授权

US06977776B2 Head-mounted optical direct visualization system 有权
标题翻译：头戴式光学直观可视化系统
公开(公告)号：US06977776B2
公开(公告)日：2005-12-20
申请号：US10750958
申请日：2004-01-05
申请人： Harald Volkenandt , Uwe Frey , Thomas Alt , Werner Schreiber
发明人： Harald Volkenandt , Uwe Frey , Thomas Alt , Werner Schreiber
IPC分类号： G02B27/02 , G02B27/00 , G02B27/01 , H04N5/64 , G02B27/14 , G09G5/00
CPC分类号： G02B27/0172 , G02B27/0176 , G02B2027/0132 , G02B2027/0136 , G02B2027/0178
摘要： A head-mounted optical direct visualization system has at least one optical deflecting device (120) with an optical end element (128) for deflecting a virtual image generated by an image source (230) onto the optical end element (128). The virtual image is emitted through the optical end element into the field of view in front of the eyes of the user. The optical deflecting device (120) is attached to the head of the user with the aid of a frame (130). The task of the invention is to configure such a conventional direct visualization system so as to be better adaptable to the requirements of the anatomical and optical features of the user and the application-specific viewing requirements. This task is solved with an adjusting device (140), which is fixed to the frame (130), for variably changing the position of at least the optical end element (128) essentially in a plane parallel to the field of view of the user.
摘要翻译：头戴式光学直接可视化系统具有至少一个具有光学终端元件（128）的光学偏转装置（120），用于将由图像源（230）产生的虚拟图像偏转到光学端部元件（128）上。虚拟图像通过光学终端元件发射到用户眼睛前方的视场中。光学偏转装置（120）借助于框架（130）附接到使用者的头部。本发明的任务是配置这种常规的直接可视化系统，以便更好地适应用户的解剖学和光学特征的需求以及特定应用的观看要求。该任务通过固定到框架（130）的调节装置（140）来解决，用于基本上在平行于用户视场的平面中可变地改变至少光学端部元件（128）的位置。

6. 发明授权

US5885952A Multifunctional detergent base 失效
标题翻译：多功能洗涤剂基
公开(公告)号：US5885952A
公开(公告)日：1999-03-23
申请号：US649938
申请日：1996-05-15
申请人： Rolf Kuratli , Claude Eckhardt , Frank Bachmann , Werner Schreiber
发明人： Rolf Kuratli , Claude Eckhardt , Frank Bachmann , Werner Schreiber
IPC分类号： C11D10/04 , C11D3/37 , D06M13/165
CPC分类号： C11D3/3788
摘要： A detergent base which is obtainable from the reaction of an ethylenically unsaturated sulfonic acid or carboxylic acid or anhydride thereof with a nonionic surfactant of the formulaR.sub.1 --O-(alkylene-O).sub.n.sbsb.1 --R.sub.2 (1)in whichR.sub.1 is C.sub.8 -C.sub.22 alkyl or C.sub.8 -C.sub.18 alkenyl;R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, a cycloaliphatic radical having at least 6 C atoms or benzyl; andn.sub.1 is a number from 1 to 60;and if appropriate with sugar derivatives.The detergent base has a good calcium-dispersing power, is very stable to electrolytes and heat and has an excellent washing action and anti-redeposition properties. It is therefore suitable for the preparation of powder and liquid detergents.
摘要翻译：可从烯属不饱和磺酸或其羧酸或其酸酐与式R1-O-（亚烷基-O）n1-R2（1）的非离子表面活性剂反应获得的洗涤剂基质，其中R1是C8-C22烷基或 C 8 -C 18烯基; R2是氢，C1-C4烷基，具有至少6个C原子的脂环族基团或苄基; n1为1〜60的数; 并酌情与糖衍生物。洗涤剂基质具有良好的钙分散能力，对电解质和热量非常稳定，具有优异的洗涤作用和抗再沉积性能。因此适用于制备粉末和液体洗涤剂。

7. 发明授权

US4327209A Process for the production of dibenzazolyl compounds 失效
标题翻译：二苯并唑化合物的制备方法
公开(公告)号：US4327209A
公开(公告)日：1982-04-27
申请号：US211481
申请日：1980-11-28
申请人： Werner Schreiber
发明人： Werner Schreiber
IPC分类号： C07D263/56 , C07D235/20 , C07D263/62 , C07D405/04 , C07D405/14 , C07D409/14 , C07D413/14 , C07D413/06
CPC分类号： C07D263/62 , C07D235/20
摘要： Benzazolyl compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are specific substituents, X is oxygen or R.sub.3 N--, Q is a radical of the formula ##STR2## wherein R.sub.4 denotes specific substituents, and A is 2,5-furylene, 2,5-thenylene or a bridge member which contains at least one double bond between 2 carbon atoms or is the direct bond. These compounds are obtained by condensation of organic carboxylic acids with aminobenzenes in diphenyl ether or a mixture of diphenyl ether and diphenyl.
摘要翻译：其中R 1和R 2是特定取代基，X是氧或R 3 N-，Q是下式的基团：其中R 4表示特定取代基，A是2,5-亚芳基，2， 5-亚苄基或包含2个碳原子之间的至少一个双键的桥连体，或者是直接键合。这些化合物通过有机羧酸与二苯基醚或二苯基醚和二苯基的混合物中的氨基苯的缩合获得。

8. 发明授权

US06200948B1 Multifunctional textile auxiliary formulations 失效
标题翻译：多功能纺织辅料
公开(公告)号：US06200948B1
公开(公告)日：2001-03-13
申请号：US08908875
申请日：1997-08-08
申请人： Rainer Hans Traber , Albert Stehlin , Vladimir Arnold , Rolf Kuratli , Werner Schreiber
发明人： Rainer Hans Traber , Albert Stehlin , Vladimir Arnold , Rolf Kuratli , Werner Schreiber
IPC分类号： C11D183
CPC分类号： C11D3/2075 , C11D1/143 , C11D1/146 , C11D1/72 , C11D1/825 , C11D1/83 , C11D1/86 , C11D1/88 , C11D1/94 , C11D3/2034 , C11D3/2041 , C11D3/2044 , C11D3/2048 , C11D3/2058 , C11D3/2065 , C11D3/2068 , C11D3/3418 , C11D3/3765 , C11D3/3773 , C11D3/378 , C11D3/3788 , D06L1/12 , D06L1/14 , D06L4/12 , D06L4/614 , D06M11/38 , D06M13/144 , D06M13/148 , D06M13/152 , D06M13/165 , D06M13/17 , D06M13/184 , D06M13/188 , D06M13/192 , D06M13/203 , D06M13/207 , D06M13/256 , D06M13/278 , D06M13/288 , D06M13/447 , D06M15/263 , D06M15/53 , D06P1/613 , D06P1/65118 , D06P1/6533 , D06P1/667
摘要： The invention discloses multifunctional textile auxiliary formulations comprising (a) 10 to 60% by weight of one or more than one nonionic surfactant of formula (1), (b) 10 to 60% by weight of the reaction product of one or more than one nonionic surfactant of formula (2) and of an ethylenically unsaturated sulfonic or carboxylic acid or an anhydride thereof, (c) 4 to 20% by weight of a hydrotropic agent, (d) 0 to 20% by weight of a nonionic surfactant of formula (3), (e) 0 to 8% by weight of a magnesium salt of an organic carboxylic acid, (f) 0 to 30% by weight of a chelating agent or sequestrant, (g) 0 to 10% by weight of a diol or polyol, and (h) 0 to 60% of water, with the proviso that the textile auxiliary formulations must contain one of components (e) to (g). The novel textile auxiliary formulations are distinguished by their low foaming properties, their storage-stability, their peroxide-stabilizing properties, their good emulsifiability and their good rewettability. In addition, the formulations are readily biogradable.
摘要翻译：本发明公开了多功能纺织辅助制剂，其包含（a）10至60重量％的一种或多于一种式（1）的非离子表面活性剂，（b）10至60重量％的一种或多种式（2）的非离子表面活性剂和烯属不饱和磺酸或羧酸或其酸酐，（c）4〜20重量％的水溶助长剂，（d）0〜20重量％的式（3），（e）0〜8重量％的有机羧酸镁盐，（f）0〜30重量％的螯合剂或多价螯合剂，（g）0〜10重量％二醇或多元醇，和（h）0至60％的水，条件是织物辅助配方必须含有组分（e）至（g）中的一种。新型纺织品辅助剂的特征在于其低起泡性，它们的储存稳定性，其过氧化物稳定性，良好的乳化性和良好的润湿性。此外，制剂易于生物降解。

9. 发明申请

US20050083579A1 Head-mounted optical direct visualization system 有权
公开(公告)号：US20050083579A1
公开(公告)日：2005-04-21
申请号：US10750958
申请日：2004-01-05
申请人： Harald Volkenandt , Uwe Frey , Thomas Alt , Werner Schreiber
发明人： Harald Volkenandt , Uwe Frey , Thomas Alt , Werner Schreiber
IPC分类号： G02B27/02 , G02B27/00 , G02B27/01 , H04N5/64 , G02B27/14
CPC分类号： G02B27/0172 , G02B27/0176 , G02B2027/0132 , G02B2027/0136 , G02B2027/0178
摘要： A head-mounted optical direct visualization system has at least one optical deflecting device (120) with an optical end element (128) for deflecting a virtual image generated by an image source (230) onto the optical end element (128). The virtual image is emitted through the optical end element into the field of view in front of the eyes of the user. The optical deflecting device (120) is attached to the head of the user with the aid of a frame (130). The task of the invention is to configure such a conventional direct visualization system so as to be better adaptable to the requirements of the anatomical and optical features of the user and the application-specific viewing requirements. This task is solved with an adjusting device (140), which is fixed to the frame (130), for variably changing the position of at least the optical end element (128) essentially in a plane parallel to the field of view of the user.

10. 发明授权

US06719922B1 Mixtures of fluorescent whitening agents 失效
标题翻译：荧光增白剂的混合物
公开(公告)号：US06719922B1
公开(公告)日：2004-04-13
申请号：US10070631
申请日：2002-07-08
申请人： Dieter Reinehr , Hanspeter Sauter , Hans Kramer , Werner Schreiber
发明人： Dieter Reinehr , Hanspeter Sauter , Hans Kramer , Werner Schreiber
IPC分类号： D06L312
CPC分类号： C07C255/51 , C11D3/42 , D06L4/636 , D06L4/65 , D06L4/664 , Y10S8/922
摘要： The present invention relates to a mixture of fluorescent whitening agents comprising 20 to 70% by weight of a compound of formula (1), 30 to 80% of a compound of formula (2) and 0.5 to 5% of a compound of formula (3), compositions containing the mixture and the use of the compositions for whitening synthetic fibers, in particular polyester.
摘要翻译：本发明涉及包含20-70％（重量）式（1）化合物，30-80％式（2）化合物和0.5-5％式（III）化合物 3），含有该混合物的组合物和用于增白合成纤维，特别是聚酯的组合物的用途。

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